• Title/Summary/Keyword: hydration of cement

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An Experimental Study on the Mechanical Healing Properties of Self-Healing Mortar with Solid Capsules Using Crystal Growth Type Inorganic Materials (결정성장형 무기재료 활용 고상 캡슐을 혼합한 자기치유 모르타르의 역학적 치유 특성에 관한 실험적 연구)

  • Choi, Yun-Wang;Nam, Eun-Joon;Oh, Sung-Rok;Lee, Kwang-Myong
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.8 no.4
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    • pp.581-589
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    • 2020
  • In this paper, a solid capsule was prepared using a crystal growth type inorganic material capable of hydration reaction, the quality and mechanical healing properties of self-healing mortar with solid capsules were evaluated. Solid capsules were mixed 5% by mass of cement. Reloading test results of compressive load, it was found to improve about 20% on average for the natural healing effect of Plain, in the case of the elastic range, the healing rate was about 79% at the 7 days of healing age and 98% at the 28 days of healing age. Reload test results of flexural load, in the case of the elastic range, the healing rate was about 79% at the 7 days of healing age and 98% at the 28 days of healing age. Through these results, it is judged that the healing performance of solid capsules has also an effect on mechanical healing properties such as strength in addition to the durability properties obtained by the permeability test. Since the strength tends to decrease as the solid capsules are mixed, it is considered necessary to compensate.

Autogeneous Shrinkage Characteristics of Ultra High Performance Concrete (초고성능 콘크리트의 자기수축 특성)

  • Kim, Sung-Wook;Choi, Sung;Lee, Kwang-Myong;Park, Jung-Jun
    • Journal of the Korea Concrete Institute
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    • v.23 no.3
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    • pp.295-301
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    • 2011
  • Recently, the use of UHPC made of superplasticizers, silica fume, and steel fibers has been increasing worldwide. Although UHPC has a very high strength as well as an excellent durability performance due to its dense microstructures, earlyage cracks may occur due to the high heat of hydration and autogenous shrinkage caused by low W/B and high unit cement content. The early-age shrinkage cracking of UHPC can be controlled by using the shrinkage reducers and expansive admixtures having autogenous shrinkage compensation effect. In this paper, ultrasonic pulse velocity of UHPC containing shrinkage reducers and expansive agents was measured to predict its stiffness change. Also, the effect of shrinkage reducers and expansive agents on the autogenous shinkage of UHPC was investigated through the shrinkage test of UHPC specimens. Furthermore, the material coefficients of autogenous shrinkage prediction model were determined using the autogenous shrinkage values of UHPC with age. Consequently, the test results showed that, by adding shrinkage reducers and expansive agents, the stiffness of UHPC was rapidly developed at early-ages and the autogenous shrinkage was considerably reduced.

Quantitative Evaluation of Free CaO in Electric Arc Furnace Reduction Slag using the Ethylene Glycol Method (에틸렌 글리콜법을 이용한 전기로 환원슬래그의 Free CaO 정량 평가에 관한 연구)

  • Kwon, Seung-Jun;Lim, Hee-Seob;Lee, Han-Seung
    • Journal of the Korea Institute of Building Construction
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    • v.18 no.4
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    • pp.321-327
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    • 2018
  • Blast furnace slag has been actively used as a substitute for cement in the construction field with high value-added through resource recycling research. However, most of the slag cannot find a clear recycling purpose. This is because some slags contain unstable materials and are used for road-use asphalt and embankment, which are low value-added materials. Electric arc furnace reduction slag(ERS) has been reported to contain a large amount of unstable free CaO due to deoxidation and component adjustment. In this study, free CaO of ERS which is generated in Korean steelmakers is quantitatively evaluated by using ethylene glycol method. As a result of free CaO quantitative evaluation of ERS, it was confirmed that there is a big difference according to the location of each field. In addition, ERS generally existed in powder form as undifferentiated characteristics, but it was confirmed that free CaO content was different due to hydration product in aggregate form due to water treatment. In addition, free CaO is an amorphous material and its crystallization characteristics are different due to the influence of temperature when it is cooled. ERS requires a long-term aging period as it contains a lot of free CaO.

A Study on Construction Methods of Roller Compacted Concrete Pavement for Bike Roads (자전거도로용 롤러 전압 콘크리트 포장의 시공 방안 연구)

  • Lee, Chang-Ho;Kim, Young-Kyu;Kang, Jae-Gyu;Park, Cheol-Woo;Lee, Seung-Woo
    • International Journal of Highway Engineering
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    • v.13 no.2
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    • pp.103-114
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    • 2011
  • Usage of bicycle has been supported the universal reduction of energy consumption and $CO_2$. For the same purpose, new constructions for long length bike roads are planned in Korea. Recently, laboratory tests of physical properties and resistance against environmental loading about optimum mix design of roller compacted concrete, that have advantages of high structural performance by cement hydration and aggregate interlocking, simple construction procedure and low construction cost, are performed for the effective construction of new bike roads. However, properties of roller compacted concrete had different results between laboratory and field tests since it had different compaction method. Also, construction method of roller compacted concrete are not defined for the application of bike roads since it had different demand performance such as thin pavement thickness, low strength and etc with road pavements. Thus, in this experimental research was launched to evaluate the core properties, visual inspection, compaction ratio, water content, thickness reduction rate of roller compaction, skid resistance and roughness by experimental construction about variable mix proportion and compaction method based on laboratory test results. And construction method of roller compacted concrete pavement were suggested for the application of bike roads.

An Experimental Study on the Influence of High Quality Fly ash and Water-Binder Ratio on Properties of the Ternary System Concrete (3성분계 콘크리트의 특성에 미치는 고품질 플라이애쉬의 치환율 및 물-결합재비 영향에 관한 실험적 연구)

  • Lee, Seung-Min;Kim, Dong-Sool;Rho, Hyoung-Nam;Jung, Yong;Lee, Sang-Soo;Song, Ha-Young
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.04a
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    • pp.877-880
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    • 2008
  • Recently the press and institute recognized fly ash as it had excellent performance. Its research and applications are on the rise largely as a substitute for cement. On the contrary, it is in a situation that the regulation of high quality fly ash remains at a low level. Accordingly, this study was to establish 8000 class of fineness of fly ash and three levels of substitute like 15%, 3 0%, and 45% in order to analyze the replacement ratio and effect of water-binder ratio for fly ash that affected the properties of ternary system concrete. As a result of experiment by planning water-binder ratio for two levels like 40% and 50%, it increased the fluidity in a fresh state, and it decreased the air content. This study has found out the setting acceleration and reduction of heat of hydration. As for the strength property in a set state, this study has shown the tendency of being equal or higher in age 28 days.

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A Study on the Compaction and Permeability According to the Mixture Ratio of Pond Ash and Bentonite for Liner Material (매립지 차수재로써 매립회-벤토나이트 혼합비에 따른 다짐 및 투수특성에 관한 연구)

  • Lee, Jungsang;Lee, Jonghwi;Lee, Jinkyu;Chun, Byungsik
    • Journal of the Korean GEO-environmental Society
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    • v.13 no.1
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    • pp.31-36
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    • 2012
  • Recently, industrial by-products are exponentially growing because energy consumption is increasing due to rapid industrial development and improved living standards. The purpose of this study is to determine the proper mixing ratio to meet the liner conditions(must be less than $1{\times}10^{-7}$cm/sec), using pond ash and bentonite as liner. As the result of the compaction test, depending on the increase mixing ratio of bentonite, the maximum dry unit weight was decreased but the optimum moisture content was tended to be increased at the compaction curve. As the result of the permeability test, depending on the increase mixing ratio of bentonite, the coefficient of permeability showed tendency to be decreased in the form of index and the tendency was caused by the hydration reactions filling the void of the pond ash. When the mixing ratio of bentonite was approximately over 15%, it was satisfied with the land fill liner conditions. In other words, it is necessary to consider other mixtures containing the cement or another material in the economical aspect for application of the pond ash.

Properties and Prediction Model for Ultra High Performance Fiber Reinforced Concrete (UHPFRC): (I) Evaluation of Setting and Shrinkage Characteristics and Tensile Behavior (초고성능 섬유보강 콘크리트(UHPFRC)의 재료 특성 및 예측모델: (I) 응결 및 수축 특성과 인장거동 평가)

  • Yoo, Doo-Yeol;Park, Jung-Jun;Kim, Sung-Wook;Yoon, Young-Soo
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.32 no.5A
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    • pp.307-315
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    • 2012
  • Recently, ultra high performance fiber reinforced concrete (UHPFRC) having over 180 MPa compressive strength and 10 MPa tensile strength has been developed in Korea. However, UHPFRC represents different material properties with normal concrete (NC) and conventional high performance concrete (HPC) such as a high early age autogenous shrinkage and a rapid dry on the surface, because it has a low water-binder ratio and high fineness admixtures without coarse aggregate. In this study, therefore, to propose suitable experimental methods and regulations, and to evaluate mechanical properties at a very early age for UHPFRC, setting, shrinkage and tensile tests were performed. From the setting test results, paraffin oil was an appropriate material to prevent drying effect on the surface, because if paraffin oil is applied on the surface, it can efficiently prevent the drying effect and does not disturb or catalyze the hydration of cement. From the ring-test results, it was defined that the shrinkage stress is generated at the time when the graph tendency of temperature and strain of inner steel ring is changed. By comparing with setting test result, the shrinkage stress was firstly occurred as the penetration resistance of 1.5 MPa was obtained, and it was about 0.6 and 2.1 hour faster than those of initial and final sets. So, the starting time of autogenous shrinkage measurement (time-zero) of UHPFRC was determined when the penetration resistance of 1.5 MPa was obtained. Finally, the tensile strength and elastic modulus of UHPFRC were measured from near initial setting time by using a very early age tensile test apparatus, and the prediction models for tensile strength and elastic modulus were proposed.

Time Evolution of Material Parameters in Durability Design of Marin Concrete (해양콘크리트의 내구성 설계를 위한 재료 매개변수의 시간단계별 해석)

  • Yoon, In-Seok;Kim, Young-Geun
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.04a
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    • pp.1077-1080
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    • 2008
  • Material parameters such as surface chloride content, water permeability coefficient, chloride diffusivity and critical chloride content are a substantial key parameter for understanding the durability performance of concrete and its micro-structural densification. Over the past few decades, a considerable number of studies on the durability design for marine concrete structures have been carried out. However, the results are different to each other. In order to establish a consistent durability design system of concrete, it is a precondition to define material parameters, which affect deterioration of concrete due to chloride penetration. Such parameters are surface chloride content, chloride diffusivity, and critical chloride content. Usually these parameters are assumed as temporary constant values or obtained from the experimental results for short term. However, it is necessary to define these parameters reasonably, because these significantly influence the calculation of service life of concrete. In this paper, it is introduced to define material parameters of concrete for chloride diffusion, such as surface chloride content $[Cl]_s$, water permeability coefficient K, chloride diffusivity $D_{Cl}$, critical chloride content $[Cl]_{cr}$. These are expressed as time function considering hydration evolution of hardened cement paste. The definition of the material parameters is a prerequisite to simulate chloride penetration into concrete as time elapsed.

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Chloride Diffusion Coefficient Evaluation in 1 Year-Cured OPC Concrete under Loading Conditions and Cold Joint (하중조건과 콜드조인트를 고려한 1년 양생된 OPC 콘크리트의 염화물 확산계수 평가)

  • Oh, Kyeong-Seok;Kwon, Seung-Jun
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.21 no.5
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    • pp.21-29
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    • 2017
  • Cold joint caused by construction delay is vulnerable to shear stress and it allows more rapid chloride penetration and diffusion. In the paper, investigation of chloride diffusion coefficient is performed for 1-year cured concrete considering compressive and tensile loading level and cold joint. The results are compared with the previous results in 91-day cured concrete. In the 1-year cured concrete without loading, 10.7% and 10.5% of diffusion reduction are evaluated for those in 91-day cured concrete, respectively. The reduction ratios are almost similar however the result in cold joint concrete shows much higher values. The results in 1-year cured concrete under 30% and 60% of compressive loading show reduction of chloride diffusion by 10.9% and 5.8% compared with 91-day cured results, which is caused by steady hydration of cement particles, so called, time effect. In the case of tensile loading, the differences in results are not significant regardless of time effect and cold joint since micro cracks which is weak point of concrete is much dominant despite of long term curing.

Evaluation of the Properties of an Environment-Friendly De-icing Agent Based on Industrial By-Products (산업부산물을 활용한 친환경제설제의 특성평가)

  • Heo, Hyung-Seok;Lee, Byung-Jae
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.21 no.6
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    • pp.132-139
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    • 2017
  • A huge amount of de-icing agent is sprayed during winter to promote traffic safety in cold regions, and the quantity of de-icing agent sprayed has increased each year. The main ingredients in commonly used de-icing agents are chlorides, such as calcium chloride($CaCl_2$) and sodium chloride(NaCl). While calcium chloride is mostly used in Korea and sodium chloride is usually used in the U.S. and Japan, all de-icing agents include chloride ions. The chlorides included in sprayed calcium chloride-based de-icing agents have severe adverse effects, including the corrosion of reinforcing steels through salt damage by infiltrating into road structures, reduced structural performance of pavement or damage to bridge structures, and surface scaling, in combination with freezing damage in winter, as well as water pollution. In addition, the deterioration of paved concrete road surface that occurs after the use of calcium chloride-based de-icing agent accelerates the development of visual problems with traffic structures. Therefore, the present study was performed to prepare an environment-friendly liquid de-icing agent through a reaction between waste organic acids and calcium-based by-products, which are industrial by-products, and to analyze the properties of the de-icing agent in order to evaluate its applicability to road facilities.