• Title/Summary/Keyword: hydration of cement

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An experimental Study on the Strength Control of High Fluidity Concrete by Maturity (적산온도방식에 의한 고유동콘크리트의 강도관리에 관한 실험적 연구)

  • 김무한;남재현;김규용;길배수;한장현
    • Journal of the Korea Concrete Institute
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    • v.12 no.2
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    • pp.79-87
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    • 2000
  • The strength development of concrete is influenced by temperature and cement type which greatly affect hydration degree of cement. There is not pertinent concrete strength management methods for estimating the in-place strength of concrete. One such method is the maturity concept. The maturity concept is based on the fact that concrete gains strength with time as a result of the cement hydration and, thus the rate of hydration, as in any chemical reaction, depends primarily on the concrete temperature during hydration. Thus, the strength of concrete is function of its time-temperature history. This goals of the present study are to investigate a relationship between strength of high-fluidity concrete and maturity that is expressed as a function of an integral of the curing period and temperature, predict strength of concrete.

The Effect of ZnO on the Hydration Reaction and Physical Properties of Cement (Cement의 수화반응 물리특성에 미치는 ZnO의 영향)

  • 김홍기;추용식;이경희;송명신
    • Journal of the Korean Ceramic Society
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    • v.34 no.4
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    • pp.399-405
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    • 1997
  • With the increase of ZnO content, heat of hydration decreased. For specimens containing ZnO more than 0.6 wt.%, the compressive stength of cement cured for 28 days could not be measured because setting was not occurred. With the increase of ZnO content, Blaine specific surface area of cement was decreased and the residue of 45 ${\mu}{\textrm}{m}$ and 90 ${\mu}{\textrm}{m}$ was increased when cement was ground. That is, grindability became worse as ZnO increased in clinker. The difference of color as a function of ZnO content could not be observed, but in the excess of amount of ZnO added, color became more white and reddish yellow.

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A Fundamental Study on the Hydration and micro Structure of high Strength Concrete Used by high Calcium Sulfate Cement (고황산염 시멘트를 이용한 고강도 콘크리트의 수화거동과 미세구조에 관한 기초적 연구)

  • 박승범;임창덕
    • Proceedings of the Korea Concrete Institute Conference
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    • 1993.04a
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    • pp.99-105
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    • 1993
  • The purpose of this fundamental study is to investigate the mechanism of high strength concrete using the high calcium sulfate cement from a point of view in cement hydration and micro structure. As a results, it was found that the internal pores of concrete are decreased by using the high calcium sulfate cement, because the hydrates of Ettringite which is densified in structure is much formed in early ages at steam curing. In addition to the ettringite needs the 32 times of free water formed mixing water for hydration. This effect are not only decreased the water to cement ratio and also increase to comp, strength of concrete. It was conclude that these above the two facts are the main mechanism of high strength concrete using high calcium sulfate cement.

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A Hydration Model for Blended Concrete utilizing Secondary Cementitious Powders (혼화재를 사용한 콘크리트의 수화모델)

  • Noh Jea Myoung;Byun Keun Joo;Song Ha-Won
    • Proceedings of the Korea Concrete Institute Conference
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    • 2004.05a
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    • pp.140-143
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    • 2004
  • Heat of hydration of concrete under different curing temperatures can be characterized with knowledge of the thermal activity, the heat rate at the reference temperature, and the total heat of hydration of the mixture. The so-called multi-component hydration model incorporates the effect of following variables: cement chemical composition, cement fineness, secondary cementitious powders, mixture proportions, and concrete properties. However, the model does not consider the use of silica fume as a secondary cementitious powder. Therefore, the model that quantifies the heat of hydration due to the use of silica fume is needed. In this thesis, the effects of silica fume on heat of hydration are evaluated and the influence on the heat of hydration are also quantified to be included in the model, so that the analysis using modified multi-component hydration model for silica fume concrete provides more accurate results than normal concrete.

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Hydration Characteristics of Cement Containing Zeolite (제올라이트가 함유된 시멘트의 수화 특성)

  • Lee, Chang-Yong;Kim, Youn Cheol;Lee, Jong-Jib
    • Applied Chemistry for Engineering
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    • v.22 no.4
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    • pp.423-428
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    • 2011
  • Hydration characteristics of cement containing zeolite mined at Daepo in Gyeongbuk province were studied for use as a mineral admixture. The cement paste containing zeolite was characterized by the measurement of heat evolution, XRD, EDS, nitrogen adsorption and mercury intrusion porosimetry. The cement paste containing zeolite exhibited tendencies toward acceleration of paste setting and promotion of cement hydration with the increase of zeolite content. The flow of mortar containing zeolite strongly reduced with increase of zeolite content. Compressive strength of the mortar containing zeolite increased very rapidly at an early age in comparison with plain mortar. These results would be related to aluminum species escaped from zeolite particles during the alkali dealumination of zeolite by the hydration process of cement.

Recycling of Sludgewater containing Set-retarder (지연제 첨가에 의한 회수수의 재이용)

  • Song, Young-Jin;Daiki, Atarashi
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.11a
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    • pp.761-764
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    • 2008
  • Most of ready-mixed concrete plants have the problem of construction waste sludge, which pollutes environment and causes economic loss due to the discard and increasing the cost of concrete. Thus, a recycling of the cement sludge has been strongly desired as one of their solution. This research is to the study on the recycling of the cement sludge, especially the study on the hydration control by the sodium gluconate as a set-retarder. The set-retarder can delay the hydration of the cement included in the sludge water, so that the sludge water can be substituted with some of new cement without the property of the cement. And it invests the effect of the sodium gluconate to the hydration of the cement in suspension. The degree of hydration of cement may be controlled by adding the sodium gliconate. The hydration delay time is observed that depends on the concentration of residual sodium gloconate, not how long the cement has been hydrated before the addition of the sodium gluconate.

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Fundamental Evaluation and Hydration Heat Analysis of Low Heat Concrete with Premixed Cement (저발열형 Premixed Cement를 사용한 콘크리트의 기초물성 평가 및 수화열 해석에 관한 연구)

  • Yoon, Ji-Hyun;Jeon, Joong-Kyu;Jeon, Chan-Ki;Kim, Ki-Hyung
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.2 no.1
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    • pp.10-18
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    • 2014
  • This study carried out to evaluate the hydration heat analysis and fundamental characteristics such as air content, slump, compressive strength and dry shrinkage according to concrete with premixed cement, ternary concrete and OPC concrete for using concrete with premixed cement. The results of experiment are founded that concrete with premixed cement have sufficient performances such as workability, compressive strength and dry shrinkage. Also, the results of hydration heat analysis are founded that concrete with premixed cement have more performance than ternary concrete and OPC concrete at a point of view for the quality control such as thermal crack reducing and economic benefit. Therefore, it is desirable that concrete with premixed cement should be used to rise durability performance and convenience of maintenance.

Hydration Heat and Crack-Reducing Properties of Cement Mortar Added Fluosilicate Salt Based Hydration Heat Reducer (규불화염계 수화열 저감제가 첨가된 시멘트 모르타르의 수화열 변화 및 균열저감 특성)

  • Kim, Jin-Yong;Lee, Hyo-Song;Rhee, Young-Woo;Kim, Do-Su;Lee, Byoung-Ky;Khil, Bae-Su;Han, Seung-Gu
    • Journal of the Korean Ceramic Society
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    • v.42 no.3 s.274
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    • pp.198-204
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    • 2005
  • Fluosilicate salts based hydration heat reducer(SWP-HR), used in this study, is composed of fluosilicate salts, soluble silica, aromatic polymer condensate and nitrate salt based inorganic compound with latent heat property. Effects of SWP-HR addition on the hydration heat and anti-crack property of cement mortar were investigated. Adiabatic hydration temperature and drying shrinkage length of SWP-HR added cement mortar had a tendency to decrease compared to those of cement mortar without SWP-HR addition. Also, it was confirmed through crack pattern experiment of plate-form specimen for elucidating crack-reducing characteristic that anti-crack property of SWP-HR added cement mortar was improved.

Properties of Low-heat Cement and Concrete (저발열 시멘트 및 콘크리트의 특성)

  • Noh, Jae-Ho;Park, Yon-Dong;Song, Yong-Soon;Kim, Hoon;Kang, Suck-Hwa
    • Proceedings of the Korea Concrete Institute Conference
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    • 1996.10a
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    • pp.345-351
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    • 1996
  • The study on the properties of low-heat cement that hear of hydration is relatively lower than that of ordinary portland cement and concrete made of this low-hear cement has been performed to test the hear of hydration and compressive strength, chemical resistance of concrete using low-hear cement to compare with concrete using other several typers of cements.

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Microstructural properties of hardened cement paste blended with coal fly ash, sugar mill lime sludge and rice hull ash

  • Opiso, Einstine M.;Sato, Tsutomu;Otake, Tsubasa
    • Advances in concrete construction
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    • v.5 no.3
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    • pp.289-301
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    • 2017
  • The synergistic interactions of supplementary cementitious materials (SCMs) with ordinary portland cement (OPC) in multi-blended systems could enhance the mechanical and durability properties of concrete and increase the amount of cement that can be replaced. In this study, the characteristics of the hydration products as well as paste microstructure of blended cement containing 20% coal fly ash, 10% rice hull ash and 10% sugar mill lime sludge in quaternary blended system was investigated. Portlandite content, hydration products, compressive strength, pore size distribution and microstructural architecture of hydrated blended cement pastes were examined. The quaternary blended cement paste showed lower compressive strength, reduced amount of Portlandite phases, and higher porosity compared to plain hardened cement paste. The interaction of SCMs with OPC influenced the hydration products, resulting to the formation of ettringite and monocarboaluminate phases. The blended cement paste also showed extensive calcium silicate hydrates and calcium aluminate silicate hydrates but unrefined compared to plain cement paste. In overall, the expected synergistic reaction was significantly hindered due to the low quality of supplementary cementitious materials used. Hence, pre-treatments of SCMs must be considered to enhance their reactivity as good quality SCMs can become limited in the future.