• Journal of the Korean Recycled Construction Resources Institute
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• v.10 no.1
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• pp.15-22
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• 2022

In this study, the hydration reaction and strength characteristic of cement mortar with spent coffee ground(SCG) was investigated. As a result of the study, it was found that as the firing temperature of the SCG increased, the mass loss due to the combustion of organic matter increased, but the density increased. In addition, when the SCG were mixed, SCG interfered with the hydration reaction and the compressive strength was significantly lowered. On the other hand, the coffee grounds ash(SCG_Ash) calcined at 800 ℃ showed a hydration reaction and a compressive strength equivalent to or higher than that of OPC mortar.

• Journal of the Korea Concrete Institute
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• v.16 no.3 s.81
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• pp.369-374
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• 2004

Calcium sulfoalumiante(CSA) was prepared for using natural calcite($CaCO_3$) and industrial by-products and wastes, such as $Al(OH)_3,\;CaSO_4{\cdot}2H_2O$. The mixture of raw materials was fired at 20, 400, 600, $1200^{\circ}C$ for 1h and cooled rapidly in air. The cement replaced by 10 wt% $C_4A_3S$ expansive additives was investigated by the measurement of the hydration products and compressive strength, setting time, expansion at wet curing condition. $C_4A_3S$ was found in x-ray diffraction pattern over the temperature $1200^{\circ}C$. The setting time or the cement pastes added clinkers fired at different temperature was shorter than ordinary portland cement. The compressive strength was higher than the ordinary portland cement about 20~30%. The mainly hydration products were ettringite, and $Ca(OH)_2$. The expansion due to the formation of ettringite during hydration decreased the drying shrinkage of hardened cement rather than the ordinary portland cement.

• Journal of the Korea institute for structural maintenance and inspection
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• v.25 no.1
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• pp.25-32
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• 2021

For developing the durable eco-concrete, water-repellent and hydrophobic emulsion were prepared by stirring and mixing polymethyl hydrosiloxane and polyvinyl alcohol. After adding the PMHS emulsion cement paste, the hydration reaction characteristics and the change in chemical composition were analyzed through BSE and EDS analysis, and the micropores were evaluated by MIP test. Cement mixed with PMHS emulsion was analyzed to increase the hydration reactivity and to decrease the capillary porosity, but it was found that the capillary porosity varies depending on the degree of dispersion of the emulsion in the cement paste. In the case of the emulsion containing metakaolin, there was little difference in hydration degree and porosity from the case of using only the PMHS emulsion. However, when the cement surface was coated with PMHS emulsion, the contact angle was found to increase significantly compared to OPC, and it was analyzed that especially when PVA fiber was used together, it changed to a hypohydrophobic surface.

• Journal of the Korea Concrete Institute
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• v.27 no.2
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• pp.127-136
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• 2015

To evaluate the effects of limestone powder and silica fume on the properties of high-strength high-volume ground granulated blast-furnace slag (GGBFS) blended cement concrete, this study investigated the rheology, strength development, hydration and pozzolanic reaction characteristics, porosity and pore size distribution of high-strength mortars with the water-to-binder ratio of 20, 50 to 80% GGBFS, up to 20% limestone powder, and up to 10% silica fume. According to test results, compared with the Portland cement mixture, the high-volume GGBFS mixture had much higher flow due to the low surface friction of GGBFS particles and higher strength in the early age due to the accelerated cement hydration by increase of free water; however, because of too low water-to-binder ratio and cement content, and lack of calcium hydroxide content, the pozzolanic reactio cannot be activated and the long-term strength development was limited. Limestone powder did not affect the flowability, and also accelerate the early cement hydration. However, because its effect on the acceleration of cement hydration is not greater than that of GGBFS, and it does not have hydraulic reactivity unlikely to GGBFS, compressive strength was reduced proportional to the replacement ratio of limestone powder. Also, silica fume and very fine GGBFS lowered flow and strength by absorbing more free water required for cement hydration. Capillary porosities of GGBFS blended mortars were smaller than that of OPC mortar, but the effect of limestone powder on porosity was not noticeable, and silica fume increased porosity due to low degree of hydration. Nevertheless, it is confirmed that the addition of GGBFS and silica fume increases fine pores.

• Proceedings of the Korea Concrete Institute Conference
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• 2006.05b
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• pp.425-428
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• 2006

The bigger of concrete strctures by a construct technique improvement, and the increase of the cement quantity which is caused by with use of the high-strength concrete for the load-carrying-capacity and a durability cause temperature cracks by a heat of hydration. The temperature crack due to the heat of hydration classified a nonstructural crack. but it has a bad effect on durability of concrete structures. especially, in case of a subway concrete box structure, when a water-proof facilities is beaked on an outer-wall, the water leakage occurs through a penetration crack generated from a wall of the concrete structure too. This paper, for the subway concrete box strucuture, the use of blended cement, the temperature of air and concrete, control joint, was considered and analysed by a three dimensional finite element method.

• Proceedings of the Korea Concrete Institute Conference
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• 2006.11a
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• pp.705-708
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• 2006

The bigger of concrete structures by a construct technique improvement, and the increase of the cement quantity which is caused by with use of the high-strength concrete for the load-carrying-capacity and a durability cause temperature cracks by a heat of hydration. The temperature crack due to the heat of hydration classified a nonstructural crack. but it has a bad effect on durability of concrete structures. especially, in case of a subway concrete box structure, when a water-proof facilities is beaked on an outer-wall, the water leakage occurs through a penetration crack generated from a wall of the concrete structure too. This paper, for the subway concrete box structure, which is located in chloride attack region, the use of blended cement, the temperature of air and concrete, was considered and analysed by a three dimensional finite element method.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2012.05a
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• pp.69-70
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• 2012

This paper is to investigate the engineering properties of the concrete incorporating different types of low heat generating binders subjected to various W/B. As expected, it is found that increase of W/B resulted in a decrease of hydration heat and compressive strength. It also showed that the application of high early strength and low carbon type mixture had favorable strength development at early and later age, while hydration heat showed rather higher than existing low heat mixture.

• Proceedings of the Korea Concrete Institute Conference
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• 2010.05a
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• pp.465-466
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• 2010

In this paper, an integrated system is proposed which can evaluate both the early-age properties and durability performance of concrete structures. This integrated system starts with a hydration model which considers both Portland cement hydration and chemical reactions of supplementary cementing materials (SCM). Based on the degree of hydration of cement and mineral admixtures, the amount of reaction products, the early age heat evolution, chemically bound water, porosity, the early age short-term mechanical behaviors, shrinkage and early-age creep are evaluated as a function of curing age and curing conditions. Furthermore, the durability aspect, such as carbonation of blended concrete and chloride attack, are evaluated considering both the material properties and surrounding environments. The prediction results are verified through experimental results.

• Journal of the Korean Ceramic Society
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• v.35 no.11
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• pp.1227-1232
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• 1998

In order to prohibit the delay of early stage hydration activator Na2SO4 was added to Fly Ash blended ce-ment and its effects were investigated. Various measurements such as Compressive strength Heat of hy-dration Pore size distribution Hydration products Microstructure were evaluated and the results show that specimens of Fly Ash(50wt%) with 5% Na2SO4 dramatically improved the compressive strength because pozzolanic reaction of Fly Ash and the formation of ettringite make th microstructure denser than OPC and flyash cement paste.

• Proceedings of the Korea Concrete Institute Conference
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• 1997.04a
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• pp.649-656
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• 1997

The properties of super-flowing concrete with low heat cement were experimentally investigated and compared with ordinary 25-240-15 concrete with type Vcement. The cement content of super-flowing concrete with the low heat cement was 400 kg/$\textrm{m}^3$. However the hydration heat of super-flowing concrete is relatively lower than that ordinary concrete with type V cement. Also the ability to resist chloride ion penetration of super-flowing concrete with low heat cement is 5 times better than that of the ordinary concrete.