• International Journal of Concrete Structures and Materials
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• 제8권2호
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• pp.173-182
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• 2014

An experimental investigation was carried out to evaluate the mechanical properties of concrete mixtures in which coarse aggregate was partially (30, 50 or 70 %) replaced with pre-washed municipal solid waste incineration (MSWI) bottom ash. Results indicated that bottom ash reduced the compressive strength, elastic modulus, and levels of heavy metals in leachate when used as a replacement for gravel, and that the maximum amount of MSWI bottom ash in concrete should not exceed 50 %. To analyze the effect mechanism of bottom ash in concrete, the degree of hydration and the following pozzolanic reaction characterized by the pozzolanic activity index, and the porosity distribution in cement mortar. The study indicates that improved properties of concrete are not solely later strength gain and reduced levels of heavy metals in leachate but also the progression of pozzolanic reactions, where a dense structure contains a higher proportion of fine pores that are related to durability.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2002년도 봄 학술발표회 논문집
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• pp.731-736
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• 2002

The degradation of reinforced concrete (RC) structures due to physical and chemical attacks has been a major issue in construction engineering. Deterioration of RC structures due to chloride attack followed by reinforcement corrosion is one of the serious problems. The objective of this study is to develop a form of mathematical model of chloride ingress into concrete. In order to overcome some limits of the previous approaches, a mathematical model of chloride ingress into concrete consisting of chloride solution intrusion through the capillary pore and chloride ion diffusion through the pore water was proposed. Moreover, the variability of diffusivity of chloride ion due to degree of hydration of concrete, relative humidity in pore, exposure condition, and variation of chloride binding was considered in the chloride ingress model.

• 콘크리트학회논문집
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• 제12권3호
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• pp.95-102
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• 2000

Crack control due to temperature is an important factor for the mass concrete structure. Pre-cooling is the effective system to reduce the highest temperature of mass concrete. In this study, for pre-cooling, cooling water, cooling water with ics flake are used. The results of a series of experimental studies indicate that the changes in properties of fresh concrete after cooling are of low degree, and compressive strength of concrete is changed very little by cooling. The adiabatic temperature rise is also measured with pre-cooling concrete specimens. It is shown that hydration heat characteristics of cement and concrete were largely affected by pre-cooling.

• 콘크리트학회논문집
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• 제16권1호
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• pp.125-129
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• 2004

Hydrating concrete pavement is typically subjected to temperature-induced stresses that drive cracking mechanisms at early concrete ages. Undesired cracking plays a key role in the long-term performance of concrete pavement systems. The loss of support beneath the concrete pavement due to curling caused by temperature changes in the pavement may induce several significant distresses such as punch out pumping, and erosion. The effect of temperature on these distress mechanisms is both significant and intricate. Because thermal conductivity dominates temperature flow in hydrating concrete over time, this material property is back-calculated by transforming governing equation of heat transfer and test data measured in laboratory. Theoretically, the back- calculated thermal conductivity simulates the heat movements in concrete very accurately. Therefore, the back- calculated thermal conductivity can be used to calibrate concrete temperature predicted by models.

• 한국세라믹학회지
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• 제27권7호
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• pp.861-868
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• 1990

Investigation for the preparation of high strength hardened cement paste using ordinary portland cement, hydroxypropyl methyl cellulose(HPMC) with SiC powder was carried out. The cement paste was mixed with 0.1 of water cement ratio by twin roll mill and cured 60 days in humidity chamber. The hydration degree of cement paste cured with W/C=0.1 in 60 days was about 30% and most pores in the paste were found to be existed as gel pores of diameter less than 0.01㎛. The maximum flexural strength of hardened cement paste was about 960kg/㎠. When the SiC powder was added to the paste, the flexural strength was 1000∼1100kg/㎠ and the Young's modulus was 8∼9×105kg/㎠.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 1997년도 가을 학술발표회 논문집
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• pp.539-545
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• 1997

Since the length of massive wall-structure is generally longer and larger than its thickness and a lift height of concrete of placement, cracks induced by hydration heat are governed by outer structural restriction rather than inner one. However, the degree of restriction control is expected to be affected by the sizes of wall thickness, length and a lift height. Thus, this analytical study aims at the development of relationship among those to minimize thermal cracks. In addition, the effect of types of cement on the thermal heats and stresses is evaluated for anti-sulphate and 2blended Portland cements concrete. It was found from analytical study that a lift height of concrete placement is the most important factor controlling thermal cracks, and the increase of lift heights is not always detrimental to structural safety.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2003년도 봄 학술발표회 논문집
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• pp.763-768
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• 2003

This study is to specify the properties of solidification/stabilization of heavy metals in connection with looking over the hydration features of non-sintering cement using industrial by-products. In this study, we added Cr and Pb to non-sintering cement(NSC), ordinary portland cement (OPC), and Blast-furnace slag cement(BSC) to specify the solidification process. Heavy metal leaching test was carried out to evaluate solidification degree of various cement. Follow result, marking no higher than 0.7% of un-solidified ratio of BSC was the most predominant result when we mixed the materials with Cr. 5.8% for NSCI and 6.2% for NSC2. On the contrary, in case of adding Pb, NSCl and NSC2 made better solidification results than those of OPC(below 0.2%) and BSC(below 0.05%), marking nearly 0%.

• Computers and Concrete
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• 제21권4호
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• pp.419-429
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• 2018

Climate changes, such as increasing of $CO_2$ concentration and global warming, will impact on the carbonation service life of concrete structures. Moreover, slag blended concrete has a lower carbonation resistance than control concrete. This study presents a probabilistic numerical procedure for evaluating the impact of climate change on carbonation service life of slag blended concrete. This numerical procedure considers both corrosion initiation period and corrosion propagation period. First, in corrosion initiation period, by using an integrated hydration-carbonation model, the amount of carbonatable substances, porosity, and carbonation depth are calculated. The probability of corrosion initiation is determined through Monte Carlo method. Second, in corrosion propagation period, a probabilistic model is proposed to calculate the critical corrosion degree at surface cracking, the probability of surface cracking, and service life. Third, based on the service life in corrosion initiation period and corrosion propagation period, the whole service life is calculated. The analysis shows that for concrete structures with 50 years service life, after considering climate changes, the service life reduces about 7%.

• 대한화학회지
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• 제36권2호
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• pp.329-334
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• 1992

단백질 수용액 중의 초음파흡수 mechanism을 규명하기 위하여 pH 7의 소혈청 albumin(BSA)수용액의 초음파흡수 측정을 주파수 100 kHz에서 1600 MHz에 걸쳐 행하였다. 측정방법은 plano-concave 공명법(0.1${\sim}$10 MHz)과 고분해능 Bragg 반사법(120${\sim}$1600 MHz)을 사용하였다. pH7에서의 초음파흡수스펙트럼은 Davidson-Cole 분포식의 거울상인 분포함수를 사용한 완화곡선과 일치하였다. 이 완화현상을 BSA 분자의 수화평행에 의한 것으로 해석하였다.

• Bulletin of the Korean Chemical Society
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• 제5권3호
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• pp.126-129
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• 1984

The reaction of aryl halides with phenoxides and alkoxides were investigated under phase transfer catalytic conditions. 2,4-Dinitro- and 4-nitrohalobenzenes reacted readily with phenoxides in NaOH(aq)-benzene in the presence of Bu4N+Br, affording the products quantitatively. Although the aryl halides did not react with alkoxides under the same condition, the reactions were completed within 2 hours at room temperature when conducted under solid-liquid phase transfenr catalytic condition. The reactivity of aryl halides was in the order, Ar = 2,4-dinitrophenyl > 4-nitrophenyl, and X = F > Cl, consistent with the SNAr mechanism. The reactivity of oxyanions increased with the change of reaction condition from liquid-liquid to solid-liquid phase transfer catalysis. The results were explained with the concentration and the degree of hydration of the anion in benzene.