• Title/Summary/Keyword: hybrid organic materials

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Advanced Treatment of Swine Wastewater using Hybrid-process (복합형 공정을 이용한 양돈폐수의 고도처리)

  • Kim, Choong-Gon;Kang, Seon-Hong;Shin, Hyun-Gon
    • Journal of the Korea Organic Resources Recycling Association
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    • v.12 no.3
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    • pp.126-133
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    • 2004
  • This study is performed to examine the removal efficiency of organic materials,$NH_4-N$ and P in Swine-Wastewater Treatment using Hybrid-process. It named SBR process, Hybrid-process as RunI(SBR), and Run II(Struvite Tank-SBR), and compared the removal efficiency of each Run. The removal efficiency of the organic materials in each Run is like this; In Run I, TS, VS and COD was 43%, 39%, and 70%, respectively. And in Run II, TS VS, and COD was 52%, 52%, and 82%, respectively. It shows that the removal efficiency of Run II using Strutive Tank is higher. And as for the removal efficiency of $NH_4-N$ and T-P in each Run, Run II using Strutive Tank was 90% and 57%, higher than 56% and 49% of RunI. Especially for $NH_4-N$, Run II showed much higher efficiency, and this proved that Strutive Tank was very efficient process of all for the removal of N and P. As a result of this study, Hybrid-process that combines Strutive Tank and SBR is proved to be a very good process in Swine Wastewater Treatment.

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Revolutionizing Energy Storage: Exploring Processing Approaches and Electrochemical Performance of Metal-Organic Frameworks (MOFs) and Their Hybrids

  • Wajahat Khalid;Muhammad Ramzan Abdul Karim;Mohsin Ali Marwat
    • Journal of Electrochemical Science and Technology
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    • v.15 no.1
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    • pp.14-31
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    • 2024
  • The text highlights the growing need for eco-friendly energy storage and the potential of metal-organic frameworks (MOFs) to address this demand. Despite their promise, challenges in MOF-based energy storage include stability, reproducible synthesis, cost-effectiveness, and scalability. Recent progress in supercapacitor materials, particularly over the last decade, has aimed to overcome these challenges. The review focuses on the morphological characteristics and synthesis methods of MOFs used in supercapacitors to achieve improved electrochemical performance. Various types of MOFs, including monometallic, binary, and tri-metallic compositions, as well as derivatives like hybrid nanostructures, sulfides, phosphides, and carbon composites, are explored for their energy storage potential. The review emphasizes the quest for superior electrochemical performance and stability with MOF-based materials. By analyzing recent research, the review underscores the potential of MOF-based supercapacitors to meet the increasing demands for high power and energy density solutions in the field of energy storage.

Electrochemical Behavior Depending on Designed-Anode and Cathodes of Hybrid Supercapacitors (하이브리드 슈퍼커패시터의 음극 및 양극 설계에 따른 전기화학적 거동)

  • Shin, Seung-Il;Lee, Byung-Gwan;Ha, Min-Woo;An, Geon-Hyoung
    • Korean Journal of Materials Research
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    • v.29 no.12
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    • pp.774-780
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    • 2019
  • The performance of Li-ion hybrid supercapacitors (asymmetric-type) depends on many factors such as the capacity ratio, material properties, cell designs and operating conditions. Among these, in consideration of balanced electrochemical reactions, the capacity ratio of the negative (anode) to positive (cathode) electrode is one of the most important factors to design the Li-ion hybrid supercapacitors for high energy storing performance. We assemble Li-ion hybrid supercapacitors using activated carbon (AC) as anode material, lithium manganese oxide as cathode material, and organic electrolyte (1 mol L-1 LiPF6 in acetonitrile). At this point, the thickness of the anode electrode is controlled at 160, 200, and 240 ㎛. Also, thickness of cathode electrode is fixed at 60 ㎛. Then, the effect of negative and positive electrode ratio on the electrochemical performance of AC/LiMn2O4 Li-ion hybrid supercapacitors is investigated, especially in the terms of capacity and cyclability at high current density. In this study, we demonstrate the relationship of capacity ratio between anode and cathode electrode, and the excellent electrochemical performance of AC/LiMn2O4 Li-ion hybrid supercapacitors. The remarkable capability of these materials proves that manipulation of the capacity ratio is a promising technology for high-performance Li-ion hybrid supercapacitors.

Porous Organic-inorganic Hybrids for Removal of Amines

  • Cho, Sung-Youl;Kim, Na-Ri;Cao, Guozhong;Kim, Joong-Gon;Chung, Chan-Moon
    • Bulletin of the Korean Chemical Society
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    • v.27 no.3
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    • pp.399-402
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    • 2006
  • Porous organic-inorganic hybrids have been prepared from tetraethylorthosilicate (TEOS) and organosilane precursors by sol-gel method. Two organosilanes, 3-(2,4-dinitrophenylamino)propyltriethoxysilane (DNPTES) and N-[[(2-nitrophenyl)methoxy]carbonyl]-3-triethoxysilylpropylamine (NPTES) were used to incorporate electron-accepting (di)nitrophenyl groups into the hybrids. The hybrids were characterized by FT-IR spectroscopy and elemental analysis, and their pore characteristics were studied by nitrogen sorption porosimetry. Surface area of the hybrids ranged from 563 to 770 $m^2$/g, pore volume, 0.23-0.30 $cm^3$/g, and porosity, 35-41%. It was demonstrated by UV-vis spectroscopy that aniline, ethylenediamine, and 1-aminonaphthalene could be removed from their hexane solutions in the presence of the hybrid powders. The removal of amines is attributable to donor-acceptor interaction between the electron-donating amines and electron-accepting (di)nitrophenyl moiety.

Corrosion Resistance Characteristics of Cr-free Coating Solution for Degraded STS316L (열화한 STS316L에 대한 Cr-free 코팅액의 내식특성)

  • Lee, So-Young;Kim, Young-Soo;Jeong, Hee-Rock;Ahn, Seok-hwan;Nam, Ki-Woo
    • Journal of Ocean Engineering and Technology
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    • v.29 no.6
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    • pp.475-480
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    • 2015
  • In this study, we developed a Cr-free organic/inorganic hybrid solution and investigated its coating properties on degraded STS316L. Both the OIBD-1 solution and OIBD-2 solution had excellent corrosion resistance and adhesion ability. However, the solution had some problems in a boiling water environment. In addition, the flexibility was excellent, and the scratch resistance was relatively good.

Effects of Organic Materials on Changes in Soil Nutrient Concentrations and Nutrient Uptake Efficiency in Sorghum-Sudangrass Hybrid (Sorghum bicolor (L.) Moench) (유기자재 처리가 토양의 양분동태 변화와 수수$^*$수단그라스의 양분이용 효율에 미치는 영향)

  • Lee, Youn;Choi, Hyun-Sug;Lee, Sang-Min;Jung, Jung-Ah;Kuk, Yong-In
    • Journal of Bio-Environment Control
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    • v.21 no.2
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    • pp.108-113
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    • 2012
  • This study was conducted to evaluate soil nutrient concentrations and fertilizer recovery of sorghum- sudangrass hybrid (Sorghum bicolor (L.) Moench) as affected by organic nutrient sources. The treatments included livestock compost, alfalfa hay, oilcake, and chemical fertilizer. Nutrient applications were made at the rates equivalent to approximately 210 kg N per hectare. The oilcake and alfalfa materials had the lowest C : N ratio, but the livestock compost had the highest C:N ratio such as 33.7 : 1. The livestock compost resulted in the highest input to ground surface, which increased nutrient concentrations in soil. The oilcake and alfalfa materials with low C : N ratios increased N-mineralization rate in soil compared to livestock. The N uptake efficiency in plants treated by alfalfa or oilcake was approximately 60% of those treated with chemical fertilizer; but those with livestock compost had N uptake efficiency lower than 20%. The $P_2O_5$ uptake efficiency was the highest in the plants treated with the alfalfa hay, but the lowest in those with livestock compost. Recommendation of organic material selection should consider C:N ratio of the raw materials based on the individual crop requirement.

Preparation of Hydrophobic Coating Layers Using Organic-Inorganic Hybrid Compounds Through Particle-to-Binder Process (유-무기 하이브리드 화합물과 Particle-Binder 공정을 이용한 소수성 코팅막 제조)

  • Hwang, Seung-Hee;Kim, Hyo-Won;Kim, Juyoung
    • Journal of Adhesion and Interface
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    • v.21 no.4
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    • pp.143-155
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    • 2020
  • Hydrophobic Organic-Inorganic (O-I) hybrid materials prepared by sol-gel process have been widely used at functional coating fields such as coatings for anti-corrosion, anti-icing, self-cleaning, anti-reflection. The key point for fabricating hydrophobic surface is to optimize the surface energy and roughness of the coating films. There are typical processes to control the surface energy and roughness which are 'In situ fabricating', 'Pre-fluorinating/Post-roughening', 'Pre-roughening/ Post-fluorinating'. In this study, particle-binder process was used for in-situ fabrication of hydrophobic coating films. Various O-I hybrid compounds prepared using several kinds of alkoxysilane compounds were used as a binder for silica nanoparticles at particle-binder process. To study effect of fluorine content and weight ratio of particle : binder on the hydrophobicity and surface morphology, Hydrophobic coating films were prepared onto glass substrate at various content of fluorine content of O-I hybrid binder and weight ratio of particle : binder. The coating films prepared using O-I hybrid binder (GPTi-HF10) having 10 wt% of fluorine content showed the highes water contact angle (107.52±1.6°). The coating films prepared at 1:3 weight ratio of GPTi-HF10 : silica nanoparticle exhibited the highest water contact angle (130.84±1.99°).