• Bulletin of the Korean Chemical Society
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• v.14 no.2
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• pp.183-187
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• 1993

Aryl carbenic anion radicals have been generated from the corresponding alkoxy-aryl diazo compounds by unimolecular decomposition reaction in various electrolyte/solvent systems. The electrochemical reductions of alkoxy-aryl diazo compounds in the electrolyte/solvent system are shown to initially be a one-electron process which affords the corresponding anion radicals. The unimolecular loss of nitrogen is favored at the propagation step and accelerated by the oxygen and carbon atoms of alkoxy group adjacent to the diazo function. The structure of the carbene anion radical in the termination is considered to be a resonance hybrid.

• International journal of advanced smart convergence
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• v.12 no.1
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• pp.199-207
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• 2023

Trend Impact Analysis is a prominent hybrid method has been used in future studies with a modified surprise- free forecast. It considers experts' perceptions about how future events may change the surprise-free forecast. It is an advanced forecasting tool used in futures studies for identifying, understanding and analyzing the consequences of unprecedented events on future trends. In this paper, we propose an advanced mechanism to generate more justifiable estimates to the probability of occurrence of an unprecedented event as a function of time with different degrees of severity using adaptive neuro-fuzzy inference system (ANFIS). The key idea of the paper is to enhance the generic process of reasoning with fuzzy logic and neural network by adding the additional step of attributes simulation, as unprecedented events do not occur all of a sudden but rather their occurrence is affected by change in the values of a set of attributes. An ANFIS approach is used to identify the occurrence and severity of an event, depending on the values of its trigger attributes.

• Journal of Information Processing Systems
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• v.18 no.6
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• pp.794-802
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• 2022

The recovery of reasonable depth information from different scenes is a popular topic in the field of computer vision. For generating depth maps with better details, we present an efficacious monocular depth prediction framework with coordinate attention and feature fusion. Specifically, the proposed framework contains attention, multi-scale and feature fusion modules. The attention module improves features based on coordinate attention to enhance the predicted effect, whereas the multi-scale module integrates useful low- and high-level contextual features with higher resolution. Moreover, we developed a feature fusion module to combine the heterogeneous features to generate high-quality depth outputs. We also designed a hybrid loss function that measures prediction errors from the perspective of depth and scale-invariant gradients, which contribute to preserving rich details. We conducted the experiments on public RGBD datasets, and the evaluation results show that the proposed scheme can considerably enhance the accuracy of depth prediction, achieving 0.051 for log10 and 0.992 for δ<1.25³ on the NYUv2 dataset.

• The Journal of Korean Institute of Communications and Information Sciences
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• v.34 no.6B
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• pp.595-604
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• 2009

The HCCA reserves the channel resources based on the mean data rate in IEEE 802.11e. It may cause either the waste of channel resource or the increase of transmission delay at MAC layer if the frame size is rapidly varied when a compressed mode video codec such as MPEG video is used. To solve these problems, it is developed that the packet scheduler allocates the wireless resource adaptation by according to the packet size. However, it is difficult to perform the admission control because of the difficulty with calculating the available resources. In this paper, we propose a CAC mechanism to solve the problem that may not satisfy the QoS by increasing traffic load in case of using EDCA. Especially, the proposed CAC mechanism calculates the EB of TSs using the traffic information transmitted by the application layer and the number of average transmission according to the wireless channel environment, and then determines the admission of the TS based on the EB. According to the simulation results of the proposed CAC mechanism, it admitted the TSs under the loads which are satisfied within the delay bound. Therefore, the proposed mechanism guarantees QoS of streaming services effectively.

• Proceedings of the Korean Vacuum Society Conference
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• 2013.02a
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• pp.311-311
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• 2013

The resistance switching memory devices have several advantages to take breakthrough for the limitation of operation speed, retention, and device scale. Especially, the metal-oxide materials such as ZnO are able to fabricate on the flexible and visible transparent plastic substrate. Also, the quantum dots (QDs) embedded in dielectric layer could be improve the ratio between the low and the high resistance becauseof their Coulomb blockade, carrier trap and induced filament path formation. In this study, we irradiated 0.2-MeV-electron beam on the ZnO/QDs/ZnO structure to control the defect and oxygen vacancy of ZnO layer. The metal-oxide QDs embedded in ZnO layer on Pt/glass substrate were fabricated for a memory device and evaluated electrical properties after 0.2-MeV-electron beam irradiations. To formation bottom electrode, the Pt layer (200 nm) was deposited on the glass substrate by direct current sputter. The ZnO layer (100 nm) was deposited by ultra-high vacuum radio frequency sputter at base pressure $1{\times}10^{-10}$ Torr. And then, the metal-oxide QDs on the ZnO layer were created by thermal annealing. Finally, the ZnO layer (100 nm) also was deposited by ultra-high vacuum sputter. Before the formation top electrode, 0.2 MeV liner accelerated electron beams with flux of $1{\times}10^{13}$ and $10^{14}$ electrons/$cm^2$ were irradiated. We will discuss the electrical properties and the physical relationships among the irradiation condition, the dislocation density and mechanism of resistive switching in the hybrid memory device.

• Journal of Advanced Navigation Technology
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• v.19 no.3
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• pp.250-256
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• 2015

Digital load is increasing suddenly for various reasons, such as easy control and management. Accordingly, a consumption pattern of load is becoming DC. However, the power supply is supplied by AC power. The load power supply substantially needs DC power. AC power has to be converted to DC power. Renewable energy sources like solar, wind and fuel cells are DC power generation, but the transfer needs to through by AC power, thus DC power has to be converted to AC power. Resultantly, a multi-stage conversion loss is constantly increasing. The power distribution system of DC-based is required for effective use of these energy sources. This requires a DC load, as well as is necessary to develop DC breaker. This study is expect for system and equipment for reliable DC power distribution through the study of the arc extinguish technology for direct current a hybrid arc extinguishing technology with permanent magnets technology.

• The Plant Pathology Journal
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• v.31 no.2
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• pp.108-114
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• 2015

Curvularia lunata is an important maize foliar fungal pathogen that distributes widely in maize growing area in China, and several key pathogenic factors have been isolated. An yeast two-hybrid (Y2H) library is a very useful platform to further unravel novel pathogenic factors in C. lunata. To construct a high-quality full length-expression cDNA library from the C. lunata for application to pathogenesis-related protein-protein interaction screening, total RNA was extracted. The SMART (Switching Mechanism At 5' end of the RNA Transcript) technique was used for cDNA synthesis. Double-stranded cDNA was ligated into the pGADT7-Rec vector with Herring Testes Carrier DNA using homologous recombination method. The ligation mixture was transformed into competent yeast AH109 cells to construct the primary cDNA library. Eventually, a high qualitative library was successfully established according to an evaluation on quality. The transformation efficiency was about $6.39{\times}10^5$ transformants/$3{\mu}g$ pGADT7-Rec. The titer of the primary cDNA library was $2.5{\times}10^8cfu/mL$. The numbers for the cDNA library was $2.46{\times}10^5$. Randomly picked clones show that the recombination rate was 88.24%. Gel electrophoresis results indicated that the fragments ranged from 0.4 kb to 3.0 kb. Melanin synthesis protein Brn1 (1,3,8-hydroxynaphthalene reductase) was used as a "bait" to test the sufficiency of the Y2H library. As a result, a cDNA clone encoding VelB protein that was known to be involved in the regulation of diverse cellular processes, including control of secondary metabolism containing melanin and toxin production in many filamentous fungi was identified. Further study on the exact role of the VelB gene is underway.

• Journal of the Society of Naval Architects of Korea
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• v.29 no.1
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• pp.1-13
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• 1992

The objective of this study is to develop knowledge-based system for the preliminary design and midship section design of bulk carrier and to enhance the applicability of knowledge engineering in the field of Naval Architecture. First, expert system shell called E.1 is developed in C language. E.1 supports backward-chaining, automatic iteration procedure and reiterative inference mechanism for efficient application of knowledge-based system in structural design. Knowledge representation in E.1 includes IF-THEN rules, 'facts'and 'tables'. Second, knowledge bases for the principal particulars and midship section design are developed by experimental formula, design standard and experiential knowlege. Third, hybrid system combined this knowledge-based system with the optimization program of midship section is developed. Finally, the simplified design method utilizing the regression analysis of the optimum results of stiffened plate is developed for facilitating the design process. Using this knowledge-based system, the design process and results for Bulk carrier and stiffened plates are discussed. It is concluded that knowledge-based system is efficient for preliminary design and midship section design of the ship. It is expected that the performance of the CAD system would be enhanced if the better knowledge-base is accumulated in the E.1 tool.

• Journal of the Korean Society for Railway
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• v.12 no.4
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• pp.590-596
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• 2009

In this study, the failure modes and energy absorption characteristics of four different kinds of circular tubes made of carbon, glass, Kevlar and carbon-Kevlar hybrid fibres composites with epoxy resin have been evaluated. To achieve these goals, compressive tests were conducted for the tubes under 10mm/min loading speed. Based on the test results, the carbon/epoxy tube showed the best energy absorption capability, while carbon-Kevlar/epoxy tubes were worst. In the failure mode during crushing, both of the carbon/epoxy tubes and the glass/epoxy tubes were crushed by brittle fracturing mode. The Kevlar/epoxy tubes were collapsed by local buckling mode like steel, while the carbon-Kevlar hybrid tubes were collapsed by mixed mode of local buckling and lamina bending.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2016.11a
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• pp.105-105
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• 2016

Recently, high power impulse magnetron sputtering (HIPIMS) has attracted considerable attentions due to its high potential for industrial applications. By pulsing the sputtering target with high power density and short duration pulses, a high plasma density and high ionization of the sputtered species can be obtained. HIPIMS has exhibited several merits such as increased coating density, good adhesion, microparticle-free and smooth surface, which make the HIPIMS technique desirable for synthesizing hard coatings. However, hard coatings present intrinsic defects (columnar structures, pinholes, pores, discontinuities) which can affect the corrosion behavior, especially when substrates are active alloys like steel or in a wear-corrosion process. Atomic layer deposition (ALD), a CVD derived method with a broad spectrum of applications, has shown great potential for corrosion protection of high-precision metallic parts or systems. In ALD deposition, the growth proceeds through cyclic repetition of self-limiting surface reactions, which leads to the thin films possess high quality, low defect density, uniformity, low-temperature processing and exquisite thickness control. These merits make ALD an ideal candidate for the fabrication of excellent oxide barrier layer which can block the pinhole and other defects left in the coating structure to improve the corrosion protection of hard coatings. In this work, CrN/Al2O3/CrN multilayered coatings were synthesized by a hybrid process of HIPIMS and ALD techniques, aiming to improve the CrN hard coating properties. The influence of the Al2O3 interlayer addition, the thickness and intercalation position of the Al2O3 layer in the coatings on the microstructure, surface roughness, mechanical properties and corrosion behaviors were investigated. The results indicated that the dense Al2O3 interlayer addition by ALD lead to a significant decrease of the average grain size and surface roughness and greatly improved the mechanical properties and corrosion resistance of the CrN coatings. The thickness increase of the Al2O3 layer and intercalation position change to near the coating surface resulted in improved mechanical properties and corrosion resistance. The mechanism can be explained by that the dense Al2O3 interlayer acted as an excellent barrier for dislocation motion and diffusion of the corrosive substance.