• Title/Summary/Keyword: hybrid ion exchange fabrics

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Synthesis of High Loading PONF-g-GMA Anion Exchange Fiber Containing Ion Exchange Resin and Their Adsorption Properties of Vanadium (이온교환 수지를 함유한 PONF-g-GMA High Loading 음이온교환 섬유의 합성 및 바나듐 흡착 특성)

  • Baek, Ki-Wan;Park, Seung-Wook;Nho, Young-Chang;Hwang, Taek-Sung
    • Polymer(Korea)
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    • v.31 no.4
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    • pp.315-321
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    • 2007
  • Aminated PONF-9-GMA ion exchange fabrics were synthesized by radiation induced graft copolymerization. Hybrid ion exchange fabrics combined with aminated PONF-g-GMA fabrics and anionic ion exchange resin were also fabricated by hot melt adhesion method and then their adsorption properties were investigated. Ion exchange capacity of the hybrid ion exchange fabrics was higher than ion exchange fabric and was lower than bead resin. The maximum value was 4.18 meq/g. Adsorption breakthrough time for vanadium of the hybrid ion exchange fabric was 550 min, which was faster than bead resin but slower than fibrous ion exchanger. The Breakthrough time of the hybrid ion exchange fabrics gets longer with increasing pH. The initial breakthrough time occurred around 400 min with increasing vanadium concentration.

Preparation of Hybrid Cation Ion Exchange Fibers by Web Spray and Their Adsorption Properties for Ammonia Gas (Web Spray 법을 이용한 복합 양이온교환섬유의 제조 및 암모니아 흡착특성)

  • Park, Seong-Wook;Lee, Hoo-Kun;Rhee, Young-Woo;Jung, Boo-Young;Hwang, Taek-Sung
    • Polymer(Korea)
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    • v.31 no.6
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    • pp.479-484
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    • 2007
  • In this study, the hybrid ion exchange fibers (HIEF) were prepared by using web spraying muthod with hot melt adhesive. Characteristics of HIEF and their adsorption properties for ammonia gas were investigated. The ion exchange capacity (IEC) of HIEF was increased with increasing the resin contents and their values were higher than those of pure resin and ion exchange fabrics. The removal efficiency for ammonia gas increased with an increase in packing density of hybrid ion exchange fabrics in the column. The adsorption breakthrough time was 270 min, which was slower than those of the resin and fibers. The maximum value of adsorption for ammonia gas was 94%. The breakthrough time was also increased with increasing the concentration and flow rate of ammonia gas. The reaction constant(k) for ammonia gas was increased with increasing the concentration and flow rate of the gas, while it was decreased an the mass was increased.

Preparation of High Performance Hybrid Chemical Filter using Hot Melt Adhesive by Web Spray and Their Adsorption Properties (핫멜트 Web spray법을 이용한 고기능성 복합 화학필터의 제조 및 흡착특성)

  • Choi, Yong Jae;Shin, Kyoung Sub;Hwang, Taek Sung
    • Journal of Adhesion and Interface
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    • v.10 no.3
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    • pp.141-147
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    • 2009
  • In this study, the high performance hybrid chemical filter (HPHCF) was prepared by web spray using hot melt adhesive. The material of HPHCF was conditionally made of ion exchange resin and PP non-woven fabric. The optimum temperature and pressure for manufacturing of HPHCF conditions were such as $170^{\circ}C$ and 50 psi, respectively. The characteristics of preparated HPHCF and their adsorption properties of ammonia gas were investigated. The ion exchange capacity (IEC) of HPHCF was increased with increasing the resin contents and their values were higher than pure resin and ion exchange fabrics. The removal efficiency for ammonia gas increased with the increase of packing density of hybrid ion exchange fabrics in the column. It showed 13 min which the adsorption breakthrough time was slower than resin and fibers. The maximum value of adsorption for ammonia gas was 98 percent. And also, the velocity was increased with increasing concentration and flow rate of ammonia gas.

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