• Title/Summary/Keyword: homogeneous reaction

Search Result 333, Processing Time 0.034 seconds

Experimental Study on HCCI Combustion Characteristics of n-heptane and iso-octane Fuel/air Mixture by using a Rapid Compression Machine (급속압축장치를 이용한 노말헵탄.이소옥탄 혼합연료의 HCCI 연소특성에 대한 연구)

  • Lim, Ock-Taeck
    • Journal of ILASS-Korea
    • /
    • v.16 no.4
    • /
    • pp.167-175
    • /
    • 2011
  • The HCCI engines have been known with high efficiency and low pollution and can be actualized as the new internal combustion engines. However, As for(??) the ignition and combustion depend strongly on the oxidation reaction of the fuel, so it is difficult to control auto-ignition timing and combustion duration. Purpose of this paper is creating the database for development of multi-dimensional simulation and investigating the influence of different molecular structure. In this research, the effect of n-heptane mole ratio in fuel (XnH) on the ignition delay from homogeneous charge compression ignition(HCCI) has been investigated experimentally. By varying the XnH, it was possible to ascertain whether or not XnH is the main resource of ignition delay. Additionally, the information on equivalence ratio for varying XnH was obtained. The tests were performed on a RCM (Rapid Compression Machine) fueled with n-heptane and iso-octane. The results showed that decreasing XnH (100, 30, 20, 10,0), the ignition delays of low temperature reaction (tL) and high temperature reaction (tH) is longer. And the temperature of reaction increases by about 30K. n-heptane partial equivalence ratio (fnH) affect on tL.and TL. When ${\phi}$nH was increased as a certain value, tL was decreased and TL was increased.

An Epithermal Neutron Beam Design for BNCT Using $^2H(d,n)^3He$ Reaction

  • Han, Chi-Young;Kim, Jong-Kyung;Chung, Kyu-Sun
    • Nuclear Engineering and Technology
    • /
    • v.31 no.5
    • /
    • pp.512-521
    • /
    • 1999
  • A feasibility study was performed to design an epithermal neutron beam for BNCT using the neutron of 2.45 MeV on the average produced from $^2H(d,n)^3$He reaction induced by plasma focus in the z-pinch instead of the conventional accelerator-based $^3H(d, n)^4$He neutron generator. Flux and spectrum were analyzed to use these neutrons as the neutron source for BNCT. Neutronic characteristics of several candidate materials in this neutron source were investigated Using MCNP Code, and $^7LiF$ ; 40%Al + 60%$AIF_3$, and Pb Were determined as moderator, filter, and reflector in an epithermal neutron beam design for BNCT, respectively. The skin-skull-brain ellipsoidal phantom, which consists of homogeneous regions of skin-, bone-, or brain-equivalent material, was used in order to assess the dosimetric effect in brain. An epithermal neutron beam design for BNCT was proposed by the repeated work with MCNP runs, and the dosimetric properties (AD, AR, ADDR, and Dose Components) calculated within the phantom showed that the neutron beam designed in this work is effective in tumor therapy. If the neutron source flux is high enough using the z-pinch plasma, BNCT using the neutron source produced from $^2H(d,n)^3$He reaction will be very feasible.

  • PDF

Synthesis and Magnetic Properties of Nanocrystalline Fe-Ni Alloys During Hydrogen Reduction of NiFe2O4 (NiFe2O4의 수소환원에 의한 나노구조 Fe-Ni 합금의 제조 및 자성특성)

  • Paek, Min Kyu;Do, Kyung Hyo;Bahgat, Mohamed;Pak, Jong Jin
    • Korean Journal of Metals and Materials
    • /
    • v.49 no.1
    • /
    • pp.52-57
    • /
    • 2011
  • Nickel ferrite ($NiFe_2O_4$) powder was prepared through the ceramic route by calcination of a stoichiometric mixture of nickel oxide (NiO) and iron oxide ($Fe_2O_3$). The pressed pellets of $NiFe_2O_4$ were isothermally reduced in pure hydrogen at 800, 900, 1000 and $1100^{\circ}C$. Based on thermogravimetric analysis, the reduction behavior and the kinetic reaction mechanisms of the synthesized ferrite were studied. The initial ferrite powder and various reduction products were characterized by XRD, SEM, reflected light microscope and VSM to reveal the effect of hydrogen reduction on the composition, microstructure, magnetic properties and reaction kinetics of the produced Fe-Ni alloy. Complete reduction of the $NiFe_2O_4$ was achieved with synthesis of homogeneous nanocrystalline Fe-Ni alloys. Arrhenius equation with the approved mathematical formulations for a gas-solid reaction was applied for calculating the activation energy ($E_a$) values and detecting the controlling reaction mechanism.

Optical Transparency and Microstructure of $TiO_2-SiO_2$ Binary Aerogels ($TiO_2-SiO_2$ 이성분계 Aerogel의 광학적 투명성과 미세구조)

  • 이종혁;최수영;김창은;김구대;이해욱
    • Journal of the Korean Ceramic Society
    • /
    • v.32 no.3
    • /
    • pp.321-330
    • /
    • 1995
  • Homogeneous and monolithic TiO2-SiO2 binary aerogels were prepared by supercritical drying. Optical transparency was increased with adding acid catalyst during two step hydrolysis and with decreasing water content. These differences in optical transparency were related to microstructures of gel network formed through polycondensation reaction during supercritical drying process, rather than the final composition of aerogel.

  • PDF

The Characteristics of Negative lons in Silane Plasma Changing the Process Variables (공정 변수 변화에 따른 실란 플라즈마내 음이온 특성)

  • Kim, Dong-Joo;Kim, Kyo-Seon
    • Journal of Industrial Technology
    • /
    • v.15
    • /
    • pp.15-22
    • /
    • 1995
  • We have studied the generation and behavior of negative ions in silane plasmas. The negative ions were formed by homogeneous reaction in silane plasma and the behavior of negative ions were predicted by solving the model equations. The concentration profiles of negative ions were shown as a function of reactor length and time. The effects of process variables such as reactor pressure, flow rate and electrical field strengths on the behavior of negative ions were analyzed.

  • PDF

A SIMPLE CHARACTERIZATION OF POSITIVITY PRESERVING SEMI-LINEAR PARABOLIC SYSTEMS

  • Haraux, Alain
    • Journal of the Korean Mathematical Society
    • /
    • v.54 no.6
    • /
    • pp.1817-1828
    • /
    • 2017
  • We give a simple and direct proof of the characterization of positivity preserving semi-flows for ordinary differential systems. The same method provides an abstract result on a class of evolution systems containing reaction-diffusion systems in a bounded domain of ${\mathbb{R}}^n$ with either Neumann or Dirichlet homogeneous boundary conditions. The conditions are exactly the same with or without diffusion. A similar approach gives the optimal result for invariant rectangles in the case of Neumann conditions.

Theoretical Analysis on the Hot Surface Ignition of a Rectangular-Shape Solid Fuel

  • Kim, Se-Won
    • Journal of Energy Engineering
    • /
    • v.4 no.2
    • /
    • pp.297-302
    • /
    • 1995
  • Ignition of a reactive solid in a shape of square corner by a hot surface is studied theoretically. Ignition time and the location of ignition point are determined as a function of dimensionless parameters, with the use of the homogeneous model of ignition. The effect of geometry on the ignition of solid fuel results in the local characteristics: the reaction is initiated in a hot point in depth of the substance. It is shown that ignition time is proportional to the dimensionless initial temperature, whereas for the ignition of the semiinfinite body this dependence was quadratic.

  • PDF

Lateral Behavior of Single Rigid Driven Pile in Non-Homogeneous Sand (비균질 지반에서 항타 관입한 단일 강성말뚝의 수평거동 연구)

  • 김영수;김병탁
    • Journal of the Korean Geotechnical Society
    • /
    • v.15 no.6
    • /
    • pp.167-185
    • /
    • 1999
  • A series of model tests was performed to find the characteristics of lateral behavior of single rigid pile. This paper shows the results of model tests on the lateral behavior of single rigid driven pile in non-homogeneous(two layered) Nak-Dong River sands. The purpose of this paper is to investigate the effect of the ratio of lower layer thickness to embedded pile length, the coefficient ratio of the subgrade reaction and the pile construction conditions(driven & embedded piles) on the characteristics of lateral behavior of single pile. The results of model tests show that the lateral behavior in non-homogeneous soil depends upon drop energy considerably, that is, in the case of H/L=0.75, as the drop energy increases three times the decrease percentage increases about 2.12 times. In the driven pile with non-homogeneous soil of $E_{h1}/E_{h2}=5.56$, the effect of upper layer with large stiffness on the decrease of lateral deflection is remarkably smaller than embedded pile. In non-homogeneous soil, the maximum bending moment of driven pile is in the range of 100 132% in comparison with embedded pile. The reason is that the stiffness of soil around pile increases with drop vibration and so the pile behavior is similar to the flexible pile behavior by means of the increase of relative stiffness of pile, In this paper, the experimental equations for lateral load and H/L on $y_D/y_E \; & \; MBM_D/MBM_E$ are suggested from model tests.

  • PDF

The investigation of Diesel Spray Combustion in DME HCCI (DME 예혼합기를 분위기로 하는 디젤 분무의 연소에 관한 연구)

  • Lim, Ock-Taeck;Iida, Norimasa
    • Proceedings of the KSME Conference
    • /
    • 2007.05b
    • /
    • pp.3329-3334
    • /
    • 2007
  • The purpose of the research is to investigate of diesel spray combustion for simultaneously reduce way NOx and PM. The pressure diesel injection were done into intermediates that are generated by very lean DME HCCI combustion using a RCM. The concentration of intermediate could not be directly measured; we estimated it by CHEMKIN calculation. DME HCCI characteristic is surveyed. Validations of the CHEMKIN calculation were confirmed pressure rise of an experiment and pressure rise of a calculation. Using a framing streak camera captured two dimensional spontaneous luminescence images from chemical species at low temperature reaction(LTR) and high temperature reaction (HTR). Also, the combustion events were observed by high-speed direct photography, the ignition and combustion were analyzed by the combustion chamber pressure profiles.

  • PDF

A Study on the Detailed Diesel Surrogate Chemical Mechanism for Analysis of HCCI Engine (HCCI 엔진 해석을 위한 Diesel Surrogate 반응 기구에 관한 연구)

  • Lee, Won-Jun;Lee, Seung-Ro;Lee, Chang-Eon
    • Transactions of the Korean Society of Automotive Engineers
    • /
    • v.19 no.4
    • /
    • pp.64-71
    • /
    • 2011
  • Homogeneous charge compression ignition (HCCI) was the best concept able to provide low NOx and PM in diesel engine emissions. This new alternative combustion process was mainly controlled by chemical kinetics in comparison with the conventional combustion in internal combustion engine. In this paper, detailed kinetic reaction mechanisms of diesel surrogate was investigated to understand the diesel HCCI engine combustion. It was tested two existing mechanisms and two new mechanisms for the comparison of experimental result. The best mechanism for diesel surrogate was suggested through this comparison.