• Title/Summary/Keyword: homocharge

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Polarization and Charge Transport in Unfilled Epoxy (비충전 에폭시의 분극 및 전하 이동)

  • Gwak, Hyun-Woo;Choi, Yong-Sung;Lee, Kyung-Sup
    • Proceedings of the KIEE Conference
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    • 2008.07a
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    • pp.2311-2312
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    • 2008
  • The investigations included the measurements of volume currents and also internal space charges on epoxy samples of mm thicknesses. The current versus time relations were shown to correspond well with classical forms of dielectric response such as the Curie-von Schweidler model. After the time transient, near steady currents were extremely small and exhibited a significant temperature dependence, similar in relation to the Poole-Frenkel hoping transport model. Equivalent resistances were on the order of 1019 ohms and represent very weak charge transport. Electrically stimulated acoustic waves were used to quantify the small internal charges that would accumulate within the epoxy. There was a notable homocharge near both anode and cathode. The dielectric response and the internal charge were related to show a consistent model for charge transport within unfilled epoxy.

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Interfacial Charge Behaviors in SXLPE/XLPE Laminates (SXLPE/XLPE laminate의 계면전하 거동)

  • 고정우;남진호;서광석
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.15 no.2
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    • pp.127-132
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    • 2002
  • Space charge distributions and behaviors in silane crosslinked polyethylene(SXLPE)/ crosslinked polyethylene(XLPE) laminates were investigated using a pulsed electroacoustic (PEA) method. In case of monolayer, XLPE shows heterocharge while SXLPE shows homocharge. It was observed that charges were accumulated at the interface of SXLPE/XLPE laminate when applied electric field was more than 20kV/mm. The charge profile at various temperatures was also acquired using temperature-controllable PEA system. Although applied electric field is only 8.6 kV.mm, positive interfacial charge starts to appear near 50$^{\circ}C$. It was found that the interfacial charge behavior of SXLPE/XLPE laminate under low voltage at high temperature is corresponding to that under high voltage at room temperature.

Charge Accunmulation Characteristics in LDPE (저밀도 폴리에틸렌의 전하축적 특성)

  • ;;Tatsuo Takada
    • The Transactions of the Korean Institute of Electrical Engineers
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    • v.41 no.1
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    • pp.42-49
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    • 1992
  • Charge accumulation characteristics in low density polyethylene (LDPE) has been discussed based upon the internal charge distrubution measured by the pulsed electroacoustic technique. When the negative voltage with respect to earth is applied to the upper electrode, the negative charges near the anode and the positive charges near the cathode are accumulated in LDPE. Also, there was an asymmetric behavior of charge accumulation exhibiting that the charge accumulation near the anode keeps increasing whereas that near the cathode increases first and then decreases. Besides, under the present test conditions the internal charge distrubution becomes stabilized eventually. When the positive voltage with respect to earth is applied to the upper electrode, on the other hand, no such asymmetric charge accumulation was found. Therefore, it can be concluded that the heterocharges are accumulated at the surface region of LDPE subjected to high do voltages and that the begavior of charge accumulation depends on the polarity of do voltage and the position of charge accumulation.

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Influense of the high-voltage conductivity on peculiarity of polarization ferroelectric polymer on based vinylidenefluoride

  • Kochervinskii, V.V.;Chubunova, E.V.;Lebedinskii, Y.Y.;Pavlov, A.S.;Pakuro, N.I.
    • Advances in materials Research
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    • v.4 no.2
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    • pp.113-132
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    • 2015
  • The phenomena of high-voltage polarization and conductivity in oriented vinylidenefluoride and tetrafluoroethylene copolymer films have been investigated. It was shown that under certain electric fields, injection of carriers from the material of electrodes appears The barrier for holes injection in the copolymer was found to be lower than that for electrons. It results in more effective screening of the external field near the anode than near cathode. Electrones, ejected from cathode, creating negative charge by trapping on the surface. It is shown that the electrons injected from cathodes create a negative homocharge on the copolymer surface and then become captured on the surface shallow traps. Their nature has been studied by the x-ray photoelectron spectroscopy. It was shown that these traps may consist of chemical defects in the form of new functional groups formed by reactions of surface macromolecules with sputtered atoms of aluminum. The asymmetric shape of hysteresis curves was explained by the difference in mobility of injected holes and electrons. These factors caused appearance of "non-closed" hysteresis curves for fluorine-containing polymer ferroelectrics. Hysteresis phenomena observed at low electric fields (below coercive ones) are to associate with the behavior of the domains localized in the ordered regions formed during secondary crystallization of copolymers.