• Macromolecular Research
• /
• v.16 no.2
• /
• pp.85-102
• /
• 2008

The development of reliable synthetic routes to polymer nanomaterials with well-defined size and morphology is a critical research topic in contemporary materials science. The ability to generate nanometer-sized polymer materials can offer unprecedented, interesting insights into the physical and chemical properties of the corresponding materials. In addition, control over shape and geometry of polymer nanoparticles affords versatile polymer nanostructures, encompassing nanospheres, core-shell nanoparticles, hollow nanoparticles, nanorods/fibers, nanotubes, and nanoporous materials. This review summarizes a diverse range of synthetic methods (broadly, hard template synthesis, soft template synthesis, and template-free synthesis) for fabricating polymer nanomaterials. The basic concepts and significant issues with respect to the synthetic strategies and tools are briefly introduced, and the examples of some of the outstanding research are highlighted. Our aim is to present a comprehensive review of research activities that concentrate on fabrication of various kinds of polymer nanoparticles.

• Proceedings of the Korean Institute of Surface Engineering Conference
• /
• 2017.05a
• /
• pp.109-109
• /
• 2017

알지네이트 하이드로 젤은 해조류에서 추출되는 천연 고분자인 알지네이트가 칼슘 또는 마그네슘 양이온과 이온가교(Ioninc cross linking)를 형성할 때 알지네이트의 고분자 구조가 칼슘, 마그네슘 양이온을 감싸면서 형성되는 고분자이다. 알지네이트 하이드로 젤은 높은 생체적합성(Biocompatibility)으로 인해 세포 재생을 위한 조직공학 및 재생의학, 약물전달 등의 제약 관련 분야에 광범위하게 적용될 수 있는 물질로 많은 연구가 이루어지고 있다. 본 연구에서는 마이크로 플루이딕 칩을 이용하여 알지네이트 튜브를 제조하였다. 먼저 유동 포커싱 방식(flow focussing)을 유도할 수 있는 PDMS(Polydimethylsiloxane) 마이크로 플루이딕 칩을 제조하였다. 마이크로 플루이딕 칩은 CNC(Computer Numeric Control) milling machine을 이용한 template를 만들고 NOA mold를 이용하여 최종 PDMS 칩을 제작하였다. 튜브를 만들기 위한 마이크로 채널은 내부 채널 ($200{\times}200um$), 중간 채널 ($200{\times}200um$) 및 외부 채널 ($200{\times}200um$)로 구성되며 내부, 중간, 외부의 유체가 합류하는 수집채널은 폭 500 um, 깊이 200 um로 구성되었다. 운반체로는 5%의 acetic acid를 함유한 mineral oil를 이용하였으며 내부의 core flow는 $H_2O$로 하였다. 중간 유체인 2% 알지네이트 프리폴리머는 칼슘 이온의 존재 하에서 젤화 과정이 매우 빠르기 때문에 마이크로 채널 내부에서의 반응을 제어하고 막힘을 방지하기 위해 수용성 복합 칼슘-에틸렌 디아민 테트라 아세트산 (EDTA)을 사용하였다. 본 마이크로 플루이딕 칩에 각각의 유체를 이동시켰을 때, 운반체인 oil phase의 수소이온은 중간 유체인 알지네이트 프리폴리머와의 계면을 통해 확산되어 Ca-EDTA 복합체로부터 칼슘 양이온의 방출을 유발하게 된다. 방출된 칼슘 양이온은 알지네이트 고분자와의 이온 가교를 통해 알지네이트 하이드로 젤을 형성하여, 각 유체의 flow에 따라 알지네이트 튜브를 쉽고 빠르게 제조 가능하였다. 본 연구에서 제조된 알지네이트 튜브는 인체 내 장기간 약물 전달을 위한 나노섬유로 활용하거나 인공혈관을 구성하는 extracellular matrix로 활용될 잠재력을 가지고 있어 추후 활발한 연구개발이 진행될 예정이다.

• Proceedings of the Korean Vacuum Society Conference
• /
• 2000.02a
• /
• pp.212-212
• /
• 2000

Since the first obserbvation of carbon nanotubes, extensive researches have been done for the synthesis using arc discharge, laser vaporization, and plasma-enhanced chemical vapor deposition. Carbon nanotubes have unique physical and chemical properties and can allow nanoscale devices. Vertically aligned carbon nanotubes with high quality on a large area is particularly important to enable both fundamental studies and applications, such as flat panel displays and vacuum microelectronics. we have grown vertically aligned carbon nanotubes on a large area of Si substrates by thermal chemical vapor deposition using C2H2 gas at 750-950$^{\circ}C$. we deposited catalytic metal on Si susbstrate using thermal evaporation. The nanotubes reveal highly purified surface. The carbon nanotubes have multi-wall structure with a hollow inside and it reveals bamboo structure agreed with base growth model. Figure 1 shows SEM micrograph showing vertically aligned carbon nanotubes whih were grown at 950$^{\circ}C$ on a large area (20mm${\times}$30mm) of Si substrates. Figure 2 shows TEM analysis was performed on the carbon nanotubes grown at 950$^{\circ}C$ for 10 min. The carbon nanotubes are multi-wall structure with bamboo shape and the lack of fringes inside the nanotube indicates that the core of the structure is hollow. In our experiment, carbon nanotubes grown by the thermal CVD indicate base growth model.

• Journal of the Korea Concrete Institute
• /
• v.28 no.4
• /
• pp.489-496
• /
• 2016

Recently, a concern about hollow core precast concrete (PC) slab has been increased as a method to improve the construction ability by reducing the self weight of structures during the construction. Hollow core slab which is known as a typical PC slab in domestic construction of PC building has a problem to put shear reinforcements in the web of element during the production of element in the factory. With regard to this point, recently, tripple ribs slab (TRS) which can be said as a new type of half PC slab system was developed. In TRS, it is possible to place shear reinforcements in PC element during the production of the element in the factory. This paper presents the shear test result of TRS which was done by one point loading test under simple support condition. Test parameters are the presence of cast-in-place (CIP) concrete and the contribution of lattice bars. From the test, it was found that the TRS has sufficient shear capacity to resist the design load and its strength can be predicted by the code equations for general beam. It is recommended to ignore the strength of lattice bar in the calculation of shear strength during the construction since its contribution is too low to be considered when CIP is not casted.

• Applied Chemistry for Engineering
• /
• v.23 no.2
• /
• pp.131-137
• /
• 2012

Polyaniline (PANI) and polypyrrole (Ppy) hollow sphere structures with controlled shell thicknesses can be easily synthesized than those of using a layer-by-layer method for cathode active material of lithium-ion batteries. Polystyrene (PS) core was synthesized by emulsion polymerization using an anion surfactant. The shell thicknesses of PANI and Ppy were controlled by amounts of aniline and pyrrole monomers. PS was removed by an organic solution. This structure increased in contact with an electrolyte and a specific capacity in lithium-ion batteries. But polymers have disadvantages such as the difficult control of molecular weights and low densities. These disadvantages were completed by controlled shell thicknesses. The amount of aniline monomer increased from 1.2, 2.4, 3.6, 4.8 to 6.0 mL, and the shell thicknesses were 30.2, 38.0, 42.2, 48.2, and 52.4 nm, respectively. And the amount of pyrrole monomer was 0.6, 1.2, 2.4 and 3.6 mL, the shell thicknesses were 16.0, 22.0, 27.0 and 34.0 nm, respectively. In the cathode materials with controlled shell thicknesses, shell thicknesses of the PANI hollow spheres were 30.2, 42.2, and 52.4 nm, and discharge specific capacities of after 10 cycle were ~18, ~29, and ~62 mAh/g, respectively. The shell thicknesses of the Ppy hollow spheres were 16.0, 22.0, 27.0 and 34.0 nm, and discharge specific capacities of after 15 cycle were ~15, ~36, ~56, and ~77 mAh/g, respectively. Thus, shell thicknesses of PANI and Ppy increased, the specific capacities increased.

• Journal of the Korean Society for Precision Engineering
• /
• v.29 no.2
• /
• pp.156-160
• /
• 2012

Recently, the demands of the large scale machine tools gradually increase to machine the large parts, such as large scale crankshaft, yaw and pitch bearings for the wind power generator and the vehicle or aircraft components. But the high technology is necessary in order to develop the huge machine tools. Furthermore, the global market of it has been monopolized by a few companies. So, we need to develop the large scale machine tools and study its core technology to rush into the increasing market. In this study, we carried out the researches for the important core technology of a multi-tasking, machine tool; a large scale 5-axis machine tool of gantry type for multi-task machining. This study is focused on the design of large size gantry type multi-axis machine. In the case of large size of machine the cross rail deflection in the X-axis is significant. To reduce the deflection due to the eccentric spindle head, a special hollow type design in the cross rail with outside ram is adapted in this study. Also, the Zig-Zag motion in the Y-axis is inevitable with the gantry geometry, which is by the un-balancing, different motion at the left and the right columns moving. We tried to reduce the influence of Zig-Zag motion using FEM with different loading conditions at the left and the right side column.

• Journal of the Society of Cosmetic Scientists of Korea
• /
• v.30 no.3 s.47
• /
• pp.321-328
• /
• 2004

Nano silica ball and nano carbon ball are developed commercially by template synthesis method. Adsorption of unpleasant smelling substances such as ammonia, trimethylamine, acetaldehyde and methyl mercaptane onto nano carbon ball with hollow macroporous core/mesoporous shell structures, nano carbon ball, was investigated and compared with that onto odor adsorbent materials, activated carbon, commercially available. The adsorption and decomposition of malodor at nano carbon ball exhibited superior than those onto activated carbon. The physicochemical properties such as mesopore size distributions, large nitrogen BET specific surface area and large pore volume and decomposition of malodor were studied to interpret the predominant adsorption performance. The nano carbon ball is expected to be useful in many applications such as deodorizers, adsorbent of pollutants.

• Journal of the Korea Institute of Military Science and Technology
• /
• v.24 no.2
• /
• pp.211-218
• /
• 2021

This paper deals with the computational work to characterize the formation and pinching of a plasma in an X-pinch configuration. A resistive magnetohydrodynamic model of a single fluid and two temperature is adopted assuming a hollow conical structure in the (r,z) domain. The model includes the thermodynamic parameter of tungsten from the corrected Thomas-Fermi EOS(equation of state), determining the average ionization charge, pressure, and internal energy. The transport coefficients, resistivity and thermal conductivity, are obtained by the corrected Lee & More model and a simple radiation loss rate by recombination process is considered in the simulation. The simulation demonstrated the formation of a core-corona plasma and intense compression process near the central region which agrees with the experimental observation in the X-pinch device at Seoul National University. In addition, it confirmed the increase in radiation loss rate with the density and temperature of the core plasma.

• Journal of Electrical Engineering and Technology
• /
• v.13 no.6
• /
• pp.2284-2291
• /
• 2018

This paper deals with optimum design of surface mounted permanent magnet synchronous motor (SPMSM) for automotive component. For a compact system structure, it was designed as a motor with a 14-pole 12-slot concentrated winding and hollow shaft. The motor is a thin type structure which stator outer diameter is relatively large compared to its axial length and is designed to have a high magnetic saturation for increasing the torque density. Since the high magnetic saturation in the stator core increases the axial leakage flux, a 3-dimensional (3-D) finite element analysis (FEA) is indispensable for torque analysis. However, optimum designs using 3-D FEA is inefficient in terms of time and cost. Therefore, equivalent 2-D FEA which is able to consider axial leakage flux is applied to the optimization to overcome the disadvantages of 3-D FEA. The structure for cost reduction is proposed and optimum design using equivalent 2-D FEA has been performed.

• Structural Engineering and Mechanics
• /
• v.45 no.4
• /
• pp.439-454
• /
• 2013

Hollow cylindrical tubes with a prismatic sandwich lining designed to replace the solid cross-sections are studied in this paper. The sections are divided by a number of revolving periodic unit cells and three topologies of unit cells (Square, Triangle and Kagome) are proposed. Some types of multiple-topology designed materials are also studied. The feasibility and accuracy of a homogenization method for obtaining the equivalent parameters are investigated. As the curved elements of a unit cell are represented by straight elements in the method and the ratios of the lengths of the curved elements to the lengths of the straight elements vary with the changing number of unit cells, some errors may be introduced. The frequencies of the first five modes and responses of the complete and equivalent models under an internal static pressure and an internal step pressure are compared for investigating the scope of applications of the method. The lower bounds and upper bounds of the number of Square, Triangular and Kagome cells in the sections are obtained. It is shown that treating the multiple-topology designed materials as a separate-layer structure is more accurate than treating the structure as a whole.