• Title/Summary/Keyword: hollow structure

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Preparation and Gas Permeation Characteristics of Polyetherimide Hollow Fiber Membrane for the Application of Hydrogen Separation (수소분리를 위한 Polyetherimide계 고분자 중공사막의 제조 및 기체투과 특성)

  • Kwon, Hyeon Woong;Im, Kwang Seop;Kim, Ji Hyeon;Kim, Seong Heon;Kim, Do Hyeong;Nam, Sang Yong
    • Membrane Journal
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    • v.31 no.6
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    • pp.456-470
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    • 2021
  • In this study, polyetherimide-based hollow fiber membranes were manufactured using the NIPS (nonsolvent induced phase separation) method. THF, Ethanol, and LiNO3 were used as additives to control the morphology of the PEI-hollow fiber membranes. Furthermore, for the development of a high hydrogen separation membrane, the spinning conditions were optimized through the characterization of SEM and gas permeance. As a result, as the content of THF increased, the hydrogen/carbon dioxide selectivity increased. However, the permeance decreased due to the trade-off relationship. When ethanol was added, a finger-like structure was shown, and when LiNO3 was added, a sponge structure was shown. In particular, in the case of a hollow fiber membrane with an optimized PDMS coating layer, the permeance was 40 GPU and the hydrogen/carbon dioxide selectivity was 5.6.

Preparation of highly hydrophobic PVDF hollow fiber composite membrane with lotus leaf-like surface and its desalination properties

  • Li, Hongbin;Zi, Xingchen;Shi, Wenying;Qin, Longwei;Zhang, Haixia;Qin, Xiaohong
    • Membrane and Water Treatment
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    • v.10 no.4
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    • pp.287-298
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    • 2019
  • Lotus leaf has a special dual micro and nano surface structure which gives its highly hydrophobic surface characteristics and so-called self cleaning effect. In order to endow PVDF hollow fiber membrane with this special structure and improve the hydrophobicity of membrane surface, PVDF hollow fiber composite membranes was obtained through the immersion coating of poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP) dilute solution on the outside surface of PVDF support membrane. The prepared PVDF composite membranes were used in the vacuum membrane distillation (VMD) for the desalination. The effects of PVDF-HFP dilute solution concentration in the dope solution and coating time on VMD separation performance was studied. Membranes were characterized by SEM, WCA measurement, porosity, and liquid entry pressure of water. VMD test was carried out using $35g{\cdot}L^{-1}$ NaCl aqueous solution as the feed solution at feed temperature of $30^{\circ}C$ and the permeate pressure of 31.3 kPa. The vapour flux reached a maximum when PVDF-HFP concentration in the dilute solution was 5 wt% and the coating time was kept in the range of 10-60 s. This was attributed to the well configuration of micro-nano rods which was similar with the dual micro-nano structure on the lotus leaf. Compared with the original PVDF membrane, the salt rejection can be well maintained which was greater than 99.99 % meanwhile permeation water conductivity was kept at a low value of $7-9{\mu}S{\cdot}cm^{-1}$ during the continuous testing for 360 h.

The Fabrication Processes for the Planarization of Sacrificial Layers over Hollow Structures (Hollow Structure에서의 희생층 평탄화 제작 공정)

  • Yoon Yong-Seop;Bae Ki-Deok;Choi Hyung;Jun Chan-Bong;Ro Kwang-Choon
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.53 no.10
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    • pp.546-550
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    • 2004
  • Two fabrication approaches are proposed to planarize the sacrificial layer over hollow structures. One is the photoresist filling method that makes use of photolithography, thermal curing and plasma ashing. The other is the lamination method that is applying pressure and temperature to the organic film over the hollow structures. The fabrication results are compared with those of CMP process. Trenches and cavities with various dimensions have been made for the porposed process. Upon measuring the planarization levels, they are dependent on planarization methods and the geometrical size of hollow structures. The photoresist filling method is so strongly dependent on the width and depth of trenches that we have problems to use it for large dimensional trenches. To the contrary, the flatness of sacrificial layer over the trenches was found to be almost independent of trench dimensions for the lamination method. A CMP process shows the most excellent results, but the fabrication is complicated and the access to it is not so easy. It is important to choose the proper planarization method by considering the required flatness levels, materials to be planarized, and connection between the planarization step and the previous or the following process of it.

Characteristics of Heaving Motion of Hollow Circular Cylinder (내부가 빈 원기둥의 수직운동 특성)

  • Bae, Yoon Hyeok;Cho, Il-Hyoung
    • Journal of Ocean Engineering and Technology
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    • v.27 no.5
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    • pp.43-50
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    • 2013
  • In the present investigation, the hydrodynamic characteristics of a vertically floating hollow cylinder in regular waves have been studied. The potential theory for solving the diffraction and radiation problem was employed by assuming that the heave response motion was linear. By using the matched eigenfunction expansion method, the characteristics of the exciting forces, hydrodynamic coefficients, and heave motion responses were investigated with various system parameters such as the radius and draft of a hollow cylinder. In the present analytical model, two resonances are identified: the system resonance of a hollow cylinder and the piston-mode resonance in the confined inner fluid region. The piston resonance mode is especially important in the motion response of a hollow circular cylinder. In many cases, the heave response at the piston resonance mode is large, and its resonant frequency can be predicted using the empirical formula of Fukuda (1977). The present design tool can be applied to analyze the motion response of a spar offshore structure with a moon pool.

Studies on the Application of High-Gloss Plastic Pigment for Paper Coating(I) (종이도공용 고광택 유기안료의 적용에 관한 연구 -유기안료의 종류가 도공지 품질에 미치는 영향-)

  • 이용규;박규재;정경모
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.32 no.3
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    • pp.32-38
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    • 2000
  • This study was carried out to determine the effect of the type of plastic pigment on the coat-ing structure and printability of coated paper. Three kinds of plastic pigments(solid-bead type binder type and hollow type) were used for hti purpose. IN this research it was observed that particle shape and structure of plastic pigment had influenced the rheology of coating color the state of packing and the properties of coated paper. Inorganic pigments used in this research were platelike kaolin clay and rhombic calcium carbonate. Three kinds of plastic pigments were blended with two inorganic pigments respec-tively. The combination of pigments were carried out(1) to determined the effect of particle structure of plastic pigment on the state of dispersion of coating color(2) to observe the effect of calendering temperature on the property of coated paper prepared with different plastic pigments. The data indicated that binder and hollow type plastic pigment gave the best results in improving the properties of coated paper such as paper gloss opacity and air pet-meability.

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A Study on the Fire Resistance Performance of RC Structure Void Slab Using The Lightweight Hollow Sphere (경량 중공체를 적용한 RC조 중공슬래브의 내화성능에 관한 연구)

  • Cho, Bum-Yean;Yeo, In-Hwan;Kim, Heung-Youl;Kim, Hyung-Jun;Kwon, In-Kyu
    • Fire Science and Engineering
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    • v.25 no.6
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    • pp.89-97
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    • 2011
  • This study is for evaluating the fire resistance performance (1~2 h) of the RC Structure void slab using the Lightweight Hollow Sphere, which can reduce the unnecessary dynamic part of removing the central concrete. For this experiment, we set up depth of concrete cover, live load, and span length as the factors. The result comes out with all the slabs under those conditions can ensure the goal fire resistance performance (120 min). And among these factors, the resisting capability changes more sensitively with the live load rather than the thickness of cover. And the shorter span length could assure the better the fire resistance performance. The result observing the character in high temperature of the Lightweight Hollow Sphere which does not used as existing RC structure slab, a delay section in temperature change is occurred due to the Glass Transition in $100^{\circ}C$. And heat transfer by conduction does not occur at lightweight hollow sphere because the polystyrene in EPS (Expanded Polystyrene) melts point in $185^{\circ}C$. Therefore temperature at lightweight hollow sphere is lower than the concrete and rebar.

Evaluation of The Nonlinear Seismic Behavior of a Biaxial Hollow Slab (2방향 중공슬래브 구조시스템의 비선형 지진거동 평가)

  • Park, Yong-Koo;Kim, Hyun-Su;Ko, Hyun;Park, Hyun-Jae;Lee, Dong-Guen
    • Journal of the Earthquake Engineering Society of Korea
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    • v.15 no.1
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    • pp.1-10
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    • 2011
  • Recently, there has been an increased interest in the noise isolation capacity of floor slabs, and thus an increase of slab thickness is required. In addition, long span floor systems are frequently used for efficient space use of building structures. In order to satisfy these requirements, a biaxial hollow slab system has been developed. To verify the structural capacity of a biaxial hollow slab system, safety verification against earthquake loads is essential. Therefore, the seismic behavior of a biaxial hollow slab system has been investigated using material nonlinear time history analyses. For efficient time history analyses, the equivalent plate element model previously proposed was used and the seismic capacity of the example structure having a biaxial hollow slab system has been evaluated using the nonlinear finite element model developed by the equivalent frame method. Based on analytical results, it has been shown that the seismic capacity of a biaxial hollow slab system is not worse than that of a flat plate slab system with the same thickness.

Development of Ceramic Hollow Fiber Membrane Contactor Modules for Carbon Dioxide Separation (이산화탄소 분리용 세라믹 중공사 접촉막 모듈 기술 개발)

  • Lee, Hong Joo;Che, Jin Woong;Park, Jung Hoon
    • Journal of Climate Change Research
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    • v.7 no.3
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    • pp.249-256
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    • 2016
  • Porous $Al_2O_3$ hollow fiber membranes were successfully prepared by dry-wet spinning/sintering method. The SEM image shows that the $Al_2O_3$ hollow fiber membrane consists mostly of sponge pore structure. The contact angle and the breakthrough pressure were $126^{\circ}$ and 1.91 bar, respectively. This results indicate that the $Al_2O_3$ hollow fiber membranes were successfully modified to hydrophobic surface. The hydrophobic modified $Al_2O_3$ hollow fiber membranes were assembled into a membrane contactor system to separate $CO_2$ from a model gas mixture of the flue gas at elevated gas velocity. The $CO_2$ absorption flux was enhanced when the gas velocity increased from $1{\times}10^{-3}$ to $6{\times}10^{-3}$ m/s. Whereas the $CO_2$ absorption flux was decreased with the number of hollow fiber membrane of a module because of the concentration polarization. Furthermore, we developed an lab-scale $Al_2O_3$ hollow fiber membrane contactor modules and their system (i.e., $CO_2$ absorption using the $Al_2O_3$ membrane and monoethanolamine (MEA)) that could dispose of over $0.02Nm^3/h$ mixture gas (15% $CO_2$) with the removal efficiency higher than 95%. The results can be useful in a field of the membrane contactor for $CO_2$ separation, helping to design and extend a equipment.

Improvement in Mechanical Strength of α-Alumina Hollow Fiber Membrane by Introducing Nanosize γ-Alumina Particle as Sintering Agent (소결조제로 나노크기 γ-알루미나 입자의 도입에 따른 α-알루미나 중공사 분리막의 기계적 강도 향상)

  • Kim, Yong-Bin;Kim, Min-Zy;Arepalli, Devipriyanka;Cho, Churl-Hee
    • Membrane Journal
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    • v.32 no.2
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    • pp.150-162
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    • 2022
  • In the field of water treatment and pharmaceutical bio an alumina hollow fiber membrane used for mixture separation. However, due to the lack of strengths it is very brittle to handle and apply. Therefore, it is necessary to study and improve the bending strength of the membrane to 100 MPa or more. In this study, as the mixing ratio of the nano-particles increased to 0, 1, 3, and 5 wt%, the viscosity of the fluid mixture increased. The pore structure of the hollow membrane produced by interrupting the diffusion exchange rate of the solvent and non-solvent during the spinning process suppresses the formation of the finger-like structure and gradually increases the ratio of the sponge-like structure to improve the membrane mechanical strength to more than 100 MPa. As a result, an interparticle space was ensured to improve the porosity of the sponge-like structure with high permeability, and it showed excellent N2 permeability of about 100000 GPU and high water permeability of 3000 L/m2 h. Therefore, it can be concluded, that the addition of γ-Al2O3 nanoparticles as sintering aid is an important method to enhance the mechanical strength of the α-alumina hollow fiber membrane to maintain high permeability.