• 제목/요약/키워드: hole transfer layer

검색결과 65건 처리시간 0.022초

수열합성법으로 제막한 MoO3 나노 구조체를 정공수송층으로 갖는 페로브스카이트 태양전지 특성분석 (Characteristics of Perovskite Solar Cell with Nano-Structured MoO3 Hole Transfer Layer Prepared by Hydrothermal Synthesis)

  • 송재관;안준섭;한은미
    • 한국재료학회지
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    • 제30권2호
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    • pp.81-86
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    • 2020
  • MoO3 metal oxide nanostructure was formed by hydrothermal synthesis, and a perovskite solar cell with an MoO3 hole transfer layer was fabricated and evaluated. The characteristics of the MoO3 thin film were analyzed according to the change of hydrothermal synthesis temperature in the range of 100 ℃ to 200 ℃ and mass ratio of AMT : nitric acid of 1 : 3 ~ 15 wt%. The influence on the photoelectric conversion efficiency of the solar cell was evaluated. Nanorod-shaped MoO3 thin films were formed in the temperature range of 150 ℃ to 200 ℃, and the chemical bonding and crystal structure of the thin films were analyzed. As the amount of nitric acid added increased, the thickness of the thin film decreased. As the thickness of the hole transfer layer decreased, the photoelectric conversion efficiency of the perovskite solar cell improved. The maximum photoelectric conversion efficiency of the perovskite solar cell having an MoO3 thin film was 4.69 % when the conditions of hydrothermal synthesis were 150 ℃ and mass ratio of AMT : nitric acid of 1 : 12 wt%.

유기발광소자의 막두께 및 음극전극의 변호에 따른 발광특성 (EL Properties of the Organic Light-Emitting-Diode with various Thickness and Cathode Electrode)

  • 김형권;이덕출
    • 한국전기전자재료학회논문지
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    • 제11권10호
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    • pp.897-902
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    • 1998
  • We prepared Organic LED with a two layer structure by vacuum evaporation. The diode consisted of hole transfer layer (thickness of 30, 50, 70 nm) and electron transfer layer (thickness of 70, 50, 30 nm) material, which was N, N'-diphenyl- N, N'-bis-(3-methyl phenyl)-1,1'-diphenyl-4,4'-diamine)(TPD) and tris(8-hydroxy quinoline) aluminum(Alq3), respectively. We investigated EL properties of the LED with various thickness and cathode electrode. The best results were obtained when thickness of the electron layer is equal to that of emission layer and when AlLi alloy was used as a cathode. The EL intensity, luminance and efficiency of organic LED with equal of layer thick were improved seven, three and two times, respectively. Alq3 was ionized by carrier injection from cathode and could produce exitons. After electron-hole pairs were formed by combination of the electrons and holes at the emission layer, Alq3 layer emitted light.

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정공전달고분자와 유기형광염료의 혼합물 박막이 이용된 발광소자의 에너지 전달특성 연구 (Studies on the Energy Transfer in LED Containing the Layer made of the Blends of Hole Transporting Polymer and Organic Phosphorescent Dye)

  • 김유진;정숙
    • 한국전기전자재료학회논문지
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    • 제17권11호
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    • pp.1192-1198
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    • 2004
  • Hole transporting polymer(poly[N-(p-diphenylamine)phenylmethacrylamide], PDPMA) was doped with nile red dye at various concentrations to study the influence of doping on the energy transfer during light emitting processes. Organic LEDs composed of ITO/blend(PDPMA -nile red)/ Alq$_3$/Al as well as thin films of blend(PDPMA -nile red)/ Alq$_3$ were manufactured for investigating photoluminescence, electroluminescence, and current-voltage characteristics. Atomic Force Microscopy was also used to observe surface morphology of the blend films. It was found that such doping. significantly influences the efficiency of the energy transfer from the Alq$_3$ layer to blended layer and the optical/electrical properties could be optimized by choosing the right concentration of the dye molecule. The results also showed a interesting correlation with the morphological aspect, i.e. the optimum luminescence at the concentration with the least surface roughness. When the concentration of nile red was 0.8 wt%, the maximum energy transfer could be achieved.

HTL:EML(DPVBi:NPB)층의 조성비 변화에 따른 청색 유기 발광 소자 개발 (Development of Blue Organic Light-emitting Diodes(OLEDs) Due to Change in Mixed Ratio of HTL:EML(DPVBi:NPB) Layers)

  • 이태성;이병욱;홍진수;김창교
    • 한국전기전자재료학회논문지
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    • 제21권9호
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    • pp.853-858
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    • 2008
  • The structure of organic light-emitting diodes(OLEDs) with typical heterostructure consists of anode, hole injection layer, hole transport layer, light-emitting layer, electron transport layer, electron injection layer, and cathode. 4,4bis[N-(1-napthyl)-N-phenyl-amino]-biphenyl(NPB) used as a hole transport layer and 4'4-bis(2,2'-diphenyl vinyl)-1,1'-biphenyl(DPVBi) used as a blue light emitting layer were graded-mixed at selected ratio. Interface at heterojunction between the hole transport layer and the elecrtron transport layer restricts carrier's transfer. Mixing of the hole transport layer and the emitting layer reduces abrupt interface between the hole transport layer and the electron transport layer. The operating voltage of OLED devices with graded mixed-layer structure is 2.8 V at 1 $cd/m^2$ which is significantly lower than that of OLED device with typical heterostructure. The luminance of OLED devices with graded mixed-layer structure is 21,000 $cd/m^2$ , which is much higher than that of OLED device with typical heterostructure. This indicates that the graded mixed-layer enhances the movement of carriers by reducing the discontinuity of highest occupied molecular orbital(HOMO) of the interface between hole transport layer and emitting layer.

DCJTB를 Doping한 적색 유기 발광소자의 특성 (Characteristics of the red organic electroluminescect devices doped with DCJTB)

  • 최완지;임민수;정득영;이정구;임기조
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2002년도 하계학술대회 논문집 Vol.3 No.2
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    • pp.1034-1037
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    • 2002
  • In this study, we fabricated red organic electrolu-minescent device with a doping material (DCJTB), and The cell structure used ITO:indium tin oxide $[20{\Omega}]$/CuPc:Hole injection layer 20nm/NPB: Hole transfer layer 40nm/$Alq_3$ (host) + DCJTB(1% or 3%) (guest) Emitting layer 40nm/$Alq_3$ : Electron transfer layer 30nm/Al :Cathode layer 150nm. the luminescent layer consisted of a host material. 8-hydrozyquinoline aluminum $(Alq_3)$, and DCJTB dye as the dopant. a stable red emission (chromaticity coordinates : x=0.64, y=0.36) was obtained in this cell with the luminance range of $100-600cd/m^2$. we study the electrical and optical properties of devices.

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종방향 와동이 유체유동 및 열전달 특성에 미치는 영향에 관한 실험적 연구 (An Experimental Study on the Effect of Fluid Flow and Heat Transfer Characteristics by the Longitudinal Vortices)

  • 양장식;김은필
    • 설비공학논문집
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    • 제12권9호
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    • pp.843-852
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    • 2000
  • The flow characteristics and the heat transfer rate on a surface by interaction of a pair of vortices were studied experimentally. The test facility consisted of a boundary-layer wind tunnel with a vortex introduced into the flow by half-delta winglet protruding from the surface. In order to control the strength of the longitudinal vortices, the angles of attack of the vortex generators were varied from $\pm20\;degree\;to\;\pm45$ degree, but spacings between the vortex generators were fixed to 4 cm. The 3-dimensional mean velocity measurements were made using a five-hole pressure probe. Heat transfer measurements were made using the thermochromatic liquid to provide the local distribution of the heat transfer coefficient. By using the method mentioned above, the following conclusions were obtained from the present experiment. The boundary layer was thinned in the regions where the secondary flow was directed toward the wall and thickened where it was directed away from the wall. The peak augmentation of the local heat transfer coefficient occurred in the downwash region near the point of minimum boundary-layer thickness.

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반대방향의 방향각을 갖는 2열 분사구조의 막냉각 특성(I) -배열의 영향- (Film Cooling from Two Rows of Holes with Opposite Orientation Angles(I) -Configuration Effect-)

  • 안준;정인성;이준식
    • 대한기계학회논문집B
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    • 제25권8호
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    • pp.1122-1130
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    • 2001
  • Film cooling performance from two rows of holes with opposite orientation angles is evaluated in terms of heat flux ratio. The film cooling hole has a fixed inclination angle of 35°and orientation angle of 45°for the downstream row and -45°for the upstream row. Four film cooling hole arrangements including inline and staggered configurations are investigated. The blowing ratio studied was 1.0. Boundary layer temperature distributions are measured to investigate injectant behaviors and mixing characteristics. Detailed distributions of the adiabatic film cooling effectiveness and the heat transfer coefficient are measured using TLC(Thermochromic Liquid Crystal). For the inline configuration, there forms a downwash flow at the downstream hole exit to make the injectant well attach to the wall, which gives high adiabatic film cooling effectiveness and heat transfer coefficient. The evaluation of heat flux ratio shows that the inline configuration gives better film cooling performance with the help of the downwash flow at the downstream hole exits.

Multi Quantum Well 구조를 이용한 Red에서 Green으로의 energy transfer mechanism의 이해

  • 김강훈;박원혁
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2015년도 제49회 하계 정기학술대회 초록집
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    • pp.145-145
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    • 2015
  • 처음 유기물의 인광 발견 이후 Host-dopant 시스템을 이용하여 Emission layer(EML)을 Co-deopsition 하는 방법으로 주로 인광 유기 발광 다이오드를 제작 하였다. [1] co-deposition을 이용해 만든 유기 발광 다이오드에 많은 장점이 있지만, 반대로 소자를 제작하는데 있어서는 많은 문제점을 가지고 있다. [2-4] 이러한 문제점을 개선하기 위하여 co-deposition 대신 non-doped Multi Quantum Well(MQW) 구조를 사용하여 doping 하지 않는 방법을 이용하는 논문들이 보고 되고 있다. Hole, electron, exciton이 MQW 구조를 지나면서, dopant well 안에 갇히게 되고, 그 안에서 다른 layer 간에 energy transfer와, hole-electron leakage가 줄어 들어, 더 효율적인 유기 발광 다이오드를 만들 수 있게 된다. [5-7] 이 연구에서는 CBP를 Potential Barrier로 사용하고, Ir(ppy)3 (Green dopant), Ir(btp)2 (Red dopant) 를 각각 Potential Well로 사용하였고, 두께는 CBP 9nm, dopant 1nm로 하였다. 이러한 소자를 만들고 dopant를 3개의 well에 적당히 배치하여, 각 well에서의 실험적인 발광 량 과, EML 안에서의 발광 mechanism 그리고 각 potential barrier를 줄여가며 dexter, forster에 의한 energy transfer에 대하여 알 수 있었다.

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더블 전자 층 간의 상호관계와 드래그 현상

  • 이가영
    • 세라미스트
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    • 제21권2호
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    • pp.19-28
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    • 2018
  • Coulomb drag is an effective probe into interlayer interaction between two electron systems in close proximity. For example, it can be a measure of momentum, phonon, or energy transfer between the two systems. The most exotic phenomenon would be when bosonic indirect excitons (electron-hole pairs) are formed in double layer systems where electrons and holes are populated in the opposite layers. In this review, we present various drag phenomena observed in different double layer electron systems, e.g. GaAs/AlGaAs heterostructures and two-dimensional material based heterostructures. In particular, we address the different behavior of Coulomb drag depending on its origin such as momentum or energy transfer between the two layers and exciton condensation. We also discuss why it is difficult to achieve electron-hole pairs in double layer electron systems in equilibrium.

TPD 첨가에 따른 poly(3-alkylthiophene)의 발광특성 (Emission Characteristics of Poly(3-alkylthiophene) with TPD Addition)

  • 서부완;김주승;구할본;이경섭;박복기;조재철
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2000년도 하계학술대회 논문집
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    • pp.308-311
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    • 2000
  • The organic electroluminescene (EL) device has gathered much interested because of its potential in materials and simple device fabrication. We fabricated EL device which have a mixed single emitting layer containing N,N'-diphenyl-N,N'-(3-methylphenyl)-1,1'-biphenyl-4,4'-diamine [TPD] and poly(3-hexylthiophene) [P3HT]. The molar ratio between P3HT and TPD chaged with 1:1, 3:1, 5:1, 3:2 and 5:2. EL intensity of ITO/P3HT+TPD/Mg:In devices is enhanced by addition of TPD into P3HT. This can be explained that the energy transfer occurs from TPD to P3HT. Recombination probability increases in emitting layer because that TPD as hole transport material plays a role more injection hole and Mg:In (3.7eV) electrode has low work function make easily electron injection. ITO/P3HT+TPD(5:2)/Mg:In devices emit orange-red light at 28V.

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