• 제목/요약/키워드: hole injection layer

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Rubrene/GDl 4234 Dual 도펀트를 이용한 적색 유기발광다이오드 (Red Organic LED with Dual Dopants of Rubrene and GDI 4234)

  • 장지근;강의정;김희원;신세진;공명선;임성규;오명환
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2005년도 추계학술대회 논문집 Vol.18
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    • pp.309-310
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    • 2005
  • In the fabrication of high performance red organic light emitting diode, 2-TNA TA [4,4',4" -tris (2-naphthylphenyl- phenylamino)-triphenylamine] as hole injection material and N PH [N,N'-bis (1-naphthyl) -N,N' -diphenyl-1, 1'-biphenyl-4,4'- diamine] as hole transport material were deposited on the ITO (indium tin oxide)/glass substrate by vacuum evaporation, And then, red color emission layer was deposited using Alq3 as a host material and Rubrene (5,6,11,12- tetraphenylnaphthacene) and GDI 4234 as dopants. Finally, small molecular weight OLED with the structure of ITO/2-TNATA/ NPB/Alq3+Rubrene+GDI4234/Alq3/LiF/Al was obtained by in-situ deposition of Alq3, LiF and Al as electron transport material, electron injection material and cathode. respectively. Green OLED fabricated in our experiments showed the color coordinate of CIE(0.65,0.35) and the maximum luminescence efficiency of 2.1 lm/W at 7 V with the peak emission wavelength of 632 nm.

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GDI 호스트-도펀트 형광체를 이용한 청색 OLED의 제작과 특성 평가 (Fabrication and Characterization of Blue OLED using GDI Host-Dopant Phosphors)

  • 장지근;신세진;강의정;김희원;장호정;오명환;김영섭;이준영;공명선;이영관
    • 한국재료학회지
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    • 제16권4호
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    • pp.253-256
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    • 2006
  • The blue emitting OLEDs using GDI host-dopant phosphors have been fabricated and characterized. In the device fabrication, 2-TNATA [4,4',4'-tris(2-naphthylphenyl-phenylamino)- triphenylamine] as a hole injection material and NPB [N,N'-bis(1-naphthyl)-N,N'-diphenyl-1,1'-biphenyl-4,4'-diamine] as a hole transport material were deposited on the ITO(indium thin oxide)/glass substrate by vacuum evaporation. And then, blue color emission layer was deposited using GDI602 as a host material and GDI691 as a dopant. Finally, small molecule OLEDs with structure of ITO/2-TNATA/NPB/GDI602:GDI691/Alq3/LiF/Al were obtained by in-situ deposition of Alq3, LiF and Al as the electron transport material, electron injection material and cathode, respectively. Blue OLEDs fabricated in our experiments showed the color coordinate of CIE(0.14, 0.16) and the maximum power efficiency of 1.1 lm/W at 11 V with the peak emission wavelength of 464 nm.

TMP-BiP 호스트와 DJNBD-1 도펀트를 이용한 청색 OLED의 제작과 특성평가 (Fabrication and Characterization of Blue OLED using TMP-BiP Host and DJNBD-1 Dopant)

  • 장지근;안종명;신상배;장호정;공수철;신현관;공명선;이칠원
    • 반도체디스플레이기술학회지
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    • 제6권2호
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    • pp.19-23
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    • 2007
  • The blue emitting OLEDs using TMP-BiP[(4'-Benzoylferphenyl-4-yl)phenyl-methanone-Diethyl(biphenyl-4-ymethyl) phosphonate] host and DJNBD-1 dopant have been fabricated and characterized. In the device fabrication, 2-TNATA [4,4',4"-tris(2-naphthylphenyl-phenylamino)-triphenylamine] as a hole injection material and NPB [N,N'-bis(1-naphthyl)N,N'-diphenyl-1,1'-biphenyl-4,4'-diamine] as a hole transport material were deposited on the ITO(indium tin oxide)/glass substrate by vacuum thermal evaporation method. Followed by the deposition, blue color emission layer was deposited using TMP-BiP as a host material and DJNBD-1 as a dopant. Finally, small molecule OLEDs with structure of $ITO/2-TNATA/NPB/TMP-BiP:DJNBD-l/Alq_3/LiF/Al$ were obtained by in-situ deposition of $Alq_3$, LiF and Al as the electron transport material, electron injection material and cathode, respectively. The effect of dopant into host material of the blue OLEDs was studied. The blue OLEDs with DJNBD-1 dopant showed that the maximum current and luminance were found to be about 34 mA and $8110\;cd/m^2$ at 11 V, respectively. In addition, the color coordinate was x=0.17, y=0.17 in CIE color chart, and the peak emission wavelength was 440 nm. The maximum current efficiency of 2.15 cd/A at 7 V was obtained in this experiment.

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Flow and Heat Transfer Measurements of Film Injectant from a Row of Holes with Compound Angle Orientations

  • Bumsoo Han;Sohn, Dong-Kee;Lee, Joon-Sik
    • Journal of Mechanical Science and Technology
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    • 제16권9호
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    • pp.1137-1146
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    • 2002
  • An experiment has been conducted on the flow and heat transfer characteristics of film coolant injected from a row of five holes with compound angle orientations of 35$^{\circ}$ inclination angle and 45$^{\circ}$ orientation angle. The Reynolds number based on the mainstream velocity and injection hole diameter 3.58${\times}$10$^4$. Three-dimensional velocity, film cooling effectiveness and heat transfer coefficient data are presented at three different mass flux ratios of 0.5, 1.0 and 2.0. Flow entrainment has been found between the vortices generated by adjacent injectants. The injectant with compound angle orientation entrains not only the mainstream boundary layer flow but also the adjacent injectant. Because of the flow entrainment, the injectant. With compound angle orientation is characterized by a single vortex while two bound vortices are usually observed in the case of simple angle injection. The strength of the secondary flow depends strongly on the mass flux ratio, which shows significant influence on the film cooling effectiveness and heat transfer coefficient.

ITO 기판의 Aquaregia 처리에 의한 녹색발광 OLED의 효율 향상 연구 (Efficiency Improvement of Green Emitting OLED by Aquaregia Treatment of ITO Substrate)

  • 최규채;김동은;김병상;권영수
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2008년도 제39회 하계학술대회
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    • pp.1291-1292
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    • 2008
  • ITO is widely used as an anode material in OLED, because of its good transparency, low electrical resistivity, high work function, and efficient hole injection properties. The interface between the electrode and the organic layer in the OLED effects the charge injection process and may influence the electrical and the luminance properties. Surface treatment of ITO, such as an Aquaregia treatment has been shown to enhance the efficiency, and luminance characteristics of the OLED. In this study, we investigated the effect of Aquaregia treatment. The fundamental structures of the OLED were ITO/NPB/$Alq_3$/LiF/Al. The current density-voltage-luminance, efficiency, and lifetime characteristics were measured with untreated and Aquaregia-treated ITO substrates. The Aquaregia treatment was found to enhance the performance of OLED. For the Aquaregia treated device, the maximum luminance and efficiency were increased by about 2 times compared to the untreated device. The mechanism of the Aquaregia treatment is discussed based on AFM analyses.

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플라스틱 기판상에 적색 OLED 제작과 특성 연구 (Fabrication and Characterization of Red OLED on the Plastic Substrate)

  • 정진철;김형석;김원기;장지근
    • 반도체디스플레이기술학회지
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    • 제8권4호
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    • pp.15-19
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    • 2009
  • A high efficient organic red light emitting device with structure of DNTPD/TAPC/$Bebq_2$ :[$(pq)_2Ir(acac)$, SFC-411]/SFC-137 was fabricated on the plastic substrate, which can be applied in the fields of flexible display and illumination. In the device structure, N,N'-diphenyl-N,N'-bis-[4-(phenyl-m-tolylamino)-phenyl]-biphenyl-4,4'-diamine[DNTPD] as a hole injection layer and 1,1-bis-(di-4-tolylaminophenyl) cyclohexane [TAPC] as a hole transport were used. Bis(10-hydroxybenzo[h]quinolinato) beryllium complex [$Bebq_2$] was used as a light emitting host material. The host material, $Bebq_2$ was doubly doped with volume ratio of 7% iridium(III)bis-(2-phenylquinoline)acetylacetonate[$(pq)_2$Ir(acac)] and 3% SFC-411[red phosphor dye coded by the proprietary company]. And then, SFC-137 was used as an electron transport layer. The luminous intensity and current efficiency of the fabricated device were $22,780\;cd/m^2$ at 9V and 17.3 cd/A under $10,000\;cd/m^2$, respectively. The maximum current efficiency of the device was 22.4cd/A under $580\;cd/m^2$.

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Efficient White Organic Light-Emitting Diodes (WOLEDs) with Device Structure Modification

  • Kim, Jun-Ho;Seo, Ji-Hoon;Seo, Ji-Hyun;Hyung, Gun-Woo;Lee, Kum-Hee;Yoon, Seoung-Soo;Kim, Young-Kwan
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2007년도 7th International Meeting on Information Display 제7권2호
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    • pp.1403-1406
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    • 2007
  • An effective WOLED structure was demonstrated which improved a luminous efficiency and white color chromaticity independent on applied bias by employing effective carrier transporting layer, without any alteration of emissive materials. The modified WOLEDs exhibited 2 times higher luminous efficiency than the control device and showed balanced white emission during an operation.

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High-Efficiency Inverted Transparent Blue Organic Light-Emitting Devices

  • Chen, Szu-Yi;Chu, Ta-Ya;Chen, Chao-Jung;Chen, Jenn-Fang;Chen, Chin H.
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2006년도 6th International Meeting on Information Display
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    • pp.984-986
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    • 2006
  • We report efficient inverted transparent blue OLEDs (ITOED) with an hole injection layer prepared by co-evaporation of $WO_3$ with NPB, which achieved a total current efficiency of 10.7 cd/A at $20mA/cm^2$ with light emits from both ITO bottom cathode and Au top anode in about 3:1 ratio.

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정공 버퍼층(PTFE) 두께에 변화에 따른 유기발광소자의 전압-전류-휘도효율 특성 (Voltage-Current-Luminance Efficiency Characteristics of Organic Lighting-Emitting Diodes with the Variation of Hole-Injection Buffer Layer(PTFE) Thickness)

  • 김원종;양재훈;김태완;홍진웅
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2004년도 추계학술대회 논문집 전기물성,응용부문
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    • pp.86-88
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    • 2004
  • 정공주입 버퍼층(PTFE)두께에 변화에 따른 유기발광소자 전압-전류-휘도 효율을 측정한 결과 ITO/PTFE/Al 구조에서 두께가 증가하면 전류 밀도 및 전압이 증가하며, 두께가 0.7 (nm)일 때 부성 저항 영역이 나타났었고, ITO/PTFE/NPB/$Alq_3$/Al 구조에서 두께가 1.0 [nm]에서는 가장 좋은 휘도와 효율을 나타났었다. 두께가 증가하면 이것은 PTFE 내의 정공의 이동을 어렵게 하기 때문에 효율이 감소하는 것으로 판단된다. 그래서 적당한 PTFE 두께만이 가장 좋은 휘도와 효율을 얻을 수가 있다.

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Mechanism of workfunction modification on HAT-CN/Cu(111) interface: ab initio study

  • Kim, Ji-Hoon;Park, Yong-Sup;Kwon, Young-Kyun
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2009년도 제38회 동계학술대회 초록집
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    • pp.357-357
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    • 2010
  • Using ab initio density functional theory, we study the structural and electronic properties of interface between Cu surface and highly electron withdrawing hexaazatriphenylene-hexanitrile (HAT-CN) known as an efficient hole injection layer for organic light emitting diodes (OLEDs). We calculate the equilibrium geometries of the interface with different HAT-CN coverages. Usually, some of C-N bonds located at the edge of the HAT-CN molecule are deformed toward Cu atoms resulting in the reconstruction of Cu surface. By analyzing the electron charge and the potential distributions over the interface, we observe the formation of surface dipoles, which modify the work function at the interface. Such dipole formation is attributed to two origins, one of which is a geometrical nature and the other is a bond dipole. The former is related to structural deformation mentioned above, whereas the latter is due to charge transfer between organic and metal surface.

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