• Title/Summary/Keyword: higher order solution

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Study on congestion of the gills in cultured eels Anguilla japonica III. Effect of NaCl treatment on congestion of the gills in cultured eels, Anguilla japonica (뱀장어 아가미 울혈증에 관한 연구 III. NaCl처리가 울혈증 치료에 미치는 영향)

  • Choi, Min-Soon;Park, Kwan-Ha;Choi, Sang-Hoon;Kim, Young-Gill;Kim, Jong-Myeon;Cho, Jeong-Gon;Jang, Seon-Il
    • Journal of fish pathology
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    • v.8 no.2
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    • pp.111-118
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    • 1995
  • This experiment was carried out in order to elucidate the effect of NaCl(0.85%) acclimation on congestion symptoms in central venous sinuses(CVS) of gill filaments and on the alteration of blood constituents in cultured eels for 1, 2, 3, 4, 5, 6 and 7days after handling stress. After giving a handling stress on eels, the frequency of gill congestion was about 90%. It gradually decreased to 40% on the 3rd day, then increased to 60% on the 7th day in NaCl(0.85%) acclimation. The values of haematocrit(Ht), methemoglobin(Met-Hb), glucose (GLU), calcium($Ca^{++}$), lactic dehydrogenase(LDH), glutamic pyruvic transaminase (GPT) and glutamic oxaloacetic transaminase(GOT) were lower than those of the control, whereas magnesium($Mg^{++}$) and haemoglobin(Hb) were higher than the control. However total protein(Tp) and albumin (ALB) levels similar to the control. When the fish after giving a handling stress were cultured in NaCl-free water as a control, the frequency of gill congestion and the value of blood components showed a similar pattern to that obtained from the NaCl acclimated experiments. However, in the early period(1-3day) after handling stress, NaCl acclimating slightly helped the natural tendancy of recovery. These results suggest that the frequency of gill congestion is not always reduced over the whole period of NaCl acclimation. However, the acclimation to NaCl solution may be a somewhat useful therapy for the gill congestion in stressed eels.

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Influences of Protease on the Removal of Protein Soils from Cotton Fabrics -Emphasis on the Characteristics of Enzyme and Soil Substrates- (단백질 분해 효소가 세척에 미치는 영향 -효소와 오염 기질의 특성을 중심으로-)

  • Lee, Jeong Sook;Shim, Yun Jeong
    • Journal of the Korean Society of Clothing and Textiles
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    • v.17 no.3
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    • pp.491-505
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    • 1993
  • The influences of protease on the removal of various protein soils from cotton fabrics were studied. The human epidermal stratum corneum, hemoglobin and casein were used as protein soils. The soiled fabrics were denatured by steaming for 30 min. before washing and laundered using Terg-O-Tometer under washing conditions. The removal efficiency was evaluated by analysis of protein on the fabrics before and after washing by means of copper-Folin method. The relations between the removal and the characteristics of protease were discussed. Also the degradation of protein were examined by microscopy. The seperation of human epidermal stratum corneum after hydrolysis was examined by SDS-PAGE. The results obtained were as follow : 1. The protein from the soiled cotton fabric was removed effectively by adding protease. The removal of protein was increased in proportion to increasing of the enzyme concentration up to a certain point, but it began to decrease above the point. The removal effect was high in the order of casein>human epidermal stratum corneum>hemoglobin. Especially the protein was more effectively removed in ADS solution(pH 9.5) containing enzyme. 2. When protease was used with ADS. the removal of protein was efficiently showed in relatively short time(5~15min.) compared to using ADS only. It is due to the properties of this enzyme that reacts with very short time. 3. Even at low temperature the removal efficiency of enzyme was relatively higher compared with the activity of enzyme. The removal of protein soil was increased up to a maximum near $50^{\circ}C$, and then decreased. 4. The removal of protein by protease was improved with the increase of alkalinity in the pH range from 9.5 to 11.0 but it began to decrease above pH 11.0. 5. According to the increase of mechanical agitation, the removal effect was increased. But the removal efficiency of protease was more effective compared with the agitation in detergency. 6. According to the SDS-PAGE separation and micrograph it was confirmed that the human epidermal corneum was effectively hydrolysed by the enzyme added. So the fragments of protein were removed more efficiently by means of the interfacial reaction of AOS.

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Preparation of Porous Polyacrylonitrile Nanofibers Membrane for the MF Application (MF 적용을 위한 다공성 PAN 나노섬유막의 제조)

  • Ahn, Hyeonryun;Jang, Wongi;Tak, Taemoon;Byun, Hongsik
    • Membrane Journal
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    • v.23 no.2
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    • pp.112-118
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    • 2013
  • Polyancrylonitrile nanofiber membrane (PAM) was prepared by using the electrospinning method with a solution of polyacrylonitrile (PAN) in DMF. The pore-diameter of PAMs and the number of PAM's layer were controlled for the microfiltration (MF) application. In addition, in order to improve the water-flux, AN-PEGMA copolymers have been synthesized via free radical polymerization with poly (ethylene glycol) methyl ether methacrylate and azobisisobutylronitrile (AIBN), and then PAN/AN-PEGMA nanofiber membranes (PAM/APM) were prepared by electrospinning with a mixture of PAN (9 wt%) and AN-PEGMA (3 wt%) in DMF (88 wt%). The prepared membranes were investigated with FT-IR and E.D.S. It was confirmed through scanning electron microscope (SEM), porometer, and porosity analysis that the porous membrane with a uniform diameter (400~600 nm) and a uniform pore characteristics (0.5~0.4 ${\mu}m$) was prepared. For the MF application, water-flux measurements were investigated and then the result was shown that the water permeability value of PAM/APMs introduced AN-PEGMA copolymers was relatively higher than that of the PVdF commercial membrane. From these results, PAN nanofiber membranes prepared by electrospinning could be utilized as a MF membrane.

Migration and Enrichment of Arsenic in Rock-Soil-Crop Plant System in Areas Covered with Black Shale and Slates of Okchon Zone (옥천대 흑색셰일 및 점판암 분포지역 암석-토양-농작물 시스템에서의 As및 관련 원소들의 분산과 이동)

  • 이지민;전효택
    • Economic and Environmental Geology
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    • v.36 no.4
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    • pp.295-304
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    • 2003
  • The Dukpyung and the Chubu areas were selected to investigate the migration and enrichment of arsenic and other toxic elements in soils and crop plants in areas covered with black shales. Rock and soil samples digested in 4-acid solution (HCI+HNO$_3$+HF+HC1O$_4$) were analyzed fer arsenic and other heavy metals by ICP-AES and ICP-MS, and plant samples by INAA. Mean concentration of As in Okchon black shale is higher than those of both world average values of shale and black shale. Especially high concentration of 23.2 mg/kg As is found in black shale from the Dukpyung area. Mean concentration of As is highly elevated in agricultural soils from the Duk-pyung (28.2 mg/kg) and the Chubu areas (32.6 mg/kg). Arsenic is highly elevated in rice stalks and leaves from the Dukpyung (1.14 mg/kg) and the Chubu areas (1.35 mg/kg). The biological absorption coefficient (BAC) of As in plant species decreases in the order of rice leaves>com leaves>red pepper>soybean leaves=sesame leaves>corn stalks>corn grains.

An Analysis of the Application Technology of Heat Recovery System from Dyeing Wastewater (염색폐수 열회시스템 적용기술 분석)

  • 장기창;박성룡;이상남;라호상;박준택;함성원;박영태
    • Journal of Energy Engineering
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    • v.10 no.3
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    • pp.195-205
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    • 2001
  • A great deal of energy is necessary with emission of lots of wastewater in dyeing and finishing process, but heat recovery from wastewater is not introduced since is technology is not developed yet. In order to obtain the method utilizing hot water produced by heat source, that is, dyeing wastewater it was investigated the characteristics of dyeing and finishing process and energy basic unit. Energy basic unit of polyester/cotton (T/C), polyester/rayon (T/R) and polyester dyeing process are higher than that of the other process. The average quantity of wastewater for each dyeing company is 20,470 ton/month, the average temperature of wastewater is about 41$^{\circ}C$. Because the SS solution of wastewater in polyester dyeing process is lower than that of the other process, the effect of corrosion in heat recovery system is low. Since the energy price for 1000 kcal produced by vapor compression heat pump is presumed to be 22.50 won, it is found to be very economic heat recovery system, and its payback is 2.09 years for the factory with LNG boiler.

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Color Sensibility Factors for Yellowish and Reddish Natural Dyed Fabrics by 40s Middle-Aged Consumers (황색과 적색계열 천연염색 직물에 대한 사십대 중년층 소비자의 색채감성요인)

  • Yi, Eun-Jou;Choi, Jong-Myoung
    • Science of Emotion and Sensibility
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    • v.12 no.1
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    • pp.109-120
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    • 2009
  • This study was carried out in order to investigate color sensation and sensibility for yellowish natural dye fabrics and reddish ones and to establish prediction models for color sensibility factors of them by color sensation and the related physical measurements focusing on 40s middle-aged people. Eight fabric stimuli which were dyed with a variety of yellowish or reddish natural dyes was subjectively evaluated in terms of color sensation and sensibility by 40s aged participants. As results, three color sensibility factors including 'Active', 'Characteristic', and 'Relax' were extracted and they were examined in respect of their relationships with color sensation and physical color properties. Color sensibility factor 'Active', the dominant factor for the naturally dyed fabrics was explained by $L^*$ and sensation 'Deep' in its predictive model and a yellowish fabric dyed with 300% solution of armur cork unmordanted was perceived the strongest in the factor. Factor 'Characteristic' was predicted by both $a^*$ and sensation 'Light' and reddish natural dye fabrics tended to be felt more strongly for it. Color sensation 'Strong' was the only predictor for factor 'Relax' in that naturally dyed fabrics with lower values for the sensation seemed to show higher 'Relax' factor and a reddish fabric dyed with safflower 125% was the highest for the color sensibility factor. These results could be utilized to design color-sensible natural dye fabrics for middle-aged people.

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Synthesis of Polyamine Type Flocculant and Properties in Potable Water Treatment (Polyamine계 고분자 응집제의 합성 및 상수 처리 특성)

  • Park, Lee-Soon;Shin, June-Ho;Choi, Sang-June;Shin, Myung-Chul;Lee, Seok-Hun
    • Applied Chemistry for Engineering
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    • v.9 no.4
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    • pp.542-547
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    • 1998
  • Polyamine type polymer flocculants were synthesized and their characterization, viscosity and flocculation studies were conducted. In order to increase the molecular weight of polyamine flocculant which was prepared by polycondensation reaction from dimethylamine and epichlorohydrin, a small amount of 1,6-hexanediamine was employed. The incorporation of 1,6-hexanediamine up to 5.5 mole % replacing corresponding part of dimethylamine gave a branched type polyamine sample with increased intrinsic viscosity ([${\eta}$]=0.46 in 1 wt % aqueous NaCl solution). The amount of 1,6-hexanediamine above 5.5 mole %, however, resulted in gelation during polymerization. Utilizing raw water from Maegok potable water treatment plant, it was found that the addition of polyamine flocculant at a concentration of 1 mg/L level could reduce the amount of polyaluminum chloride (PAC) inorganic flocculant by half (15 mg/L). It was also observed that the incoporation of polyamine flocculant at 1 mg/L level was effective in the higher pH raw water, while PAC inorganic flocculating agent alone was not effective.

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Study on Mixing Condition of the Rubber Composite Containing Functionalized S-SBR, Silica and Silane : II. Effect of Mixing Temperature and Time (변성 S-SBR Silica-Silane 고무복합체의 배합조건에 대한 연구 : II. 배합온도와 시간의 영향)

  • Jang, Suk-Hee;Kim, Wook-Soo;Kang, Yong-Gu;Han, Min-Hyun;Chang, Sang-Mok
    • Elastomers and Composites
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    • v.48 no.2
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    • pp.103-113
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    • 2013
  • The properties of the rubber composites containing a silane and silica were evaluated by changing the mixing time and temperature, in order to find the optimum mixing conditions. Characteristics of the compounds were evaluated after mixing at $120^{\circ}C$, $140^{\circ}C$, and $160^{\circ}C$ with various mixing time. With increasing of mixing time, mooney viscosity decreased while the bound rubber contents of the compounds increased. Viscosity rise by increased mixing time was bigger at low temperature and the higher the mixing temperature the faster in the formation of bound rubber. With lower mixing temperature of $120^{\circ}C$, cross-linking rate was almost constant. Dynamic viscoelastic properties and dispersity of the compound showed that dispersion of ingredients and reaction was not sufficient with the mixing time of less than 10min. On the contrary, with high temperature, it was obvious that good dynamic and physical properties could be obtained due to sufficient coupling reaction, however it was thought this high temperature is not optimum because of sensitive cross-linking rate and physical properties and excessive formation of bound rubber. Consequently, it was confirmed that the mixing condition of 10min at $140^{\circ}C$ was optimum for the silane coupling reaction and dispersion of functionalized S-SBR containing silica and silane.

Study on Mixing Condition of the Rubber Composite Containing Functionalized S-SBR, Silica and Silane : I. Effect of Mixing Temperature (변성 S-SBR Silica-Silane 고무복합체의 배합조건에 대한 연구 : I. 배합온도의 영향)

  • Jang, Suk-Hee;Kim, Wook-Soo;Kang, Yong-Gu;Han, Min-Hyun;Chang, Sang-Mok
    • Elastomers and Composites
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    • v.48 no.2
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    • pp.94-102
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    • 2013
  • Characteristics of rubber mixture were evaluated in order to find the optimum mixing conditions of compounds containing silica and silane at various temperatures. With different mixing temperatures of 105, 120, 130, 140 and $160^{\circ}C$, the viscosity of the compound mixed at $105^{\circ}C$ showed a very high viscosity value. Compounds mixed the temperature range from at $120^{\circ}C$ to $140^{\circ}C$ showed lower viscosity than the compound mixed at $105^{\circ}C$. However, the difference was found to be small in those temperature ranges. On the contrary, at the mixing temperature of $160^{\circ}C$, the viscosity of compound increased again. Through the physical and dynamic observations, it was verified that at the mixing temperature below $120^{\circ}C$ only insufficient silica-silane reaction has been obtained. In addition, with the elevated mixing temperature of $160^{\circ}C$, Cross-linking occurred during mixing by the sulfur contained in coupling agent. In the temperature ranges from $120^{\circ}C$ to $140^{\circ}C$, because of the fast coupling reaction at higher temperature, it was thought to be more advantageous during reaction even though the trend of viscosity and dynamic mechanical property was not clear.

Phase Behavior of Simvastatin Drug in Mixtures of Dichloromethane and Supercritical Carbon Dioxide and Microparticle Formation of Simvastatin Drug Usins Supercritical Anti-Solvent Process (디클로로메탄과 초임계 이산화탄소의 혼합용매에서 Simvastatin 약물의 상거동과 초임계 역용매 공정을 이용한 Simvastatin 약물 미세입자의 제조)

  • Oh, Dong-Joon;Lee, Byung-Chul
    • Clean Technology
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    • v.13 no.1 s.36
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    • pp.34-45
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    • 2007
  • Phase behavior of the ternary systems of water-insoluble simvastatin drug, which is well known to be effective drugs for hypercholesterolemia therapy, in solvent mixtures of dichloromethane and supercritical carbon dioxide was investigated to present a guideline of establishing operating conditions in the particle formation of the drugs by a supercritical anti-solvent recrystallization process utilizing dichloromethane as a solvent and carbon dioxide as an anti-solvent. The solubilities of simvastatin in the mixtures of dichloromethane and carbon dioxide were determined as functions of temperature, pressure and solvent composition by measuring the cloud points of the ternary mixtures at various conditions using a high-pressure phase equilibrium apparatus equipped with a variable-volume view cell. The solubility of the drug increased as the dichloromethane composition in solution and the system pressure increases at a fixed temperature. A lower solubility of the drug was obtained at a higher temperature. The second half of this work is focused on the particle formation of the simvastatin drug by a supercritical anti-solvent recrystallization process in a cylindrical high-pressure vessel equipped with an impeller. Microparticles of the simvastatin drug were prepared as functions of pressure (8 MPa to 12 MPa), temperature (303.15 K, 313,15 K), feed flow rate of carbon dioxide, and stirring speed (up to 3000 rpm), in order to observe the effect of those process parameters on the size and shape of the drug microparticles recrystallized.

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