• Title/Summary/Keyword: high-solid

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Comparative Analysis of Performance and Microbial Characteristics Between High-Solid and Low-Solid Anaerobic Digestion of Sewage Sludge Under Mesophilic Conditions

  • Lu, Qin;Yi, Jing;Yang, Dianhai
    • Journal of Microbiology and Biotechnology
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    • v.26 no.1
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    • pp.110-119
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    • 2016
  • High-solid anaerobic digestion of sewage sludge achieves highly efficient volatile solid reduction, and production of volatile fatty acid (VFA) and methane compared with conventional low-solid anaerobic digestion. In this study, the potential mechanisms of the better performance in high-solid anaerobic digestion of sewage sludge were investigated by using 454 high-throughput pyrosequencing and real-time PCR to analyze the microbial characteristics in sewage sludge fermentation reactors. The results obtained by 454 highthroughput pyrosequencing revealed that the phyla Chloroflexi, Bacteroidetes, and Firmicutes were the dominant functional microorganisms in high-solid and low-solid anaerobic systems. Meanwhile, the real-time PCR assays showed that high-solid anaerobic digestion significantly increased the number of total bacteria, which enhanced the hydrolysis and acidification of sewage sludge. Further study indicated that the number of total archaea (dominated by Methanosarcina) in a high-solid anaerobic fermentation reactor was also higher than that in a low-solid reactor, resulting in higher VFA consumption and methane production. Hence, the increased key bacteria and methanogenic archaea involved in sewage sludge hydrolysis, acidification, and methanogenesis resulted in the better performance of high-solid anaerobic sewage sludge fermentation.

Spark Plasma Sintering Technique and Application for All-Solid-State Batteries (전고상 전지를 위한 스파크 플라스마 소결 기술과 응용)

  • Lee, Seokhee
    • Ceramist
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    • v.22 no.2
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    • pp.170-181
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    • 2019
  • All-solid-state batteries have received increasing attention because of their high safety aspect and high energy and power densities. However, the inferior solid-solid interfaces between solid electrolyte and active materials in electrode, which cause high interfacial resistance, reduce ion and electron transfer rate and limit battery performance. Recently, spark plasma sintering is emerging as a promising technique for fabricating solid electrolytes and composite-electrodes. Herein, this paper focuses on the overview of spark plasma sintering to fabricate solid electrolytes and composite-electrodes for all-solid-state batteries. In the end, future opportunities and challenges associated with SPS technique for all-solid-state batteries are described.

Studies on Relations between High Solid Coating and Quality Changes(II) - Effect of high solid coating on coated paper properties - (고농도 도공과 품질변화의 상관성 연구(2보) -도공지의 품질과 고농도 도공의 효과-)

  • Lee, Yong-Kyu;Yoo, Sung-Jong;Cho, Byoung-Uk;Kim, Yong-Sik
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.39 no.3
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    • pp.52-59
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    • 2007
  • This paper confirms that high solid coating can increase coating speed and reduce drying cost. Low solid coating color with the synthetic thickener and high solid coating color with the rheology modifier and with higher ratio of GCC were prepared. Coated paper was then produced with an industrial coater, varying coating speed and dryer temperature in order to keep the moisture content of the coated paper constant. Coating color concentration was able to be increased from 66% to 69% and from 68% to 71% without an adverse effect on coating color rheology. With a help of the rheology modifier, the increased ratio of GCC in high solid coating did not show harmful effects on the coated paper quality.

Curing Reaction and Physical Properties of High-Solid Acrylic/Isocyanate Coatings (하이솔리드 아크릴/이소시아네이트 도료의 경화반응과 도막물성)

  • Park, Hong-Soo;Shim, Il-Woo;Jo, Hye-Jin;Kim, Seong-Kil;Kim, Myung-Soo
    • Journal of the Korean Applied Science and Technology
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    • v.22 no.4
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    • pp.371-378
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    • 2005
  • In the previous study, three kinds of monomers and the functional monomer, acetoacetoxyethyl methacrylate (AAEM), which could improve the film property and cross-linkage, were polymerzied into acrylic resin copolymers (HSA-98-20, HSA-98-0, HSA-98+20) containing 80% solid content. In this study, the high-solid coatings(HSA-98-20C, HSA-98-0C, HSA-98+20C) were prepared by the curing reaction between acrylic resins containing 80% solid content and isocyanate at room temperature. Various properties were examined for the film coated with the prepared high-solid coatings. The introduction of AAEM in the coatings enhanced the abrasion resistance and solvent resistance of coatings, which indicated the possible use of high-solid coatings for top-coating materials of automobile. The curing times measured by viscoelastic measurement were 350, 264, and 212 min for HSA-98-20C, HSA-98-0C, and HSA-98+20C, respectively. This shows that the curing times become shorter with increasing $T_g$ values.

Assessment of mechanical Properties of Thixotropic Al-Si Materials in Semi-Solid Forming Process (반용융 성형공정에서 Thixotropic Al-Si 소재의 기계적 성질 평가)

  • 허재찬
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2000.04a
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    • pp.56-62
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    • 2000
  • Semi-solid forming process has some advantages such as successful manufacturing of high quality components with less inner defects suitable for less machining high productivity and energy-saving effect. the thixotropic behavior(solid-like in the unperturbed state and liquid-like during shearing) has been the basis for the semi-solid forming process. The main focus of this article is the investigation of the effect of T6 heat treatment and alloying elements on the mechanical properties in the semi-solid formed products using thixotropic hypoeutectic (A357 and ALTHIX 86S) and hypereutectic(A390) materials. The new methods to produce semi-solid formed components with high quality are also proposed and discussed in terms of a die design and the development of a lubricant.

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Interfacial Reaction between Li Metal and Solid Electrolyte in All-Solid-State Batteries (리튬금속과 고체전해질의 계면 반응)

  • Jae-Hun Kim
    • Corrosion Science and Technology
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    • v.22 no.4
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    • pp.287-296
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    • 2023
  • Li-ion batteries have been gaining increasing importance, driven by the growing utilization of renewable energy and the expansion of electric vehicles. To meet market demands, it is essential to ensure high energy density and battery safety. All-solid-state batteries (ASSBs) have attracted significant attention as a potential solution. Among the advantages, they operate with an ion-conductive solid electrolyte instead of a liquid electrolyte therefore significantly reducing the risk of fire. In addition, by using high-capacity alternative electrode materials, ASSBs offer a promising opportunity to enhance energy density, making them highly desirable in the automotive and secondary battery industries. In ASSBs, Li metal can be used as the anode, providing a high theoretical capacity (3860 mAh/g). However, challenges related to the high interfacial resistance between Li metal and solid electrolytes and those concerning material degradation during charge-discharge cycles need to be addressed for the successful commercialization of ASSBs. This review introduces and discusses the interfacial reactions between Li metal and solid electrolytes, along with research cases aiming to improve these interactions. Additionally, future development directions in this field are explored.

Application of Acrylic Resins Containing Caprolactone Group and 90% Solid Contents to High-Solid Coatings (카프로락톤기 함유 90% 고형분인 아크릴수지의 하이솔리드 도료에의 적용)

  • Park, Hong-Soo;Yang, In-Mo;Kim, Seung-Jin;Kim, Young-Geun;Jung, Choong-Ho
    • Journal of the Korean Applied Science and Technology
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    • v.24 no.2
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    • pp.149-159
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    • 2007
  • In order to prepare high-solid coatings, acrylic resins, HSCs [poly (EA/EMA/2-HEMA/CLA)] that contain 90% solid, were synthesized by copolymerization of ethyl acrylate (EA), ethyl methacrylate (EMA), 2-hydroxyethyl methacrylate (2-HEMA) and caprolactone acrylate (CLA). The high-solid coatings named as CHSCs (HSCs/HDI-trimer) were prepared by the curing reaction between the acrylic resins containing 90% solid contents and the isocyanates (HDI-trimer) curing agent room temperature. The curing behavior and various properties were examined on the film coated with the both high-solid coatings. The glass transition temperatures $(T_g)$ of CHSCs increased proportionally with increasing the predicted $T_g$ value by Fox equation, and had nothing to do with the solid contents. The prepared film showed good properties for $60^{\circ}$ specular gloss, impact resistance, cross-hatch adhesion and heat resistance, and bad properties for pencil hardness, drying time, and pot-life. Among the film properties, the heat resistance was very excellent and could be explained by the introduction of functional monomers of CLA.

High Pressure Vibrational Study of $C_{70}$ Using Diamond Anvil Cell

  • Ahn, Hang-Sun;Jeon, Seung-Joon
    • The Korean Journal of Ceramics
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    • v.3 no.2
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    • pp.82-87
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    • 1997
  • High pressure FTIR and Raman spectra of soild $C_{70}$ were measured at pressure up to 11 GPa and room temperature. The slope (dv/dp) of the frequency-pressure plots for several IR and Raman mode changed around 1.5 GPa, where a solid-solid transition might occur. In IR study, we can observe new mode appeared around 777$cm^{-1}$1 above 5.5 GPa which might indicate another solid-solid transition. Our study showed that this transition might be irreversible.

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High-harmonic Generation from Solid Surface Using an Oscillating Mirror Model and Plasma Mirror System for High Contrast Laser Pulse

  • Kim, I-Jong;Choi, Il-Woo;Janulewicz, Karol Adam;Lee, Jong-Min
    • Journal of the Optical Society of Korea
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    • v.13 no.1
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    • pp.15-21
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    • 2009
  • High-order harmonic generation from a solid surface affected by the contrast of a laser pulse was studied using an oscillating mirror model. High-order harmonics generated from solid surfaces have unusual properties such as spectral redshift, and an intensity difference between even- and odd-order harmonics which is not reported for high-order harmonics generated by a gas medium. We confirmed that high-order harmonics from solid surfaces have selectivity of polarization as well as cut-off extension and the enhancement of conversion efficiency proportional to laser intensity. And the principle of operation and the characteristics of a plasma mirror system developed for achieving high contrast laser pulses to pursue the experimental realization of high-harmonic generation from solid surfaces are reported. Energy fluence on the plasma mirrors is tunable between $10\;J/cm^2$ and $1000\;J/cm^2$ and around 1000 shots are available before the plasma mirrors require replacement.

Degradation of All-Solid-State Lithium-Sulfur Batteries with PEO-Based Composite Electrolyte

  • Lee, Jongkwan;Heo, Kookjin;Song, Young-Woong;Hwang, Dahee;Kim, Min-Young;Jeong, Hyejeong;Shin, Dong-Chan;Lim, Jinsub
    • Journal of Electrochemical Science and Technology
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    • v.13 no.2
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    • pp.199-207
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    • 2022
  • Lithium-sulfur batteries (LSBs) have emerged as a promising alternative to lithium-ion batteries (LIBs) owing to their high energy density and economic viability. In addition, all-solid-state LSBs, which use solid-state electrolytes, have been proposed to overcome the polysulfide shuttle effect while improving safety. However, the high interfacial resistance and poor ionic conductivity exhibited by the electrode and solid-state electrolytes, respectively, are significant challenges in the development of these LSBs. Herein, we apply a poly (ethylene oxide) (PEO)-based composite solid-state electrolyte with oxide Li7La3Zr2O12 (LLZO) solid-state electrolyte in an all-solid-state LSB to overcome these challenges. We use an electrochemical method to evaluate the degradation of the all-solid-state LSB in accordance with the carbon content and loading weight within the cathode. The all-solid-state LSB, with sulfur-carbon content in a ratio of 3:3, exhibited a high initial discharge capacity (1386 mAh g-1), poor C-rate performance, and capacity retention of less than 50%. The all-solid-state LSB with a high loading weight exhibited a poor overall electrochemical performance. The factors influencing the electrochemical performance degradation were revealed through systematic analysis.