• 콘크리트학회논문집
• /
• 제12권5호
• /
• pp.131-139
• /
• 2000

Porous Concrete usually contains large amount of voids(about 10∼20%) after compaction so that it has relatively high permeability. It has been introduced in domestic since early 1980's but it has problems such as lack of optimized mixture, low strength and durability, and other defects, etc. The purpose of this study is to manufacture high-performance porous concrete using polymer to enhance the mechanical properties. The results of this study are as follows; the compressive strength range 12 92∼207kgf/㎠, the tensile strength range is 14∼28kgf/㎠, the bending stength range is 42∼73kgf/㎠, and the coefficient permeability range is 5.77×10-2∼6.79×10-1cm/sec. To develope high-performance porous concrete. further studies are needed on optimum mixture of fineness modulus and admixture.

• 한국재료학회:학술대회논문집
• /
• 한국재료학회 1998년도 IUMRS-ICEM ABSTRACT BOOK
• /
• pp.54.3-54
• /
• 1998

• 한국구조물진단유지관리공학회 논문집
• /
• 제16권6호
• /
• pp.9-17
• /
• 2012

콘크리트 하수 암거는 항상 유해이온에 노출되어 있으므로 사용기간의 증가에 따라 내구적인 문제점을 보이며, 이러한 열화는 구조적인 문제로 진전된다. 콘크리트 하수암거는 일단 매립 후 유지관리가 어려우므로 초기에 높은 내구성 및 안전성을 요구한다. 최근 들어 역학적 특성과 내구적 성능의 개선을 위하여 폴리머 콘크리트가 사용되고 있다. 본 논문에서는 폴리머 콘크리트를 이용한 하수암거에 대한 공학적 성능을 평가하였으며, 축소 모형을 통하여 이음부의 누수와 접착강도를 평가하였다. 제작된 폴리머 하수암거는 100MPa 이상의 높은 압축강도를 확보하였으며, 낮은 투수성 및 염소이온 침투성을 확보하고 있었다. 또한 내화학성 및 생물학적 시험 등에서도 우수한 저항성을 확보하고 있었다. 축소모형실험을 통하여, 이음부 누수가 없고 높은 접착강도를 확보하고 있음을 평가하였으며 연결부의 일체거동을 확인하였다. 본 연구에서 제작된 프리캐스트 폴리머 하수암거는 하수도관과 같이 열악한 환경조건에 적극적으로 사용될 수 있다고 판단된다.

• Korea-Australia Rheology Journal
• /
• 제18권3호
• /
• pp.153-160
• /
• 2006

We analyzed the non-Newtonian and non-isothermal flow with Carreau-Yasuda viscosity model in co-rotating and counter-rotating twin screw extruder systems. The mixing performances with respect to the screw speed, the screw pitch, and the rotating direction have been investigated. The dynamics of mixing was studied numerically by tracking the motions of particles. The extent of mixing was characterized in terms of the deformation rate, the residence time distribution, and the average strain. The results showed that the high screw speed decreases the residence time but increases the deformation rate. Small screw pitch increases the residence time. It is concluded that the high screw speed increases the dispersive mixing performance, while the small screw pitch increases the distributive mixing performance. Co-rotating screw extruder has the better conveying performance and the distributive mixing performance than counter-rotating screw extruder with the same screw speed and pitch. Co-rotating screw extruder developed faster transport velocity and it is advantageous the flow characteristics to the mixing that transfers polymer melt from one barrel to the other barrel.

• 한국수소및신에너지학회논문집
• /
• 제29권5호
• /
• pp.442-449
• /
• 2018

Research on High temperature polymer electrolyte fuel cell (HT-PEMFC) has actively been conducted all over the world. Since the HT-PEMFC can be operated at a high temperature of $120-180^{\circ}C$ using phosphoric acid-doped polybenzimidazole (PBI) electrolyte membrane, it has considerable advantages over conventional PEMFC in terms of operating conditions and system efficiency. However, If the thermal distribution is not uniform in the stack unit, degradation due to local reaction and deterioration of lifetime are difficult to prevent. The thin plate separator reduces the volume of the fuel cell stack and improves heat transfer, consequently, enhancing the cooling effect. In this paper, a large area flow field of thin plate separator for HT-PEMFC is designed and sub-stack is fabricated. We have studied stack performance evaluation under various operating conditions and it has been verified that the proposed design can achieve acceptable stack performance at a wide operating range.

• 한국신재생에너지학회:학술대회논문집
• /
• 한국신재생에너지학회 2010년도 추계학술대회 초록집
• /
• pp.85.2-85.2
• /
• 2010

There is widespread effort to develop polymer membranes in place of Nafion for high temperature polymer electrolyte membrane fuel cell(PEMFC). In our study, SiO2 membranes are arranged by electrospinning method. For impregnation solution, the modified sulfonated poly(ether ether ketone)(SPEEK) polymer is prepared from sulfonation, sulfochlorination, partial reduction and lithiation reaction. The modified polymer is cross-linked with 1,4-diiodobetane in NMP solvent and then blended with Heteropoly acid(HPA). The characterization of membranes is confimed by FT-IR, Thermogravimetry(TGA), water uptake test and single cell performance test for PEMFC, etc. The composite membrane shows satisfactory thermal and mechanical properties. Beside, The membrane exhibits good ion exchange capacity and high proton conductivity. As a result, The composite membrane is promising as an alternative membrane in high temperature PEMFC.

• Journal of Electrochemical Science and Technology
• /
• 제9권2호
• /
• pp.126-132
• /
• 2018

For the first time, an innovative approach using P(VDF-TrFE) as a polymer electrolyte for high efficiency, all-solid-state supercapacitors is presented. The polymer electrolyte was successfully achieved by dissolving P(VDF-TrFE) copolymers in dimethylformamide (DMF). Thermal analysis and infrared spectroscopy revealed excellent thermal stability up to $400^{\circ}C$ and copolymer's interaction with DMF. Electrochemical capacitors fabricated using P(VDF-TrFE) in DMF and ZnO NWs demonstrated high capacitive performance. Furthermore, the gel electrolyte-based supercapacitors demonstrated excellent mechanical durability up to a bend angle of $120^{\circ}$. Novel P(VDF-TrFE) electrolytes could be a promising approach for applications in flexible, fabric-based, and high-efficiency energy devices.

• 한국도로학회논문집
• /
• 제14권5호
• /
• pp.47-55
• /
• 2012

PURPOSES: SUPERPAVE binder grade tests including Multiple Stress Creep and Recovery(MSCR) test are applied to evaluate rheological properties of four polymer modified binders. METHODS: To evaluate grade of four modified binders, PG testing protocols, such as DSR, BBR and MSCR are employed. RESULTS: It is observed that MSCR test shows different performance grades especially on modified binders. Both DMP and EG binder show similar high temperature performance to SBS 5% modified binder. CONCLUSIONS: Binder Grading system in Korea need to be reviewed to properly reflect the performnace of modified binders. The binders modified with DMP and EG can be possible alternatives SBS 5% modified binder considering its performance and cost.

• 한국전기화학회:학술대회논문집
• /
• 한국전기화학회 2004년도 수소연료전지공동심포지움 2004논문집
• /
• pp.211-214
• /
• 2004

• 마이크로전자및패키징학회지
• /
• 제9권3호
• /
• pp.43-48
• /
• 2002

본 연구는 고분자 전해질 연료전지에 이용하기 위한 membrane electrode assembly를 제조하는데 있어서 핵심소재인 고성능 전극촉매를 개발하기 위한 것이다. 전극 성능에 영향을 미치는 촉매 조성물 중 Nafion용액과 백금 함침량을 변화시켜 I-V특성을 측정하였다. 또한, 연료전지의 운전조건 중 단위전지의 온도에 따른 전극 성능의 변화를 관찰하였다. Nafion 용액이 5 wt%, 백금 함침량이 0.5 mg/$\textrm{cm}^2$의 조성이 될 때, 전극 성능이 가장 우수하였다. Nafion용액의 함량이 증가할수록 전극 성능은 저하하였다. 또한, 단위전지는 온도가 $80^{\circ}C$가 되었을 때, I-V 특성이 가장 우수함을 알 수 있었다. 저전류밀도에서의 성능차이는 거의 없으나, 고전류밀도에서는 온도가 상승됨에 따라 전압값이 향상됨을 알 수 있었다.