• Journal of Powder Materials
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• v.28 no.3
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• pp.221-226
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• 2021

We fabricate the non-equiatomic high-entropy alloy (NE-HEA) Fe_49.5Mn₃₀Co₁₀Cr₁₀C_0.5 (at.%) using spark plasma sintering under various sintering conditions. Each elemental pure powder is milled by high-energy ball milling to prepare NE-HEA powder. The microstructure and mechanical properties of the sintered samples are investigated using various methods. We use the X-ray diffraction (XRD) method to investigate the microstructural characteristics. Quantitative phase analysis is performed by direct comparison of the XRD results. A tensile test is used to compare the mechanical properties of small samples. Next, electron backscatter diffraction analysis is performed to analyze the phase fraction, and the results are compared to those of XRD analysis. By combining different sintering durations and temperature conditions, we attempt to identify suitable spark plasma sintering conditions that yield mechanical properties comparable with previously reported values. The samples sintered at 900 and 1000℃ with no holding time have a tensile strength of over 1000 MPa.

• 한국신재생에너지학회:학술대회논문집
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• 2009.06a
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• pp.130-133
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• 2009

$Cu_2ZnSnSe_4$(CZTSe) is one of the promising materials for the solar cell due to its abundant availability in the nature. In this study, we report the fabrication of CZTSe thin film by Pulsed Laser Deposition(PLD) method using quaternary compound target on sodalime glass substrate. The quaternary CZTSe compound target was synthesized by solid state reaction method using elemental powders of Cu, Zn, Sn and Se. Powders were milled in high purity ethanol using zirconia ball with mixed size of 1 and 3 mm at the same proportions for 72 hours milling time. The structural, chemical and mechanical properties of the synthesized CZTSe powders were investigated prior to the deposition process. The CZTSe compound powder, and $500^{\circ}C$ of sintering temperature shows the best properties for PLD target. Results show that the as-deposited CZTSe thin films with the precursors by PLD have a composition near-stoichiometric.

• Proceedings of the Materials Research Society of Korea Conference
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• 1992.05b
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• pp.126-126
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• 1992

Solid and liquid sintering behaviors of mechanically alloyed 75W-25Cu powders have been studied by using a dilatometry technique. The sintering was performed under hydrogen atmosphere of 1 atm with a heating rate of 3 $^{\circ}C$/min. The mechanically alloyed 75W-25Cu powders were prepared by high energy ball milling process under argon atmosphere of 1 atm with alloying times of 0 to 400 h. To compare with the sintering behaviors of mechanically alloyed powders, pure Cu and W powders were also sintered under the above conditions, As the mechanical alloying time increased from 0 to 400 h, the shrinkage behavior of the alloyed powders was enhanced during the sintering, and staring temperature of liquid sintering decreased from 1083 to 1068 $^{\circ}C$. The saturation temperature, above which the shrinkage was completed, of liquid phase sintering decreased from 1248 to 1148 $^{\circ}C$ with increasing mechanical alloying time from 200 to 400 h. The residual stress of the mechanically alloyed powder was measured by X-raydiffractometer. The microstructure of sintered spcimen was observed by optical and scanning electron microscope. From these results, variations of solid and liquid sintering behaviors with mechanical alloying time were discussed in terms of the amount of residual stress and the distribution of W and Cu powders in the mechanically alloyed powder.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.33 no.4
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• pp.440-446
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• 2009

This paper was designed to fabricate the miniature spur gear with pitch circle of 2.25mm using extrusion process of a mechanically alloyed Al-78wt%Zn powder. The mechanical alloying of the powder particles were performed for ball milled times of 4h, 8h, 16 and 32h by the planetary ball milling. The mechanical properties of these alloyed powders, which were compacted and sintered-cylindrical preforms, were estimated using compression test. The results showed that the alloyed powder with average particle size of $10{\mu}m$ milled for 32h has the highest compressive(fractured) strength(288MPa). Extrusions of the miniature spur gear using the alloyed powder were carried out at different extrusion temperatures. Extrusion temperature of $300^{\circ}C$ provided the spur gear with the highest relative density and Vickers hardness and without any surface defects.

• Journal of the Korean Society for Heat Treatment
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• v.22 no.3
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• pp.149-154
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• 2009

Dense $5Cu_{0.6}Fe_{0.4}-Al_2O_3$ composite was consolidated from mechanically synthesized powders by pulsed current activated sintering method within 1 min. $5Cu_{0.6}Fe_{0.4}-Al_2O_3$ powder was synthesized from 3CuO and 2FeAI using the high energy ball milling. Dense $5Cu_{0.6}Fe_{0.4}-Al_2O_3$ with relative density of up to 95% was produced under simultaneous application of a 80 MPa pressure and the pulsed current. Mechanical properties and grain size of the composite were investigated.

• Journal of Powder Materials
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• v.27 no.5
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• pp.414-419
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• 2020

In the present study, we investigated the austenite stability of a sintered Fe-based nanocrystalline alloy. The volume fraction of austenite was measured based on the X-ray diffraction data of sintered Fe-based nanocrystalline alloys, which were prepared by high-energy ball milling and spark plasma sintering. The sintered alloy samples showed a higher volume fraction of austenite at room temperature as compared to the equilibrium volume fraction of austenite obtained using thermodynamic calculations, which resulted from the nanosized crystalline structure of the sintered alloy. It was proved that the austenite stability of the sintered Fe-based alloy increased with a rise in the amount of austenite stabilizing elements such as Mn, Ni, and C; however, it increased more effectively with a decrease in the actual grain size. Furthermore, we proposed a new equation to predict the martensite starting temperature for sintered Fe-based alloys.

• Korean Journal of Materials Research
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• v.23 no.11
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• pp.620-624
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• 2013

Nanocrystalline materials have recently received significant attention in the area of advanced materials engineering due to their improved physical and mechanical properties. A solid-solution nanocrystalline powder, (Ti,Mo)C, was prepared via high-energy milling of Ti-Mo alloys with graphite. Using XRD data, the synthesis process was investigated in terms of the phase evolution. Rapid sintering of nanostuctured (Ti,Mo)C hard materials was performed using a pulsed current activated sintering process (PCAS). This process allows quick densification to near theoretical density and inhibits grain growth. A dense, nanostructured (Ti,Mo)C hard material with a relative density of up to 96 % was produced by simultaneous application of 80 MPa and a pulsed current for 2 min. The average grain size of the (Ti,Mo)C was lower than 150 nm. The hardness and fracture toughness of the dense (Ti,Mo)C produced by PCAS were also evaluated. The fracture toughness of the (Ti,Mo)C was higher than that of TiC.

• Journal of Magnetics
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• v.21 no.1
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• pp.61-64
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• 2016

In this study, we report the as-prepared MgO-doped $BaFe_{12}O_{19}$, which was prepared by calcination technique and high-energy ball milling process, as an electromagnetic wave absorber. The phase analysis of $BaFe_{12}O_{19}$ and the as-prepared MgO-doped $BaFe_{12}O_{19}$ was detected utilizing X-ray Diffractometer (XRD). The microstructure was characterized using Scanning Electron Microscope (SEM). By means of the transmission/reflection coaxial line method, the electromagnetic properties and microwave absorbing properties of the as-prepared electromagnetic wave absorber were studied. It is found that the electromagnetic wave absorber has a minimum reflection loss value of -41 dB at 4.27 GHz with a matching thickness of 2.6 mm. The experiment results revealed that the as-prepared electromagnetic wave absorber could find potential applications in many military as well as commercial industries.

• Journal of Powder Materials
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• v.9 no.4
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• pp.235-244
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• 2002

The effects of residual impurities on solid state sintering of the powder injection molded (PIMed) W-15wt%Cu nanocomposite powder were investigated. The W-Cu nanocomposite powder was produced by the mech-ano-chemical process consisting of high energy ball-milling and hydrogen reduction of W blue powder-cuO mixture. Solid state sintering of the powder compacts was conducted at $1050^{\circ}C$ for 2~10 h in hydrogen atmosphere. The den-sification of PIM specimen was slightly larger than that of PM(conventional PM specimen), being due to fast coalescence of aggregate in the PIM. The only difference between PIM and PM specimens was the amount of residual impurities. The carbon as a strong reduction agent effectively reduced residual W oxide in the PIM specimen. The $H_2O$ formed by $H_2$ reduction of oxide disintegrated W-Cu aggregates during removal process, on the contrary to this, micropore volume rapidly decreased due to coalescence of the disintegrated W-Cu aggregates during evolution of CO.It can be concluded that the higher densification was due to the earlier occurred Cu phase spreading that was induced by effective removal of residual oxides by carbon.

• Journal of ILASS-Korea
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• v.17 no.1
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• pp.14-19
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• 2012

The present study conducts experimental investigation on spreading and deposition characteristics of a $4.3{\mu}l$ de-ionized (DI) water droplet impacting upon aluminum (Al 6061) flat and textured surfaces. The micro-textured surface consisted the micro-hole arrays (hole diameter: $125{\mu}m$, hole depth: $125{\mu}m$) fabricated by the conventional micro-computer numerical control (${\mu}$-CNC) milling machine process. We examined the surface effect of texture area fraction ${\varphi}_s$ ranging from 0 to 0.57 and impact velocity of droplet ranging from 0.40 m/s to 1.45 m/s on spreading and deposition characteristics from captured images. We used a high-speed camera to capture sequential images for investigate spreading characteristics and the image sensor to capture image of final equilibrium deposition droplet for analyze spreading diameter and contact angle. We found that the deposition droplet on textured surfaces have different wetting states. When the impact velocity is low, the non-wetting state partially exists, whereas over 0.64 m/s of impact velocity, totally wetting state is more prominent due to the increase kinetic energy of impinging droplet.