• Title/Summary/Keyword: high-energy density science

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Impedance Characteristics of Blue Fluorescent OLED According to Elapsed Time (경과 시간에 따른 청색 형광 OLED의 Impedance 특성)

  • Kong, Do-Hoon;Yang, Jae-Woong;Ju, Sung-Hoo
    • Journal of the Korean institute of surface engineering
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    • v.50 no.5
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    • pp.405-410
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    • 2017
  • In order to study current-voltage-luminance and impedance characteristics according to elapsed time, a blue fluorescent OLED was fabricated. The current density and luminance gradually decreased in accordance with elapsed time and did not emit light after 480 hours, and the threshold voltage increased as time elapsed. The Cole-Cole plot was a semicircular shape of a very large size at 2 V of the applied voltage below the threshold voltage, and the maximum value of the real number impedance did not change greatly from 9314.5 to $9902.2{\Omega}$ as time elapsed. Applied voltages 4, 6, and 8 V above the threshold voltage showed a large change in the real number impedance value at the semicircle end to 9,678.2, 9,826, $9,535.4{\Omega}$ according to the elapsed time from 2,222.5, 183.7, $48.2{\Omega}$ immediately after fabricating the device. By increasing the applied voltage beyond the threshold voltage just after device fabrication, the energy difference between the device and the organic layer was overcome and the current flowed, the maximum value of the real number impedance sharply decreased. As time passed, current did not flow through the element even at high applied voltage due to degradation of the element, and even when the applied voltage was higher than the threshold voltage, it showed an impedance value such as applied voltage equal to or less than the threshold voltage. As a result, it can be learned that the change in the impedance with elapsed time reflects the characteristics due to the degradation of the OLED and can predict the characteristics and lifetime of the OLED.

AKARI FAR-INFRARED ALL-SKY SURVEY MAPS

  • Doi, Yasuo;Komugi, Shinya;Kawada, Mitsunobu;Takita, Satoshi;Arimatsu, Ko;Ikeda, Norio;Kato, Daisuke;Kitamura, Yoshimi;Nakagawa, Takao;Ootsubo, Takafumi;Morishima, Takahiro;Hattori, Makoto;Tanaka, Masahiro;White, Glenn J.;Etxaluze, Mireya;Shibai, Hiroshi
    • Publications of The Korean Astronomical Society
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    • v.27 no.4
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    • pp.111-116
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    • 2012
  • Far-infrared observations provide crucial data for the investigation and characterisation of the properties of dusty material in the Interstellar Medium (ISM), since most of its energy is emitted between ~ 100 and $200{\mu}m$. We present the first all-sky image from a sensitive all-sky survey using the Japanese AKARI satellite, in the wavelength range $50-180{\mu}m$. Covering > 99% of the sky in four photometric bands with four filters centred at $65{\mu}m$, $90{\mu}m$, $140{\mu}m$, and $160{\mu}m$ wavelengths, this achieved spatial resolutions from 1 to 2 arcmin and a detection limit of < 10 MJy $sr^{-1}$, with absolute and relative photometric accuracies of < 20%. All-sky images of the Galactic dust continuum emission enable astronomers to map the large-scale distribution of the diffuse ISM cirrus, to study its thermal dust temperature, emissivity and column density, and to measure the interaction of the Galactic radiation field and embedded objects with the surrounding ISM. In addition to the point source population of stars, protostars, star-forming regions, and galaxies, the high Galactic latitude sky is shown to be covered with a diffuse filamentary-web of dusty emission that traces the potential sites of high latitude star formation. We show that the temperature of dust particles in thermal equilibrium with the ambient interstellar radiation field can be estimated by using $90{\mu}m$, $140{\mu}m$, and $160{\mu}m$ data. The FIR AKARI full-sky maps provide a rich new data set within which astronomers can investigate the distribution of interstellar matter throughout our Galaxy, and beyond.

Examining Diurnal Thermal Variations by Urban Built Environment Type with ECOSTRESS Land Surface Temperature Data: Evidence from Seoul, Korea (도시 건조환경 유형에 따른 서울시 주간 지표면 온도 변동성 분석: ECOSTRESS 데이터의 활용)

  • Gyuwon Jeon;Yujin Park
    • Journal of the Korean Regional Science Association
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    • v.40 no.2
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    • pp.107-130
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    • 2024
  • Urban land surface temperature (LST) change is a major environmental factor that affects the thermal comfort, energy consumption, and health of urban residents. Most studies that explored the relationship between LST and urban built-environment form analyzed only midday LST. This study explores the diurnal variation of summertime LST in Seoul using ECOSTRESS data, which observes LST at various times of the day and analyzes whether the LST variation differs by built environment type. Launched in 2018, ECOSTRESS operates in a non-sun-synchronous orbit, observing LST with a high resolution of 70 meters. This study collected data from early morning (6:25) to evening (17:26) from 2019 to 2022 to build time-series LST. Based on greenery, water bodies, and building form data, eight types of Seoul's built environment were derived by hierarchical clustering, and the LST fluctuation characteristics of each cluster were compared. The results showed that the spatial disparity in LST increased after dawn, peaked at noon, and decreased again, highlighting areas with rapid versus stable LST changes. Low-rise and high-rise compact districts experienced fast, high temperature increases and high variability, while low-density apartments experienced moderate LST increases and low variability. These results suggest urban forms that can mitigate rapid daytime heating.

Optimization Process Models of Gas Combined Cycle CHP Using Renewable Energy Hybrid System in Industrial Complex (산업단지 내 CHP Hybrid System 최적화 모델에 관한 연구)

  • Oh, Kwang Min;Kim, Lae Hyun
    • Journal of Energy Engineering
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    • v.28 no.3
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    • pp.65-79
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    • 2019
  • The study attempted to estimate the optimal facility capacity by combining renewable energy sources that can be connected with gas CHP in industrial complexes. In particular, we reviewed industrial complexes subject to energy use plan from 2013 to 2016. Although the regional designation was excluded, Sejong industrial complex, which has a fuel usage of 38 thousand TOE annually and a high heat density of $92.6Gcal/km^2{\cdot}h$, was selected for research. And we analyzed the optimal operation model of CHP Hybrid System linking fuel cell and photovoltaic power generation using HOMER Pro, a renewable energy hybrid system economic analysis program. In addition, in order to improve the reliability of the research by analyzing not only the heat demand but also the heat demand patterns for the dominant sectors in the thermal energy, the main supply energy source of CHP, the economic benefits were added to compare the relative benefits. As a result, the total indirect heat demand of Sejong industrial complex under construction was 378,282 Gcal per year, of which paper industry accounted for 77.7%, which is 293,754 Gcal per year. For the entire industrial complex indirect heat demand, a single CHP has an optimal capacity of 30,000 kW. In this case, CHP shares 275,707 Gcal and 72.8% of heat production, while peak load boiler PLB shares 103,240 Gcal and 27.2%. In the CHP, fuel cell, and photovoltaic combinations, the optimum capacity is 30,000 kW, 5,000 kW, and 1,980 kW, respectively. At this time, CHP shared 275,940 Gcal, 72.8%, fuel cell 12,390 Gcal, 3.3%, and PLB 90,620 Gcal, 23.9%. The CHP capacity was not reduced because an uneconomical alternative was found that required excessive operation of the PLB for insufficient heat production resulting from the CHP capacity reduction. On the other hand, in terms of indirect heat demand for the paper industry, which is the dominant industry, the optimal capacity of CHP, fuel cell, and photovoltaic combination is 25,000 kW, 5,000 kW, and 2,000 kW. The heat production was analyzed to be CHP 225,053 Gcal, 76.5%, fuel cell 11,215 Gcal, 3.8%, PLB 58,012 Gcal, 19.7%. However, the economic analysis results of the current electricity market and gas market confirm that the return on investment is impossible. However, we confirmed that the CHP Hybrid System, which combines CHP, fuel cell, and solar power, can improve management conditions of about KRW 9.3 billion annually for a single CHP system.

Characteristics of Marine Litters Distribution on the Sea-bed of the East China Sea (동중국해의 해저 폐기물 분포특성)

  • Jeong, Sun-Beom;Lee, Dae-In;Cho, Hyeon-Seo;Kim, Young-Joo
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.8 no.4
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    • pp.220-226
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    • 2005
  • This study evaluated the composition and distribution of marine litters on the sea-bed of the East China Sea. Surveys have been conducted by a benthic trawlnet of Dong-baek training ship of Yosu national university during the cruise of 2002-2004. Distribution density showed high value in C5 (north-western area of Jeju Island) with $110.3kg/km^2$ and those of annual mean were about $31-43kg/km^2$. Fishing gears such as nets, pots, octopus jars and etc. were about 42-72% of debris collected in the East China Sea. Composition ratio of rubber, vinyl. metal, plastic, glass, wood, cloth and etc. were within 25% except C5. Rope and drum showed strong fluctuations with 0-30% according to the trawling sites. Some vinyls and nets made in Korea, China and Japan were much collected. It is estimated that fishing gears were discarded to the sea by fishing operation, deliberately or not. An comprehensive program including continuous research, monitoring for marine litters in the Korean sea were necessary.

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Analysis of wet chemical tunnel oxide layer characteristics capped with phosphorous doped amorphous silicon for high efficiency crystalline Si solar cell application

  • Kang, Ji-yoon;Jeon, Minhan;Oh, Donghyun;Shim, Gyeongbae;Park, Cheolmin;Ahn, Shihyun;Balaji, Nagarajan;Yi, Junsin
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.406-406
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    • 2016
  • To get high efficiency n-type crystalline silicon solar cells, passivation is one of the key factor. Tunnel oxide (SiO2) reduce surface recombination as a passivation layer and it does not constrict the majority carrier flow. In this work, the passivation quality enhanced by different chemical solution such as HNO3, H2SO4:H2O2 and DI-water to make thin tunnel oxide layer on n-type crystalline silicon wafer and changes of characteristics by subsequent annealing process and firing process after phosphorus doped amorphous silicon (a-Si:H) deposition. The tunneling of carrier through oxide layer is checked through I-V measurement when the voltage is from -1 V to 1 V and interface state density also be calculated about $1{\times}1012cm-2eV-1$ using MIS (Metal-Insulator-Semiconductor) structure . Tunnel oxide produced by 68 wt% HNO3 for 5 min on $100^{\circ}C$, H2SO4:H2O2 for 5 min on $100^{\circ}C$ and DI-water for 60 min on $95^{\circ}C$. The oxide layer is measured thickness about 1.4~2.2 nm by spectral ellipsometry (SE) and properties as passivation layer by QSSPC (Quasi-Steady-state Photo Conductance). Tunnel oxide layer is capped with phosphorus doped amorphous silicon on both sides and additional annealing process improve lifetime from $3.25{\mu}s$ to $397{\mu}s$ and implied Voc from 544 mV to 690 mV after P-doped a-Si deposition, respectively. It will be expected that amorphous silicon is changed to poly silicon phase. Furthermore, lifetime and implied Voc were recovered by forming gas annealing (FGA) after firing process from $192{\mu}s$ to $786{\mu}s$. It is shown that the tunnel oxide layer is thermally stable.

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Characteristics of Soil Conditioner Pellets Fabricated by Self-propagating Combustion Methods Using Coal Refuse (석탄폐석의 자열소성을 이용한 토양개량용 펠릿의 제조와 특성)

  • Kim, Byoung-Gon;Lee, Gye-Seung;Nam, Chul-Woo;Park, Chong-Lyuck
    • Korean Journal of Soil Science and Fertilizer
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    • v.41 no.6
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    • pp.379-386
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    • 2008
  • Calcined clay granules (pellet) have been used as a soil conditioner. The space among the pellets can secure drainage of water in soil and, simultaneously, can keep water for plants in the inner pore of that. However, the usage of the pellet has been restrained because fabrication of that requires a high energy and cost for heating over the temperate of $1000^{\circ}C$. Recently, SCS(Self-propagating Combustion and Sintering) method was developed and this method use the combustion energy of the preliminary mixed combustible. The SCS method is suitable to fabrication of small porous aggregate and requires a very low cost. This research applied the SCS method to coal refuses for fabrication of soil conditioner pellets. The coal refuses were pulverized under the size of $100{\mu}m$ and the pulverized powders were pelletized to the size of 4~6mm. The pellets were heated at the temperature of $1200^{\circ}C$ in the SCS furnace that was specially prepared for this research. Characteristics of the pellets were investigated and were compared with that of ordinary calcined clay pellet of kaolin; porosity, pore size distribution, bulk density, pH and etc.. Characteristics of the moisture retention in the pellets were measured by the centrifugal method: ASTM D425-88. The pellets of the coal refuses showed the higher values of the field capacity and the plant-available water than that of kaolin pellet. These results suggest the very low cost process that can utilize the coal refuses and can fabricate the lightweight porous soil conditioner of the very high plant-available water.

The Effect of Synthesis Conditions on the Electrochemical Properties of LiFePO4 for Cathode Material of Secondary Lithium Ion Batteries (리듐 2차 전지용 약극활물질 LiFePO4의 합성 조건에 다른 전기화학적 특성)

  • Kim, Do-Gyun;Park, Hyun-Min;Jeong, Yeon-Uk;Lee, Joon-Hyung;Kim, Jeong-Joo
    • Journal of the Korean Ceramic Society
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    • v.43 no.2 s.285
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    • pp.121-125
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    • 2006
  • [ $LiFePO_4$ ] is one of the promising materials for cathode material of secondary lithium batteries due to its high energy density, low cost, environmental friendliness and safety. $LiFePO_4$ was synthesized by the solid-state reaction method at 500 - 800°C. The crystal structure of $LiFePO_4$ was analyzed by X-ray powder diffraction. The samples synthesized at 600 and $700^{\circ}C$ showed a single phase of a olivine structure. The particle sizes were increased and the specific surface areas were decreased with heating temperatures. The electrochemical performance was investigated by coin cell test. The discharge capacities at 0.1 C-rate were 118 mAh/g and 112 mAh/g at $600^{\circ}C,\;700^{\circ}C$, respectively. In an attempt to improve the electrical conductivity of cathode materials, $LiFePO_4/graphite$ composite was prepared with various graphite contents. The electrical conductivity and discharge capacity were increased with increasing the graphite contents in composite samples. The rate capabilities at high current densities were also improved.

R & D Trends on Direct Formic Acid Fuel Cells (직접 개미산 연료전지의 연구동향)

  • Kwon, Yongchai;Han, Jonghee;Kim, Jinsoo
    • Applied Chemistry for Engineering
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    • v.19 no.6
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    • pp.583-591
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    • 2008
  • Recently, as a demand for the portable device is surged, there are needs to develop a new fuel cell system for replacing the conventionally used secondary battery. For this purpose, it becomes important to develop direct formic acid fuel cell (DFAFC) that uses formic acid as a fuel. The formic acid can offer typical advantages such as excellent non-toxicity of the level to be used as food additive, smaller crossover flux through electrolyte, and high reaction capability caused by high theoretical electromotive force (EMF). With the typical merits of formic acid, the efforts for optimizing reaction catalyst and cell design are being made to enhance performance and long term stability of DFAFC. As a result, to date, the DFAFC having the power density of more than $300mW/cm^2$ was developed. In this paper, basic performing theory and configuration of DFAFC are initially introduced and future opportunities of DFAFC including the development of catalyst for the anode electrode and electrolyte, and design for the optimization of cell structure are discussed.

Sorghum extract exerts an anti-diabetic effect by improving insulin sensitivity via PPAR-${\gamma}$ in mice fed a high-fat diet

  • Park, Ji-Heon;Lee, Sun-Hee;Chung, Ill-Min;Park, Yong-Soon
    • Nutrition Research and Practice
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    • v.6 no.4
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    • pp.322-327
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    • 2012
  • This study investigated the hypothesis that a sorghum extract exerts anti-diabetic effects through a mechanism that improves insulin sensitivity via peroxisome proliferator-activated receptor gamma (PPAR-${\gamma}$) from adipose tissue. Seven C57BL/6 mice were fed an AIN-93M diet with fat consisting of 10% of total energy intake (LF) for 14 weeks, and 21 mice were fed a high-fat AIN diet with 60% of calories derived from fat (HF). From week 8, the HF diet-fed mice were orally administered either saline (HF group), 0.5% (0.5% SE group), or 1% sorghum extract (1% SE group) for 6 weeks (n = 7/group). Perirenal fat content was significantly lower in the 0.5% SE and 1% SE groups than that in the HF mice. Levels of total and low-density lipoprotein cholesterol, triglycerides, glucose, and the area under the curve for glucose were significantly lower in mice administered 0.5% SE and 1% SE than those in HF mice. Serum insulin level was significantly lower in mice administered 1% SE than that in HF mice or those given 0.5% SE. PPAR-${\gamma}$ expression was significantly higher, whereas the expression of tumor necrosis factor-${\alpha}$ was significantly lower in mice given 1% SE compared to those in the HF mice. Adiponectin expression was also significantly higher in mice given 0.5% SE and 1% SE than that in the HF mice. These results suggest that the hypoglycemic effect of SE may be related with the regulation of PPAR-${\gamma}$-mediated metabolism in this mouse model.