• Computers and Concrete
• /
• 제7권1호
• /
• pp.17-38
• /
• 2010

This research aimed to investigate the influence of high-volume mineral admixtures (MAs), i.e., fly ash and slag, on the hydration characteristics and microstructures of cement pastes. Degree of cement hydration was quantified by the loss-on-ignition technique and degree of pozzolanic reaction was determined by a selective dissolution method. The influence of MAs on the pore structure of paste was measured by mercury intrusion porosimetry. The results showed that the hydration properties of the blended pastes were a function of water to binder ratio, cement replacement level by MAs, and curing age. Pastes containing fly ash exhibited strongly reduced early strength, especially for mix with 45% fly ash. Moreover, at a similar cement replacement level, slag incorporated cement paste showed higher degrees of cement hydration and pozzolanic reaction than that of fly ash incorporated cement paste. Thus, the present study demonstrates that high substitution rates of slag for cement result in better effects on the short- and long-term hydration properties of cement pastes.

• 한국콘크리트학회:학술대회논문집
• /
• 한국콘크리트학회 2002년도 가을 학술발표회 논문집
• /
• pp.567-572
• /
• 2002

This research investigates experimentally an effect on the quality performances of the high flowing concrete according to binder types. The purpose of this study is to determine the optimum mix proportion of the high flowing concrete having good flowability, viscosity and no-segregation. For this purpose, two types using belite cement＋lime stone powder(LSP) and furnace slag cement+lime stone powder are selected and tested by design factors including water cement ratio, fine and coarse aggregate volume ratio. As test results of this study, the optimum mix proportion for binder types is as followings. 1) One type based belite cement ; water cement ratio $51^{\circ}C$, fine aggregate volume ratio $43^{\circ}C$ and coarse aggregate volume ratio $53^{\circ}C$, replacement ratio of LSP $42.7^{\circ}C$. 2) Another type based slag cement : water cement ratio $41^{\circ}C$, fine aggregate volume ratio $47^{\circ}C$ and coarse aggregate volume ratio $53^{\circ}C$, replacement ratio of LSP $13.5^{\circ}C$.

• 콘크리트학회논문집
• /
• 제27권2호
• /
• pp.177-184
• /
• 2015

시멘트를 대체하여 고로슬래그 미분말을 건설재료로 대량으로 활용하기 위해서는 잠재수경성을 향상시켜 조기강도를 개선시킬 수 있는 적절한 활성화제가 필요하다. 이 연구에서는 경석고와 황산나트륨을 이용하여 하이볼륨 고로슬래그 시멘트의 수화특성에 대한 연구를 수행하였다. 수화특성을 평가하기 위해 고로슬래그 미분말을 전체 바인더의 80%로 고정하였으며, 나머지 20%를 시멘트와 활성화제로 구성하였다. 경석고와 황산나트륨의 치환율(1~7%)에 따른 응결, 압축강도, 미소수화열 및 미세구조 특성을 시멘트만을 사용한 경우와 비교하여 분석하였다. 이 연구에서는 경석고와 황산나트륨을 활성화제로 사용한 경우, 하이볼륨 고로슬래그 미분말의 조기 수화특성을 향상을 위해 필요한 $SO_3$ 함량을 전체 바인더 중량대비 약 3~5% 제안하였다.

• 한국콘크리트학회:학술대회논문집
• /
• 한국콘크리트학회 2006년도 추계 학술발표회 논문집
• /
• pp.881-884
• /
• 2006

Wasted phosphogypsum is a by-product from the phosphoric acid process of manufacturing fertilizers. It consists mainly of $CaSO_4{\cdot}2H_2O$ and contains some impurities. The purpose of this study is to utilize wasted phosphogypsum into an admixture for concrete products cured by steam This paper is to investigate the strength properties of cement composites containing high volume phosphogypsum. The cement composites were composed of OPC, phosphogypsum, fly-ash and granulated blast-furnace slag with activators. As a result, the strength of cement composites containing high volume wasted phosphogypsum were shown high level when granulated blast-furnace slag was mixed. Therefore, PG could be used as a steam curing admixture for concrete 2th production with reduction of OPC.

• 콘크리트학회논문집
• /
• 제17권3호
• /
• pp.473-480
• /
• 2005

In this study, a mix design for self compacting concrete was based on Okamura's method and concrete incorporated just a ground granulated blast furnace slag. Replacement ratio of slag is in the range of $20-80\%$ of cement matrix by volume. For the optimal self compactability in mixture incorporating ground granulated blast furnace slag, the paste and mortar tests were first completed. Then the slump flow, elapsed time of 500mm slump flow, V funnel time and filling height by U type box were conducted in concrete. The volume of coarse aggregate in self compacting concrete was in the range of $50-60\%$ to the solid volume percentage of coarse aggregate. Finally, the compressive and splitting tensile strengths were determined in the hardened self compacting concrete incorporating ground granulated blast furnace slag. From the test results, it is desirable for self compacting concrete that the replacement of ground granulated blast furnace slag is in the range of $40-60\%$ of cement matrix by volume and the volume of coarse aggregate to the solid volume percentage of coarse aggregate with a limit of $55\%$.

• 한국세라믹학회지
• /
• 제44권11호
• /
• pp.633-638
• /
• 2007

The setting time of alkali activated slag cement tends to be much faster than ordinary Portland cement, and its compressive strength had been higher from the 1 day but became lower than that of the cement on the 28 days. According to the results of the surface observation, weight loss, compressed strength, and erosion depth tests on the sulphuric acid solution. It has been drawn that alkali activated slag cement has a higher sulphate resistance than ordinary Portland cement, and in particular, the alkali activated slag cement added 5 wt% alumina cement has little deterioration on the sulphuric acid solution. The reason why the alkali activated slag cement has higher sulphate resistance than other hardened cement pastes is that it has no $Ca(OH)_2$ reactive to sulphate ion, and there is little $CaSO_4{\cdot}2H_2O$ production causing volume expansion, unlike other pastes. And it is supposed that $Al(OH)_3$ hydrates with high sulphate resistance, which is produced by adding the alumina cement increases the sulfate resistance.

• 한국건축시공학회:학술대회논문집
• /
• 한국건축시공학회 2017년도 춘계 학술논문 발표대회
• /
• pp.212-213
• /
• 2017

The study investigated the fluidity and compressive strength of non-cement porous block using blast furnace slag powder to reduce CO₂ in the construction industry.

• 시멘트 심포지엄
• /
• 통권39호
• /
• pp.137-142
• /
• 2012

• 한국건설순환자원학회논문집
• /
• 제5권1호
• /
• pp.8-13
• /
• 2017

본 연구는 $CO_2$를 다량 발생시키는 시멘트의 사용량을 줄이기 위한 일련의 연구로서, 산업부산물인 고로슬래그 미분말을 다량 치환하고 기존 알칼리 자극제를 대체하여 전기분해한 알칼리 수용액을 사용한 하이볼륨 시멘트 경화체의 개발을 위한 기초적인 연구를 수행하였다. 즉, 일반적인 시멘트를 사용한 시험체와 고로슬래그 미분말 40%, 60%에 일반적인 물과 전기분해 알칼리 수용액을 사용한 시험체에 대하여 압축강도, XRD 및 SEM을 측정하였다. 그 결과, 고로슬래그 미분말을 사용하는 경화체에 있어서 알칼리 수용액을 사용할 시 강도가 증가하고 입자 표면에 수화물이 다량 생성되는 결과를 얻었다. 특히, 고로슬래그 미분말을 40% 치환하고 알칼리 수용액을 사용한 경우, 일반적인 시멘트 경화체 보다 높은 압축강도를 발현하였다. 그러나 본 연구는 재령 10일에 한정하여 실시한 연구로서, 고로슬래그 및 전기분해 알칼리 수용액을 사용한 시험체에 대한 추가적인 연구가 필요하다고 판단된다.

• 한국건축시공학회:학술대회논문집
• /
• 한국건축시공학회 2012년도 추계 학술논문 발표대회
• /
• pp.103-105
• /
• 2012

With blast-furnace slag is a by-product generated when pig iron is produced. It has been used as the concrete admixture due to high reactivity. However, It causes low strength development during early age. In order to make up for this drawback, in this study, we evaluated compressive strength of mortar replaced with high volume blast-furnace slag. Experimental results, Compressive strength of mortar based on blast-furnace slag is affected by cement type, substitution rate of blast-furnace slag and pH after mixing.