• Computers and Concrete
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• v.7 no.1
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• pp.17-38
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• 2010

This research aimed to investigate the influence of high-volume mineral admixtures (MAs), i.e., fly ash and slag, on the hydration characteristics and microstructures of cement pastes. Degree of cement hydration was quantified by the loss-on-ignition technique and degree of pozzolanic reaction was determined by a selective dissolution method. The influence of MAs on the pore structure of paste was measured by mercury intrusion porosimetry. The results showed that the hydration properties of the blended pastes were a function of water to binder ratio, cement replacement level by MAs, and curing age. Pastes containing fly ash exhibited strongly reduced early strength, especially for mix with 45% fly ash. Moreover, at a similar cement replacement level, slag incorporated cement paste showed higher degrees of cement hydration and pozzolanic reaction than that of fly ash incorporated cement paste. Thus, the present study demonstrates that high substitution rates of slag for cement result in better effects on the short- and long-term hydration properties of cement pastes.

• Journal of the Korea institute for structural maintenance and inspection
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• v.26 no.6
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• pp.112-119
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• 2022

Recently, as carbon neutrality has been important factor in the construction industry, many studies have been conducted on the high-volume fly ash concrete. High volume fly ash concrete(HVFC) is usually made by replacing more than 50% of cement with fly ash. However, HVFC has a disadvantage of low compressive strength in early age. To overcome this shortcoming of HVFC, improve this, interest in techonolgy using nanomaterials is increasing. Nano silica is expected to improve the early age strength of HVFC as a pozzolanic material. This study investigated the effect of nano silica on the early hydration reaction and microstructure of HVFC. The early hydration reaction of HFVC was analyzed through setting time, isothermal calorimeter, compressive strength and thermal weight analysis. In addition, the microstructure of HVFC was measured by mercury intrusion porosimetry. From the test results, it was confirmed that nano silica increased the early age strength and improve the microstructure of HVFC.

• Journal of the Korean Recycled Construction Resources Institute
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• v.4 no.4
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• pp.439-445
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• 2016

Recently, a large number of researches about concrete containing high volume fly-ash(HVFA) have been carried to obtain carbon dioxide reduction, resource recycle and durable option in concrete industry. The quality of fly-ash such as chemical composition and fineness has high variability due to the differences of used fuels, operation condition in power plant. The aim of this study is to investigate the performances of fly-ash cement mortar containing different type of fly-ashes. The basic analysis of fly ash such as chemical composition, SEM image analysis were performed. Many mortar specimens were fabricated to evaluate the properties (compressive strength, drying shrinkage and carbonation) of mortar with various fly ash. From the test results, the quality of each fly ash must be considered and fully weighted in fly ash concrete.

• Proceedings of the Korean Society of Agricultural Engineers Conference
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• 1998.10a
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• pp.130-135
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• 1998

This paper presents results of research performed to identify optimum mix proportions for production of flowable fill with high volume fly ash content. The fly ash used in this study met the requirements of KS L 5405 and ASTM C 618 for Class F material. Tests were carried out on concrete designed to have 10 ~ 15kg/$\textrm{cm}^2$ compressive strength at the 28-day age with fly ash contents of approximately 280kg/㎥. Slump was held at 25$\pm$1cm for all mixtures produced compressive strengths at 28 days were found to range from 5.03 to 13.69kg/$\textrm{cm}^2$.

• Journal of the Korea Institute of Building Construction
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• v.10 no.1
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• pp.39-47
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• 2010

Fly ash has the advantages, among others, of improving the characteristics of concrete, reducing the price of concrete products, improving the durability, and reducing hydration heat. However, when added in mass, it leads to problems such as insufficient concrete intensity, increase of AE use, and others, resulting in a limitation of the use volume. Therefore, this study is undertaken to solve the problems associated with themass use of fly ash through the high concentration powder ($4000{\sim}8000cm^2/g$) of fly ash, curing method, the addition of an alkali stimulation agent and others for the purpose of increasing the added value of the fly ash. The research showed that the intensity manifestation has an outstanding status, with the hydrates reaching a very stable condition if the rate of addition of a stimulation agent is appropriately used with the heightening of the fineness of the fly ash in the temperature range of $40^{\circ}C$, and if the applicable study is continued, it is likely to result ineffective value generation on the massive replacement of fly ash.

• International Journal of Concrete Structures and Materials
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• v.10 no.1
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• pp.113-124
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• 2016

This paper presents the effect of silica fume and nano silica, used individually and in combination with the set accelerator and/or hydrated lime, on the properties of class F high volume ultra fine fly ash (HV-UFFA) cement composites, replacing 80 % of cement (OPC). Compressive strength test along with thermogravimetric analysis, X-ray diffraction and scanning electron microscopy were undertaken to study the effect of various elements on the physico-chemical behaviour of the blended composites. The results show that silica fume when used in combination with the set accelerator and hydrated lime in HV-UFFA cement mortar, improves its 7 and 28 day strength by 273 and 413 %, respectively, compared to the binary blended cement fly ash mortar. On the contrary, when nano silica is used in combination with set accelerator and hydrated lime in HV-UFFA cement mortar, the disjoining pressure in conjunction with the self-desiccation effect induces high early age micro cracking, resulting in hindering the development of compressive strength. However, when nano silica is used without the additives, it improves the 7 and 28 day strengths of HV-UFFA cement mortar by 918 and 567 %, respectively and the compressive strengths are comparable to that of OPC.

• Journal of the Korea Institute of Building Construction
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• v.3 no.2
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• pp.129-134
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• 2003

In this research, we used fly-ash and blast-furnace slag as substitute material of cement and fine aggregate, and we, through experiments, researched and analyzed the features of high-flowable concrete added high efficiency AE water reduction agent. The results are below. 1. Liquefaction generally presented high-slump flow value; on the other hand, partial segregation was observed in case of mixing proportion with 65 cm slump flow and above. This segregation was partially improved in accordance with mixing admixture. 2. Compressive strength according to mixing admixture and increasing mixing ratio of fly-ash were subject to be declined when it was initially cast-in, but its gap was improved when time was fully passed. 3. After mixing blast-furnace slag and fly-ash as substitute material, the result showed that the modulus of elasticity against freezing & melting was improved according to mixing blast-furnace slag and also increased in accordance with increasing pulverulent-body volume. 4. According to increasing the mixing volume of fly-ash, the durability factor was deteriorated because compressive strength became lower as well as air content was decreased when it was initially case-in. 5. The minimum air content to secure durability was 3.7%, for that reason, we had better secure admixture such as air entraining agent when cast-in high-flowable concrete.

• Proceedings of the Korea Concrete Institute Conference
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• 2002.10a
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• pp.437-442
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• 2002

Drying shrinkage is the decrease in the volume of a concrete element when it loses moisture by evaporating. Because of low water/binder ratio(W/B) and the use of chemical and mineral admixtures for high-strength concrete, the evolutions of moisture and the rate of cement hydration in high- strength concrete are significantly different from those in normal strength concrete. In this study, the drying shrinkage of high-strength concrete with and without fly ash was measured up to the age of 200 days. From the experimental test results, it was observed that the drying shrinkage decreased as the W/B decreased. As the W/B is lowered from 0.50 to 0.27, the difference of drying shrinkage between the fly ash concrete and the ordinary concrete is gradually increased.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2021.05a
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• pp.129-130
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• 2021

In order to solve the problem of low early-age compressive strength of high volume fly ash concrete. This paper studies the effect of 2% sodium sulfate (Na₂SO₄) as a chemical activator on the paste with 40% fly ash content and a water-binder ratio of 0.30. The results indicate that the addition of Na₂SO₄ can effectively improve the early-age compressive strength of the fly ash-cement system, and the strength improvement rate on the first day reached nearly 70%. In addition, calorimetric analysis reveals that the incorporation of Na₂SO₄ promotes the early hydration of cement and fly ash, increases the cumulative hydration heat and delays the heat peak of the aluminum phase.

• Proceedings of the Korea Concrete Institute Conference
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• 2008.11a
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• pp.637-640
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• 2008

In this study, the characteristics of strength development on high volume fly ash concrete(HVFAC)with Type 4 cement was experimentally investigated. Three levels of W/B were selected. Four levels of fly ash replacement ratios and two levels of silica fume replacement ratios were adopted. In the concrete mix, the water content of 125kg/m$^3$ was used, which is less than that of usual water content. As a result, it appeared that the compressive strength gradually decreased with increasing fly ash replacement ratio until 91days. However, regarding the compressive strength, the proper replacement ratio is about 20%, which is low compared to Type I cement case. It was observed that the tensile strength is proportional to the 0.72 power of the compressive strength. It appears that the prediction equation presented in Concrete Standard Specification overestimate the tensile strength in the low strength range, underestimate the tensile strength in the hi호 strength range.