• 한국신재생에너지학회:학술대회논문집
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• 2010.11a
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• pp.80.2-80.2
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• 2010

The development of high temperature-proton exchange fuel cell (HT-PEFC) is a key in solving the problem of carbon monoxide poisoning of the platinum at anode as well as water management in PEFCs operated below $90^{\circ}C$. In order to overcome these main issues, PEFCs must be operated at high temperature above $120^{\circ}C$. Ionic liquids are available for HT-PEFC due to exhibiting non-volatility and thermal stability. Ionic liquids are however leached out from polymeric matrix resulting in the increase of gas permeability. In this study, we have prepared and characterized the composite membranes with the ionic liquids consisting of 1-(4-vinylbenzyl)-3-butyl imidazolium chloride immobilized by the cross-linkers in pore-filling membrane to prevent to be leached out from the membrane. We confirmed that cross-linked ionic liquids were not leached out from the composite membranes through the various characteristic analyses. It was also verified that the prepared membranes are thermally stable from the result of TG analysis. The pore-filling membranes with the immobilized ionic liquids have a high proton conductivity over $10^{-2}$ S/cm at high temperature (> $120^{\circ}C$).

• Transactions of the Korean hydrogen and new energy society
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• v.24 no.1
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• pp.70-75
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• 2013

It has fabricated membrane electrode assemblies (MEA) for proton exchange membrane fuel cell by hot-pressing method. The hot-pressing was used for the fabrication of MEA which is composed of commercial platinum electrode on carbon paper. The performance of MEA was studied with different fabrication conditions of temperature, pressure and torque. As the temperature increased, the performance of MEA was increased. and started to decrease l after arrived at the maximum performance of MEA. This is related with good contact between electrode and polymer electrolyte membrane at high temperature and microstructural change at much higher temperature. Similarly, as the pressure increased, the performance of the MEA increased up to highest values and start to decrease. According to the our results, the maximal performance of the MEA was at the temperature of $140^{\circ}C$ and the pressure of $1.5{\times}10^3$ kPa. The optimal torque to assemble the single stack was 3.2 N m.

• Bulletin of the Korean Chemical Society
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• v.33 no.10
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• pp.3279-3284
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• 2012

Poly(benzimidazole-co-benzoxazole)s (PBI-co-PBO) are synthesized by polycondensation reaction with 3,3'-diaminobenzidine, terephthalic acid and 3,3'-dihydroxybenzidine or 4,6-diaminoresorcinol in polyphosphoric acid (PPA). All polymer membranes are prepared by the direct casting method (in-situ fabrication). The introduction of benzoxazole units (BO units) into a polymer backbone lowers the basic property and $H_3PO_4$ doping level of the copolymer membranes, resulting in the improvement of mechanical strength. The proton conductivity of $H_3PO_4$ doped PBI-co-PBO membranes decrease as a result of adding amounts of BO units. The maximum tensile strength reaches 4.1 MPa with a 10% molar ratio of BO units in the copolymer. As a result, the $H_3PO_4$ doped PBI-co-PBO membranes could be utilized as alternative proton exchange membranes in high temperature polymer electrolyte fuel cells.

• Transactions of the Korean hydrogen and new energy society
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• v.29 no.1
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• pp.41-55
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• 2018

General polymer electrolyte fuel cell (PEMFC) operates at less than $80^{\circ}C$. Therefore liquid phase water resulting from electrochemical reaction accumulates and floods the cell which in turn increases the mass transfer loss. To prevent the flooding, it is common to employ serpentine flow channel, which can efficiently export liquid phase water to the outlet. The major drawback of utilizing serpentine flow channel is the large pressure drop that happens between the inlet and outlet. On the other hand, in the high temperature polymer electrolyte fuel cell (HT-PEMFC), since the operating temperature is 130 to $180^{\circ}C$, the generated water is in the state of gas, so the flooding phenomenon is not taken into consideration. In HT-PEMFCs parallel flow channel with lower pressure drop between the inlet and outlet is employed therefore, in order to circulate hydrogen and air in the cell less pumping power is required. In this study we analyzed HT-PEMFC's different flow channels by parallel computation using previously developed 3-D isothermal model. All the flow channels had an active area of $25cm^2$. Also, we numerically compared the performance of HT-PEMFC parallel flow channel with different manifold area and Rib interval against the original serpentine flow channel. Results of the analysis are shown in the form of three-dimensional contour polarization curves, flow characteristics in the channel, current density distribution in the Membrane, overpotential distribution in the catalyst layer, and hydrogen and oxygen concentration distribution. As a result, the performance of a real area fuel cell was predicted.

• Transactions of the Korean hydrogen and new energy society
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• v.22 no.6
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• pp.819-826
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• 2011

The proton exchange membrane fuel cell (PEMFC) is regarded as the most promising alternative power sources for unmanned aerial vehicle (UAV) due to its high energy density and silent operation. Since there are many load changes during UAV flight, thermal management is one of the important factor for the performance of PEMFC. In order to reduce the UAV weight for the stable operation of UAV, thermal management system (TMS) studied in this work does not use the fan but use the air flowing into UAV by UAV flight. In order to develop the passive type heat exchanger (HEX) for 1kW PEMFC, four types of HEXs are fabricated and their cooling performances are compared. The parametric study on the cooling performance of HEXs has performed with the variation of operating parameters such as mass flow rates and inlet temperature of air and coolant. Type 4 has the best performance in every case. This study can be helpful to achieve the optimal design of HEX for PEMFC powered UAV.

• Transactions of the Korean hydrogen and new energy society
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• v.27 no.1
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• pp.42-48
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• 2016

This study presents an experiment investigation on natural convection heat transfer of air-cooling Proton exchange membrane fuel cells (PEMFCs) in a enclosure system for unmanned aerial vehicles (UAVs). Considered are replacing fuel cell stack with Aluminum block for heat generating inside a enclosure chamber. The volume ratio of fuel cell stack and chamber for simulation to the actual size of aerial vehicle is 1 to 15. The parameters considered for experimental study are the environmental temperature range from $25^{\circ}C$ to $-60^{\circ}C$ and the block heat input of 10 W, 20 W and 30 W. Effect of the thermal conductivity of the block and power level on heat transfer in the chamber are investigated. Experimental results illustrate the temperature rise at various locations inside the chamber as dependent upon heat input of fuel cell stack and environmental temperature. From the results, dimensionless correlation in natural convection was proposed with Nusselt number and Rayleigh number for designing air-cooling PEMFC powered high altitude long endurance (HALE) UAV.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.33 no.12
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• pp.1022-1030
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• 2009

Numerical analysis was carried out to investigate the effect of GDL (Gas diffusion layer) porosity on the performance of PEMFC (proton exchange membrane fuel cell). A complete three-dimensional model was chosen for single straight channel geometry including cooling channel. Main emphasis is placed on the heat and mass transfer through the GDL with different porosity. The present numerical results show that at high current densities, the cell voltage is influenced by the GDL porosity while the cell performance is nearly the same at low current densities. At high current densities, low value of GDL porosity results in decrease of the fuel cell performance since the diffusion of reactant gas through GDL becomes slow with decreasing porosity. On the other hand, for high GDL porosity, the effective thermal conductivity becomes low and the heat generated in the cell is not removed rapidly. This causes the temperature of fuel cell to increase and gives rise to dehydration of the membrane, and ultimately increase of the ohmic loss.

• Korean Membrane Journal
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• v.9 no.1
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• pp.52-56
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• 2007

A proton exchange membrane was prepared by ${\gamma}-irradiation-induced$ grafting of styrene into poly(tetrafluoro-ethylene-co-perfluoropropyl vinyl ether) (PFA) and subsequent sulfonation reaction. The degree of grafting (DOG) increased with an increase in the absorbed dose. The prepared membranes showed high ion exchange capacity reaching 3.0 meq/g, which exceeded the performance of commercially available perfluorosulfonic acid membranes such as Nafion. The proton conductivity of PFA-g-PSSA membrane increased with the DOG and reached 0.17 S/cm for the highest sample at room temperature. The DMFC performance of the prepared membranes with 50% DOG was comparable to that of Nafion membrane.

• Applied Chemistry for Engineering
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• v.30 no.6
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• pp.659-666
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• 2019

Proton exchange membrane fuel cells (PEMFCs) generate electricity by electrochemical reactions of hydrogen and oxygen. PEMFCs are expected to alternate electric power generator using fossil fuels with various advantages of high power density, low operating temperature, and environmental-friendly products. PEMFCs have widely been used in a number of applications such as fuel cell vehicles (FCVs) and stationary fuel cell systems. However, there are remaining technical issues, particularly the long-term durability of each part of fuel cells. Degradation of a carbon supported-platinum catalyst in the anode and cathode follows various mechanistic origins in different fuel cell operating conditions, and thus accelerated stress test (AST) is suggested to evaluate the durability of electrocatalyst. In this article, comparable protocols of the AST durability test are intensively explained.

• Transactions of the Korean hydrogen and new energy society
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• v.24 no.1
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• pp.50-60
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• 2013

High temperature proton exchange membrane fuel cells (PEMFCs) using phosphoric acid (PA) doped polybenzimidazole (PBI) membranes have been concentrated as one of solutions to the limits with traditional low temperature PEMFCs. However, the amount of reported experimental data is not enough to catch the operational characteristics correlated with cell performance and durability. In this study, design of experiments (DOE) based operational optimization method for high temperature PEMFCs has been proposed. Response surface method (RSM) is very useful to effectively analyze target system's characteristics and to optimize operating conditions for a short time. Thus RSM using central composite design (CCD) as one of methodologies for design of experiments (DOE) was adopted. For this work, the statistic models which predict the performance and degradation rate with respect to the operating conditions have been developed. The developed performance and degradation models exhibit a good agreement with experimental data. Compared to the existing arbitrary operation, the expected cell lifetime and average cell performance during whole operation could be improved by optimizing operating conditions. Furthermore, the proposed optimization method could find different new optimal solutions for operating conditions if the target lifetime of the fuel cell system is changed. It is expected that the proposed method is very useful to find optimal operating conditions and enhance performance and durability for many other types of fuel cell systems.