• Title/Summary/Keyword: high temperature high pressure

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Numerical analysis of the coupled heat and mass transfer phenomena in a metal hydride hydrogen storage reactor(I) - Model development of analyzation for hydrogen absorption reaction using the $LaNi_5$ bed (금속수소화물 수소저장 용기 내부의 열 및 물질전달 현상에 대한 수치적 연구(I) - $LaNi_5$ 베드를 이용한 수소 흡장반응 해석 모델 개발)

  • Nam, Jinmoo;Ju, Hyunchul
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.06a
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    • pp.225.1-225.1
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    • 2010
  • Within recent years attention has been focused on the method of hydrogen storage using metal hydride reactor due to its high energy density, durability, safety and low operating pressure. In this paper, a numerical study is carried out to investigate the coupled heat and mass transfer process for absorption in a cylindrical metal hydride hydrogen storage reactor using a newly developed model. The simulation results demonstrate the evolution of temperature, equilibrium pressure, H/M atomic ratio and velocity distribution as time goes by. Initially, hydrogen is absorbed earlier from near the wall which sets the cooling boundary condition owing to that absorption process is exothermic reaction. Temperature increases rapidly in entire region at the beginning stage due to the initial low temperature and enough metal surface for hydrogen absorption. As time goes by, temperature decreases slowly from the wall region due to the better heat removal. Equilibrium pressure distribution appears similarly with temperature distribution for reasons of the function of temperature. This work provides a detailed insight into the mechanism and corresponding physicochemical phenomena in the reactor during the hydrogen absorption process.

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The Characteristics of Local Reaction Intensity with Changing Combustor Pressure in the Swirl-stabilized Flame (스월화염에서 연소실 압력 변동에 의한 국소 반응강도의 특성)

  • Noh, Young-Gu;Kim, Jong-Ryul;Kim, Tae-Hyung;Seo, Sang-Il;Kim, Sung-Chul;Na, Jong-Moon;Choi, Gyung-Min;Kim, Duck-Jool
    • Journal of the Korean Society of Combustion
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    • v.14 no.4
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    • pp.41-47
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    • 2009
  • An experimental study was performed to confirm the effect of the changing combustor pressure(-30~30 kpa), combustion characteristics were investigated by measuring the local chemiluminescence intensity, the local temperature distribution and emission. In order to investigate combustion ones, the combustor pressure index($P^*$) was controlled in the range of 0.7~1.3 for each equivalence ratio in the present combustion system, where $P^*$ is defined as the ratio of absolute pressure to atmospheric one. The local mean temperature showed the uniform distributions for lower pressure index, which increased with increasing equivalence ratio. The mean $OH^*$ chemiluminescence intensity, showed high level for lower pressure index for ${\Phi}{\get}1.0$ conditions. EINOx decreased with decreasing pressure index for overall equivalence ratio conditions.

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Effects of Deposition Pressure on the Phase Formation and Electrical Properties of BiFeO3 Films Deposited by Sputtering

  • Park, Sang-Shik
    • Korean Journal of Materials Research
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    • v.19 no.11
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    • pp.601-606
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    • 2009
  • $BiFeO_3$ (BFO) thin films were prepared on $Pt/TiO_2/Si$ substrate by r.f. magnetron sputtering. The effects of deposition pressure on electrical properties were investigated using measurement of dielectric properties, leakage current and polarization. When BFO targets were prepared, Fe atoms were substituted with Mn 0.05% to increase electrical resistivity of films. (Fe+Mn)/Bi ratio of BFO thin films increases with increasing partial pressure of $O_2$ gas. The deposited films showed the only BFO phase at 10 mTorr, the coexistence of BFO and $Bi_2O_3$ phase at 30-50 mTorr, and the only $Bi_2O_3$ phase at 70 mTorr. The crystallinity of BFO films was reduced due to the higher Bi contents and the decrease of surface mobility of atoms at high temperature. The porosity and surface roughness of films increased with the increase of the deposition pressure. The films deposited at high pressure showed low dielectric constant and high leakage current. The dielectric constant of films deposited at various deposition pressures was 84${\sim}$153 at 1 kHz. The leakage current density of the films deposited at 10${\sim}$70 mTorr was about $7{\times}10.6{\sim}1.5{\times}10.2A/cm^2$ at 100 kV/cm. The leakage current was found to be closely related to the morphology and composition of the BFO films. BFO films showed poor P-E hysteresis loops due to high leakage current.

Numerical Study on Cavitation Reduction in Velocity-Control Trim of Valve with High Pressure Drop (고차압 밸브의 속도제어형 트림에서 케이테이션 억제에 관한 수치적 연구)

  • Kim, Dae Kwon;Sohn, Chae Hoon
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.37 no.9
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    • pp.863-871
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    • 2013
  • Flow characteristics of velocity-control trim in a valve is investigated numerically with high pressure drop. A basic trim widely used for a valve in domestic powerplants is selected and designed for a baseline of velocity-control trim. The numerical analysis is focused on flow rate and cavitation with the basic trim. For a condition of high-pressure drop, pressure drop between inlet and outlet and fluid temperature are selected to be 18.1 MPa and $160^{\circ}C$, respectively, which are typical ones considering operating conditions adopted in powerplants. With this baseline model and condition, design changes are made for improvement of flow rate and cavitation phenomenon. For re-design, trim is divided into three zones in radial direction and design parameters of flow area, stage, and flow direction are considered in each zone. With these combined parameters applied to each zone, 4 models with design changes are proposed and their flow rates and cavitation areas are investigated. From comparison with those in the baseline model of a basic trim, proposed models show better performance in both flow rate and cavitation.

A Study on Soot Formation in Premixed Constant-Volume Combustion at High Pressures (高壓下의 定積 豫混合氣燃燒에 있어서 煤煙생成에 關한 硏究)

  • 임재근;배명환;김종일
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.16 no.3
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    • pp.589-597
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    • 1992
  • The effect of pressure on soot formation in premixed propane-air combustion is investigated at high pressures over the pressure range of 1 to 5 MPa by using a specially designed constant volume combustion bomb. The combustiom chamber of disk type with eight spark plugs located on the circumference at an interval of 45deg is 100mm in diameter by 14mm thick. The end gases are compressed to high pressures by the eight converging flames. The soot volume fraction in the chamber center during the final stage of combustion at the highest pressure is measured by the in-situ laser extinction technique, and the burnt gas temperature during the same period is measured by the two-color method. It is found that the soot yield rises with 50 to 100% for the respective equivalence ratio range of 1.9-2.2 at an interval of 0.1 when the combustion pressure is increased from 1 to 5 MPa, and that the turbulent flames decrease in the soot yield as compared with the laminar flames because the burnt gas temperatures increase with the drop of heat loss.

Denaturation of Heat Treated Lysozyme under High Pressure Conditions (고압조건에서 가열 처리된 Iysozyme의 변성)

  • Cho, Rae-Kwang;Hong, Jin-Hwan
    • Korean Journal of Food Science and Technology
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    • v.23 no.3
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    • pp.366-369
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    • 1991
  • In order to elucidate texturization mechanism of extrudated protein, egg white lysozyme was heated under high pressure conditions, and its solubility and changes of molecular weight were investigated. Under high pressure conditions of $100,\;300\;and\;600\;kg/cm^2$, solubility decreased gradually with increasing temperature in the samples heated at $70,\;120\;and\;150^{\circ}C$ and decreased notably with increasing pressure at $200^{\circ}C$. Polymerization was found in the samples heated at $150\;and\;200^{\circ}C$ while a band which located below monomer(low-molecular) could be recognized. Molecular weight of the low-molecular was estimated to be about $6,000{\sim}9,000$ and no smaller peptide was recognized. The polymerization may have occured by disulfide crosslinking in the samples heated at $120^{\circ}C$ but other crosslinking may have played a role in those at $150\;and\;200^{\circ}C$.

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The Relationship between the Arctic Oscillation and Heatwaves on the Korean Peninsula (여름철 북극 진동과 한반도 폭염의 관련성)

  • Jeong-Hun Kim;El Noh;Maeng-Ki Kim
    • The Korean Journal of Quaternary Research
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    • v.33 no.1_2
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    • pp.25-35
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    • 2021
  • In this study, we identified characteristics of heatwaves on the Korean Peninsula and related atmospheric circulation patterns using data on the daily maximum temperature (TMX) and reanalysis data for the past 42 years (1979-2020) and analyzed their connection to the Arctic oscillation (AO). The heatwave on the Korean Peninsula showed to be stronger and more frequent in the 2000s. The recent strong and frequent heatwaves on the Korean Peninsula are mainly affected by abnormal high-pressure over the Korean Peninsula on the middle/upper-level atmosphere and the strengthening of the North Pacific high pressure. Interestingly, composite difference of sea level pressure showed very similar results to the positive AO pattern. The correlation coefficients between the summertime AO and the TMX and HWD of the Korean Peninsula were 0.407 and 0.437, respectively, which showed a statistical significance in 1%, and showed a clear relationship with the abnormal high-pressure over the Korean Peninsula and the strengthening of the North Pacific high pressure. In addition, in the positive AO phase, the TMX and HWD of the Korean peninsula were approximately 30.1 ℃ and 14.6 days, which were about 1.2 ℃ and 8.8 days higher than in the negative AO phase, respectively. As a result of the 15-year moving average correlation analysis, the relationship between the heatwave and AO on the Korean Peninsula has increased significantly since 2003, and the linear relationship between them has become more apparent. Moreover, after the 2000s, when the relationship developed, AO had more strongly induced the atmospheric circulation pattern to be more favorable to the occurrence of heatwaves in the Korean Peninsula. This study implies that understanding the AO, which is the large-scale variability in the Northern Hemisphere, and the Arctic-mid latitude teleconnection, can improve the performance of global climate models and help predict the seasonality of the summer heatwave on the Korean Peninsula.

A CFD Analysis Study on the Characteristics of Hydrogen Production by High Temperature Steam Electrolysis(HTSE) Using High Temperature Heat (고온열을 이용한 고온수증기전기분해장치(HTSE)에 의한 수소생산 특성에 관한 전산유체해석적 연구)

  • Han, Won-Hui;Choi, Jung-Sik;Yoon, Seok-Hun;Yoon, Doo-Ho;Choi, Jae-Hyuk
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.17 no.4
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    • pp.419-427
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    • 2011
  • The characteristics for hydrogen production and the thermochemical properties of high temperature steam electrolysis(HTSE) device have been numerically analyzed in a two-dimension, steady-state with using the COMSOL $Multiphysics^{(R)}$. The main parameters for the calculation are applied voltage, ASR(Area-specific Resistance), temperature and pressure of the inlet gas flow. The results showed that thermal-neutral voltage was 1.2454 V and rather than the cell temperature increases or decreases with increasing applied voltage by thermal-neutral voltage starting this voltage the temperature in high voltage tended to rise and temperature in the low voltage tended to fall. And with, increasing the values of ASR, temperature inside the cell and the hydrogen production rate were decreased.

Micro-mechanical Modeling of the Consolidation Processes in Titanium Metal Matrix Composites (티타늄금속기 복합재료의 강화공정에 관한 미시역학적 모델링)

  • 김준완;김태원
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2002.05a
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    • pp.207-210
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    • 2002
  • Metal matrix composites(MMCs) are increasingly attractive for high technology components such as aerospace applications and transportations due to their high strength, stiffness, and toughness. Many processes for fabricating MMCs have been developed, and relatively simple Foil-Fiber-Foil method is usually employed in solid state consolidation processes. During the consolidation processes at high temperature, densification occurs by the inelastic flow of the matrix materials, and the process is coupled with the conditions of pressure, temperature and volume fraction of fiber and matrix materials. This is particularly important in titanium matrix composites, and thus a generic model based on micro-mechanical approaches enabling the evolution of density over time to be predicted has been developed. The mode developed is then implemented into FEM so that practical process simulation has been carried out. Further the experimental investigation of the consolidation behavior of SiC/Ti-6Al-4V composites using vacuum hot pressing has been performed, and the results obtained are compared with the model predictions.

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Characterization and Construction of Chemical Vapor Deposition by using Plasma (rf 플라즈마 화학기상증착기의 제작 및 특성)

  • 김경례;김용진;현준원;이기호;노승정;최병구
    • Journal of Surface Science and Engineering
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    • v.33 no.2
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    • pp.69-76
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    • 2000
  • The rf plasma chemical vapor deposition is a common method employed for diamond or amorphous carbon deposition. Diamond possesses the strongest bonding, as exemplified by a number of unique properties-extraordinary hardness, high thermal conductivity, and a high melting tempera tore. Therefore, it is very important to investigate the synthesis of semiconducting diamond and its use as semiconductor devices. An inductively coupled rf plasma CVD system for producing amorphous carbon films were developed. Uniform temperature and concentration profiles are requisites for the deposition of high quality large-area films. The system consists of rf matching network, deposition chamber, pumping lines for gas system. Gas mixtures with methane, and hydrogen have been used and Si (100) wafers used as a substrate. Amorphous carbon films were deposited with methane concentration of 1.5% at the process pressure of S torr~20 torr, and process temperature of about $750^{\circ}C$. The nucleation and growth of the amorphous carbon films have been characterized by several methods such as SEM and XRD.

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