• Title/Summary/Keyword: high temperature high pressure

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Flexible Dye-sensitized Solar Cells by a Low-temperature Sintering Method (저온소결법에 의한 플렉시블 염료감응 태양전지)

  • Baek, Ji-Hye;Kim, Joo-yong;Kang, Wee-Kyung
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.06a
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    • pp.320-322
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    • 2007
  • A new binder-free $TiO_{2}$ paste was prepared by common ion applying effect, enabling low temperature fabrication required for flexible solar cells. The binder-free and high viscosity $TiO_{2}$ coating solution was produced by adding 7.5% aniline in $TiO_{2}$ colloid solution obtained from the high pressure water-heat response method. The resulting pastes had high level of viscosities proper for optimal coating and thus revealed excellent performances in terms of thickness uniformity and I-V characteristics.

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Multiscale modeling of the anisotropic shock response of β-HMX molecular polycrystals

  • Zamiri, Amir R.;De, Suvranu
    • Interaction and multiscale mechanics
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    • v.4 no.2
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    • pp.139-153
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    • 2011
  • In this paper we develop a fully anisotropic pressure and temperature dependent model to investigate the effect of the microstructure on the shock response of ${\beta}$-HMX molecular single and polycrystals. This micromechanics-based model can account for crystal orientation as well as crystallographic twinning and slip during deformation and has been calibrated using existing gas gun data. We observe that due to the high degree of anisotropy of these polycrystals, certain orientations are more favorable for plastic deformation - and therefore defect and dislocation generation - than others. Loading along these directions results in highly localized deformation and temperature fields. This observation confirms that most of the temperature rise during high rates of loading is due to plastic deformation or dislocation pile up at microscale and not due to volumetric changes.

Characteristics of Hot Embossing using DVD/Blu-ray Stamper (DVD/Blu-ray 스템퍼를 이용한 핫엠보싱 특성)

  • Kim B. H.;Ban J. H.;Shin J. K.;Kim H. Y.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2004.10a
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    • pp.305-310
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    • 2004
  • The Hot Embossing Lithography(HEL) as a method for the fabrication of nanostructure with polymer is becoming increasingly important because of its simple process, low cost, high replication fidelity and relatively high throughput. In this study, we investigated the characteristics of hot embossing lithography as a nanoreplication technique. To grasp characteristics of nano patterning rheology by process parameters(embossing temperature, pressure and time), we have carried out various experiments by using the DVD(400nm pattern width) and Blu-ray nickel stamps(150nm pattern width). During the hot embossing process, we have observed the characteristics of the size effect. The quality of products made by hot embossing is affected by its cooling shrinkage. The demolding process at the glass transition temperature results in low quality because of the shrinkage of the polymer. Therefore, the quantification of the temperature condition is essential for the replication of high quality.

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Use of High-Temperature Gas-Tight Electrochemical

  • Park, Jong-Hee;Beihai Ma;Park, Eun-Tae
    • The Korean Journal of Ceramics
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    • v.4 no.2
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    • pp.103-113
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    • 1998
  • By using a gas-tight electrochemical cell, we can perform high-temperature coulometric titration and measure electronic transport properties to determine the elecronic defect structure of metal oxides. This technique reduces the time and expense required for conventional thermogravimetric measurements. The components of the gas-tight coulometric titration cell are an oxygen sensor, Pt/yttria stabilitized zirconia(YSZ)/Pt, and an encapsulated metal oxide sample. Based on cell design, both transport and thermodynamic measurements can be performed over a wide range of oxygen partial pressure ($pO_2=10^{-35}$ to 1 atm). This paper describes the high-temperature gas-tight electrochemical cells used to determine electronic defect structures and transport properties for pure and doped-oxide systems, such as YSZ, doped and pure ceria $(Ca-CeO_2 \;and\; CeO_2)$, copper oxides and copper-oxide-based ceramic superconductors, transition metal oxides, $SrFeCo_{0.5}O_x,\; and \;BaTiO_2$.

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Microstructure and Mechanical Properties of Rapidly Solidified Powder Metallurgy Al-Fe-V-Si-X Alloys

  • Genkawa, Takuya;Yamasaki, Michiaki;Kawamura, Yoshihito
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09b
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    • pp.1041-1042
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    • 2006
  • High heat-resistant Al-Fe-V-Si and Al-Fe-V-Si-X rapidly solidified powder metallurgy (RS P/M) alloys have been developed under well-controlled high purity argon gas atmosphere. The $Al_{90.49}Fe_{6.45}V_{0.68}Si_{2.38}$ (at. %) RS P/M alloy exhibited high elevated-temperature strength exceeding 300 MPa and good ductility with elongation of 6 % at 573 K. Reduction of $H_2O$ partical pressure in P/M processing atmosphere led to improvement in mechanical properties of the powder-consolidated alloys under elevated-temperature service conditions. Ti addition to the Al-Fe-V-Si conduced to enhancement of the strength at room temperature. The tensile yeild strength and ultimate strenght were 545 MPa and 722 MPa, respectively.

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Fabrication of SiCN structures using PDMS mold for high-temperature applications (PDMS 몰드를 이용한 초고온용 SiCN 구조물의 제작)

  • Woo, Hyung-Soon;Kim, Gue-Hyun;Chung, Gwiy-Sang
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.11a
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    • pp.376-379
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    • 2003
  • In this paper, a novel processing technique for fabrication of high-temperature MEMS based on polymer-derived SiCN microstructures is described. PDMS molds are fabricated on SU-8 photoresist using standard UV-photolithographic processes. Liquid precursors are injected into the PDMS mold. And then, the resulting solid polymer structures are crosslinked under isostatic pressure, and pyrolyzed to form a ceramic capable of withstanding over $1500^{\circ}C$. These fabricated SiCN structures would be applied for high-temperature applications, such as heat exchanger and combustion chamber.

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An Experimental Study on Spalling Reduction Methode of Polymer Modified Cement Mortar Using Fiber Cocktail (섬유혼입 공법을 이용한 폴리머 시멘트 모르타르의 폭렬저감방안에 관한 실험적 연구)

  • Kim, Ji-Hoon;Ryu, Dong-Woo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2020.06a
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    • pp.96-97
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    • 2020
  • Polymer modified cement mortar (PCM) is commonly used as a repair material. However, in high-temperature environments such as fire, it is more likely to explode than cement mortar. The polymer is thermally decomposed at a high temperature to form a gas, and the gas remaining inside the structure increases the internal pressure to generate a burst. When an spalling occurs, the coating is peeled off and dropped, and high temperature is transmitted to the inside of the structure. In severe cases, even the reinforcing bar is exposed, which can lead to the collapse of the structural member due to severe loss of strength. In this study, in order to reduce spalling of PCM, a fiber mixing method was selected from the refractory method to find an appropriate blending ratio of fibers and polymers.

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Study on the fuel rail temperature and pressure characteristics with LPG composition during hot restart condition of LPi engine with turbine type pump (터빈방식 펌프 LPi연료공급 시스템의 엔진 고온재시동 시 LPG 조성비에 따른 연료레일에서의 압력 및 온도특성에 관한 연구)

  • Lee, Kang-Ju;Kim, Ju-Won;Myung, Cha-Lee;Park, Sim-Soo
    • Proceedings of the KSME Conference
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    • 2007.05b
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    • pp.3323-3328
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    • 2007
  • Conventional LPG pump for Liquified Petroleum injection(LPi) engine has been adopted vane type. But the BLDC type fuel pump for LPi system has complicated structure and its price is high. Therefore, as a alternative, this study has mainly focused on the development of turbine type LPG pump which has lower cost and simple structure than conventional BLDC type. To verify the possibility of substitute the performance tests were performed for each fuel pump. The comparative items were pressure settling time, variation of fuel outlet temperature and engine performance of hot restart ability. As a result, performances of turbine type LPG pump were equivalent or high comparing to the BLDC type all over the tests for different fuel composition.

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Reflections of shocks in nonequilibrium flow of air

  • Park, Tae-Hoon
    • Communications of the Korean Mathematical Society
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    • v.10 no.3
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    • pp.767-781
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    • 1995
  • In this paper we present computation of a reflected shock in the hypersonic flow of air with chemical reactions. We consider two dimensional steady inviscid hypersonic flow of air around bodies including chemical reaction effects. At a high Mach number, a strong shock is formed in front of the body when a wedge is placed against the flow. In front of the shock, temperature and pressure increase greatly and the flow is in nonequilibrium state. If the shock hits a wall, then a reflected shock is formed in the nonequilibrium flow region. Behind this reflected shock, the temperature and pressure are very high. We carry out the computation of the reflected shock and the flow behind it. The jump conditions at the reflected shock are presented. A technique combining smooth transforms of domain and implicit difference methods is used to overcome numerical difficulties associated with the lack of resolution behind the shock and near the body.

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Integrated Expansion Analysis of Pipe-In-Pipe Systems

  • Choi, Han-Suk;Do Chang-Ho
    • Journal of Ocean Engineering and Technology
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    • v.20 no.5 s.72
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    • pp.9-14
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    • 2006
  • This paper presents an analytical method, application of expansion, mechanical design, and integrated expansion design of subsea insulated pipe-in-pipe (PIP) systems. PIP system consists of a flowline and a casing pipe for the transport of high temperature and high pressure product from the subsea wells. To prevent heat lass from the fiowline, insulation material is applied between the pipes. The fiawline pipe and the casing pipe have mechanical connections through steel ring plate (water stops) and bulkheads. Pipeline expansion is defined by temperature, internal pressure, soil resistance, and interaction force between the flowline and the casing pipe. The results of the expansion analysis, the mechanical design of connection system of the two pipes and tie-in spool design are integrated for the whole PIP system.