• Title/Summary/Keyword: high temperature high pressure

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A Study of Hydrodenitrogenation of Quinoline Catalyzed by Sulfided $Ni-Mo/\gamma - Al_2O_3$ (황화 $Ni-Mo/\gamma - Al_2O_3$ 촉매상에서 Quinoline의 수소첨가탈질반응에 관한 연구)

  • 최응수;이원묵;김경림
    • Journal of Korean Society for Atmospheric Environment
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    • v.5 no.1
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    • pp.52-61
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    • 1989
  • The hydrodenitrogenation of quinoline dissolved in n-heptane was studied over sulfided Ni-Mo/$\gamma-Al_2O_3$ catalyst at the range of the temperature between 553 K and 673 and the total pressure between $20 \times 10^5$ Pa and $60 \times 10^5$ Pa in a fixed bed flow reactor. Quinoline conversion was very high at relatively low temperature and total pressure, and decreased with quinoline partial pressure. The thermodynamic equilibrium between quinoline and Py-THQ existed in wide ranges of experimental conditions and shifted in favor of quinoline at higher temperature. At the range of the temperature betwwen 553 K and 673 K and at the total pressure $60 \times 10^5$ Pa, the quinoline reaction rate was 1st order with respect to the concentr4ation of quinoline and its apparent activation energy was 7.15 Kcal/mole.

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수송기계 엔진용 3C-SiC 마이크로 압력센서의 제작

  • Han, Gi-Bong;Jeong, Gwi-Sang
    • Proceedings of the Korean Society Of Semiconductor Equipment Technology
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    • 2006.10a
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    • pp.10-13
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    • 2006
  • This paper describes on the fabrication and characteristics of a 3C-SiC (Silicon Carbide) micro pressure sensor for harsh environment applications. The implemented micro pressure sensor used 3C-SiC thin-films heteroepitaxially grown on SOI (Si-on-insulator) structures. This sensor takes advantages of the good mechanical properties of Si as diaphragms fabricated by D-RIE technology and temperature properties of 3C-SiC piezoresistors. The fabricated pressure sensors were tasted at temperature up to $250^{\circ}C$ and indicated a sensitivity of 0.46 mV/V*bar at room temperature and 0.28 mV/V*bar at $250^{\circ}C$. The fabricated 3C-Sic/SOI pressure sensor presents a high-sensitivity and excel lent temperature stability.

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A Turbulent Bounbary Layer Effect of the De-Laval Nozzle on the Combustion Chamber Pressure (De-Laval 노즐의 난류 경계층 유동이 연소실 압력에 미치는 영향)

  • 장태호;이방업;배주찬
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.10 no.5
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    • pp.635-644
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    • 1986
  • A Compuressible turbulent boundary layer effect of the high temperature, accelerating gas flow through the De-Laval nozzle on combustion chamber pressure is numerically investigated. For this purpose, the coupled momentum integral equation and energy integral equation are solved by the Bartz method, and 1/7 power law for both the turbulent boundary layer velocity distribution and temperature distribution is assumed. As far as the boundary layer thicknesses are concerned, we can obtain reasonable solutions even if relatively simple approximations to the skin friction coefficient and stanton number have been used. The effects of nozzle wall cooling and/or mass flow rate on the boundary layer thicknesses and the combustion chamber pressure are studied. Specifically, negative displacement thickness is appeared as the ratio of the nozzle wall temperature to the stagnation temperature of the free stream decreases, and, consequently, it makes the combustion chamber pressure low.

Properties of Electron Temperature and Density in Inductively Coupled Plasma of Xenon (유도결합형 제논 플라즈마의 전자온도, 밀도 특성)

  • Her, In-Sung;Yang, Jong-Kyung;Lee, Jong-Chan;Park, Dae-Hee
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.05b
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    • pp.41-45
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    • 2005
  • In this paper, parameters of electron temperature and density for the mercury-free lighting-source were measured to diagnosis and analyze in Xe based inductively coupled plasma(ICP). In results at several dependences of 20~100 mTorr Xenon pressure, 50~200W RF power and horizontal distribution were especially mentioned. When Xe pressure was 20mTorr and RF power was 200W, the electron temperature and density were respectively 3.58eV and $3.56{\times}10^{12}cm^{-3}$. The key parameters of Xe based ICP depended on Xe pressure more than RF power that could be verified. A high electron temperature and low electron density with a suitable Xe pressure are indispensible parameters for Xe based ICP lighting-source.

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Fabrication of Metal Thin-Film Type Pressure Sensors (금속박막형 압력센서의 제작)

  • 최성규;김병태;남효덕;정귀상
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.11a
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    • pp.587-590
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    • 2000
  • This paper presents the characteristics of metal thin-film pressure sensors. The micro pressure sensors consists of a chrom thin-film, patterned on a Wheatstone bridge configuration, sputter-deposited onto thermally oxidized Si wafer an aluminium interconnection layer. The fabricated micro pressure sensors shows a low temperature coefficient of resistance, high-sensitivity, low non-linearity and excellent temperature stability. The sensitivity is 1.16~1.21 mV/V.kgf/$\textrm{cm}^2$ in the temperature range of 25~l0$0^{\circ}C$ and the maximum non-linearity is 0.21 %FS.

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Properties of Electron Temperature and Electron Density in Inductively Coupled Xenon Plasma (유도결합형 제논 플라즈마의 전자온도, 전자밀도 특성)

  • Her, In-Sung;Choi, Gi-Seung;Lee, Jong-Chan;Park, Dae-Hee
    • Proceedings of the KIEE Conference
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    • 2005.07c
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    • pp.2418-2420
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    • 2005
  • In this paper, parameters of electron temperature and density for the mercury-free lighting-source were measured to diagnosis and analyze in Xe based inductively coupled plasma(ICP). In results at several dependences of $20{\sim}100mTorr$ Xenon pressure, $50{\sim}200W$ RF power and horizontal distribution were especially mentioned. When Xe pressure was 20mTorr and RF power was 200W, the electron temperature and density were respectively 3.58eV and $3.56{\times}10^{12}cm^{-3}$. The key parameters of Xe based ICP depended on Xe pressure more than RF power that could be verified. A high electron temperature and low electron density with a suitable Xe pressure are indispensible parameters for Xe based ICP lighting-source.

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Discernibly Temperature-insensitive Pressure Sensitivity in Porous Random-Hole Optical Fibers

  • Kim, Jeong;Kominsky, Dan;Pickrell, Gary
    • Journal of the Optical Society of Korea
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    • v.17 no.4
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    • pp.300-304
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    • 2013
  • Novel breakthrough random-hole optical fibers (RHOFs) are fabricated in a draw tower facility, by tapering an optical fiber preform packed with a silica powder mixture capable of producing air holes in situ at the high temperature of tens of hundreds in degrees Celsius. Structural and propagation characteristics of the porous RHOF are explained briefly. Experimental investigations of the invented RHOF are performed for pressure sensor applications. Remarkable results are obtained for the RHOF with desirable pressure sensitivity independent of temperature, as is required for harsh conditions as in oil reservoirs.

Effect of Heat-treatment on Microstructure and Tensile Properties in Cast Alloy 718 (주조 합금 Alloy 718에서 미세조직과 인장특성에 미치는 열처리의 영향)

  • Do, Jeong-Hyeon;Kim, In-Soo;Choi, Baig-Gyu;Jung, Joong-Eun;Jung, In-Yong;Jo, Chang-Yong
    • Journal of Korea Foundry Society
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    • v.36 no.5
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    • pp.167-173
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    • 2016
  • The effect of various types of heat-treatment on the mechanical properties of cast Alloy 718 has been investigated. Cast Alloy 718 bars were subjected to 'standard heat-treatment'_(SHT), 'HIP (Hot Isostatic Pressing) heat-treatment'_(HHT), and 'HIP-simulated heat-treatment'_(HS). In the absence of long time high temperature heat-treatment, a small amount of Laves phase remained in the 'SHT' specimen, and needle shaped ${\delta}$ precipitated in the vicinity of the Laves phase. Due to the formation of the Laves and ${\delta}$ phases in the 'SHT' specimen, it exhibited lower tensile properties than those of the others_specimens. On the other hand, the Laves phase was completely dissolved into the matrix after 'HHT' and 'HS' treatments. It is known that isostatic pressure reduces the self-diffusion coefficient, because of the lower self-diffusivity under HIP conditions in the interdendritic region, Nb segregation and the high amount of ${\gamma}^{{\prime}{\prime}}$ precipitation that occurs. Due to the higher fraction of coarse ${\gamma}^{{\prime}{\prime}}$ phases, the 'HHT' treated Alloy 718 showed excellent tensile strength.

The Effects of Chamber Temperature and Pressure on a GDI Spray Characteristics in a Constant Volume Chamber

  • Oh, Seun-Sung;Kim, Seong-Soo
    • Journal of Power System Engineering
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    • v.18 no.6
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    • pp.186-192
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    • 2014
  • The spray structures under the stratified and homogeneous charge condition of a gasoline direct injection were investigated in a visualized constant volume chamber. The chamber pressure was controlled from 0.1 MPa to 0.9 MPa by the high pressure nitrogen and the chamber temperatures of $25^{\circ}C$, $60^{\circ}C$ and $80^{\circ}C$ were controlled by the band type heater. The fuel, iso-octane was injected by a 6-hole injector with the pressures of 7 MPa and 12 MPa. From the experiments results, it is confirmed that at lower chamber pressure, the penetration length and spray angle are mainly affected by the chamber temperature with the vaporization of the fuel droplets and generated vortices at the end region of the spray. And at higher chamber pressure, the penetration lengths at the end of the injection were about 50~60% of that at lower chamber pressure regardless of the chamber temperature and the effect of fuel injection pressure is larger than that of the chamber temperature which results from larger penetration lengths at higher fuel injection pressure than at lower fuel injection pressure regardless of the chamber temperatures.

The Study on the Physicochemical Properties of Fluid under High Pressure (Ⅱ). The Effect of Pressure and Temperature on the Hexamethyl Benzene-Iodine Charge Transfer Complex in n-Hexane

  • Kwun Oh Cheun;Kim Jeong Rim
    • Bulletin of the Korean Chemical Society
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    • v.6 no.4
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    • pp.186-191
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    • 1985
  • The effect of pressure and temperature on the stabilities of the charge transfer complexes of hexamethyl benzene with iodine in n-hexane has been investigated by UV-spectrophotometric measurements. In this experiment the absorption spectra of mixed solutions of hexamethyl benzene and iodine in n-hexane were measured at 25, 40 and $60^{\circ}C$ under 1,200, 600, 1200 and 1600 bar. The equilibrium constant of the complex formation was increased with pressure while being decreased with temperature raising. Changes of volume, enthalpy, free energy and entropy for the formation of the complexes were obtained from the equilibrium constants. The red shift at higher pressure, the blue shift at higher temperature and the relation between pressure and oscillator strength were discussed by means of thermodynamic functions. In comparison with the results in the previous studies, it can be seen that the pressure dependence of oscillator strength has a extremum behavior in durene as the variation of ${\Delta}H$ or ${\Delta}S$ with the number of methyl groups of polymethyl benzene near atmospheric pressure in the previous study. The shift or deformation of the potential in the ground state and in the excited state of the complexes formed between polymethyl benzene and iodine was considered from the correlation between the differences of the electron transfer energies and the differences of free energies of the complex formation for the pressure variation.