• Title/Summary/Keyword: high temperature high pressure

Search Result 4,161, Processing Time 0.04 seconds

The Study of Antiferromagnetic Spin-lattice Coupling of FeCr2Se4 (FeCr2Se4의 반강자성 스핀-격자 상호작용 연구)

  • Kang, Ju-Hong;Son, Bae-Soon;Kim, Sam-Jin;Kim, Chul-Sung;Lee, H.G.;Park, Min-Seok;Lee, Sung-Ik
    • Journal of the Korean Magnetics Society
    • /
    • v.17 no.2
    • /
    • pp.86-89
    • /
    • 2007
  • [ $FeCr_2Se_4$ ] prepared under the high pressure (3 GPa) has been studied with x-ray, neutron diffraction techniques, superconducting quantum interference device (SQUID) magnetometer, resistance, and Mossbauer spectroscopy. The temperature dependence of resistance is explained by Mott-VRH and small polaron model for the regions I (T<20 K) and II (T>42 K), respectively. Neutron diffraction results show an antiferromagnetic spin-lattice coupling near the Neel temperature. So finally the distance of atom is enlarged in region (110$FeCr_2Se_4$ shows convex type of temperature dependence.

Gold Mineralization of the Sepola District in Mali, Africa: Occurrence Characteristics of Gold and Fluid Inclusion Study (아프리카 말리 세폴라 지역의 금광화작용:금의 산출특성 및 유체포유물연구)

  • Heo, Chul-Ho
    • Economic and Environmental Geology
    • /
    • v.42 no.3
    • /
    • pp.167-175
    • /
    • 2009
  • The geology of Sepola district in Mali is consisted of Birrimian group with metasedimentary rocks of lower Proterozoic and volcanoclastics, and later intrusive igneous rocks. Ore diposit in this district has the characteristics of vein- and disseminated-type gold deposit which was formed by infilling the secondary fracture zones related to the large-scale fault zone of NW direction within Birrimian group. It is confirmed as promising that Barani district has the gold grade of 0.53${\sim}$9.21 g/t with the extension of 1.3 km and width of 1 to 20.1 m. The ore mineralogy is simple with electrum, pyrite and galena. Fineness of gold grain ranges from 848 to 915(average 891) indicating mesothermal to hypothermal environment. Fluid inclusions are classified as liquid-rich type I. gas-rich type II and liquid-$CO_2$ bearing type III. Primary and pseudosecondary inclusions homogenize from 236 to 393$^{\circ}C$ with salinity of 0.0 to 8.6 wt% NaCl. Secondary inclusions homogenize from 103 to 184$^{\circ}C$ with salinity of 0.7 to 8.6 wt.%. From the relationship between homogeniztion temperature and salinity, it may be thought that auriferous fluid experienced dilution and cooling through inflow of meteoric water after fluid unmixing derived from pressure decrease in the temperature range of 400 to 250$^{\circ}C$. From the massive occurrence of quartz vein, simple mineralogy with paucity of sulfide, and presence of liquid-$CO_2$ bearing with high homogenization temperature, it is thought that gold mineralization in Sepola district correspods to the mesothermal to hypothermal ore deposit.

Effects of Hydrological Condition on the Coupled Thermal-Hydrological-Mechanical Behavior of Rock Mass Surrounding Cavern Thermal Energy Storage (암반 공동 열에너지저장소 주변 암반의 수리적 조건에 따른 열-수리-역학적 연계거동 분석)

  • Park, Jung-Wook;Rutqvist, Jonny;Lee, Hang Bok;Ryu, Dongwoo;Synn, Joong-Ho;Park, Eui-Seob
    • Tunnel and Underground Space
    • /
    • v.25 no.2
    • /
    • pp.168-185
    • /
    • 2015
  • The thermal-hydrological-mechanical (T-H-M) behavior of rock mass surrounding a large-scale high-temperature cavern thermal energy storage (CTES) at a shallow depth has been investigated, and the effects of hydrological conditions such as water table and rock permeability on the behavior have been examined. The liquid saturation of ground water around a storage cavern may have a small impact on the overall heat transfer and mechanical behavior of surrounding rock mass for a relatively low rock permeability of $10^{-17}m^2$. In terms of the distributions of temperature, stress and displacement of the surrounding rock mass, the results expected from the simulation with the cavern below the water table were almost identical to that obtained from the simulation with the cavern in the unsaturated zone. The heat transfer in the rock mass with reasonable permeability ${\leq}10^{-15}m^2$ was dominated by the conduction. In the simulation with rock permeability of $10^{-12}m^2$, however, the convective heat transfer by ground-water was dominant, accompanying the upward heat flow to near-ground surface. The temperature and pressure around a storage cavern showed different distributions according to the rock permeability, as a result of the complex coupled processes such as the heat transfer by multi-phase flow and the evaporation of ground-water.

Supercritical Fluid Extraction of Sesame Oil with High Content of Sesamol (초임계 유체를 이용한 세사몰 고함유 참기름 추출 연구)

  • Ju Young-Woon;Son Min-Ho;Lee Ju-Suk;Lee Moon-Young;Byun Sang Yo
    • KSBB Journal
    • /
    • v.20 no.3
    • /
    • pp.205-209
    • /
    • 2005
  • Studies for the commercial production of sesame oil using th supercriticl carbon dioxide were made. Characteristics of sesame oil containing one of natural antioxidant 'sesamol', which only exist at sesame seed were also studied during the supercritical fluid extraction. Among the various factors influencing the sesamol contents in the sesame oil, the roasting time and temperature were checked, because sesamol can be converted from sesamol in through pyrolysis. We found that the sesamol content was increased rapidly under the condition of roasting temperature over $200^{\circ}C$ with longer roasting time. The sesamol content was increased as the temperature and pressure increased, which was caused by increase of solubility of sesamol against sesamol oil. And the sesamol content was increased also with lower speed of supercritical fluid, which increased the contact time with the raw material. The sesamol content was also increased using water increase up to $1\%$ as the entrainer. When the extraction performance with the supercritical fluid was compared to the conventional compressed extraction, the sesamol content was increased up to 11.5 times with the entrainer.

A Study on the Growth of KTP$(KTiOPO_4)$ Single Crystal (KTP$(KTiOPO_4)$ 단결정의 육성에 관한 연구)

  • 차용원;최원웅;장지연;오근호;김판채
    • Journal of the Korean Crystal Growth and Crystal Technology
    • /
    • v.3 no.1
    • /
    • pp.12-17
    • /
    • 1993
  • Growth runs of KTP single crystals were carried out by the hydrothermal method. KTP powders used for the crystal growth were prepared as a single phase by the solid state reaction of a stoichiometric mixture of $KH_2PO_4 and TiO_2$ at TEX>$800^{\circ}C$ and subsequently by the hydrothermal treatment at $250^{\circ}C$ 4m KF solution. The most effective solvents for the crystal growth of KTP were KF and K $K_2HPO_4$ solutions. Solubilities of KTP in these solutions were positive over the range $350~450^{\circ}C$.Seed crystals of good quality could be obtained by the horizontal temperature gradient method at temperatures over the range 380~430^{\circ}C$ in these solutions. The hydrothermal conditions for the high growth rates of seed crystals are as follows: growth method; vertical temperature gradient method, solvent; 4m KF or $K_2HPO_4$ solution, temperature region; $400~450^{\circ}C$, pressure region; $1000~1500kg/cm^2$, where solubility of KTP was large enough to proceed the growth. Under such conditions, seed crystals of KTP are grown at a rate of approximately 0.06-0.08mm/day in the direction of the c-axis. Morphologies of grown crystals tended to be bounded by (100), (011) and (201) faces.

  • PDF

An Experimental Study of Sprinkler system for Sandwich Panel Wall Protection (샌드위치패널 벽면보호용 스프링클러설비 적용 실험)

  • Seo, Dong-Hun;Kim, Won-Hyung;Kim, Jong-Hoon;Lee, Young-Jae
    • Fire Science and Engineering
    • /
    • v.31 no.5
    • /
    • pp.37-43
    • /
    • 2017
  • Domestic sandwich panel buildings are widely used on walls and roofs of factories and warehouse facilities. Factory and warehouse facilities have high fire load and rapid spread of fire due to their use characteristics, leading to large fires. Due to the characteristics of materials, walls and roofs are collapsed, resulting in life damage and property damage. In this regard, this study examined domestic and international standards of sprinkler facilities to prevent ignition of sandwich panel walls. Also, in order to check whether the fire was prevented by installing the head on the wall of the sandwich panel, the fire test was carried out with 10 cm, 60 cm, and 120 cm from the wall along the sprinkler head installation standard of domestic fire safety standards. As a result of the fire test, it was confirmed that the sandwich panel was prevented from igniting when the head of water pressure 0.1 MPa and water quantity K-80 was installed. According to the separation distance, it was impossible to measure the temperature at 10 cm, but at 60 cm, At the maximum temperature of $525^{\circ}C$ and 120 cm, the maximum temperature of the wall of the sandwich panel was measured as $276^{\circ}C$. As a result of the fire test, considering the fire point of 450 degrees Celsius in the fire test of the sandwich panel, the distance from the sandwich panel wall to the combustible is more than 120 cm.

Analysis of Cloud Properties Related to Yeongdong Heavy Snow Using the MODIS Cloud Product (MODIS 구름 산출물을 이용한 영동대설 관련 구름 특성의 분석)

  • Ahn, Bo-Young;Cho, Kuh-Hee;Lee, Jeong-Soon;Lee, Kyu-Tae;Kwon, Tae-Yong
    • Korean Journal of Remote Sensing
    • /
    • v.23 no.2
    • /
    • pp.71-87
    • /
    • 2007
  • In this study, 14 heavy snow events in Yeongdong area which are local phenomena are analyzed using MODIS cloud products provided from NASA/GSFC. The clouds of Yeongdong area at observed at specific time by MODIS are classified into A, B, C Types, based on the characteristic of cloud properties: cloud top temperature, cloud optical thickness, Effective Particle Radius, and Cloud Particle Phase. The analysis of relations between cloud properties and precipitation amount for each cloud type show that there are statistically significant correlations between Cloud Optical Thickness and precipitation amount for both A and B type and also significant correlation is found between Cloud Top Temperature and precipitation amount for A type. However, for C type there is not any significant correlations between cloud properties and precipitation amount. A-type clouds are mainly lower stratus clouds with small-size droplet, which may be formed under the low level cold advection derived synoptically in the East sea. B-type clouds are developed cumuliform clouds, which are closely related to the low pressure center developing over the East sea. On the other hand, C-type clouds are likely multi-layer clouds, which make satellite observation difficult due to covering of high clouds over low level clouds directly related with Yeongdong heavy snow. It is, therefore, concluded that MODIS cloud products may be useful except the multi-layer clouds for understanding the mechanism of heavy snow and estimating the precipitation amount from satellite data in the case of Yeongdong heavy snow.

A Study on the Thermal Flow of Waste Heat Recovery Unit (WHRU) for Ship's Organic Rankine Cycle Power Generation System using CFD Method (CFD를 활용한 선박고온도차발전용 WHRU의 열유동 해석에 관한 연구)

  • Whang, Dae-jung;Park, Sang-kyun;Jee, Jae-hoon;Bang, Eun-shin;Oh, Cheol
    • Journal of the Korean Society of Marine Environment & Safety
    • /
    • v.27 no.5
    • /
    • pp.647-655
    • /
    • 2021
  • The IMO (International Maritime Organization) is discussing the improvement of energy ef iciency of ships in order to reduce greenhouse gas emissions from ships. Currently, by applying an ORC power generation system using waste heat generated from ships, high energy conversion efficiency can be expected from ships. This technology uses an organic medium based on Freon or hydrocarbons as the working fluid, which evaporates at a lower temperature range than water. Through this, it is possible to generate steam (gas) and generate power at a low and low temperature relatively. In this study, the analysis of heat flow between the refrigerant and waste heat in the ORC power generation system, which is an organic Rankine cycle, is analyzed using 3D simulation techniques to determine the temperature change, velocity change, pressure change, and mass change of the fluid flowing of the WHRU (Waste Heat Recovery Unit) inside and the outside the structure. The purpose of this study is to analyze how the mass change affects the structure, and this study analyzed the heat transfer of the heat exchanger from the refrigerant and the exhaust gas of the ship's main engine in the ORC power generation system using this technique.

Comparative Analysis of Annual Tropospheric Delay by Season and Weather (계절과 날씨에 따른 연간 대류권 지연오차량 변화)

  • Lim, Soo-Hyeon;Kim, Ji-Won;Park, Jeong-Eun;Bae, Tae-Suk;Hong, Sungwook
    • Journal of the Korean Society of Surveying, Geodesy, Photogrammetry and Cartography
    • /
    • v.37 no.1
    • /
    • pp.1-7
    • /
    • 2019
  • In this study, we estimated the tropospheric delay of GNSS (Global Navigation Satellite System) signals during passing through the atmosphere in relation to weather and seasonal factors. For this purpose, we chose four CORS (Continuously Operating Reference Station) stations from inland (CCHJ and PYCH) and on the coast (GEOM and CHJU). A total of 48 days for each station (one set of data for each week) were downloaded from the NGII (National Geographic Information Institute) and processed it using the scientific GNSS software. The average tropospheric delays in winter are less than 2,400 mm, which is about 200 mm less than those in summer. The estimated tropospheric delay shows a similar pattern from all stations except the absolute bias in magnitude, while a large delay was observed for the station located on the coast. In addition, the delay during the day was relatively stable in winter, and the average tropospheric delay was strongly related to the orthometric height. The inland stations have tropospheric delays by the precipitation rather than humidity due to dry weather and difference in temperature. On the contrary, it was primarily caused by the humidity on the sea. The correlation between temperature and water vapor pressure is 0.9 or larger for all stations, and the tropospheric delay showed a high linear relationship with temperature. It is necessary to analyze the GNSS data with higher temporal resolution (e.g. all RINEX data of the year) to improve the stability and reliability of the correlation results.

Long-term performance of drainage system for leakage treatment of tunnel operating in cold region (한랭지역에서 운영 중인 터널의 누수처리를 위한 유도배수시스템의 장기 성능 평가)

  • Kim, Dong-Gyou
    • Journal of Korean Tunnelling and Underground Space Association
    • /
    • v.20 no.6
    • /
    • pp.1177-1192
    • /
    • 2018
  • The objective of this study is to develop the existing drainage system for catching the partial leakage of tunnel structures operating in cold region. The drainage system consists of drainage board, Hotty-gel as a waterproofing material, cover for preventing protrusion of Hotty-gel, air nailer, fixed nail, pipe for collecting ground leak, pipe for conveying ground leak, wire-mesh, and sprayed cement mortar. The drainage systems were installed in conventional concrete lining tunnels to evaluate the site applicability and constructability. The performances of waterproof and the drainage in the drainage system were evaluated by injecting 1,000 ml of red water in the back of the drainage system at 7 days, 14 days, 21 days, 28 days, 2 months, 3 months, 4 months, 5 months, 6 months, 7 months and 8 months. During 8 months of field test, the average daily temperature of the tunnel site was measured from $-16.0^{\circ}C$ to $25.6^{\circ}C$. The daily minimum temperature was $-21.3^{\circ}C$ and the daily maximum temperature was $30.8^{\circ}C$. There was no problem in waterproof and drainage performance of the drainage board in the drainage system. However, the pipe for conveying ground leak had the leakage problem from 14 days. It is considered that the leakage of the pipe for conveying ground leak was caused by the deformation of the pipe of the flexible plastic material having a thickness of 0.2 cm by using the high pressure air nailer and the fixing pin and the insufficient thickness and width of the hotty-gel for preventing the leakage.