• Title/Summary/Keyword: high temperature high pressure

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An Experimental Study on the Heat Transfer Characteristics of the Conversion Efficiency in the Concentrated Photovoltaic Cells (방열 특성에 따른 집광형 태양전지의 광전변환효율 변화에 관한 실험적 연구)

  • Kim, Kangho;Jung, Sang Hyun;Kim, Youngjo;Kim, Chang Zoo;Jun, Dong Hwan;Shin, Hyun-Beom;Lee, Jaejin;Kang, Ho Kwan
    • Current Photovoltaic Research
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    • v.2 no.4
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    • pp.168-172
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    • 2014
  • Under concentrated illuminations, the solar cells show higher efficiencies mainly due to an increase of the open circuit voltage. In this study, InGaP/InGaAs/Ge triple-junction solar cells have been grown by a low pressure metalorganic chemical vapor deposition. Photovoltaic characteristics of the fabricated solar cells are investigated with a class A solar simulator under concentrated illuminations from 1 to 100 suns. Ideally, the open circuit voltage should increase with the current level when maintained at the same temperature. However, the fabricated solar cells show degraded open circuit voltages under high concentrations around 100 suns. This means that the heat sink design is not optimized to keep the cell temperature at $25^{\circ}C$. To demonstrate the thermal degradation, changes of the device performance are investigated with different bonding conditions and heat sink materials.

EFFECT OF ADDED Si ON DENSIFICATION OF Ni-AI INTERMETALLIC COATING ON SPHEROIDAL GRAPHITE CAST IRON SUBSTRATES

  • Kim, Tetsuro ata;Keisuke Uenishi;Akira Ikenaga;Kojiro F. Kobayashi
    • Proceedings of the KWS Conference
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    • 2002.10a
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    • pp.726-731
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    • 2002
  • Reaction synthesis is a process to form ceramics, intermetallics and their composites from elemental powder mixture. Application of this process to a surface modification techniques has a possibilities to enable the process at a lower temperature or for a shorter time, although synthesized materials are likely to include voids and unreacted elements. This paper intend to examine the effect of Si addition to the mixture of Al and Ni on the densification of synthesized Ni-Al intermetallic compounds and to evaluate the surface properties of obtained coatings. By the Si addition, exothermic reaction temperature to form Ni-Al intermetallic was lowered to be below the melting point of Al. Si soluted $Al_3$Ni$_2$, $Al_3$Ni and $Al_{6}$Ni$_3$Si were mainly formed in the coating layer when powder mixture was heated to 973K for 300s. Besides, densification was enhanced by increasing hot press pressure, Si additions and heating rate. When the composition of eutectic Al-Si reaches 78%, void ratio of sintered compact reduced to 0.4%. It is caused by higher flowability of Al-Si liquid phase generated and its infiltration into the void. Since the hardness of NiAl(Si) compound (about 600HV) formed in the coating layer is higher than that of Ni-Al compound (about 400HV), coating layer with high density and superior wear property is obtained by hot press using reaction synthesis from Al-Ni-Si powder mixture.

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Influence of Alumina on Hydrothermal Synthesis of 11Å Tobermorite (알루미나가 11Å Tobermorite의 수열합성에 미치는 영향)

  • Yim Going;Yim Chai Suk
    • Korean Journal of Materials Research
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    • v.15 no.2
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    • pp.97-105
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    • 2005
  • [ $11\AA$ ] tobermorite$(5CaO{\cdot}6SiO_2{\cdot}5H_2O)$ is synthesized from the mixtures of calcium hydroride and quartz using alumina in a molar ratio $Ca(OH)_2/SiO_2$ of 0.8 at $180^{\circ}C$ for 8 and 24 hrs under saturated steam pressure. The influence of alumina on the formation of $11\AA$ tobermorite was investigated by X-ray diffraction, differential thermal analysis and infrared spectroscopy. $11\AA$ tobermorite containing increasingly larger amounts of aluminum showed a shift of the basal spacing from 11.3 to $11.6\AA$. In general, there was a direct linear relation between the basal spacing and added content of alumina. The differential thermal analysis curves showed that $11\AA$ tobermorite with increasing alumina contents exhibited the exothermic peak at high temperature, namely $11\AA$ tobermorite containing aluminum gave a sharp exothermic peak at temperature around $850\~860^{\circ}C$ in the case of $S_3\~S_5$. The absorption band at $1607\~1620cm^{-1}$ is attributed to the bending vibration of water, and the position of the main O-H stretching and Si-O lattice vibration of $11\AA$ tobermorite at 3500 and $965cm^{-1}$ respectively is not altered. Consequently the existence of alumina accelerates the crystallization of $11\AA$ tobermorite, and that the aluminum ion appears to substitute for the silicon ion in $11\AA$ tobermorite structure. Al-containing tobermorite is distinguished from Al-free tobermorite.

Preliminary Study of a Turbopump Pyro Starter (터보펌프 파이로 시동기 기초연구)

  • Hong, Moon-Geun;Lee, Soo-Yong
    • Journal of the Korean Society of Propulsion Engineers
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    • v.12 no.2
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    • pp.74-80
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    • 2008
  • The feasibility study into the development of turbine spinners, which start up the turbo-pump, has been carried out and the design requirements and parameters ranges have been presented. Turbine spinners use the solid propellant as such composite propellant based AN compound with high energy plasticizers, coolants, and phase stabilizer which relieves a sensible volume change due to the phase transformation of AN near room temperature. Propellants which have a homing rate of $0.2{\sim}0.3\;mm/s$ and pressure exponent ranged from 0.3 to 0.6, showed stable burn-out in the standard motor tests. Both the magnitude of ignition energy and its thermal transfer mechanism have been proved to have a tangible effect on the ignition of the pyre starter, and the results of this study showed that a flame temperature of 1400K would be quite adequate to get a stable ignition for the AN composite propellant.

Study of Inhibition Characteristics of Slurry Additives in Copper CMP using Force Spectroscopy

  • Lee, Hyo-Sang;Philipossian Ara;Babu Suryadevara V.;Patri Udaya B.;Hong, Young-Ki;Economikos Laertis;Goldstein Michael
    • Transactions on Electrical and Electronic Materials
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    • v.8 no.1
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    • pp.5-10
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    • 2007
  • Using a reference slurry, ammonium dodecyl sulfate (ADS), an anionic and environmentally friendly surfactant, was investigated as an alternative to BTA for its inhibition and lubrication characteristics. Results demonstrated that the inhibition efficiency of ADS was superior to that of BTA. Coefficient of friction (COF) was the lowest when the slurry contained ADS. This suggested that adsorbed ADS on the surface provided lubricating action thereby reducing the wear between the contacting surfaces. Temperature results were consistent with the COF and removal rate data. ADS showed the lowest temperature rise again confirming the softening effect of the adsorbed surfactant layer and less energy dissipation due to friction. Spectral analysis of shear force showed that increasing the pad-wafer sliding velocity at constant wafer pressure shifted the high frequency spectral peaks to lower frequencies while increasing the variance of the frictional force. Addition of ADS reduced the fluctuating component of the shear force and the extent of the pre-existing stick-slip phenomena caused by the kinematics of the process and collision event between pad asperities with the wafer. By contrast, in the case of BTA, there were no such observed benefits but instead undesirable effects were seen at some polishing conditions. This work underscored the importance of real-time force spectroscopy in elucidating the adsorption, lubrication and inhibition of additives in slurries in CMP.

Diesel Combustion Strategies Effect on Exhaust Emissions and Hydrocarbon Species (디젤 연소 전략에 따른 배기가스 및 탄화수소 종 분석)

  • Han, Man-Bae
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.36 no.7
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    • pp.759-765
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    • 2012
  • This study investigates the effect of diesel combustion strategies on exhaust emissions and hydrocarbon species emissions for a 1.7 L common rail direct injection diesel engine at 1500 rpm and 3.9 bar BMEP. The first strategy is a method to adopt no EGR with a split injection composed of pilot and main injection (split injection). The second is to adopt a moderate EGR rate with main injection only (single-1). The third is to use a high level of EGR and main injection with rail pressure increase, $i.e.$ low-temperature diesel combustion (single-2). Split injection and single-1 showed a renowned phenomenon of a PM-NOx trade-off, whereas single-2 was observed of a PM-NOx trade-off to reduce PM and NOx simultaneously. HC speciation results show that the split injection produced the least amount of HC species, regardless of the carbon number bin, followed by single-1 and single-2. The ratios of methane, acetylene, and CO to THC increased as a combustion A/F ratio is richer due to reduced oxygen content in the vicinity of the combustion zone, thus enhancing pyrolysis.

Experimental Study of Vane Expander Prototype Applied to Micro Organic Rankine Cycle (초소형 유기랭킨사이클 적용 프로토 타입 베인 팽창기에 관한 실험적 연구)

  • Shin, Dong Gil;Kim, Young Min
    • Journal of Energy Engineering
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    • v.23 no.4
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    • pp.230-235
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    • 2014
  • In this study, performances of the vane expander protype for micro organic Rankine cycle with refrigerant R134a as a working fluid have been analyzed. While operating organic Rankine cycle for analysing expander efficiencies such as overall efficiencies, volumetric efficiencies and mechanical efficiencies under $110^{\circ}C$ of expander inlet temperature, the power of the expander, inlet temperature of expander, inlet pressure of expander and the flow rate of the working fluid(refrigerant R134a) have been measured while varying the rotational speed of the expander. It was found that the more the expander revolution speed is high, the more the expander power, overall efficiencies and volumetric efficiencies are higher. In case of 500 rpm of rotational speed, overall efficiencies are 6~7% and in case of 1000 rpm, overall efficiencies are 11~12%. We have found that low volumetric efficiencies result in poor overall efficiencies.

A Comparative Study on the Formation of Methane Hydrate Using Natural Zeolite and Synthetic Zeolite 5A (천연 제올라이트와 합성 제올라이트 5A를 이용한 메탄 하이드레이트의 생성에 대한 비교 연구)

  • Park, Sung-Seek;Park, Yun-Beom;Kim, Nam-Jin
    • New & Renewable Energy
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    • v.8 no.2
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    • pp.24-32
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    • 2012
  • Natural gas hydrates have a high potential as the 21st century new energy resource, because it have a large amount of deposits in many deep-water and permafrost regions of the world widely. Natural gas hydrate is formed by physical binding between water molecule and gas mainly composed of methane, which is captured in the cavities of water molecules under the specific temperature and pressure. $1m^3$ methane hydrate can be decomposed to the methane gas of $172m^3$ and water of $0.8m^3$ at standard condition. Therefore, there are a lot of practical applications such as separation processes, natural gas storage transportation and carbon dioxide sequestration. For the industrial utilization of methane hydrate, it is very important to rapidly manufacture hydrate. However, when methane hydrate is artificially formed, its reaction time may be too long and the gas consumption in water becomes relatively low, because the reaction rate between water and gas is low. So in this study, hydrate formation was experimented by adding natural zeolite and Synthetic zeolite 5A in distilled water, respectively. The results show that when the Synthetic zeolite 5A of 0.01 wt% was, the amount of gas consumed during the formation of methane hydrate was higher than that in the natural zeolite. Also, the natural zeolite and Synthetic zeolite 5A decreased the hydrate formation time to a greater extent than the distilled water at the same subcooling temperature.

Species composition of the catches collected by trammel net in the coastal waters off Ulleungdo of Korea (울릉도해역에서 삼중자망에 의한 어획물의 종조성)

  • CHUNG, Sangdeok;CHA, Hyung Kee;LEE, Jae Bong;LEE, Hae Won;YANG, Jae Hyeong
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.51 no.4
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    • pp.567-575
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    • 2015
  • Species composition in the coastal waters off Ulleungdo of Korea were examined based on catches bimonthly collected by trammel net in 2013. A total of 711 individuals and 181.9 Kg were caught and catches were composed of 4 classes 15 orders 27 families 52 species including 44 Pisces, 4 Gastropoda, 3 Cephalopoda, and 1 Echinodermata. The dominant species in biomass were File fish (Thamnaconus modestus), Atka mackerel (Pleurogrammus azonus), and Greenling (Hexagrammos otakii). Data were summarized using hierarchical cluster analysis (HCA) and detrended correspondence analysis (DCA) to examine similarity in species composition for each month, and community structure in Ulleungdo was divided into two groups. Community structures in February, April and December with low temperature and well-mixed surface water were distinguished from those in June, August and October with high temperature and strong stratification, which could be attributed to temporal changes in dominant species. Atka mackerel and Spear squid mainly caught in February and April, disappearing in June, August and October, and File fish outburst was shown in October. Because the water off Ulleungdo has been under low human pressure, it could be a good case study to elucidate effects of climate change on community structure and ecosystem in the East sea. Continuous surveys and further studies are required to demonstrate migration route and distribution of dominant species and long-term changes in community structure in the water of Ulleungdo.

CFD Analysis on Base Region of Small Scaled 4 Nozzle Clustered Engine Configuration (CFD를 이용한 축소형 공기 클러스터드 노즐의 저부 유동 분석)

  • Kim, Seong-Lyong;Kim, In-Sun
    • Aerospace Engineering and Technology
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    • v.11 no.1
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    • pp.68-77
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    • 2012
  • Flow characteristics of base region of small scaled 4 nozzle clustered engine has been analyzed with CFD approach along with the tests of numerical methods. The numerical test shows that Spalart-Allmaras turbulence model is appropriate for the present research. Plumes expanded from nozzles exits collide with each other and make high pressure stagnation region. Some of collided plumes expand again reversely into the base region with supersonic speeds. The reversed plume in the base region goes out to the outer region through the minimum vent area formed by the nearest nozzle exterior surfaces. But different from the empirical theory, the minimum vent area does not play a role of throat. Additionally the temperature of the nozzle inner surface strongly affects the temperature of the reversed plumes.