• Title/Summary/Keyword: high temperature high pressure

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High Pressure X-ray Diffraction Study of LiFePO4/C-olivine-like Phase (LiFePO4/C-유사 감람석 결정구조에 대한 고압 X-선회절연구)

  • Hwang, Gil-Chan;Kim, Young-Ho
    • Journal of the Mineralogical Society of Korea
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    • v.26 no.1
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    • pp.35-44
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    • 2013
  • Synthetic carbon-coated olivine-like structured lithium iron phosphate ($Li^+Fe^{2+}(PO_4)^{3-}/C$) powder composites were compressed up to 35.0 GPa in the symmetrical diamond anvil cell at room temperature. Bulk modulus of $LiFePO_4/C$ was determined to be $130.1{\pm}10.3$ GPa. New peak appears at the d-spacing of 3.386 ${\AA}$ above 18 GPa, and another new one at 2.854 ${\AA}$ around 35 GPa. The crystallographic symmetry of the sample (i.e. orthorhombic) is apparently retained up to 35 GPa as no clear evidence for the phase transition into spinel structure has been observed. The pressure-induced volume change in the M1 site ($Li^+O_6$) is more significant than those in M2($Fe^{2+}O_6$) and $PO_4$ tetrahedral sites.

Stabilization of Abnormal Combustion of Dry Low NOx Gas Turbine Combustor for Power Generation (발전용 저 NOx 가스터빈의 연소 불안정 안정화에 관한 연구)

  • 정재모;안달홍;박정규
    • Journal of Energy Engineering
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    • v.13 no.2
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    • pp.144-151
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    • 2004
  • Stabilization and reduction of combustion noise and NOx emission from dry low NOx combustor of GE MS7001F gas turbine were achieved. Dry low NOx gas turbines that adopt the lean premixed combustion technology frequently generate the flame instability and high NOx emissions if not adequately tuned. Dynamic pressure oscillation during the combustion mode transfer increased as ambient temperature decreased with frequency of 80㎐ and magnitude of 4-9 psi. Effects of both combustor tuning for uniform fuel flow with burner nozzles and fuel pre-filling into transfer fuel valves on stabilisation of the dry low NOx combustor were very significant. Dynamic pressure oscillation during the combustion mode change was decreased up to 2.5 psi. Also, NOx emission from GE7F DLN-1 combustor can be maintained as low as 35-43ppm (15% O$_2$) in base load operation of 150 MW.

Characteristics of surface damage with applied current density and cavitation time variables for 431 stainless steel in seawater (431 스테인리스강의 해수 내 적용 전류밀도 및 캐비테이션 시간 변수에 따른 표면손상 특성)

  • Kim, Seong-Jong;Chong, Sang-Ok
    • Journal of Advanced Marine Engineering and Technology
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    • v.38 no.7
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    • pp.883-889
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    • 2014
  • It is generated for cavitation erosion due to the local static boiling by pressure differentials in high speed rotating fluid environment. The cavitation is influenced by various elements such as pressure, velocity, temperature, pH of fluid and medium. In particular, the damage of material is accelerated due to the electrochemical corrosion by $C1^-$ and cavitation erosion due to cavities in seawater. In this paper, hence, it investigated for martensite stainless steel the damage behavior with applied current density and cavitation time in natural seawater solution. Less damage depth at the cavitation condition was observed than static condition as a result of galvanostatic experiment. Furthermore, it was shown that dramatic increase of weightloss, damage rate and damage depth after 3 hour of cavitation test.

Development of In-Service Inspection Techniques for PGSFR (PGSFR 가동중검사기술 개발)

  • Kim, Hoe Woong;Joo, Young Sang;Lee, Young Kyu;Park, Sang Jin;Koo, Gyeong Hoi;Kim, Jong Bum;Kim, Sung Kyun
    • Transactions of the Korean Society of Pressure Vessels and Piping
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    • v.12 no.1
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    • pp.93-100
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    • 2016
  • Since the sodium-cooled fast reactor is operated in a hostile environment due to the use of liquid sodium as its coolant, advanced techniques for in-service inspection are required to periodically verify the integrity of the reactor. This paper presents the development of in-service inspection techniques for Proto-type Generation IV Sodium-cooled Fast Reactor. First, the 10 m long plate-type ultrasonic waveguide sensor has been developed for in-service inspection of reactor internals, and its feasibility was verified through several under-water and under-sodium experiments. Second, the combined inspection system for in-service inspection of ferromagnetic steam generator tubes has been developed. The remote field eddy current testing and magnetic flux leakage testing can be conducted simultaneously by using the developed inspection system, and the detectability was demonstrated through several damage detection experiments. Finally, the electro-magnetic acoustic transducer which can withstand high temperature and be installable in the remote operated vehicle has been developed for in-service inspection of the reactor vessel, and its detectability was investigated through damage detection experiments.

Oscillation Characteristics of Turbulent Channel Flow with Wall Blowing (채널유동에서 질량분사에 의한 표면유동의 진동 특성)

  • Na, Yang;Lee, Chang-Jin
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.37 no.1
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    • pp.62-68
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    • 2009
  • The interaction between wall blowing and oxidizer flow can generate a very complicated flow characteristics in combustion chamber of hybrid rockets. LES analysis was conducted with an in-house CFD code to investigate the features of turbulent flow without chemical reactions. The numerical results reveal that the flow oscillations at a certain frequency exists on the fuel surface, which is analogous to those observed in the solid propellant combustion. However, the observation of oscillating flow at a certain frequency is only limited to a very thin layer adjacent to wall surface and the strength of the oscillation is not strong enough to induce the drastic change in temperature gradient on the surface. The visualization of fluctuating pressure components shows the periodic appearance of relatively high and low pressure regions along the axial direction. This subsequently results in the oscillation of flow at a certain fixed frequency. This implies that the resonance phenomenon would be possible if the external disturbances such as acoustic excitation could be imposed to the oscillating flow in the combustion chamber.

Dynamic Modeling & Analysis of Vapor Phase Blowdown of Depressurized Vessel (기체 블로우 다운의 동적 모델링 및 분석)

  • Kim, Kyungwoon;Seo, Ji Won;Hwang, Sungwon;Lee, Yun Ju;Moon, Young Sik
    • Korean Chemical Engineering Research
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    • v.54 no.3
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    • pp.350-359
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    • 2016
  • For accurate estimation over the change of pressure and temperature of the vessel during blowdown period, a new dynamic blowdown model was developed in this work. In particular, heat transfer from the vessel wall to discharge gas at both laminar or turbulent flow in the vessel was embedded to the model to increase the accuracy of blowdown estimation. For thermodynamics, the whole blowdown period was discretized into finite pressure decrement steps, and the step size was adjusted so that the calculation can be more efficiently carried out, while maintaining the model's accuracy. Both Peng-Robinson and Soave-Redlich-Kwong equation of states were applied to the model, and the results were compared each other. Finally, the simulation results was compared with Haque and coworkers' experimental results, and it proved high accuracy of the model.

A Study on the Damage Range According to Leakage Scenarios in Natural Gas Pipeline of LNG Fueled Ship (LNG 추진선의 천연가스 배관에서 누출 시나리오에 따른 피해범위에 관한 연구)

  • Lee, Yoon-Ho
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.26 no.4
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    • pp.317-326
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    • 2020
  • In this study, damages caused by flash fire, overpressure, and thermal radiation based on the sizes of leak holes were evaluated using the areal location of hazardous atmospheres when natural gas leaked owing to the damage of pipeline in a LNG fueled ship. In addition, environmental variables (wind speed, atmospheric temperature, and atmospheric stability) and process variables (pipe pressure and pipe length) were classified to analyze the damage impact ranges caused by various scenarios. From the results, the damage range caused by the environmental variables was the largest, followed by overpressure and thermal radiation. Additionally, for the process variables, regardless of the pressure, length, or size of the leak holes, the damage range attributed to flash fire was the most significant, and the damage range was high in the order of overpressure and thermal radiation, similar to the environmental variables. The larger the size of the leak holes, the higher the values of the environmental and process variables, and the higher the damage range caused by jet fire compared to the environmental variables.

Hydrothermal Synthesis of Smectite from Dickite (딕카이트로부터 스멕라이트의 수열합성)

  • Ryu Gyoung-Won;Jang Young-Nam;Bae In-Kook;Chae Soo-Chun;Choi Sang-Hoon
    • Journal of the Mineralogical Society of Korea
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    • v.17 no.3
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    • pp.267-275
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    • 2004
  • A hydrothermal process was used to synthesize dioctahedral smectite from dickite [$A1_2$$Si_2$$O_{5}$ $(OH)_4$], Dickite was previously activated by heating at $800^{\circ}C$ far 4 hours with $Na_2$$CO_3$. After the heat-treatment, $SiO_2$ was added for stoichiometry, The autoclaving was carried out in closed stainless steel vessel (about 1 liter) at the condition of various temperature, pressure, time etc. High quality smectite could be obtaind by heating at $290^{\circ}C$ under the pressure of 60 kgf/$\textrm{cm}^2$ for 48 hours. This experiment reveals that pH of the solution was an important factor and should be maintained at 10 to 11 for the formation of dioctahedral smectite. The synthesized smectite was identified as Na-beidellite by the treatment of ethylene glycol and Greene-Kelly test.

CFD Analysis of a Concept of Nuclear Hybrid Heat Pipe with Control Rod (원자로 제어봉과 결합된 하이브리드 히트파이프의 CFD 해석)

  • Jeong, Yeong Shin;Kim, Kyung Mo;Kim, In Guk;Bang, In Cheol
    • The KSFM Journal of Fluid Machinery
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    • v.17 no.6
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    • pp.109-114
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    • 2014
  • After the Fukushima accident in 2011, it was revealed that nuclear power plant has the vulnerability to SBO accident and its extension situation without sufficient cooling of reactor core resulting core meltdown and radioactive material release even after reactor shutdown. Many safety systems had been developed like PAFS, hybrid SIT, and relocation of RPV and IRWST as a part of steps for the Fukushima accident, however, their applications have limitation in the situation that supply of feedwater into reactor is impossible due to high pressure inside reactor pressure vessel. The concept of hybrid heat pipe with control rod is introduced for breaking through the limitation. Hybrid heat pipe with control rod is the passive decay heat removal system in core, which has the abilities of reactor shutdown as control rod as well as decay heat removal as heat pipe. For evaluating the cooling performance hybrid heat pipe, a commercial CFD code, ANSYS-CFX was used. First, for validating CFD results, numerical results and experimental results with same geometry and fluid conditions were compared to a tube type heat pipe resulting in a resonable agreement between them. After that, wall temperature and thermal resistances of 2 design concepts of hybrid heat pipe were analyzed about various heat inputs. For unit length, hybrid heat pipe with a tube type of $B_4C$ pellet has a decreasing tendency of thermal resistance, on the other hand, hybrid heat pipe with an annular type $B_4C$ pellet has an increasing tendency as heat input increases.

Seat Tightness of Flexible Metal Seal of Butterfly Valve at Cryogenic Temperatures (초저온 버터플라이 밸브용 탄성 메탈실의 누설방지에 관한 연구)

  • Ahn, Jun-Tae;Lee, Kyung-Chul;Lee, Yong-Bum;Han, Seung-Ho
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.35 no.6
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    • pp.643-649
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    • 2011
  • For the development of butterfly valves used in liquefied natural gas (LNG) vessels, the seat tightness is one of the important factors to be taken into account in the valve-design process. An O-ring-type metal seal with a retaining ring showing good seat tightness at cryogenic temperatures has been widely used, despite the high manufacturing costs involved. As an alternative, a flexible solid metal seal offers not only sufficient tightness of the butterfly valve, meeting specification requirements, but also relatively low manufacturing costs. In this study, a design criterion to ensure the seat tightness of the butterfly valve using the flexible solid metal seal is proposed. The contact pressure can be calculated by the simulation of the frictional contact behavior between the surface of the metal seal and the valve disc. The geometry of the flexible solid metal seal is determined so that it satisfies the design criterion for sufficient seat tightness, and is verified by experiments according to BS6755 and BS6364.