• Title/Summary/Keyword: high temperature high pressure

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Investigation on the Change of Ammonia Dissociation for Satellite Thruster According to the Catalyst Loss (위성추력기에서 촉매유실에 따른 암모니아 해리도 변화에 대한 연구)

  • Hwang, Chang-Hwan;Lee, Sung-Nam;Baek, Seung-Wook;Kim, Su-Kyum;Yu, Myoung-Jong
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2011.11a
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    • pp.218-222
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    • 2011
  • During the development of the iridium catalyst for domestic production, the catalyst failure, loss, sintering phenomena are observed by high pressure and temperature. By these abnormal failure of catalyst bed, the performance of thruster is degraded. To figure out the detail phenomena on the damaged catalyst bed, a numerical analysis code is developed by assuming the catalyst bed as an one dimensional porous media. The numerical analysis code is validated with experiment data. Thereby, resulting physical phenomena are examined by considering the variation of catalyst bed characteristics incurred by catalyst granule failure. Through these numerical analyses we figure out the effect of the catalyst loss on the decomposition of hydrazine and ammonia.

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Stress Analyses of the Gimbal Bellows for a Lox Pipe (산화제 배관 김발 주름관 응력 해석)

  • Yoo, Jae-Han;Moon, Il-Yoon;Lee, Soo-Yong
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2011.11a
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    • pp.477-480
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    • 2011
  • The stress analyses of the 'U'-shaped multi-ply reinforced gimbal bellows under high pressure and rotational displacement loadings are performed at the room and cryogenic temperatures. The bellows are used for the Lox pipe line which connects the combustion chamber with the turbopump of a liquid rocket engine. The distributions of the stress, the strains and the contact pressures are obtained from the finite element analysis considering the geometric non-linearities of the contacts between the plies and the material one of the isotropic plasticity. Those are compared with the stress results from EJMA (Expansion Joint Manufacturing Association) standard. Also, the effects of the operating temperature and the reinforcing ring on the stresses are investigated.

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Characteristic evaluation of waxy oil behavior using vane rheometer (베인 레오미터를 이용한 왁스오일의 특성 연구)

  • Oh, Kyeong-Seok
    • Journal of the Korean Applied Science and Technology
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    • v.32 no.3
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    • pp.497-504
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    • 2015
  • Apart from hydrates, asphaltenes, and inorganic minerals, paraffinic waxes are also very important in flow assurance area. Evaluation of wax gel behavior has been important as off-shore oil recovery becomes more popular in oil production. Restart after either planned or emergency shutdown requires pump operation in high pressure since a waxy oil forms troublesome gel. In this paper, vane method is introduced to determine wax gel strength by determining yield stress. Prediction of gel strength are discussed in qualitative and quantitative manners.

Characterization of the Yellow Croaker Larimichthys polyactis muscle Oil Extracted with Supercritical Carbon Dioxide and an Organic Solvent

  • Lee, Joo-Hee;Asaduzzaman, A.K.M.;Yun, Jun-Ho;Yun, Jun-Hyun;Chun, Byung-Soo
    • Fisheries and Aquatic Sciences
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    • v.15 no.4
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    • pp.275-281
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    • 2012
  • Yellow croaker Larimichthys polyactis muscle oil was extracted using an environmental friendly solvent, supercritical carbon dioxide (SC-$CO_2$), in a semi-batch flow extraction process. SC-$CO_2$ was applied at temperature $35^{\circ}C$ to $45^{\circ}C$ and $150^{\circ}C$ to $250^{\circ}C$ bar of pressure. The flow rate of $CO_2$ (27.79 g/min) was constant throughout the entire 1.5 h extraction period. The oil extraction yield was influenced by the physical properties of SC-$CO_2$ at different temperatures and pressures. The extracted oil was analyzed by gas chromatography to determine the fatty acid composition. According to our results, the SC-$CO_2$ extracted oil was high in eicosapentaenoic acid and docosahexaenoic acid. In addition, the SC-$CO_2$ extracted oil showed greater stability than n-hexane extracted oil based on the peroxide value and acid value. Thus, the quality of yellow croaker oil obtained by SC-$CO_2$ extraction was slightly higher than that of oil obtained by n-hexane extraction.

Sensor Fault Detection and Analysis of Fault Status using Smart Sensor Modeling

  • Kim, Sung-Shin;Baek, Gyeong-Dong;Lee, Soo-Jin;Jeon, Tae-Ryong
    • Journal of information and communication convergence engineering
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    • v.6 no.2
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    • pp.207-212
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    • 2008
  • There are several sensors in the liquid cargo ship. In the liquid cargo ship, we can get values from various sensors that are level sensor, temperature sensor, pressure sensor, oxygen sensor, VOCs sensor, high overfill sensor, etc. It is important to guarantee the reliability of sensors. In order to guarantee the reliability of sensors, we have to study the diagnosis of sensor fault. The technology of smart sensor is widely used. In this paper, the technology of smart sensor is applied to diagnosis of level sensor fault for liquid cargo ship. In order to diagnose sensor fault and find the sensor position, in this paper, we proposed algorithms of diagnosis of sensor fault using independent sensor diagnosis unit and self fault diagnosis using sensor modeling. Proposed methods are demonstrated by experiment and simulation. The results show that the proposed approach is useful. Proposed methods are useful to develop smart level sensor.

Measurements of the Benzene Absorption Cross Section in the Range of Ultra Violet (UV) (UV 영역에서 벤젠의 흡수 단면적의 측정)

  • Lee, J.S.;Ryu, S.Y.;Kim, H.H.;Woo, J.C.;Kim, K.B.
    • Journal of Korean Society for Atmospheric Environment
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    • v.22 no.6
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    • pp.922-928
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    • 2006
  • An absolute absorption cross section of benzene was measured with a spectrometer system including a mono-chrometer and a grating in the wavelength region of $240{\sim}280nm$ under the atmospheric pressure and room temperature in the laboratory. A certificated reference benzene gas ($98{\mu}mol/mol$ in $N_2$) was used to measure its absorption cross section. A 710 mm cell with a quartz window and a 150 W Xe arc lamp were employed. The magnitude of absorption cross section of $1.41{\times}10^{-18}cm^2$ was lower than that of the reference spectra ($2.5{\times}10^{-18}cm^2$) of high resolution spectrometer, Total measurement uncertainty was estimated to be 4.0%.

Etching Characteristics of Au Thin Films using Inductively Coupled CF4 / Cl2 / Ar Plasma

  • Kim Dong-Pyo;Kim Chang-Il
    • Transactions on Electrical and Electronic Materials
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    • v.4 no.3
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    • pp.1-4
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    • 2003
  • The etching of Au thin films has been performed in an inductively coupled $CF_4 / Cl_2 / Ar$ plasma. The etch properties including etch rate and selectivity were examined as $CF_4$ content adds from o to $30\%$ to $Cl_2/Ar$ plasma. The $Cl_2/(Cl_2 + Ar)$ gas mixing ratio was fixed at $20\%$. Other parameters were fixed at an rf power of 700 W, a dc bias voltage of -150 V, a chamber pressure of 15 mTorr, and a substrate temperature of $30^{\circ}C$. The highest etch rate of the Au thin film was 370 nm/min at a $10\%$ additive $CF_4$ into $Cl_2/Ar$ gas mixture. The surface reaction of the etched Au thin films was investigated using x-ray photoelectron spectroscopy (XPS) analysis. The XPS analysis shows that the intensities of Ail peaks are changed, indicating that there is a chemical reaction between Cl and Au. Au-Cl is hard to remove on the surface because of its high melting point. However, etching products can be sputtered by Ar ion bombardment.

A Study on Heat and Mass Transfer Characteristics of LiBr-$H_2$O Solution with a Sufactant Flowing over a Cooled Horizontal Tube (계면활성제 첨가시 수평 냉각관 외부를 흘러내리는 LiBr수용액의 열 및 물질전달 특성에 관한 연구)

  • 김경희;설신수;이상용
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.14 no.4
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    • pp.341-349
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    • 2002
  • Heat and mass transfer characteristics of a surfactant-added LiBr-$H_2O$ solution flowing over a single horizontal tube were examined experimentally. The parameters considered were surfactant (2-ethyl-1-hexanol) concentration, solution temperature at the top of the tube and absorber pressure. Even with an amount of the surfactant below the solubility limit, heat and mass transfer performances were enhanced tremendously. The Nusselt and Sherwood numbers increased by about 70% and 340%, respectively, when 10 ppm of the surfactant was added. However, an excess amount of the surfactant in the solution did not bring a further enhancement. The absorption performance deteriorated when the non-condensable gases were extracted from the system (by a vacuum pump) since the vaporized surfactant was also extracted during the process. Therefore, it is desirable to add a sufficient amount of the surfactant (more than 10 ppm) to maintain high performance of absorption.

Ferroelectric and Structural Properties of Nd-substituted $Bi_4Ti_3O_{12}$ Thin Films Fabricated by MOCVD

  • Kang, Dong-Kyun;Park, Won-Tae;Kim, Byong-Ho
    • Proceedings of the Korean Society Of Semiconductor Equipment Technology
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    • 2006.10a
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    • pp.166-169
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    • 2006
  • A promising capacitor, which has conformable step coverage and good uniformity of thickness and composition, is needed to manufacture high-density non-volatile FeRAM capacitors with a stacked cell structure. In this study, ferroelectric $Bi_{3.61}Nd_{0.39}Ti_3O_{12}$ (BNT) thin films were prepared on $Pt(111)/Ti/SiO_2/Si$ substrates by the liquid delivery system MOCVD method. In these experiments, $Bi(ph)_3$, $Nd(TMHD)_3$ and $Ti(O^iPr)_2(TMHD)_2$ were used as the precursors and were dissolved in n-butyl acetate. The BNT thin films were deposited at a substrate temperature and reactor pressure of approximately $600^{\circ}C$ and 4.8 Torr, respectively. The microstructure of the layered perovskite phase was observed by XRD and SEM. The remanent polarization value (2Pr) of the BNT thin film was $31.67\;{\mu}C/cm^2$ at an applied voltage of 5 V.

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Characteristics of Pure Mg Powder Compacts Prepared by Spark Plasma Sintering Process (방전플라즈마 소결법으로 제작된 순 마그네슘 분말 소결체의 특성평가)

  • Hong, Ji-Min;Son, Hyeon-Taek;Chang, Se-Hun;Lee, Jae-Seoul;Cha, Yong-Hun;Oh, Ik-Hyun
    • Korean Journal of Materials Research
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    • v.17 no.6
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    • pp.331-336
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    • 2007
  • The pure Mg powder compacts were successfully fabricated using SPS process. The machined chip powder showed flake shaped morphology with coarse surfaces, while gas atomized powders were spherical in morphology with smooth surfaces. In this study, SPS process was used to consolidate the pure Mg powder because this process allows high density consolidation in a short time. The results showed that increased sintering temperature from $350^{\circ}C$ to $500^{\circ}C$ with pressure of 30MPa, the maximum values of the density was increased from 98.1% to 99.8% of theoretical density, respectively. However, density of the sintered chip powders was higher than that of gas-atomized powder due to larger contact areas between particles.