• Title/Summary/Keyword: high temperature high pressure

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Characteristics of Auto-ignition and Micro-explosion for Array of Emulsion Droplets (유화액적 배열에서의 자발화와 미소폭발의 특성)

  • Jeong, In-Cheol;Lee, Kyung-Hwan;Kim, Jae-Soo
    • Journal of Energy Engineering
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    • v.16 no.3
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    • pp.113-119
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    • 2007
  • The auto-ignition characteristics and combustion behaviors of one-dimensional array of water-in-fuel droplets suspended in a high temperature chamber have been investigated experimentally with various droplet spacing and number of droplets. The fuels used were pure n-decane and emulsified n-decane with water contents varied from 10% to 30%. All experiments have been performed at 920 K under the atmospheric pressure. The number of droplets in an array were fixed as 3 or 5 and its spacing was varied from 3 mm to 7 mm by 1mm interval. The imaging technique with a high-speed camera has been adopted to measure the ignition delay and flame life time. The micro-explosion behaviors were also observed. As the droplet array sparing increased, the ignition delay also increased regardless of water contents. However, the life time of droplet array decreased as the droplet spacing increased. The full combustion time in array of 3 droplets was found to be longer than that for 5 droplets case due to the longer ignition delay.

Optimising Ink Setting Properties on Double Coated Wood-free Papers

  • Bluvol, Guillermo;Carlsson, Roger
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2006.06b
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    • pp.215-225
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    • 2006
  • Today's requirements for print-press runnability and print quality demand an optimised absorption and adhesion of printing ink on the paper surface. Modern coating concepts for high glossing offset grades use ultra fine pigments, whereas binder level has continuously been decreased to a minimum in recent years to achieve the highest possible sheet gloss development and for economical reasons. Both the ultra fine pigments and the reduced binder levels lead in many cases to a faster ink setting rate. On the other hand, matt paper grades use relatively coarse pigments leading to a slow ink setting compared to the high glossing papers. Both too fast and too slow ink setting properties implicate drawbacks in print quality and print press runnability. The mechanisms behind the interactions between ink and coating have been presented in many previous publications. The purpose of this study was to determine and quantify how the ink setting rate is influenced by pigment system (GCC and GCC/clay blends), latex level and latex properties in the topcoat of double coated sheet fed offset paper. The roles of binder level and type in the precoat were also assessed. The effect of calendering (temperature and pressure) was studied with one formulation. The resulting ink setting characteristics were tested using three different laboratory testing instruments. The correlation amongst the different laboratory testing methods is discussed. The results show that by varying the latex properties, the pigment system and/or latex addition level, the ink tack development of ink applied to a topcoat pigment system can be significantly influenced. It can be slowed down as often desired with ultra fine pigments or speeded up in the case of coarse pigments. There was no visible effect on the ink setting rate by using different binder systems in the precoat..

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Studies on the Production of Bacterial Amylase(I) Isolation, Bacteriological Characteristics, Cultural Conditions and its Amylase Characteristics of a High Amylase Producing Strain (세균(細菌) Amylase 생산(生産)에 관(關)한 연구(硏究)(제(第) 1 보(報)) 균(菌)의 분리(分離), 동정(同定), Amylase 생산조건(生産條件) 및 생성효소(生成酵素)의 효소적성질(酵素的性質)에 대(對)하여)

  • Bae,, Jung-Surl;Park,, Yoon-Choong
    • Korean Journal of Food Science and Technology
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    • v.1 no.1
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    • pp.85-89
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    • 1969
  • 1. According to the Bergey's manual of determinative bacteriology, the high amylase producing strain A-162 isolated from corn was similar to Bacillus subtilis in the characteristics. 2. The addition of corn powder 30%, milk casein 5% and $CaCO_3$. 5% to wheat bran was excellent as amylase producing media. 3. According to vessel content and quantities of the media, the optimum steaming condition of media was different. Excessive steaming (pressure and time) suppressed the growth of Bacillus subtilis var. A-162. 4. The optimum temperature of amylase produced was about $50^{\circ}C$ and its optimum pH 6.0.

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Development of Automated Ultrasonic Testing System for Partial Joint-Weld of Heat Exchanger's Header to Tube in Power Plant (발전소 열교환기 헤더와 튜브의 부분 용입형 용접부 초음파 자동검사시스템 개발)

  • Lee, Jin-Hyuk;Lim, Seong-Jin;Park, Ik-Keun;Kim, Dae-Hyun
    • Journal of the Korean Society for Nondestructive Testing
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    • v.30 no.4
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    • pp.367-372
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    • 2010
  • A power plant's heat exchangers work under poor conditions, such as high temperature, high pressure, corrosion, mechanical stress and vibration. Especially, partial joint-weld of heat exchanger's header to stub-tube is the place where incomplete penetration flaws can easily occur. But, it is hard to evaluate the safety of the structure by conventional nondestructive testing techniques. So it is necessary to test integrity of the weld inside and to develop testing technique and equipment that can detect the flaws at the weld point in order to enhance reliability of the test result. In this study, we developed a suitable automated ultrasonic testing system that can inspect the partial joint-weld of header to stub-tube of power plant. Finally, we showed the efficiency of the automated ultrasonic-testing-system from the application.

Electronic Structure of Ce-doped ZrO2 Film: Study of DFT Calculation and Photoelectron Spectroscopy

  • Jeong, Kwang Sik;Song, Jinho;Lim, Donghyuck;Kim, Hyungsub;Cho, Mann-Ho
    • Applied Science and Convergence Technology
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    • v.25 no.1
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    • pp.19-24
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    • 2016
  • In this study, we evaluated the change of electronic structure during redox process in cerium-doped $ZrO_2$ grown by sol gel method. By sol-gel method, we could obtain cerium-doped $ZrO_2$ in high oxygen partial pressure and low temperature. After post annealing process in nitrogen ambient, the film is deoxidized. We used spectroscopic and theoretical methods to analysis change of electronic structure. X-ray absorption spectroscopy (XAS) for O K1-edge and Density Functional Theory (DFT) calculation using VASP code were performed to verify the electronic structure of the film. Also, high resolution x-ray photoelectron spectroscopy (HRXPS) for Ce 3d was carried out to confirm chemical bond of cerium doped $ZrO_2$. Through the investigation of the electronic structure, we verified as followings. (1) During reduction process, binding energy of oxygen is increase. Simultaneously, oxidation state of cerium was change to 4+ to 3+. (2) Cerium 4+ and cerium 3+ states were generated at different energy level. (3) Absorption states in O K edge were mainly originated by Ce 4+ $f_0$ and Ce 3+, while occupied states in valance band were mainly originated from Ce 4+ $f_2$.

Synthesis and Photovoltaic Properties of Conducting Polymers Based on Phenothiazine (Phenothiazine계 전도성고분자의 합성 및 유기박막태양전지로의 적용 연구)

  • Yoo, Han-Sol;Park, Yong-Sung
    • Applied Chemistry for Engineering
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    • v.24 no.1
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    • pp.93-98
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    • 2013
  • In this paper, four conducting polymers (poly[(N-butyl-phenothiazine)-sulfide] (PBPS), poly[(N-hexyl-phenothiazine)-sulfide] (PHPS), poly[(N-decyl-phenothiazine)-sulfide] (PDPS), and poly[(N-(2-ethylhexyl)-phenothiazine)-sulfide] (PEHPS)) were synthesized with a high temperature and high pressure reaction. The structures of synthesized polymers were confirmed by $^1H-NMR$ and characterized by UV-Vis, cyclic voltammetry, and GPC. From the UV-Vis absorption spectra, the ${\lambda}_{max}$ values of PBPS, PHPS, PDPS, and PEHPS were 338, 341, 340, and 334 nm, respectively and their optical band gaps were 3.11, 3.13, 3.16, and 3.05 eV, respectively. To evaluate the feasible applicability as a photovoltaic cell, the devices composed of for example, ITO/PEDOT : PSS/polymer (PBPS, PDPS) : $PC_{71}BM$ (1 : 3, w/w)/$BaF_2$/Ba/Al were fabricated using the blends of the PBPS and PDPS as a donor, and $PC_{71}BM$ as an acceptor. Then, the power conversion efficiencies (PCE) of devices were estimated as 0.076% of PBPS and 0.136% of PDPS by solar simulator.

Improving Conductivity of Metal Grids by Controlling Sintering Process (배선 함몰 전극의 배선 소결공정 최적화에 따른 전기적 특성 향상)

  • Ahn, Wonmin;Jung, Sunghoon;Kim, Do-Geun
    • Journal of Surface Science and Engineering
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    • v.48 no.4
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    • pp.158-162
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    • 2015
  • To substitute indium tin oxide (ITO), many substituents have been studied such as metal nanowires, carbon based materials, 2D materials, and conducting polymers. These materials are not good enough to apply to an electrode because theses exhibit relatively high resistance. So metal grids are required as an additionalelectrode to improve the conductivities of substituents. The metal grids were printed by electrohydrodynamic printing system using Ag nanoparticle based ink. The Ag grids showed high uniformity and the line width was about $10{\mu}m$. The Ag nanoparticles are surrounded by dispersants such as unimolecular and polymer to prevent aggregation between Ag nanoparticles. The dispersants lead to low conductivity of Ag grids. Thus, the sintering process of Ag nanoparticles is strongly recommended to remove dispersants and connect each nanoparticles. For sintering process, the interface and microstructure of the Ag grid were controlled in 1.0 torr Ar atmosphere at aound $400^{\circ}C$ of temperature. From the sintering process, the uniformity of the Ag grid was improved and the defects on the Ag grids were reduced. As a result, the resistivity of Ag grid was greatly reduced up to $5.03({\pm}0.10){\times}10^{-6}{\Omega}{\cdot}cm$. The metal grids embedded substrates containing low pressure Ar sintered Ag grids showed 90.4% of transmittance in visible range with $0.43{\Omega}/{\square}$ of sheet resistance.

RETINOL STABILIZATION BY PSEUDO-LIPOSOME AND LAMELLAR LIQUID CRYSTAL

  • Lee, Seung-Ji;Jo, Byoung-Kee;Lee, Young-Jin;Ryu, Chang-Suk;Kim, Beom-Jun;Suk, Chang-Hyun
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.24 no.3
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    • pp.116-122
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    • 1998
  • It is well known that all-trans-retinol is not only very unstable in heat, light, air, and water, but also skin-irritant despite a good anti-wrinkle effect. Therefore, it is very difficult to stabilize retinol and make the safe retinol containing cosmetics by using a certain concentration of retinol with real effect. In order to dissolve these problems and apply retinol for skin care cream, firstly retinol is to be encapsulated in the vesicle called Liposphere (pseudo-liposome) which is made by homogenizing under high pressure the mixtures of lecithin, retinol, caprylic/capric triglyceride, and hydroalcoholic solution ; and then this retinol containing Liposphere is to be intercalated in lamellar liquid crystal layer which is prepared by emulsifying in an optimal ratio the mixtures composed of non-ionic emulsifier (cetearyl glucoside, sorbitan stearate & sucrose cocoate etc), cetearyl alcohol, stearic acid, cholesterol, and ceramide. In addition, the stability of the retinol containing oil in water cream by adding the polymeric emulsifier such as acrylate /C10-30 alkyl alkylate crosspolymer is to be ensured even at 55 C. Retinol containing oil in water cream prepared through above procedure could be very stable at 45 C for at least 50 days. The structure identification of lamellar liquid crystal was determined using polarized light microscope and electron microscope Conclusively, we could make the very stable retinol containing oil in water cream by triple procedure, that is, encapsulation of retinol in Liposphere, intercalation of retinol in lamellar liquid crystal layer, and assurance of the high temperature stability of cream even at 55 C.

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Effect of Lead Concentration on Surface Oxide Formed on Alloy 600 in High Temperature and High Pressure Alkaline Solutions (고온, 고압 알칼리 수용액에서의 Alloy 600 산화막 특성에 미치는 납 농도 영향)

  • Kim, Dong-Jin;Kim, Hyun Wook;Moon, Byung Hak;Kim, Hong Pyo;Hwang, Seong Sik
    • Corrosion Science and Technology
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    • v.11 no.3
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    • pp.96-102
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    • 2012
  • Outer diameter stress corrosion cracking (ODSCC) has occurred for Alloy 600 (Ni 75 wt%, Cr 15 wt%, Fe 10 wt%) as a heat exchanger tube of the steam generator (SG) in nuclear power plants (NPP) during long term operation. Among many causes for SCC, lead (Pb) is known to be one of the most deleterious species in the secondary system. In the present work, the oxide formed on Alloy 600 was characterized as a function of the PbO content in 0.1 M NaOH at $315^{\circ}C$ by using an electrochemical impedance spectroscopy (EIS), a transmission electron microscopy (TEM), equipped with an energy dispersive x-ray spectroscopy (EDS). The oxide property was analyzed in view of SCC susceptibility.

Stereospecific anticancer effects of ginsenoside Rg3 epimers isolated from heat-processed American ginseng on human gastric cancer cell

  • Park, Eun-Hwa;Kim, Young-Joo;Yamabe, Noriko;Park, Soon-Hye;Kim, Ho-Kyong;Jang, Hyuk-Jai;Kim, Ji Hoon;Cheon, Gab Jin;Ham, Jungyeob;Kang, Ki Sung
    • Journal of Ginseng Research
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    • v.38 no.1
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    • pp.22-27
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    • 2014
  • Background: Research has been conducted with regard to the development of methods for improving the pharmaceutical effect of ginseng by conversion of ginsenosides, which are the major active components of ginseng, via high temperature or high-pressure processing. Methods: The present study sought to investigate the anticancer effect of heat-processed American ginseng (HAG) in human gastric cancer AGS cells with a focus on assessing the role of apoptosis as an important mechanistic element in its anticancer actions. Results and Conclusion: HAG significantly reduced the cancer cell proliferation, and the contents of ginsenosides Rb1 and Re were markedly decreased, whereas the peaks of less-polar ginsenosides [20(S,R)-Rg3, Rk1, and Rg5] were newly detected. Based on the activity-guided fractionation of HAG, ginsenoside 20(S)-Rg3 played a key role in inducing apoptosis in human gastric cancer AGS cells, and it was generated mainly from ginsenoside Rb1. Ginsenoside 20(S)-Rg3 induced apoptosis through activation of caspase-3, caspase-8, and caspase-9, as well as regulation of Bcl-2 and Bax expression. Taken together, these findings suggest that heat-processing serves as an increase in the antitumor activity of American ginseng in AGS cells, and ginsenoside 20(S)-Rg3, the active component produced by heat-processing, induces the activation of caspase-3, caspase-8, and caspase-9, which contributes to the apoptotic cell death.