• Title/Summary/Keyword: high temperature high pressure

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Hydrogenation Properties on MgHx-Sc2O3 Composites by Mechanical Alloying (MgHx-Sc2O3 복합재료의 수소화 특성)

  • Kim, Kyeong-Il;Kim, Yong-Sung;Hong, Tae-Whan
    • Journal of Hydrogen and New Energy
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    • v.21 no.2
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    • pp.81-88
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    • 2010
  • Hydrogen energy applications have recognized clean materials and high energy carrier. Accordingly, Hydrogen energy applies for fuel cell by Mg and Mg-based materials. Mg and Mg-based materials are lightweight and low cost materials with high hydrogen storage capacity. However, commercial applications of the Mg hydride are currently hinder by its high absorption/desorption temperature, and very slow reaction kinetics. Therefore one of the most methods to improve kinetics focused on addition transition metal oxide. Addition to transition metal oxide in $MgH_x$ powder produce $MgH_x$-metal oxide composition by mechanical alloy and it analyze XRD, EDS, TG/DSC, SEM, and PCT. This report considers kinetics by transition metal oxide rate and Hydrogen pressure. In this research, we can see behavior of hydriding/dehydriding profiles by addition catalyst (transition metal oxide). Results of PCI make a excellent showing $MgH_x$-5wt.% Sc2O3 at 623K, $MgH_x$-10wt.% $Sc_2O_3$ at 573K.

A Study on the Formation of Air Bubble by the Droplet Volume and Dispensing Method in UV NIL (UV NIL공정에서 액적의 양과 도포방법에 따른 기포형성 연구)

  • Lee, Ki Yeon;Kim, Kug Weon
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.14 no.9
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    • pp.4178-4184
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    • 2013
  • Nanoimprint lithography (NIL) is an emerging technology enabling cost-effective and high-throughput nanofabrication. Recently, the major trends of NIL are high throughput and large area patterning. UV curable type NIL (UV NIL) can be performed at room temperature and low pressure. And one advantage of UV NIL is that it does not need vacuum, which greatly simplifies tool construction, so that vacuum oprated high-precision stages and a large vacuum chamber are no longer needed. However, one key issue in non-vacuum environment is air bubble formation problem. Namely, can the air bubbles be completely removed from the resist. In this paper, the air bubbles formation by the method of droplet application in UV NIL with non-vacuum environment are experimentally studied. The effects of the volume of droplet and the number of dispensing points on air bubble formation are investigated.

FUEL PERFORMANCE CODE COSMOS FOR ANALYSIS OF LWR UO2 AND MOX FUEL

  • Lee, Byung-Ho;Koo, Yang-Hyun;Oh, Jae-Yong;Cheon, Jin-Sik;Tahk, Young-Wook;Sohn, Dong-Seong
    • Nuclear Engineering and Technology
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    • v.43 no.6
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    • pp.499-508
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    • 2011
  • The paper briefs a fuel performance code, COSMOS, which can be utilized for an analysis of the thermal behavior and fission gas release of fuel, up to a high burnup. Of particular concern are the models for the fuel thermal conductivity, the fission gas release, and the cladding corrosion and creep in $UO_2$ fuel. In addition, the code was developed so as to consider the inhomogeneity of MOX fuel, which requires restructuring the thermal conductivity and fission gas release models. These improvements enhanced COSMOS's precision for predicting the in-pile behavior of MOX fuel. The COSMOS code also extends its applicability to the instrumented fuel test in a research reactor. The various in-pile test results were analyzed and compared with the code's prediction. The database consists of the $UO_2$ irradiation test up to an ultra-high burnup, power ramp test of MOX fuel, and instrumented MOX fuel test in a research reactor after base irradiation in a commercial reactor. The comparisons demonstrated that the COSMOS code predicted the in-pile behaviors well, such as the fuel temperature, rod internal pressure, fission gas release, and cladding properties of MOX and $UO_2$ fuel. This sufficient accuracy reveals that the COSMOS can be utilized by both fuel vendors for fuel design, and license organizations for an understanding of fuel in-pile behaviors.

A Study of Weldability for Pure Titanium by Nd:YAG Laser(III) - Weld Properties of Edge Welding - (순티타늄판의 Nd:YAG 레이저 용접성에 관한 연구(III) - 에지 용접 특성 -)

  • Kim, Jong-Do;Kil, Byung-Lea;Kwak, Myung-Sub;Song, Moo-Keun
    • Journal of Welding and Joining
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    • v.27 no.6
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    • pp.74-79
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    • 2009
  • Titanium and titanium alloy can be reproduced immediately even if oxide films($TiO_2$) break apart in sea water. Therefore, since titanium demonstrates large specific strength and outstanding resistance to stress corrosion cracking, crevice corrosion, pitting and microbiologically influenced corrosion in sea water environment, it has been widely applied to heat exchanger for ships. In particular, with excellent elongation, pure titanium may be deemed as optimal material for production of heat exchanger plate which is used with wrinkles formed for efficient heat exchange. Conventional plate type heat exchanger prevented leakage of liquid through insertion of gasket between plates and mechanical tightening by bolts and nuts, but in high temperature and high pressure environment, gasket deterioration and leakage occur, so heat exchanger for LPG re-liquefaction device etc do not use gasket but weld heat exchanger plate for use. On the other hand, since welded plate cannot be separated, it is important to obtain high quality reliable welds. In addition, for better workability and production performance, lasers that can obtain weldment with large aspect ratio and demonstrate fast welding speed even in atmospheric condition not in vacuum condition are used in producing products. So far, 1st report and 2nd report compared and analyzed embrittlement degrees by bead colors of weldment through quantitative analysis of oxygen and nitrogen and measurement of hardness as fundamental experiment for the evaluation of titanium laser welding, and evaluated the welding performance and mechanical properties of butt welding. This study welded specimens in various conditions by using laser and GTA welding machine to apply edge welding to heat exchanger, and evaluated the mechanical strength through tensile stress test. As a result of tensile test, laser weldment demonstrated tensile strength 4 times higher than GTA welds, and porosity could be controlled by increasing and decreasing slope of laser power at overlap area.

Leak Detection and Evaluation for Power Plant Boiler Tubes Using Acoustic Emission (음향방출을 이용한 보일러튜브 누설평가)

  • Lee, Sang-Guk
    • Journal of the Korean Society for Nondestructive Testing
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    • v.24 no.1
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    • pp.45-51
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    • 2004
  • Boiler tubes in power plants are often leaked due to various material degradations including creep and thermal fatigue damage under severe operating conditions such as high temperature and high pressure over an extended period of time. To monitor and diagnose the tubes on site and in real time, the acoustic emission (AE) technology was applied. We developed an AE leak detection system, and used it to study the variation of AE signal from the on-site tubes in response to the changes in the boiler operation condition and to detect the locations of leakage based on it. Detection of leak was performed by acquiring and evaluating the signals in separate regimes of high and low frequency signal. As a result of these studies, we found that on-line monitoring and detection of leak location for boiler tubes is possible using the developed system. Thus, the system is expected to contribute to the safe operation of power plants, and prevent economic losses due to potential leak.

Multi-stage Compression Molding Technology of Fast Curing CF/Epoxy Prepreg (속경화용 탄소섬유/에폭시 프리프레그의 다단 압축 성형기술)

  • Kwak, Seong-Hun;Mun, Ji-Hun;Hong, Sang-Hwui;Kwon, Soon-Deok;Kim, Byung-Ha;Kim, Tae-Yong
    • Composites Research
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    • v.34 no.5
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    • pp.269-276
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    • 2021
  • PCM (Prepreg Compression Molding) process is a high-speed molding technology that can manufacture high-quality CFRP (Carbon Fiber Reinforced Plastic) parts. Compared to the autoclave process, it generates less waste and can significantly reduce cycle time, so various studies are being conducted in the aerospace and automobile industries. In this study, in order to improve the quality of the PCM process, a molding method was developed to increase the compression pressure of the press step by step according to the curing behavior of the prepreg. It was confirmed that this multi-stage compression molding technology is a good means to produce high-quality CFRP products and shorten cycle times. And, the laminated prepreg at room temperature was immediately put into the mold and preheated and molded at the same time, so that it could be molded without a separate preheating process. In addition, as a result of applying the same process conditions optimized for flat plate molding to three-dimensional shapes, a product similar to a flat plate in appearance could be made without the process of establishing process conditions.

Material Life Cycle Assessment of Mg-CaO-10 wt.% MWCNT Hydrogen Storage Composites (수소저장용 Mg-CaO-10 wt.% MWCNT 복합체의 물질 전과정 평가)

  • HAN, JEONG-HEUM;LEE, YOUNG-HWAN;YU, JAE-SEON;HONG, TAE-WHAN
    • Journal of Hydrogen and New Energy
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    • v.30 no.3
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    • pp.220-226
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    • 2019
  • Magnesium hydride has a high hydrogen storage capacity (7.6 wt.%), and is cheap and lightweight, thus advantageous as a hydrogen storage alloy. However, Mg-based hydrides undergo hydrogenation/dehydrogenation at high temperature and pressure due to their thermodynamic stability and high oxidation reactivity. MWCNTs exhibit prominent catalytic effect on the hydrogen storage properties of $MgH_2$, weakening the interaction between Mg and H atoms and reducing the activation energy for nucleation of the metal phase by co-milling Mg with carbon nanotubes. Therefore, it is suggested that combining transition metals with carbon nanotubes as mixed dopants has a significant catalytic effect on the hydrogen storage properties of $MgH_2$. In this study, Material life cycle evaluation was performed to analyze the environmental impact characteristics of Mg-CaO-10 wt.% MWCNTs composites manufacturing process. The software of material life cycle assessment (MLCA) was Gabi 6. Through this, environmental impact assessment was performed for each process.

A Study on the Safety Training System based on Virtual Reality in Large Scale Plant (대규모 플랜트에서의 가상현실 기반 플랜트 안전훈련 시스템에 관한 연구)

  • Lee, Jae Yong;Kim, Hyoung-Jin;Lee, Chunsik;Park, Chan Cook
    • Journal of the Korean Institute of Gas
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    • v.23 no.2
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    • pp.55-60
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    • 2019
  • To develop a plant safety training system using virtual reality technology, we constructed a training system for a large scale plant. Compared with safety training for small plants or unit equipment, many system configurations such as virtual plant model, in-process data processing, work instruction, etc. are required and integrated system works have been carried out. The target plant, RDS process, is a high-risk process(high-temperature, high-pressure) that takes into account the training scenarios that can be taken in the event of a leaking fire in the range and refer to the actual shutdown procedure. The proposed safety training integration system can be used in similar situations that can occur in the RDS process and can be a platform for safety training using virtual reality in a large plant.

Review on Membrane Materials to Improve Plasticization Resistance for Gas Separations (가소화 저항 향상을 위한 기체분리막 소재 개발 동향)

  • Jo, Jin Hui;Chi, Won Seok
    • Membrane Journal
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    • v.30 no.6
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    • pp.385-394
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    • 2020
  • In the gas separation process, the separation membranes have to not only show high gas transport and selectivity but also exhibit exceptional stability at high temperature and pressure. However, when the polymeric membranes (particularly, glassy polymers) are exposed to the condensable gases (i.e., CO2, H2S, hydrocarbon, etc.), the polymer chains are prone to swell, leading to low stability. As a result, the plasticization behavior reduces the gas selectivity in the separation of mixture gases at high pressures and thus results in limited applications to the separation processes. To address these issues, many strategies have been studied such as thermal treatment, polymer blending, thermally rearrangement, mixed-matrix membranes, cross-linking, etc. In this review, we will understand the plasticization behavior and suggest potential methods based on the previously reported studies.

Electrochemical Technologies : Water Treatment (전기화학공학 기술 : 수처리 공정)

  • Lee, Jaeyoung;Lee, Jae Kwang;Uhm, Sunghyun;Lee, Hye Jin
    • Applied Chemistry for Engineering
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    • v.22 no.3
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    • pp.235-242
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    • 2011
  • This perspective describes recent advances made in the development of various electrochemical technologies to treat waste water containing organic pollutants, reducible/oxidizable and non-reducible/non-oxidizable anions and cations using redox reactions on the solid surface as well as at the interface between solid electrode and liquid electrolyte. Some of representative multiplexing and hybrid electrochemical treatment technologies are discussed, which have great advantages of high efficiency, stability and cost-effective instrumentation without the need of considering non-specific conditions such as high-temperature and high-pressure; however, choices and usages of electrode materials are absolutely critical issues.