• Title/Summary/Keyword: high temperature high pressure

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Synthesis of SiNx:H films in PECVD using RF/UHF hybrid sources

  • Shin, K.S.;Sahu, B.B.;Lee, J.S.;Hori, M.;Han, Jeon G.
    • Proceedings of the Korean Vacuum Society Conference
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    • 2015.08a
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    • pp.136.1-136.1
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    • 2015
  • In the present study, UHF (320 MHz) in combination with RF (13.56 MHz) plasmas was used for the synthesis of hydrogenated silicon nitride (SiNx:H) films by PECVD process at low temperature. RF/UHF hybrid plasmas were maintained at a fixed pressure of 410 mTorr in the N2/SiH4 and N2/SiH4/NH3 atmospheres. To investigate the radical generation and plasma formation and their control for the growth of the film, plasma diagnostic tools like vacuum ultraviolet absorption spectroscopy (VUVAS), optical emission spectroscopy (OES), and RF compensated Langmuir probe (LP) were utilized. Utilization of RF/UHF hybrid plasmas enables very high plasma densities ~ 1011 cm-3 with low electron temperature. Measurements using VUVAS reveal the UHF source is quite effective in the dissociation of the N2 gas to generate more active atomic N. It results in the enhancement of the Si-N bond concentration in the film. Consequently, the deposition rate has been significantly improved up to 2nm/s for the high rate synthesis of highly transparent (up to 90 %) SiNx:H film. The films properties such as optical transmittance and chemical composition are investigated using different analysis tools.

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High-$J_c$ $GdBa_2Cu_3O_y$ films on $BaHfO_3$ buffered IBAD MgO template ($BaHfO_3$ 완충층을 사용한 IBAD MgO 기판 위에 제조된 고임계전류밀도의 $GdBa_2Cu_3O_y$ 박막)

  • Ko, K.P.;Lee, J.W.;Ko, R.K.;Moon, S.H.;Oh, S.S.;Yoo, S.I.
    • Progress in Superconductivity and Cryogenics
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    • v.13 no.1
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    • pp.6-11
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    • 2011
  • The $BaHfO_3$ (BHO) buffer layer on the IBAD MgO template was turned to be effective for a successful fabrication of $GdBa_2Cu_3O_{7-{\delta}}$ (GdBCO) films with high critical current density ($J_c$). Both the BHO buffer layers and GdBCO films were prepared by pulsed laser deposition (PLD). The effects of the PLD conditions, including substrate temperature ($T_s$), oxygen partial pressure ($PO_2$), and deposition time on the in-plane texture, surface roughness, and microstructures of the BHO buffer layers on the IBAD MgO template were systematically studied for processing optimization. The c-axis oriented growth of BHO layers was insensitive to the deposition temperature and the film thickness, while the in-plane texture and surface roughness of those were improved with increasing $T_s$ from 700 to $800^{\circ}C$. On the optimally processed BHO buffer layer, the highest $J_c$ value (77 K, self-field) of 3.68 $MA/cm^2$ could be obtained from GdBCO film deposited at $780^{\circ}C$, representing that BHO is a strong candidate for the buffer layer on the IBAD MgO template.

Detecting the Honeycomb Sandwich Composite Material's Moisture Impregnating Defects by Using Infrared Thermography Technique

  • Kwon, Koo-Ahn;Park, Hee-Sang;Choi, Man-Yong;Park, Jeong-Hak;Choi, Won-Jae
    • Journal of the Korean Society for Nondestructive Testing
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    • v.37 no.2
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    • pp.99-105
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    • 2017
  • Many composite materials are used in the aerospace industry because of their excellent mechanical properties. However, the nature of aviation exposes these materials to high temperature and high moisture conditions depending on climate, location, and altitude. Therefore, the molecular arrangement chemical properties, and mechanical properties of composite materials can be changed under these conditions. As a result, surface disruptions and cracks can be created. Consequently, moisture-impregnating defects can be induced due to the crack and delamination of composite materials as they are repeatedly exposed to moisture absorption moisture release, fatigue environment, temperature changes, and fluid pressure changes. This study evaluates the possibility of detecting the moisture-impregnating defects of CFRP and GFRP honeycomb structure sandwich composite materials, which are the composite materials in the aircraft structure, by using an active infrared thermography technology among non-destructive testing methods. In all experiments, it was possible to distinguish the area and a number of CFRP composite materials more clearly than those of GFRP composite material. The highest detection rate was observed in the heating duration of 50 mHz and the low detection rate was at the heating duration of over 500 mHz. The reflection method showed a higher detection rate than the transmission method.

A Numerical Analysis on Combustion Characteristics of the Gasoline Engine using Methanol Reformulated Fuels under WOT Condition (전부하 운전조건에서 메탄올 개질연료를 사용한 가솔린 엔진의 연소특성에 대한 수치해석)

  • Lee, Suk-Young;Jeon, Chung-Hwan
    • Journal of Energy Engineering
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    • v.20 no.2
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    • pp.163-169
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    • 2011
  • This research is to decide the possibility of using RM50(reformulated methanol fuel) without any modification of engine by the method of numerical analysis. Comparing the heat release rate, the difference among each fuel was decreased according to the increase of the engine speed, and the maximum heat release rate was higher in the order of RM50 and gasoline fuel. Also, this order corresponds to the order of burning speed. RM50 had the higher turbulent burning speed, and the curve of turbulent intensity was showed similar tendency to the curve of turbulent burning speed. RM50 had relatively high burning speed, short quenching length, high temperature in cylinder, so that it might increase NO emission, but owing to chemical reaction dynamics, it was decreased NO emission. Therefore, in order to predict the possibility of using RM50, it is needed to consider not only the temperature in cylinder by low heating value, but also combustion characteristics including burning speed.

An analysis on the utility of congealing water to improve efficiency of the air cooling equipment and save energy (냉방설비 성능개선 및 에너지 절약을 위한 응결수 활용성 분석)

  • Park, Keun-Soo;Park, Young-Ho;Yu, Jeong-Beom
    • Proceedings of the KSR Conference
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    • 2007.11a
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    • pp.974-981
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    • 2007
  • Seoul Metro has operated the air cooling equipment established in a machine room of a station building to improve our services focused on our customers who use Seoul Metro during the summer season. However, a new set of problems has arisen with the cooling tower to support a heat exchange of cooling water. One of them is loss of efficiency in the air conditioner. The leading cause of this problem is that we use an underground type of the cooling tower. As the machine room of a station building is located in the underground of inner city because of the nature of the subway, it is difficult to establish the cooling tower on the ground. The underground structure of the No. $1{\sim}4$ subway line is unsuitable for the location requirements of the underground type of the one because it has a limited space to set up the air cooling equipment, for example, the cooling tower and a ventilating opening. As a result of such an unfavorable condition, the cooling tower doesn't work efficiently and the warmth of cooling water because of insufficiency of a heat exchange and a refrigerator's technical obstacle such as a high-temperature and a high-pressure has arisen. Accordingly, the efficiency of the air conditioning is getting lower and lower. Another problem is too wasteful with water. Each station uses the water over 30 tons every day with waterworks to replenish the cooling tower such as a evaporation, a scattering and a distribution of water. Nevertheless, the more an air conditioner increase, the more the use of water supply increase. For this reason, we can't help wasting an enormous amount of water and discharging the congelation of a low temperature(about $15^{\circ}C$) occurred in a heat exchanger inside an air conditioner. The purpose of this study is to analyze the utility of congealing water to improve efficiency of the air cooling equipment and save energy as a supplementary water for the cooling tower.

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Wet Synthesis of Hydroxylammonium Nitrate (HAN) and Solid Phase Extraction Using Dual Organic Solvents (수산화암모늄나이트레이트(HAN)의 습식합성 및 이중 유기용매를 이용한 고체상 추출)

  • Kim, Sohee;Kwon, Younja;Jeon, Jong-Ki;Jo, Youngmin
    • Applied Chemistry for Engineering
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    • v.31 no.3
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    • pp.317-322
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    • 2020
  • Hydroxylammonium nitrate (HAN; NH3OHNO3) is an ionic energy material having a low melting temperature and vapor pressure with a high oxygen balance. To utilize it as an oxidizer for a high content liquid mono-propellant, a dual solvent was used to obtain HAN in a solid particulate form. The dehydrated crystal from an aqueous HAN was washed with dual organic solvents including acetone and ethanol, finally resulting in the moisture content of 13.8 wt%. When acetone was applied as a single solvent, the maximum synthesis yield of 88%, the HAN content evaluated by TGA of 86.2%, and the decomposition temperature ranged 160℃ to 205℃ were achieved.

Fabrication of Silicon Window for Low-price Thermal Imaging System (저가형 열영상 시스템을 위한 실리콘 윈도우 제작)

  • Sung, Byung Mok;Jung, Dong Geon;Bang, Soon Jae;Baek, Sun Min;Kong, Seong Ho
    • Journal of Sensor Science and Technology
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    • v.24 no.4
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    • pp.264-269
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    • 2015
  • An infrared (IR) bolometer measures the change of resistance by absorbing incident IR radiation and generates a signal as a function of the radiation intensity. Since a bolometer requires temperature stabilization and light filtering except for the infrared rays, it is essential for the device to be packaged meeting conditions that above mentioned. Minimization of heat loss is needed in order to stabilize temperature of bolometer. Heat loss by conduction or convection requires a medium, so the heat loss will be minimized if the medium is a vacuum. Therefore, vacuum packaging for bolometer is necessary. Another important element in bolometer packaging is germanium (Ge) window, which transmits IR radiation to heat the bolometer. To ensure a complete transmittance of IR light, anti-reflection (AR) coatings are deposited on both sides of the window. Although the transmittance of Ge window is high for IR rays, it is difficult to use frequently in low-price IR bolometer because of its high price. In this paper, we fabricated IR window by utilizing silicon (Si) substrate instead of Ge in order to reduce the cost of bolometer packaging. To enhance the IR transmittance through Si substrate, it is textured using Reactive Ion Etching (RIE). The texturing process of Si substrate is performed along with the change of experimental conditions such as gas ratio, pressure, etching time and RF power.

Optimization of the Processing Conditions for Heated Garlic Juice by Response Surface Methodology

  • Lee, Youn-Ri;Lee, Yun-Kyoung;Hwang, In-Guk;Lee, Yoon-Jeong;Woo, Koan-Sik;Han, Chung-Su;Kim, Eui-Su;Jeong, Heon-Sang
    • Preventive Nutrition and Food Science
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    • v.13 no.4
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    • pp.334-339
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    • 2008
  • This study was designed to determine the optimum conditions of heating temperature, heating time and dilution rates for producing heated garlic juice by using central composite design of response surface methodology. Garlic 3Department of Biosystems Engineering, Chungbuk National University, Cheongju 361-763, Korea was heated using a high temperature and pressure treatment apparatus. Total soluble solid contents ranged from 4.4 at $130^{\circ}C$ 3 hr and 6 fold dilution to 5.89 at $115^{\circ}C$ for 2 hr and 8 fold dilution. The highest total acidity was 0.55% at $120^{\circ}C$ for 3 hr and 2 fold dilution. The pH ranged from 4.01 at $130^{\circ}C$, 3 hr and 6 fold dilution to 5.85 at $120^{\circ}C$, 1 hr and 6 fold dilution. From the results of statistical analysis on the sensory evaluation the predicted optimum processing conditions for best color, taste, flavor and overall acceptance were $119.41^{\circ}C$, 3.11 hr, 5.85 fold dilution, $118.23^{\circ}C$, 3.57 hr, 3.15 fold dilution, $120.54^{\circ}C$, 3.47 hr, 5.01 fold dilution and $119.54^{\circ}C$, 3.18 hr, 5.66 fold dilution, respectively. The application of response surface methodology for preparing heated garlic juice processing showed a good correlation with high significance.

An Artificial Intelligence Method for the Prediction of Near- and Off-Shore Fish Catch Using Satellite and Numerical Model Data

  • Yoon, You-Jeong;Cho, Subin;Kim, Seoyeon;Kim, Nari;Lee, Soo-Jin;Ahn, Jihye;Lee, Eunjeong;Joh, Seongeok;Lee, Yang-Won
    • Korean Journal of Remote Sensing
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    • v.36 no.1
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    • pp.41-53
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    • 2020
  • The production of near- and off-shore fisheries in South Korea is decreasing due to rapid changes in the fishing environment, particularly including higher sea temperature in recent years. To improve the competitiveness of the fisheries, it is necessary to provide fish catch information that changes spatiotemporally according to the sea state. In this study, artificial intelligence models that predict the CPUE (catch per unit effort) of mackerel, anchovies, and squid (Todarodes pacificus), which are three major fish species in the near- and off-shore areas of South Korea, on a 15-km grid and daily basis were developed. The models were trained and validated using the sea surface temperature, rainfall, relative humidity, pressure,sea surface wind velocity, significant wave height, and salinity as input data, and the fish catch statistics of Suhyup (National Federation of Fisheries Cooperatives) as observed data. The 10-fold blind test results showed that the developed artificial intelligence models exhibited accuracy with a corresponding correlation coefficient of 0.86. It is expected that the fish catch models can be actually operated with high accuracy under various sea conditions if high-quality large-volume data are available.

Studies on the Oxygen Permeability and It's Proofness of the Various Commercial Polymer Films (상업용 고분자 필름의 산소투과도 및 산소투과 방지도에 관한 연구)

  • Suh, Hwan-Kyu;Kim, Joon-Soo;Lee, Jung-Keun
    • Elastomers and Composites
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    • v.15 no.1
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    • pp.3-9
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    • 1980
  • The oxygen permeability and it's proofness of te various commercial polymer films have been investigated at the constant pressure and temperature. Oxygen proofness, the reciprocals of the oxygen permeability for the various samples, were determined by means of a coulometric oxygen permeability tester. The testing of sample films was performed at constant temperature $(23{\pm}1^{\circ}C)$ under 1 atm. for 24 hours. The order of the relative proofness observed are as follows; oriented Nylon (O. Nylon)> oriented Polyester (O. PET)>nonoriented Nylon (N. Nylon)>nonoriented Polyester (N.PET)> rigid Polyvinyl chloride (Rigid PVC)>semirigid Polyvinyl chloride (Semirigid PVC)> oriented Polypropylene (O. PP)>plasticized Polyvinyl chloride (P. PVC)> casted Polypropylene (C. PP)> low density Polyethylene (LDPE)>high density Polyethylene (HDPE, Inflation)> high density-polyethylene (HDPE, T-die) The oxygen proofness of the films was increased with the polarity cf polymer, the film thickness and mechanical orientation and decreased with the addition of plasticizer in PVC. For the use of wrapping materials, one film with the polar property in the main chain of the polymer molecule and the others with nonpolar property in it are laminated for the protection from oxygen and moisture.

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