• Title/Summary/Keyword: high temperature high pressure

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Extinguishing Characteristics of Liquid Pool Eire by Water Mist Containing Sodium Salt (나트륨 염이 첨가된 미분무수의 액체 pool fire소화특성)

  • Park Jae-Man;Shin Chang-Sub
    • Fire Science and Engineering
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    • v.19 no.3 s.59
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    • pp.13-19
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    • 2005
  • An experimental study is presented for extinguishing characteristics of liquid fuel fire by water mist containing sodium acetate trihydrate. To evaluate the extinguishing performance of water mist containing an additive, the evaporation characteristics of a water droplet on a heated surface was examined. The evaporation process was recorded by a charge-coupled-device camera. Also, small-scale extinguishing tests were conducted for n-heptane pool fire in ventilated space to measure flame temperature variation. The average evaporation rate of a water droplet containing an additive was lower than that of a pure water droplet at a given surface temperature due to the precipitation of salt in the liquid-film and change of surface tension. In case of using an additive, the flame temperature was lower than that of pure water at a given discharge pressure and it was because the momentum of a water droplet containing an additive was increased reducing flame size. And also dissociated metal atoms, sodium, were reacted as a scavenger of the major radical species OH^-,\;H^+$ which were generated for combustion process. Moreover, at a high pressure of 4MPa, the fire was extinguished through blowing effect as well as primary extinguishing mechanisms.

Characteristics of amorphous indium tin oxide films on PET substrate grown by Roll-to-Roll sputtering system (저온 Roll-to-Roll 스퍼터 시스템을 이용하여 PET 기판위에 성막 시킨 ITO 박막의 전기적, 광학적, 구조적 특성)

  • Cho, Sung-Woo;Bae, Jung-Hyeok;Choi, Kwang-Hyuk;Moon, Jong-Min;Jeong, Jin-A;Jeong, Soon-Wook;Kim, Han-Ki
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.11a
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    • pp.380-381
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    • 2007
  • This paper reports on the deposition conditions and properties of ITO films used as electrode layer in a organic light emitting diodes on a PET substrate. The deposition technique employed was specially designed roll-to-roll sputtering. The oxide was deposited at room temperature in an argon and oxygen plasma on a transparent conducting ITO layer on a PET film. The influence of deposition parameters such as DC power, working pressure and oxygen partial pressure has been investigated, in order to obtain the best compromise between a high deposition rate and adequate electro-optical properties. Electrical and optical properties of ITO films were analyzed by Hall measurement examinations with van der pauw geometry at room temperature and UV/Vis spectrometer analysis, respectively. In addition, the structural properties and surface smoothness were measured by x-ray diffraction and scaning electron microscopy, respectively. From optimized ITO films grown by roll-to-roll sputter system, good electrical$(6.44{\times}10^{-4}\;{\Omega}-cm)$ and optical(above 86 % at 550 nm) properties were obtained. Also, the ITO films exhibited amorphous structure and very flat surface beacause of low deposition temperature.

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The Deposition of $SnO_2$ Films by Spray Pyrolysis (분무열분해법에 의한 $SnO_2$ 박막의 증착)

  • Kim, Tae-Heui
    • Solar Energy
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    • v.15 no.2
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    • pp.91-99
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    • 1995
  • The influence of deposition parameters on the deposition of $SnO_2$ thin films by spray pyrolysis has been studied. In the case of spray solution with tile concentration of 0.01M, at low deposition temperature the deposition was controlled by surface reaction and portion controlled by mass transfer is increased with increasing deposition temperature to $400^{\circ}C$. Above $400^{\circ}C$, the deposition is controlled by mass transfer at low spray pressure, and by surface reaction at high spray pressure. As the concentration of spray solution increased the deposition rate increased, and in this experiment the deposition depends on the Rideal-Eley mechanism. The deposition rate increased with increasing substrate temperature up to $400^{\circ}C$ and then decreased due to homogeneous nucleation. The thickness of the deposit increased with increasing spray duration, and the adhesion between substrate and deposit was formed physically.

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Distillation of Cd- ZrO2 and Cd- Bi in Crucible With Splatter Shield

  • Kwon, S.W.;Kwon, Y.W.;Jung, J.H.;Kim, S.H.;Lee, S.J.
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2018.11a
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    • pp.103-103
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    • 2018
  • The liquid cathode processing is necessary to separate cadmium from the actinide elements in the pyroprocessing since the actinide deposits are dissolved or precipitated in a liquid cathode. Distillation process was employed for the cathode processing owing to the compactness. It is very important to avoid a splattering of cadmium during evaporation due to the high vapor pressure. Several methods have been proposed to lower the splattering of cadmium during distillation. A multi-layer porous round cover was proposed to avoid a cadmium splattering in our previous study. In this study, distillation behavior of $Cd-ZrO_2$ and Cd - Bi systems were investigated to examine a multi-layer porous round cover for the development of the cadmium splatter shield of distillation crucible. It was designed that the cadmium vapor can be released through the holes of the shield, whereas liquid drops can be collected in the multiple hemisphere. The cover was made with three stainless steel round plates with a diameter of 33.50 mm. The distance between the hemispheres and the diameter of the holes are 10 and 1 mm, respectively. Bismuth or zirconium oxide powder was used as a surrogate for the actinide elements. About 40 grams of Cd was distilled at a reduced pressure for two hours at various temperatures. The mixture of the cadmium and the surrogate was distilled at 470, 570 and $620^{\circ}C$ in the crucible with the cover. Most of the bismuth or zirconia remained in the crucible after distillation at 470 and $570^{\circ}C$ for two hours. It was considered that the crucible cover hindered the splattering of the liquid cadmium from the distillation crucible. A considerable amount of the surrogate material reduced after distillation at $620^{\circ}C$ due to the splattering of the liquid cadmium. The low temperature is favorable to avoid a liquid cadmium splattering during distillation. However, the optimum temperature for the cadmium distillation should be decided further, since the evaporation rate decreases with a decreasing temperature.

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Processing and Mechanical Properties of Mullite Fiber / Fe Composite

  • Niibo, Yoshihide;Yuchi, Kazuhiro;Sameshima, Soichiro;Hirata, Yoshihiro
    • Proceedings of the Korea Association of Crystal Growth Conference
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    • 2000.06a
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    • pp.195-214
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    • 2000
  • The high-speed steel (shorten as HSS) consists of Fe and several kinds of transition metal carbides. The cutting tools or wear-resistant materials made from HSS experience relatively high thermal shock because a coolant such as water or oil is flowed over the surface of heated HSS. The purpose of this research is to increase the hardness, strength, fracture toughness and thermal shock resistance of HSS. A possible strategy is to incorporate a hard ceramic material with high strength in HSS matrix. This paper describes the processing, microstructure and mechanical properties of the oriented unidirectional mullite fiber/HSS composite. The unidirectional mullite fibers of 10${\mu}{\textrm}{m}$ diameter were dispersed by the ultrasonic irradiation of 38 kHz in an ethylenglycol suspension containing HSS powder of 11${\mu}{\textrm}{m}$ median size. The dried green composites with 4-68 vol% fibers were hot-pressed for 2h at 100$0^{\circ}C$ in Ar atmosphere under a pressure of 39 MPa. The higher density was achieved in the composite with a lower content of fibers. The oriented unidirectional fibers were well dispersed in the HSS matrix. The average distance between the center of fibers in the cross section was close to the value calculated from the fiber fraction. No reaction occurred at the interfaces between HSS and mullite fibers in the composites. The composite with 13.6 vol% fibers showed 100 MPa of four point flexural strength at room temperature. The thermal expansion of composite with heating was influenced by the orientation of mullite fibers.

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Fundamental Study of Fire-Proof Characteristics of High Strength Concrete Using Meta-Kaolin and Waste Tire Chip (메타카올린과 폐타이어 잔입자를 사용한 고강도콘크리트의 내화성능에 관한 기초적 연구)

  • Lee, Mun-Hwan;Lee, Sea-Hyun
    • Journal of the Korea Concrete Institute
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    • v.20 no.1
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    • pp.89-97
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    • 2008
  • By replacing the meta-kaolin with cement and the waste tire chip with fine aggregate separately, the high strength concrete is protected from the spalling in fire and the method to constrain the temperature increase of steel bar within the concrete and the basic properties of the high strength concrete mixed with the material are reviewed. As the result, meta-kaolin increases the self fire proof characteristics of the concrete, the waste tire chip can share the internal expanding pressure so it can be deleted. In detail, using the meta-kaolin about the cement in 4$\sim$8% of weight ratio about the cement and the waste tire chip under the grade scope of 0.6$\sim$3 mm in 5$\sim$10% of weight ratio about the sand is very effective to prevent the spalling.

The Effect of Pulp type and Initial Calendering on the Characteristics of Recycled Fiber (펄프의 종류 및 초기 캘린더링이 리사이클 섬유의 특성에 미치는 영향)

  • 손상돈;안병준;백기현
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.31 no.4
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    • pp.41-48
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    • 1999
  • This study was intended to investigated the effect of pulp type and intital calendering on the properties of recycled fiber. As the number of recycling is increased, at least by the fourth recycling , the freeness of the SW-BKP and HW-BKP increased. And then that decrease after the fifth recycling. Especially the freeness of CTMP increased more rapidly than any other pulp in first recycling. And there was no difference of freeness in all kind of pulp by initial calendering . The speed of dewatering in making sheet consistetly became slow by proceeding recycling on condition of all calendering. and the order of the speed of dewatering was as followed. CTMP>HW-BKP>SW-BKP. However in case of HW-BKP, which was low -yield pulp, the tendency of the speed of dewatering was similar to that of CTMP which was high-yield pulp and had high content lignin . There was no change of fiber length and no effect of calendering by recycling of HW-BKP and CTMP. Howeverfiber length of SW-BKP generally decreased, especially in calendering of high temperature and high pressure conditions. The WRV of SW-BKP diminished by proceeding recycling but that of HW-BKP and CTMP diminished in the first recycling and then there was no change of the WRV of HW-BKP and CTMP. The contents of fines of HW-BKP consistently decreased by the fourth recycling and then increased in the fifth recycling . On the other hand there was no tendency in the content of fines of SW-BKP and CTMP by the number of recycling.

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Potential Performance Enhancement of Dual Heat Pump Systems through Series Operation (히트펌프 직렬운전에 의한 성능 향상 가능성에 관한 연구)

  • Baik, Young-Jin;Kim, Min-Sung;Chang, Ki-Chang;Lee, Young-Soo;Kim, Hyeon-Ju
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.36 no.8
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    • pp.797-802
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    • 2012
  • In this study, the potential performance enhancement in a dual heat pump system through series operation was investigated by a comparison between the performance for parallel and series operation for a heating supply temperature of $60^{\circ}C$. To compare the performance of each configuration fairly, the heat transfer surface area of the heat exchangers was fixed. The inlet temperatures and the flow rates of the heat source and the load were also fixed. In addition, the heat transfer and pressure drop characteristics of the working fluids were considered to achieve a more realistic comparison. The results show that the heating coefficient of performance (COP) of the series configuration is approximately 5% higher than that of the parallel configuration under the simulation conditions considered in the present study.

A Study of New Technique Development for Creep Evaluation of Heat Resistant Steel Weldment(I) (내열강 용접부의 크리프 평가 신기술 개발에 관한 연구)

  • 유효선;백승세;권일현;이송인
    • Journal of Welding and Joining
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    • v.20 no.6
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    • pp.30-30
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    • 2002
  • It has been reported that the creep characteristics on weldment which is composed of weld metal(W.M), fusion line(F.L), heat-affected zone(HAZ), and base meta(B.M) could be unpredictably changed in severe service conditions such as high temperature and high pressure. However, the studies done on creep damage in power plant components have been mostly conducted on B.M and not the creep properties of the localized microstructures in weldment have been thoroughly investigated yet. In this paper, it is investigated the creep characteristics for three microstructures like coarse-grain HAZ(CGHAZ), W.M, and B.M in X20CrMoV121 steel weldment by the small punch-creep-(SP-Creep) test using miniaturized specimen(l0×10×0.5mm). The W.M microstructure possesses the higher creep resistance and shows lower creep strain rate than the B.M and CGHAZ. In the lower creep load the highest creep strain rate is exhibited in CGHAZ, whereas in the higher creep load the B.M represents the high creep strain rate. The power law correlation for all microstructures exists between creep rate and creep load at 600℃. The values of creep load index (n) based on creep strain rate for B.M, CGHAZ, and W.M are 7.54, 4.23, and 5.06, respectively and CGHAZ which shows coarse grains owing to high welding heat has the lowest creep loade index. In all creep loads, the creep life for W.M shows the highest value.

The Option Study of Oversea Shipment of DUPIC Fuel Elements to Canada (고방사성 산화물핵연료의 해외수송방안 분석)

  • 이호희;박장진;양명승;서기석
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2003.11a
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    • pp.614-620
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    • 2003
  • KAERI has developed DUPIC nuclear fuel with the refabrication of spent PWR fuel discharged from domestic nuclear power plant by a dry process at M6 hot-cell in IMEF To verify the performance of DUPIC nuclear fuel, irradiation test at the operating conditions of commercial power plant is essential. Since the HANARO research reactor of KAERI does not have fuel test loop(FTL) for irradiating nuclear fuel under high temperature and high pressure conditions, DUPIC fuel cannot be irradiated in the FTL of HANARO. In the 13-th PRM among Korea, Canada, USA and IAEA, AECL proposed that KAERI fabricated DUPIC fuel can be irradiated in the FTL of the NRU research reactor without charge of neutrons. The transportation quantity of DUPIC fuel to Canada is 10 elements(about 6kg). This transportation package is classified as the 7-th class according to "recommendation on the transport of dangerous goods" made by the United Nations. In case of air shipment, until now, there is no proper air transportation cask for DUPIC fuel. In case of sea transportation is possible but requires very high cost.high cost.

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