• Title/Summary/Keyword: high temperature high pressure

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An Experimental Study on the Atomization Characteristics of Coal-Water-Mxture (CWM의 미립화특성에 대한 실험적 연구)

  • 김윤태;전영남;채재우
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.14 no.5
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    • pp.1330-1336
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    • 1990
  • The factors to act on atomization of liquid fuel are viscosity, geometric shape of nozzle, atomizing pressure, etc. Most of high viscous liquid fuels show decrease in viscosity by raising the preheat temperature, but the viscosity of liquid fuel like CWM does not readily change with fuel temperature. As an experimental study to investigate the atomizing characteristics of CWM, CWM fuel is atomizing with a twin-fluid atomizer, and the effects of the geometric shape of spray nozzle on atomization are investigated by measuring the Sauter`s Mean Diameter (SMD) of CWM. The summarized results obtained in this study are as follows ; (1) As the ratio of the mass flows of atomizing air to that of fuel (W$_{a}$ /W$_{1}$) increases, 능 decreases when fuel temperature is constant. (2) At the ratio (t/d) 4 of thickness (t) of spray nozzle hole to the diameter (d) of the hole, there is the best atomization. And SMD decreases when t/d is between 1 to 4 and increases when t/d > 4.

The Distribution Characteristics of Polychlorinated Biphenyls in Rural Atmosphere

  • Yeo, Hyun-Gu;Park, Minkyu;Chun, Man-Young;Young Sunwoo
    • Journal of Korean Society for Atmospheric Environment
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    • v.18 no.E3
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    • pp.143-151
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    • 2002
  • Atmospheric concentrations of polychlorinated biphenyl (PCB) congeners were measured every two weeks from July, 1999 to January, 2000 at Hankyong University in Ansung, Kyounggi-do. Atmospheric concentrations of ∑$_{24}$PCB showed a range of 19.8~71.9 pg/m3. The highest concentration of PCB homolog was tri-CBs (sum of PCB 18, 27, 28, 33, 38) which had a comparatively higher vapor pressure than other homologs. The contribution ratio of lighter PCB homologs (tri-CBs) to total PCBs was 44.5%, and these homologs were the main components of PCBs. The ratio PCB homologs/deca-CB (PCB 209) suggested that the contribution of vapor phase PCBs increased greatly in summer relative to other seasons. In addition, the regression lines for PCB homologs/deca-CB (PCB 209) and temperature ($^{\circ}C$) appeared as an exponential function with high correlation (R2>0.67, p< 0.01). This suggests that the concentration of vapor phase PCB homologs increases steeply with increasing temperature.

The Effect of Extrusion Temperature and Die Angle on Mechanical Properties of $SiC_p$/2024Al Composites Fabricated by Powder Extrusion Method (분말압출법으로 제조된 $SiC_p$/2024Al 복합재료에 있어서 압출온도와 다이각이 기계적 성질에 미치는 영향)

  • 성병진
    • Journal of Powder Materials
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    • v.2 no.1
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    • pp.44-52
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    • 1995
  • Effects of the extrusion temperature and die angle on the tensile properties of SiCIyAl composites in powder extrusion have been investigated. SiCP/Al composites were extruded at various extrusion temperatures (450, 500, $550^{\circ}C$) under the extrusion ratio of 25 : 1. The ram speed was maintained at 13 cm/min for all the extrusion conditions. The surface of the extruded rod appeared to be smooth without tearing at 450 and 50$0^{\circ}C$, whereas it was very rough due to tearing at $550^{\circ}C$. It was found that the tensile strength and elongation of the composites extruded at $500^{\circ}C$ are greater than those of composites extruded at $450^{\circ}C$ This is due to the easier plastic deformation of composite extruded at $500^{\circ}C$, compared with the composites extruded at $450^{\circ}C$. The effect of die angle was examined under 20=60, 120, $180^{\circ}$die angles at extrusion temperature of $500^{\circ}C$ under 25:1 extrusion ratio. The tensile strength of the composites extruded with 20=$60^{\circ}$approved to be higher than that of the composties extruded with 28 : 120 and $180^{\circ}$This is attributable to the higher extrusion pressure, which mixed composite powders could be densely consolidated at elevated temperatures, resulting from high friction force between billet and sliding surface of conical die.

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Fundamental Kinetics of Cephradine Oxidation in Supercritical Water (초임계수에서 Cephradine 산화반응속도)

  • 김영권;김인배
    • Journal of Environmental Health Sciences
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    • v.30 no.2
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    • pp.133-139
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    • 2004
  • The objective of this study was to investigate the destruction efficiency and to determine the fundamental parameters of oxidation kinetics under the supercritical water(SCW) condition. Target material was cephradine, toxic and antibiotic material, in the pharmaceutical wastewater. For this purpose, the effect of reaction temperature and oxidant were investigated on the destruction efficiency of cephradine. And the oxidation kinetics of cephradine was derived by using a empirical power-law model. The experiment was carried out in a cylindrical batch reactor made of Hastelloy C-276 which was endurable high temperature and pressure. The destruction efficiency of cephradine increased with increment of the temperature and reaction time. Also the type of oxidants was effected and oxidants(Air and $H_2O$$_2$) were enhanced the destruction efficiency. The global oxidation kinetics for cephradine has led to two rate expressions according to type of oxidant. - In the presence of air oxidant: Rate=k. $e^{-Ea}$RT/(Ceph.)$^{1.0}$ ( $O_2$)$^{0.51}$$\pm$0.05(k=3.27${\times}$$10^{5}$ sec. Ea=63.25 kJ/mole) - In the presence of $H_2O$$_2$ oxidant : Rate=kㆍ $e^{-Ea}$RT/(Ceph.)$^{1.0}$ ($H_2O$$_2$)$^{0.62}$$\pm$0.02(k=2.76${\times}$$10^4$/sec. Ea=47.65 kJ/mole)ole))

Characteristics of joint resistance with different kinds of HTS tapes for heater trigger switch

  • Lee, Jeyull;Park, Young Gun;Lee, Woo Seung;Jo, Hyun Chul;Yoon, Yong Soo;Ko, Tae Kuk
    • Progress in Superconductivity and Cryogenics
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    • v.16 no.1
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    • pp.32-35
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    • 2014
  • Recently, many researches on the system of superconducting power supply and superconducting magnetic energy storage (SMES) using high temperature superconducting (HTS) tapes has been progressed. Those kinds of superconducting devices use the heater trigger switches that have a control delay problem at moments of heating up and cooling down. One way to reduce the time delay is using a different HTS tape at trigger part. For example, HTS tape having lower critical temperature can reduce time delay of heating up and heating down stage for heater trigger operation. This paper deals with resistances joint with different kinds of HTS tapes which have different properties to verify usefulness of the suggested method. Three kinds of commercial HTS tapes with different specifications are selected as samples and two kinds of solders are used for comparison. Joint is performed with temperature and pressure controllable joint machine and the joint characteristics are analyzed under the repeatable conditions.

Effective Interdiffusion of Co/Pd multilayers

  • Kim, Jai-Young;Jan E. Evetts
    • Journal of Magnetics
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    • v.2 no.3
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    • pp.86-92
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    • 1997
  • An artificially modulated magnetic Co/Pd multilayer is one of the promising candidates for high density magneto-optic (MO) recording media in the wavelength of a blue laser beam, due to large Kerr rotation angle. However, since the Co/Pd multilayer is a non-equilibrium state in terms of free energy and MO recording is a kind of thermal recording which is conducted around Curie temperature (Tc) of the recording media, the assessment of the thermal stability in the Co/Pd multilayer is crucially important both for basic research and applications. As the parameter of the thermal stability in this research, effective interdiffusion coefficients (Deff) perpendicular to the interface of the Co/Pd multilayers are measured in terms of Ar sputtering pressure and heat treatment temperature. From the results of the research, we find out that the magnetic exchange energy between Co and Pd sublayers strongly affects Deff of the Co/Pd multilayers. This discovery will provide the understanding of the magnetic exchange energy in the effective interdiffusion process of a magnetic multilayer structure and suggest the operating temperature range for MO recording in the Co/Pd multilayer for the basic research and applications, respectively.

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A Study on Fatigue Crack Behavior of Metal Matrix Composites for Automobile Engine (자동차엔진용 금속기 복합재료의 피로균열거동에 관한 연구)

  • 박원조;허선철;정재욱;이해우;부명환
    • Transactions of the Korean Society of Automotive Engineers
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    • v.11 no.5
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    • pp.140-146
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    • 2003
  • Metal matrix composites had generated a lot of interest in recent time because of their high specific strength and stiffness in specific properties. It was also highlighted as the material of frontier industry because strength, heat-resistance, corrosion-resistance and wear-resistance were superiored. In this study, the strength properties of $Al_{18}B_{4}O_{33}$/AC4CH composites were represented mixing the binder of $SiO_2$. It was also fabricated by squeeze casting. $Al_{18}B_{4}O_{33}$/AC4CH was fabricated at the melt temperature of $760^{\circ}C$, the perform temperature of $700^{\circ}C$ and mold temperature of $200^{\circ}C$ under the pressure of 83.4MPa. Consequently, fatigue life was observed roughly in the order of AC4CH> nobiner> $SiO_2$, independently on crack propagation direction and stress ratio.

Evaporation Rate of Lead in Molten Copper Alloy by Gas Injection (가스취입에 의한 용융 동 합금 중 납의 증발속도)

  • Kim, Hang-Su;Jeong, Seong-Yeop;Jeong, U-Gwang;Yun, Ui-Han;Son, Ho-Sang
    • Korean Journal of Materials Research
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    • v.12 no.1
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    • pp.68-74
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    • 2002
  • The lead has to be removed for the recycling of copper alloy. The lead cannot be removed from the copper alloy by oxidation. It can be removed by the evaporation because of its high vapor pressure. However, rare information is found on removal of lead from copper alloy. The purpose of present work is to provide a fundamental knowledges on the removal of lead from the copper alloy by evaporation. Gas injection was made in molten copper alloy, and the evaporation rate of lead was measured. The influence of Ar gas flow rata(2~4 L/min), initial contents of lead(2~4wt%Pb), temperature(1200~140$0^{\circ}C$) was investigated based on the thermodynamic and the kinetics. The rate constant is increased with increasing flow rate of Ar and temperature. Though amount of lead removed is increased with higher initial lead concentration, the rate constant is not changed significantly. The activation energy is estimated from the temperature dependence of the rate constant. Also removal of lead from the copper by adding chloride was made for the comparison.

Effect of Salt Concentration and Temperature in Synthetic Dyestuff Wastewater Treatment using Plate and Frame Membrane Module (평판형 막모듈을 이용한 합성염료 폐수처리에 있어서 염농도 및 온도의 영향)

  • Kim, Sun-Il;Lee, Bong-Woo;Yun, Young-Jae
    • Journal of Environmental Science International
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    • v.7 no.2
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    • pp.209-216
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    • 1998
  • Nanofiltration[NF45] and reverse osmosis membrane(HR98PP) separation treatment of dyestuff wastewater was carried out In order to separate relatively pure water from synthetic dyestuff wastewater, which consists of reactive dye, acid dye, basic dye, direct dye, and disperse dye. The experiments were performed by using the plate and frame membrane module. In the nanofiltration and reverse osmosis membrane separation, When the NaCl concentration was 0.1, 5.0, and 20.091, retention was 63.0, 46.0, 0.9%, respectively. When permeate flux was 125.0, 67.5, and 45.0 L/$m^2$ h, the osmotic pressure increased with Increasing the NaCl concentration. Permeate flux of two membranes Increased as temperature Increased due to segmental movement of polymer of the membrane and the rejection rate of dyestuff was decreased gradually. It was found that the rejection rate was about 95% in the nanofiltratlon, while the reverse osmosis membrane showed a high rejection rate of 99% under all temperature and pressures conditions.

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A study on the Electrical Characteristics of $\alpha$-Sexithiophene Thin Film ($\alpha$-Sexithienyl 박막의 전기적 특성에 관한 연구)

  • 오세운;권오관;최종선;김영관;신동명
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1997.11a
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    • pp.518-520
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    • 1997
  • Recently, thiophene oligomer with short chain lengths has received much attention as model compounds for facilitating better understanding of electronic and optical properties of polymers, because oligomer is well-defined chemical systems and its conjugation chain length can be exactly controlled. Moreover, organic this films based on conjugated thiophene oligomer have potential for application to electronic and optoelectronic devices such as MISFETs(metal-insulator-semiconductor field-effect transistors) and LEDs(light-emitting diodes). However, there is little knowledge on electronic and structural properties of linear-conjugated oligothiophenes in solid states, compared with those in solutions. $\alpha$-sexithienyl($\alpha$-6T) thin-films were deposited by OMBD(Organic Molecular Beam Deposition) technique, where the $\alpha$-6T was synthesized and purified by the sublimation method. The $\alpha$-6T films were deposited under various conditions. The effects of deposition rate, substrate temperature, and vacuum pressure on the formation of these films have been studied. The molecules in the $\alpha$-6T film deposited at a low deposition rate under a high vacuum were aligned almost perpendicular to the substrate. The $\alpha$-6T films deposited at an elevated substrate temperature showed higher conductivity than the film deposited at room temperature. Electrical characterization of these films will be also executed by using four-point probe measurement technique.

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