• Title/Summary/Keyword: high temperature high pressure

Search Result 4,161, Processing Time 0.046 seconds

Resistive Switching Behavior of Cr-Doped SrZrO3 Perovskite Thin Films by Oxygen Pressure Change (산소 분압의 변화에 따른 Cr-Doped SrZrO3 페로브스카이트 박막의 저항변화 특성)

  • Yang, Min-Kyu;Park, Jae-Wan;Lee, Jeon-Kook
    • Korean Journal of Materials Research
    • /
    • v.20 no.5
    • /
    • pp.257-261
    • /
    • 2010
  • A non-volatile resistive random access memory (RRAM) device with a Cr-doped $SrZrO_3/SrRuO_3$ bottom electrode heterostructure was fabricated on $SrTiO_3$ substrates using pulsed laser deposition. During the deposition process, the substrate temperature was $650^{\circ}C$ and the variable ambient oxygen pressure had a range of 50-250 mTorr. The sensitive dependences of the film structure on the processing oxygen pressure are important in controlling the bistable resistive switching of the Cr-doped $SrZrO_3$ film. Therefore, oxygen pressure plays a crucial role in determining electrical properties and film growth characteristics such as various microstructural defects and crystallization. Inside, the microstructure and crystallinity of the Cr-doped $SrZrO_3$ film by oxygen pressure were strong effects on the set, reset switching voltage of the Cr-doped $SrZrO_3$. The bistable switching is related to the defects and controls their number and structure. Therefore, the relation of defects generated and resistive switching behavior by oxygen pressure change will be discussed. We found that deposition conditions and ambient oxygen pressure highly affect the switching behavior. It is suggested that the interface between the top electrode and Cr-doped $SrZrO_3$ perovskite plays an important role in the resistive switching behavior. From I-V characteristics, a typical ON state resistance of $100-200\;{\Omega}$ and a typical OFF state resistance of $1-2\;k{\Omega}$, were observed. These transition metal-doped perovskite thin films can be used for memory device applications due to their high ON/OFF ratio, simple device structure, and non-volatility.

The interaction between helium flow within supersonic boundary layer and oblique shock waves

  • Kwak, Sang-Hyun;Iwahori, Yoshiki;Igarashi, Sakie;Obata, Sigeo
    • Proceedings of the Korean Society of Propulsion Engineers Conference
    • /
    • 2004.03a
    • /
    • pp.75-78
    • /
    • 2004
  • Various jet engines (Turbine engine family and RAM Jet engine) have been developed for high speed aircrafts. but their application to hypersonic flight is restricted by principle problems such as increase of total pressure loss and thermal stress. Therefore, the development of next generation propulsion system for hypersonic aircraft is a very important subject in the aerospace engineering field, SCRAM Jet engine based on a key technology, Supersonic Combustion. is supposed as the best choice for the hypersonic flight. Since Supersonic Combustion requires both rapid ignition and stable flame holding within supersonic air stream, much attention have to be given on the mixing state between air stream and fuel flow. However. the wider diffusion of fuel is expected with less total pressure loss in the supersonic air stream. So. in this study the direction of fuel injection is inclined 30 degree to downstream and the total pressure of jet is controlled for lower penetration height than thickness of boundary layer. Under these flow configuration both streams, fuel and supersonic air stream, would not mix enough. To spread fuel wider into supersonic air an aerodynamic force, baroclinic torque, is adopted. Baroclinic torque is generated by a spatial misalignment between pressure gradient (shock wave plane) and density gradient (mixing layer). A wedge is installed in downstream of injector orifice to induce an oblique shock. The schlieren optical visualization from side transparent wall and the total pressure measurement at exit cross section of combustor estimate how mixing is enhanced by the incidence of shock wave into supersonic boundary layer composed by fuel and air. In this study non-combustionable helium gas is injected with total pressure 0.66㎫ instead of flammable fuel to clarify mixing process. Mach number 1.8. total pressure O.5㎫, total temperature 288K are set up for supersonic air stream.

  • PDF

Process Parameters on Quality Characteristics of Jacopever (Sebastes schlegeli Hilgendorf) under Treatment of Hydrostatic Pressure (고압처리 공정변수가 조피볼락의 초기 품질특성에 미치는 영향)

  • Kim, Min-Ji;Lee, Soo-Jeong;Kim, Chong-Tai
    • The Korean Journal of Food And Nutrition
    • /
    • v.29 no.3
    • /
    • pp.371-381
    • /
    • 2016
  • The present study investigated the effects of processing parameters such as time (10, 20, 30, 40 min), pressure (25, 50, 75, 100 MPa), and the salinity of brine (0~10%(w/v)) on jacopever (Sebastes schlegeli Hilgendorf) in order to establish optimization of the three factors using a high hydrostatic pressure (HHP) machine. To do so, it analyzed the quality characteristics of volatile basic nitrogen (VBN), trimethylamine (TMA), total bacterial counts, dynamic viscoelasticities, and differential scanning calorimetry (DSC) properties. First, when the time increased to 40 mins, by 10 min intervals, the total bacterial counts in HHP groups under $25^{\circ}C$, 100 MPa, and 4%(w/v) brine were significantly decreased except for the first 10 min in comparison to the control group. In regards to DSC properties, the onset temperature ($T_O$) of the first endothermal curve was significantly reduced. Second, when the pressure level increased up to 100 MPa by 25 MPa increments, the total bacterial counts in the HHP samples significantly decreased for 20 min at 50 MPa or higher. As the pressure increased, G', G" and the slope of tan ${\delta}$ decreased (except for 50 MPa). Third, in regards to the salinities of brine, when the HHP processing was treated at 100 MPa, $25^{\circ}C$ for 20 min, the total bacterial counts of all the HHP groups significantly decreased in comparison to those of the control group. A significant difference was found in the enthalpy of the second endothermic curve in the 6~10%(w/v) (except 7%(w/v)) HHP groups. Therefore, the salinity of the immersion water under the HHP condition was appropriate when it was lower than 6%(w/v). The present study demonstrated that the optimum parameter condition according to/under the condition of the microbial inhibition and economic effects using an HHP would be the reaction time for 20 min, reaction pressure at 100 MPa, and the salinity of 4%(w/v) brine.

Effect of pre-post injection timing of diesel fuel for naval vessel on the combustion and emission characteristics in an optically-accessible single cylinder diesel engine (단기통 디젤엔진에서 함정용 디젤유의 전·후 분사시기가 연소 및 배출가스 특성에 미치는 영향)

  • Lee, Hyungmin
    • Journal of Advanced Marine Engineering and Technology
    • /
    • v.38 no.7
    • /
    • pp.868-876
    • /
    • 2014
  • The objective of this study is focused on the analyzing combustion, carbon monoxide and hydrocarbon emission characteristics of marine diesel oil, utilized for naval propulsion engine, with varying pre-post injection timing of an optically accessible single cylinder engine. And also the combustion process is analyzed by means of a high speed camera visualization. On the result of retarding pre-injection timing toward main injection timing, the mean effective pressure and maximum pressure of combustion chamber are increased; however, the heat release rate is decreased. Furthermore, the emission rates of carbon monoxide and hydrocarbon are reduced in this case. In hence, when a post-injection timing is advanced, the mean effective pressure and maximum pressure are increased, because the combustion has been performed under the high temperature and high pressurized environment during main injection time, and the emission rates of carbon monoxide and hydrocarbon are increased. From the experimental results, it considered that retarding of pre-injection timing affects to shorten the ignition delay of main injection clearly, and to raise the flame intensity comparing to the advanced state. The ignition delay during post-injection is not appeared at any post-injection time, but the flame intensity has been weakened gradually according to the retarding of post-injection timing.

Structural Design Requirements and Safety Evaluation Criteria of the Spent Nuclear Fuel Disposal Canister for Deep Geological Deposition (심지층 고준위폐기물 처분용기에 대한 설계요구조건 및 구조안전성 평가기준)

  • Kwon, Young-Joo;Choi, Jong-Won
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
    • /
    • v.5 no.3
    • /
    • pp.229-238
    • /
    • 2007
  • In this paper, structural design requirements and safety evaluation criteria of the spent nuclear fuel disposal canister are studied for deep geological deposition. Since the spent nuclear fuel disposal canister emits high temperature heats and much radiation, its careful treatment is required. For that, a long term(usually 10,000 years) safe repository for the spent nuclear fuel disposal canister should be secured. Usually this repository is expected to locate at a depth of 500m underground. The canister which is designed for the spent nuclear fuel disposal in a deep repository in the crystalline bedrock is a solid structure with cast iron insert, corrosion resistant overpack and lid and bottom, and entails an evenly distributed load of hydrostatic pressure from underground water and high pressure from swelling of bentonite buffer. Hence, the canister must be designed to withstand these high pressure loads. If the canister is not designed for all possible external loads combinations, structural defects such as plastic deformations, cracks, and buckling etc. may occur in the canister during depositing it in the deep repository. Therefore, various structural analyses must be performed to predict these structural problems like plastic deformations, cracks, and buckling. Structural safety evaluation criteria of the canister are studied and defined for the validity of the canister design prior to the structural analysis of the canister. And structural design requirements(variables) which affect the structural safety evaluation criteria should be discussed and defined clearly. Hence this paper presents the structural design requirements(variables) and safety evaluation criteria of the spent nuclear fuel disposal canister.

  • PDF

Studies of application of artificial ground freezing for a subsea tunnel under high water pressure - focused on case histories - (고수압 해저터널 건설을 위한 동결공법 적용성에 관한 연구 - 사례를 중심으로 -)

  • Son, Young-Jin;Lee, Kyu-Won;Ko, Tae Young
    • Journal of Korean Tunnelling and Underground Space Association
    • /
    • v.16 no.5
    • /
    • pp.431-443
    • /
    • 2014
  • In this paper case studies of artificial ground freezing, which have not been applied in Korea, have been investigated for the water cut-off in a subsea tunnel under high water pressure and the most commonly used cooling mediums of brine and liquid nitrogen are examined. Since sea water with pressure has the lower freezing point than pure water, the lower temperature cooling medium is required in the application of subsea tunnel. Also, the cooling medium must have refrigeration safety and is able to reduce executing time. Brine freezing system can reuse cooling medium and is safer than liquid nitrogen freezing. But it takes more time to freeze ground and needs complex circulation plants. On the other hand, liquid nitrogen freezing system can't recycle cooling medium and may cause breathing problems or asphyxiation through oxygen deficiency. But, freezing with liquid nitrogen is fast and requires simple refrigeration equipment. Principal elements of design for ground freezing in subsea tunnel have been extracted and these elements are needed further research.

Optimization Study for the Production of 6-Shogaol-rich Ginger (Zingiber officinale Roscoe) under Conditions of Mild Pressure and High Temperature (가압조건에서 생강 유래 6-shogaol 변환을 위한 가열 조건 최적화)

  • Park, Ho-Young;Ha, Sang Keun;Choi, Jiwon;Choi, Hee-Don;Kim, Yoonsook;Park, Yongkon
    • Korean Journal of Food Science and Technology
    • /
    • v.46 no.5
    • /
    • pp.588-592
    • /
    • 2014
  • Under optimized condition mild pressure in combination with specific temperature for heat treatment transform the 6-gingerol into 6-shogaol. The purpose of this study was to optimize the conditions used for heat treatment under pressure for increasing 6-shogaol content in ginger (Zingiber officinale Roscoe). A central composite experimental design was used to evaluate the effects of application temperature ($70-130^{\circ}C$) and temperature-holding time (95-265 min) on the transformation of 6-shogaol. The experimental values were shown to be in significantly good agreement with the predicted values (adjusted determination coefficient, $R^2{_{Adj}}=0.9857$). 6-Shogaol content increased as the application temperature and temperature-holding time increased. By analyzing the response surface plots, the optimum conditions of heat treatment (temperature and time) for increasing 6-shogaol content were found to be $127^{\circ}C$ and 109 min, respectively. Under these optimal conditions, the predicted 6-shogaol content was 3.98 mg/g dried ginger. The adequacy of the model equation for predicting the optimum response values was effectively verified by the validation data.

Experimental Study on the Determination of Heat Transfer Coefficient for the KURT (KURT 내 열전달계수 결정에 관한 실험적 연구)

  • Yoon, Chan-Hoon;Kwon, Sang-Ki;Kim, Jin
    • Tunnel and Underground Space
    • /
    • v.19 no.6
    • /
    • pp.507-516
    • /
    • 2009
  • In cases of high-level radioactive waste repositories, heat load is apparent by radioactive waste decay. The safety of a waste repository would be influenced by changing circumstances caused by heat transfer through rock. Thus, a ventilation system is necessary to secure the waste repository. The first priority for building an appropriate ventilation system is completing a computer simulation research with thermal rock properties and a heat transfer coefficient. In this study, the heat transfer coefficient in KURT was calculated using the measurement of inner circumstance factors that include dry bulb and wet bulb temperature, rock surface temperature, and barometric pressure. The heater that is 2 m in length and 5 kw in capacity heats the inside of rock in the research module by $90^{\circ}C$. As a result of determining the heat transfer coefficient in the heating section, the changes of heat transfer coefficient were found to be a maximum of 7.9%. The average heat transfer coefficient is approximately 4.533 w/$m^2{\cdot}K$.

SUPERELASTICITY OF CAST SHAPE MEMORY Ni-Ti ALLOY (주조 형상기억 니켈-티타늄 합금의 초탄성)

  • Choi, Dong-Ik;Choie, Mok-Kyun
    • Journal of the Korean Academy of Esthetic Dentistry
    • /
    • v.3 no.1
    • /
    • pp.32-43
    • /
    • 1995
  • Ni-Ti alloy has excellent corrosion resistance, biocompatibility, shape memory effect and superelasticity, so it has been used widely in biomedical fields. But it has difficulty in casting due to its high melting temperature and oxygen affinity at high temperature. Recently it has been attempted to cast Ni-Ti alloy using new casting machine and investment. The purpose of this study was to examine the superelastic behavior of cast shape memory Ni-Ti alloy and to compare the mechanical properties of the cast shape memory alloy with those of commercial alloys for removable partial denture framework. Ni-Ti alloy(Ni 50.25%, Ti 49.75% : atomic ratio) was cast with dental argon-arc pressure casting machine and Type IV gold alloy, Co-Cr alloy, Ni-Cr alloy, pure titanium were cast as reference. Experimental cast Ni-Ti alloy was treated with heat($500{\pm}2^{\circ}C$) in muffle furnace for 1 hour. Transformation temperature range of cast Ni-Ti alloy was measured with differential scanning calorimetry. The superelastic behavior and mechanical properties of cat Ni-Ti alloy were observed and evaluated by three point bending test, ultimate tensile test, Vickers microhardness test and scanning electron microscope. The results were as follows : 1. Cast Ni-Ti alloy(Ni 50.25%, Ti 49.75% : atomic ratio) was found to have superelastic behavior. 2. Stiffness of cast Ni-Ti alloy was considerably lesser than that of commercial alloys for removable partial denture. 3. Permanent deformation was observed in commercial alloys for removable partial denture framework at three point bending test over proportional limit(1.5mm deflection), but was not nearly observed in cast Ni-Ti alloy. 4. On the mechanical properties of ultimate tensile strength, elongation and Vickers microhardness number, cast Ni-Ti alloy was similiar to Type IV gold alloy, Co-Cr alloy, Ni-Cr alloy and pure titanium. With these results, cast Ni-Ti alloy had superelastic behavior and low stiffness. Therefore, it is suggested that cast Ni-Ti alloy may be applicated to base metal alloy for removable partial denture framework.

  • PDF

Simulation Study on the Application of LNG Cold Energy for Hydrogen Liquefaction Process (수소액화공정에서 LNG 냉열 적용에 관한 시뮬레이션 연구)

  • HAN, DANBEE;BYUN, HYUNSEUNG;BAEK, YOUNGSOON
    • Journal of Hydrogen and New Energy
    • /
    • v.31 no.1
    • /
    • pp.33-40
    • /
    • 2020
  • As hydrogen utilization becomes more active recently, a large amount of hydrogen should be supplied safely. Among the three supply methods, liquefied hydrogen, which is an optimal method of storage and transportation convenience and high safety, has a low temperature of -253℃, which is complicated by the liquefaction process and consumes a lot of electricity, resulting in high operating costs. In order to reduce the electrical energy required for liquefaction and to raise the efficiency, hydrogen is cooled by using a mixed refrigerant in a precooling step. The electricity required for the precooling process of the mixed refrigerant can be reduced by using the cold energy of LNG. Actually, LNG cold energy is used in refrigeration warehouse and air liquefaction separation process, and a lot of power reduction is achieved. The purpose of this study is to replace the electric power by using LNG cold energy instead of the electric air-cooler to lower the temperature of the hydrogen and refrigerant that are increased due to the compression in the hydrogen liquefaction process. The required energy was obtained by simulating mixed refrigerant (MR) hydrogen liquefaction system with LNG cold heat and electric system. In addition, the power replacement rate of the electric process were obtained with the pressure, the temperature of LNG, the rate of latent heat utilization, and the hydrogen liquefaction capacity, Therefore, optimization of the hydrogen liquefaction system using LNG cold energy was carried out.