• Journal of the Korean Chemical Society
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• v.32 no.1
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• pp.48-52
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• 1988

Kinetics of the reaction of 2-phenethyl p-bromobenzenesulfonate with substituted pyridines in acetonitrile were investigated by an electric conductivity method at 1-2000 bars and $45{\sim}55{\circ}C$. The rates of these reactions were increased with raising temperatures, pressures and by changing electron-donating substitutents in pyridine. When raising pressure the Hammett reaction parameter $I{\rho}I$ and Bronsted ${\beta}$ values were increased, and isokinetic temperature observed from isokinetic relations hip between ${\Delta}H^{\neq}$ and TEX>${\Delta}S^{\neq}$ was decreased. These results indicate that the $S_N2$ characters were increased with raising pressure.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2009.11a
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• pp.107-110
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• 2009

A basic design for a Technical Development Model (TDM) of liquid oxygen lines from the turbopump exit to the oxidizer valves of the combustion chamber and the gas generator was conducted to develop a turbopump-fed liquid rocket engine. The TDM is composed of straight lines, elbows, bellows, a branch, an orifice, flanges and a heat insulator. Materials were determined by consideration of operation conditions, weight constraint and manufacturing procedures. The size and the location of each component were determined by flow analysis of the required flowrate and the pressure loss. Basic designs of the components were conducted by consideration of the operating temperature and the maximum expectation operating pressure. The safety factors were evaluated by structural analysis of design of each component.

• Proceedings of the Korean Geotechical Society Conference
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• 2008.03a
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• pp.754-761
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• 2008

In general, stress measurement of existent shotcrete lining be used by pressure cells. but, measuring instrument is lost by high pressure at shotcrete lining construction and pressure cell's measurement value have to low believability by natural conditions like curing temperature. In this study, proposed techniques to measure without utilizing sensitive stress sensor in natural condition at point that want stress of shotcrete lining after shotcrete lining construction. Executed numerical analysis to forecast stress level that interact in tunnel shotcrete lining, measured strain of hole by load action through hole in shotcrete lining. 3D FEM(finite element method) is enforced through various parameters curing time of shotcrete lining, thickness, load condition. Different model cases applied by parametic study. As analysis result, it could grasp development possibility of method that propose this time because it could examine corelation with strain by near hole of shotcrete lining and stress about load condition.

• Proceedings of the KSME Conference
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• 2001.11a
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• pp.87-92
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• 2001

In this paper, high strength pressure vessel steels having the same chemical compositions were manufactured by the two different steel-making processes, such as vacuum degassing(VD) and electro-slag remelting(ESR) methods. After the steel-making process, they were normalized at $955^{\circ}C$, quenched at $843^{\circ}C$, and finally tempered at $550^{\circ}C$ or $450^{\circ}C$, resulting in tempered martensitic microstructures with different yielding strengths depending on the tempering conditions. Low-cycle fatigue(LCF) tests, fatigue crack growth rate(FCGR) tests, and fracture toughness tests were performed to investigate the fatigue and fracture behaviors of the pressure vessel steels. In contrast to very similar monotonic, LCF, and FCGR behaviors between VD and ESR steels, a quite difference was noticed in the fracture toughness. Fracture toughness of ESR steel was higher than that of VD steel, being attributed to the removal of impurities in steel-making process.

• Proceedings of the KSME Conference
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• 2000.11b
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• pp.247-254
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• 2000

The base pressure of vacuum vessel of the KSTAR (Korea Superconducting Tokamak Advanced Research) Tokamak is to be a ultra high vacuum, $10^{-6}{\sim}10^{-7}Pa$, to produce clean plasma with low impurity containments. For this purpose, the KSTAR vacuum vessel and plasma facing components need to be baked up to at least $250^{\circ}C,\;350^{\circ}C$ respectively, within 24 hours by hot nitrogen gas from a separate baking/cooling line system to remove impurities from the plasma-material interaction surfaces before plasma operation. Here by applying the implicit numerical method to the heat balance equations of the system, overall temperature distributions of the KSTAR vacuum vessel and plasma facing components are obtained during the whole baking process. The model for 2-dimensional baking analysis are segmented into 9 imaginary sectors corresponding to each plasma facing component and has up-down symmetry. Under the resulting combined loads including dead weight, baking gas pressure, vacuum pressure and thermal loads, thermal stresses in the vacuum vessel during bakeout are calculated by using the ANSYS code. It is found that the vacuum vessel and its supports are structurally rigid based on the thermal stress analyses.

• Proceedings of the KSME Conference
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• 2003.04a
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• pp.1572-1577
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• 2003

High-power pulsed laser ablation under atmospheric pressure is studied utilizing numerical and experimental methods with emphasis on recondensation ratio, and the dynamics of the laser induced vapor flow. In the numerical calculation, the temperature pressure, density and vaporization flux on a solid substrate are first obtained by a heat-transfer computation code based on the enthalpy method, and then the plume dynamics is calculated by using a commercial CFD package. To confirm the computation results, the probe beam deflection technique was utilized for measuring the propagation of a laser induced shock wave. Discontinuities of properties and velocity over the Knudsen layer were investigated. Related with the analysis of the jump condition, the effect of the recondesation ratio on the plume dynamics was examined by comparing the pressure, density, and mass fraction of ablated aluminum vapor. To consider the effect of mass transfer between the ablation plume and air, unlike the most previous investigations, the equation of species conservation is simultaneously solved with the Euler equations. Therefore the numerical model computes not only the propagation of the shock front but also the distribution of the aluminum vapor. To our knowledge, this is the first work that employed a commercial CFD code in the calculation of pulsed ablation phenomena.

• Proceedings of the IEEK Conference
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• 2001.10a
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• pp.398-403
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• 2001

There is a potential usability of electric arc furnace(EAF) dust produced during the iron manufacturing process as a recycled resource, because valuable materials such as Zn, Pb and Fe are contained in it. In this study, metallic Zn was recycled from the fine electric arc furnace dust by a solid state reduction method using carbon at relatively low temperature. It was possible to recover metallic zinc by using of high vapour pressure of zinc with this reduction method. The feasibility of recycled zinc for cold bonded pellet(CBP) was investigated. The main composition of EAF dust were franklinite(ZnFe$_2$O$_4$), magnetite(Fe$_3$O$_4$) and zincite(ZnO), and Pb and Cl were completely removed by a heat treatment in oxidation environment. The reduction ratio increased as the solid carbon content increased, and it increased with decreasing of dust particle size and increasing of compaction pressure due to a increase of contact area.

• Journal of the Korean Society of Safety
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• v.32 no.2
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• pp.1-6
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• 2017

Modern society has been experiencing by population growth and urbanization that bring, a change of eating habits which has occurred a various types of waste in a large amount. Even though these wastes are required an immediate treatment with difficulties unsanitary handling and existing waste treatment method are by incineration, fermentation, drying and etc. however a bad smell occurs after the treatment that need's a lot of energy in processing organic wastes with high moisture contents and wasteful and inefficient problem. The strength assessment of the organic waste agitating vessel is required in terms of safety due to the differences of loading on the shaft that was treated by agitating the mixture of food waste. The damage of agitating axis is depended on steam pressure, temperature condition and the force moment that exerted by the food waste. Thus the strength assessment and stability evaluation are very important, especially to handle a hard waste. In this study the rotation capacity of agitation is about 5 tons considering general structural rolled steel pressure vessel strength and steam pressure. The purpose is to estimate the safety and strength evaluation for a agitator axis and impellers according to the rotating angle of the axis under the condition of the 3.2 ton capacity reactor.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.25 no.12
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• pp.1748-1755
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• 2001

The shell and tube heat exchangers were introduced to apply to a big capacity condenser and a high pressure feed water heater for power plant in the beginning of 1990s. Design and manufacturing technology fur shell and tube heat exchangers have been developed until now. But it is very difficult to calculate the expected performance characteristics of the shell and tube heat exchanger, because there are many design parameters to be considered according to internal structure and the shell side heat transfer mechanism complicately related to the design parameters. Design parameters to be considered in the design stage of shell and tube heat exchanger are shell and tube side fluids, flow rate, inlet and outlet temperature, physical properties, type of heat exchanger, outer diameter, thickness, length of tube, tube arrangement, tube pitch, permissive pressure loss on both sides, type of baffle plate, baffle cutting ratio. The propose of study is an analysis TEMA(Tubular Exchanger Manufacturers Association) E shell and tube heat exchanger performance with changing a number of baffles(3, 5, 7, 9, 11) and tubes(16, 20) and determined optimal baffle spacing.

• Transactions of the Korean Society of Pressure Vessels and Piping
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• v.11 no.1
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• pp.74-78
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• 2015

Nuclear power plant steam generator that is one of the main component has several thousands of thin tubes. And the steam generator tube is subject to damage because of the severe operation conditions such as the high temperature and pressure. Therefore periodic inspections are conducted to ensure the integrity of steam generator component. Hanul unit 3 also has been inspected in accordance with in-service inspection program and is scheduled to be replaced for exceeding the plugging rate which was recommended by manufacturer. During the steam generator replacement activity, we found several clustered porosity on inner surface of main feed water pipe. Additionally crack-like indications were found at weld interface between base material and weld of main feed water pipe. This paper describes the field experience and visual testing results for inner surface of main feed water pipes. The destructive test result had shown that these indications were porosities which were caused by manufacturing process not by operation service.