• Title/Summary/Keyword: high temperature high pressure

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Joining and Performance of Alkali Metal Thermal-to-electric Converter (AMTEC) (알칼리금속 열전기변환장치의 접합과 출력성능)

  • Suh, Min-Soo;Lee, Wook-Hyun;Woo, Sang-Kuk
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.41 no.7
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    • pp.665-671
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    • 2017
  • The alkali-Metal Thermal-to-electric Converter (AMTEC) is one of the promising static energy conversion technologies for the direct conversion of thermal energy to electrical energy. The advantages over a conventional energy converter are its high theoretical conversion efficiency of 40% and power density of 500 W/kg. The working principle of an AMTEC battery is the electrochemical reaction of the sodium through an ion conducting electrolyte. Sodium ion pass through the hot side of the beta"-alumina solid electrolyte (BASE) primarily as a result of the pressure difference. This pressure difference across the BASE has a significant effect on the overall performance of the AMTEC system. In order to build the high pressure difference across the BASE, hermeticity is required for each joined components for high temperature range of $900^{\circ}C$. The AMTEC battery was manufactured by utilizing robust joining technology of BASE/insulator/metal flange interfaces of the system for both structural and electrical stability. The electrical potential difference between the anode and cathode sides, where the electrons emitted from sodium ionization and recombined into sodium, was characterized as the open-circuit voltage. The efforts of technological improvement were concentrated on a high-power output and conversion efficiency. This paper discusses about the joining and performance of the AMTEC systems.

Quality characteristics of Hijikia fusiforme extracts with different extraction method (추출방법에 따른 톳 추출물의 품질특성)

  • Kwon, Yu-Ri;Youn, Kwang-Sup
    • Food Science and Preservation
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    • v.22 no.1
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    • pp.70-77
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    • 2015
  • The physiological properties of water extracts from Hizikia fusiformis extracted using different extraction methods (water extraction, WE; autoclave extraction, AE; high pressure extraction, HPE) were investigated. The freeze-dried powder yields from HPE, AE and WE were 29.33, 27.84 and 23.63%, respectively. The $L^*$ and $b^*$ color values were higher in WE, while the $a^*$ color values were higher in WE and AE. The total sugar content of AE (60.14%) was higher than those of WE (47.10%), HPE (40.97%). The reducing sugar content (7.88%) and protein content (42.83%) of AE was higher than those of WE, and HPE. The uronic acid (5.04%), total free amino acid (785.19 mg/g), taurine (19.16 mg/g), aspartic acid (66.63 mg/g), asparagine (204.84 mg/g), alanine (188.87 mg/g) and ammonium chloride (243.91 mg/g) contents, however, were the highest in HPE. Additionally, the crude polysaccharide yield was higher in HPE (4.75%) than in AE and WE, and the crude saccharide (fucose, galactose, glucose, xylose and fucose) yields were higher in AE. It can be concluded that optimum conditions for the efficient extraction of Hizikia fusiformis depending on components are high pressure and a lower temperature than in the typical process.

Investigation of Molding Characteristics in Injection Compression Molding According to Molding Conditions through Birefringence (사출압축성형에서 복굴절을 통한 성형조건에 따른 성형특성 고찰)

  • Lee, Dan Bi;Nam, Yun Hyo;Lyu, Min-Young
    • Polymer(Korea)
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    • v.38 no.2
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    • pp.193-198
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    • 2014
  • Lens and DVD require high quality of optical property. Conventional injection molded products contain high residual stress and this invokes birefringence since high cavity pressure and high temperature variation are involved in a molding process. Thus these products are often molded by injection compression molding in order to minimize the residual stress through reducing cavity pressure and uniform cavity pressure. In this study, molding parameters affecting molding quality such as property uniformity in injection compression molding were investigated through experiment. Molding quality deviations among the cavities in multi-cavity mold were also studied. Transparent resins, PC and PS were used in this study. Compression gap, compression speed, compression force, and compression delay time for processing variables in injection compression molding were applied in experiment. Compression force, compression delay time, and compression gap significantly affected the optical property of product. The degree of influence of process variable on the product quality was different in different resins. This implies that the optimal operational conditions in injection compression molding existed for each resin according to flow property.

On the effect of filters for the design of solid propellant gas generators (고체추진제 가스발생기 설계를 위한 필터 효과에 대한 고찰)

  • Hong, Moon-Geun;Lee, Soo-Yong
    • Proceedings of the KSME Conference
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    • 2007.05b
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    • pp.2524-2527
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    • 2007
  • Solid propellant gas generators (SPGG) play a role as a turbopump starter in liquid propellant propulsion systems by supplying pressurized gas to power turbines for engine start. For such a purpose, the propellants should burn with a relative low flame temperature and the combustion gas should not contain corrosive constituents such as chlorine compounds. In accordance with these requirements, stabilized AN-based propellants have been usually used as the most appropriate oxidizer for propellant compositions. However, the burning area of the propellant intends to increase to satisfy the required mass flux because of its low burning rate. Consequently the burning area incensement brings on the SPGG size augmentation. A flow restriction such as filters is applied to decrease the SPGG size by rising up the combustion pressure resulting in increasing the burning rate. The feasibility of the size reduction of SPGG by the employment of filters have been studied. The preliminary results of this study show that the considerable reduction of SPGG size would be achievable just by installing a filter with relatively high pressure loss coefficient.

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Kinetic Study on the Reaction of para-substitued Benzylbromide with Isoquinoline under High Pressure (고압하에서의 이소퀴놀린과 브롬화 벤질류의 반응에 관한 속도론적인 연구)

  • Kim, Young Cheul;Lim, Jong Wan;Choi, Sung Yong
    • Journal of the Korean Chemical Society
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    • v.42 no.2
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    • pp.150-155
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    • 1998
  • Kinetic studies on the reaction of isoquinoline with para-substituted benzylbromides were conducted under various pressures (1 ~1000 bar) in acetonitrile. From the rate constants obtained, the activation parameters such as$\DeltaV^{\neq}, \Delta\beta^{\neq}, \DeltaH^{\neq}, \DeltaS^{\neq}, \DeltaG^{\neq}$ and Ea were evaluated. Reaction rate increasing the pressure and temperature. The activation compressibility coefficient and the activation entropy showed negative values. From the substituent effect and the results, it was found that the reaction proceeds through $S_N2$ mechanism, but the structure of transition state was slightly changed with substituents and pressure.

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Studies on Ionic Conduction in Ce0.95Eu0.05P2O7 at Intermediate Temperatures

  • Wang, Hongtao;Sun, Lin;Luo, Chunhua;Fan, Suhua
    • Bulletin of the Korean Chemical Society
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    • v.35 no.5
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    • pp.1465-1468
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    • 2014
  • In this study, an intermediate temperature ionic conductor, $Ce_{0.95}Eu_{0.05}P_2O_7$, was prepared by solid state reaction. The variation of conductivities with the pressure $pH_2O$ or time were studied. The highest conductivity of $Ce_{0.95}Eu_{0.05}P_2O_7$ sample was observed in dry air atmosphere at $300^{\circ}C$ to be $1.1{\times}10^{-4}S{\cdot}cm^{-1}$ and in wet air atmosphere ($pH_2O=7.4{\times}10^3Pa$) at $100^{\circ}C$ to be $1.4{\times}10^{-3}S{\cdot}cm^{-1}$, respectively. The log ${\sigma}$ ~ log ($pO_2$) plot result indicated that $Ce_{0.95}Eu_{0.05}P_2O_7$ was almost a pure ionic conductor under high oxygen partial pressure and a mixed conductor of ion and electron under low oxygen partial pressure.

A Study on the Structural Characteristics of Miniature Metal Bellows in Joule-Thomson Micro-Cryocooler (줄-톰슨 마이크로 냉각기용 소형 금속 벨로우즈의 구조적 특성에 관한 연구)

  • Lee, Seung-Ha;Lee, Tae-Won
    • Journal of the Korean Society for Precision Engineering
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    • v.25 no.9
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    • pp.95-102
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    • 2008
  • A miniature metal bellows is used to minimize the excessive flow of the cryogenic gas in Joule-Thomson micro cryocooler. It is made of metal alloy and its geometry is axisymmetric. The bellows is filled with high pressure gas. It contracts or expands in the axial direction for a wide change of temperature, because the pressure and volume inside the bellows must be satisfied with state equation of the gas. Therefore, in order to design the bellows in Joule-Thomson micro-cryocooler, it is important to evaluate deformation of the bellows under internal pressure exactly. Considering geometric nonlinearity, deformations analysis of the bellows were obtained by a commercial finite element code ANSYS, The bellows was modeled by 3-node axisymmetric shell elements with reduced integration. Experiments were also performed to prove the validity of proposed numerical analysis. The results by numerical analysis and experiments were shown in good agreements.

Structural Design for Key Dimensions of Printed Circuit Heat Exchanger (인쇄기판형열교환기 핵심치수 구조설계)

  • Kim, Yong Wan;Kang, Ji Ho;Sah, In Jin;Kim, Eung Seon
    • Transactions of the Korean Society of Pressure Vessels and Piping
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    • v.14 no.1
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    • pp.24-31
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    • 2018
  • The mechanical design procedure is studied for the PCHE(printed circuit heat exchanger) with electrochemical etched flow channels. The effective heat transfer plates of PCHE are assembled by diffusion bonding to make a module. PCHE is widely used for industrial applications due to its compactness, cost efficiency, and serviceability at high pressure and/or temperature conditions. The limitations and technical barriers of PCHE are investigated for application to nuclear components. Rules for design and fabrication of PCHE are specified in ASME Section VIII but not in ASME Section III of nuclear components. Therefore, the calculation procedure of key dimensions of PCHE is defined based on ASME section VIII. The effective heat transfer region of PCHE is defined by several key dimensions such as the flow channel radius, edge width, wall thickness, and ridge width. The mechanical design procedure of key dimensions was incorporated into a program for easy use in the PCHE design. The effect of assumptions used in the key dimension calculation on stress values is numerically investigated. A comparative analysis is done by comparing finite element analysis results for the semi-circular flow channels with the formula based sizing calculation assuming rectangular cross sections.

CLSM [Confocal Laser Scanning Microscope] Observation of the Surface Roughness of Pressurized Rock Samples During Freeze/Thaw Cycling

  • Kim, Hye-jin;Choi, Junghae;Chae, Byung-gon;Kim, Gyo-won
    • The Journal of Engineering Geology
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    • v.25 no.2
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    • pp.165-178
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    • 2015
  • Physical and chemical weathering degrades rock, affecting its structural properties and thus the stability of stone buildings or other structures. Confocal laser scan microscopy (CLSM) is used here to observe temporal changes in the surface roughness of rock samples under simulated accelerated weathering. Samples were pressurized to 50, 55, or 70 MPa using a pressure frame, and subjected to freeze/thaw cycling controlled by a thermostat. The temperature was cycled from -20℃ to 40℃ and back. After each 20 cycles, CLSM was used to assess the change in surface roughness, and roughness factors were calculated to quantify the progression of the surface condition over time. Variations in cross-section line-roughness parameters and surface-roughness parameters were analyzed for specific parts of the sample surfaces at 5× and 50× magnification. The result reveals that the highest and lowest values of the roughness factors are changed according to elapsed time. Freezing/thawing at high pressure caused larger changes in the roughness factor than at low pressure.

Preparation and Characteristics of Catalyst Coated Cordierite Filter (촉매 처리된 코디어라이트 필터의 제조 및 그 특성)

  • Kim, Yeong-Bae;Jo, Eul-Hun;Jang, Yun-Yeong;Sin, Min-Cheol;Lee, Hui-Su;Choe, Deok-Gyun
    • Korean Journal of Materials Research
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    • v.12 no.2
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    • pp.129-134
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    • 2002
  • The optimum condition for fabricating cordierite disc type filter element was deduced. Cordierite monolith was used as starting material for filter element because it has many advantages such as high thermal shock resistance and good catalytic activity compared with $TiO_2$and SiC. The contents of organic additives and foaming agent were optimized to control the porosity and mechanical strength of cordierite filter. Among the required properties to be adopted as filter elements, the pressure drop and NOx removal efficiency were investigated depending on processing variables. It was found that pressure drop depends on particle size distribution of cordierite monolith and organic additives added as forming agent. The pressure drop at 5cm/sec of face velocity was in the range of 15~655mm$H_2O$ at room temperature. The NOx removal efficiency of catalytic filter with $V_2O_5$ as catalyst was over 85% at $450^{\circ}C$.