• Title/Summary/Keyword: high temperature high pressure

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Influence of MBE Growth Temperature on the Sulfur Compositional Variation Of ZnSSe Epitaxial Layers on GaAs Substrates

  • Kim, Dong-Lyeul;Bae, In-Ho;Son, Jeong-Sik;Kim, In-Su;Lee, Jae-Young m;Akira Yoshida
    • Transactions on Electrical and Electronic Materials
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    • v.1 no.3
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    • pp.18-22
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    • 2000
  • In this work, we reported the sulfur compositional variation of ZnS$\_$x/Se$\_$1-x/ epitaxial layers with growth temperature and BEP ration of ZnX/Se/)P$\_$ZnS//P$\_$Se/) grown on GaAs substrates by molecular beam epitaxy. The sulfur composition of ZnSSe epitaxial layers was varied sensitively on the growth temperature and show different linear relationship with growth temperature and BEP ration of ZnS/Se(P$\_$ZnS//P$\_$Se/), which revealed -0.107 %$\^{C}$ at (P$\_$ZnS//P$\_$Se/)=0.30 and -0.052 %$\^{C}$ at (P$\_$ZnS//P$\_$Se/)=0.158 rspectively. A reference data for the accurate control of the sulfur composition and the growth of high quality ZnSSe/GaAs epitaxial layers was provided.

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Quadrant Analysis in Correlation between Mechanical and Electrical Properties of Low-Temperature Conductive Film Bonded Crystalline Silicon Solar Cells

  • Baek, Su-Wung;Choi, Kwang-Il;Lee, Woo-Hyoung;Lee, Suk-Ho;Cheon, Chan-Hyuk;Hong, Seung-Min;Lee, Kil-Song;Shin, Hyun-Woo;Yan, Yeon-Won;Lim, Cheolhyun
    • Current Photovoltaic Research
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    • v.3 no.1
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    • pp.1-4
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    • 2015
  • In this study, we analyzed the correlation between mechanical and electrical properties of low-temperature conductive film (LT-CF) bonded silicon solar cells by a quadrant analysis (horizontal axis (peeling strength), vertical axis (power loss)). We found that a series of points with various bonding parameters such as bonding temperature, pressure and time were distributed in the different three regimes; weak regime (Q2: weak bonding strength and high power loss), moderate regime (Q4 : strong bonding strength and low power loss) and hard regime (Q3 : weak bonding strength and low power loss). Using this analogous technique, it was possible to fabricate the LT-CF bonded silicon solar cells with the various conditions displayed in Q3 of the quadrant plots, possessing the peeling strength of ~ 1N/mm and power loss of 2~3%.

Microstructure and Tensile Properties of $SiC_p$-reinforced Aluminum Alloy Composites Fabricated by Die Casting Method (다이캐스팅법에 의해 제조된 SiC 입자강화 알루미늄합금기 복합재료의 미세조직 및 인장특성)

  • Lee, Tae-Won;Lee, Chi-Hwan
    • Journal of Korea Foundry Society
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    • v.17 no.4
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    • pp.385-392
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    • 1997
  • The main objective of this study is to investigate the microstructure and tensile strength of $SiC_p$/Al alloy composites fabricated by die casting method. Die casting was performed using the preheated mold at the pouring temperature range of $620{\sim}750^{\circ}C$ under the pressure of $1,039 kgf/cm^2$. The low speed and a following high injection speed were 0.4 and 2.1 m/s, respectively. The microstructure of $SiC_p$/Al alloy composites fabricated by die casting method was found to be finer than that of composites fabricated by gravity casting. Also, SiC particulates were homogeneously distributed in refined Al matrix due to rapid solidification. The tensile strength of $SiC_p$/Al alloy composites fabricated by die casting method was found to be varied with cast temperature. The maximun tensile strength of $SiC_p$(10 vol.% and 20 vol.%)/Al alloy composites showed 380 MPa at the cast temperature of $750^{\circ}C$ and 363 MPa at the cast temperature of $700^{\circ}C$, respectively.

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Copolymerization of L-Lactide and ${\varepsilon}$-Caprolactone in Supercritical Fluid

  • Prabowo, Benedictus;Choi, Dong-Hoon;Kim, Soo-Hyun
    • Macromolecular Research
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    • v.17 no.8
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    • pp.575-579
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    • 2009
  • Copolymerization of L-lactide and s-caprolactone initiated by tin (II) octoate (Sn(Oct)$_2$) was carried out in supercritical chlorodifluoromethane (R22) with varying reaction conditions (time and temperature) and amounts of monomer and catalyst, under a pressure of 250 bar. The optimum conditions were a reaction time of 10 h and a temperature of 130 $^{\circ}C$, which is similar to the temperature used in bulk copolymerization system. The conversion increased from 56% to 76% by increasing the reaction time from 1 to 10 h. The molecular weight also increased to 75,900 g.mol$^{-1}$ over the same period, while the increased monomer concentration resulted in a high molecular weight of 86,400 g.mol$^{-1}$ and a monomer conversion of 84%. Raising the reaction temperature from 90 to 130 $^{\circ}C$ increased the monomer conversion as well as the poly-L-lactide-co-${\varepsilon}$-caprolactone (PLCL) molecular weight. The variation on the stannous octoate catalyst suggested that less catalyst would decrease the caprolactone content of the polymer.

Effect of Injection Temperature Condition on Root Mean Square and Peak-to-Valley of F-theta Lens (사출온도조건이 에프세타 렌즈의 표면조도와 표면형상에 미치는 영향에 관한 연구)

  • Park, Yong-Woo;Moon, Seong-Min;Lyu, Sung-Ki
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.20 no.6
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    • pp.114-120
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    • 2021
  • This study is focused on the root mean square and peak-to-valley based on the injection conditions of the f-theta lens, one of the main components of laser printers and laser scanning systems. The f-theta lens of an aspherical plastic lens requires ultra-preaction. Injection molding is typically used for the mass production of aspherical plastic lenses. In the injection-molding method, the resin in the lens shape is filled with the resin after melting the plastic pellets at a constant temperature and then cooled. It is necessary to maintain a uniform injection molding system to produce high-quality lenses. These injection-molding systems are influenced by different factors, such as pressure, speed, temperature, mold, and cooling. It is possible to obtain a lens that exhibits the optical characteristics required to achieve harmony. We investigated the root mean square and peak-to-valley caused by variations in temperature, a critical parameter in the melting and cooling of plastic resins generated inside and outside the injection mold.

Evolution of dynamic mechanical properties of heated granite subjected to rapid cooling

  • Yin, Tubing;Zhang, Shuaishuai;Li, Xibing;Bai, Lv
    • Geomechanics and Engineering
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    • v.16 no.5
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    • pp.483-493
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    • 2018
  • Experimental study of the deterioration of high-temperature rock subjected to rapid cooling is essential for thermal engineering applications. To evaluate the influence of thermal shock on heated granite with different temperatures, laboratory tests were conducted to record the changes in the physical properties of granite specimens and the dynamic mechanical characteristics of granite after rapid cooling were experimentally investigated by using a split Hopkinson pressure bar (SHPB). The results indicate that there are threshold temperatures ($500-600^{\circ}C$) for variations in density, porosity, and P-wave velocity of granite with increasing treatment temperature. The stress-strain curves of $500-1000^{\circ}C$ show the brittle-plastic transition of tested granite specimens. It was also found that in the temperature range of $200-400^{\circ}C$, the through-cracks induced by rapid cooling have a decisive influence on the failure pattern of rock specimens under dynamic load. Moreover, the increase of crack density due to higher treatment temperature will result in the dilution of thermal shock effect for the rocks at temperatures above $500^{\circ}C$. Eventually, a fitting formula was established to relate the dynamic peak strength of pretreated granite to the crack density, which is the exponential function.

Decadal Changes in the Relationship between Arctic Oscillation and Surface Air Temperature over Korea (북극진동과 한반도 지표기온 관계의 장기변동성)

  • Jun, Ye-Jun;Song, Kanghyun;Son, Seok-Woo
    • Atmosphere
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    • v.31 no.1
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    • pp.61-71
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    • 2021
  • The relationship between the Arctic Oscillation (AO) and surface air temperature (SAT) over Korea is re-examined using the long-term observation and reanalysis datasets for the period of December 1958 to February 2020. Over the entire period, Korean SAT is positively correlated with the AO index with a statistically significant correlation coefficient, greater than 0.4, only in the boreal winter. It is found that this correlation is not static but changes on the decadal time scale. While the 15-year moving correlations are as high as 0.6 in 1980s and 1990s, they are smaller than 0.3 in the other decades. It is revealed that this decadal variation is partly due to the AO structure change over the North Pacific. In the period of 1980s-1990s, the AO-related sea level pressure fluctuation is strong and well defined over the western North Pacific and the related temperature advection effectively changes the winter SAT over Korea. In the other periods, the AO-related circulation anomaly is either weak or mostly confined within the central North Pacific. This result suggests that Korean SAT-AO index relationship, which becomes insignificant in recent decades is highly dependent on mean flow change in the North Pacific.

Effect of Pressure and Stoichiometric Air Ratio on NOx Emissions in Gas-Turbine Dump Combustor with Double Cone Burner (이중원추형 모형연소기에서 압력과 공기비에 따른 NOx 배출특성)

  • Nam, Dong-Hyun;Nam, Hyun-Su;Han, Dong-Sik;Kim, Gyu-Bo;Cho, Seung-Wan;Kim, Han-Suk;Jeon, Chung-Hwan
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.36 no.3
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    • pp.251-257
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    • 2012
  • This work presents an experimental investigation of NOx emissions according to inlet air temperature (550-660 K), stoichiometric air ratio (${\lambda}$, 1.4-2.1), and elevated pressure (2-5 bar) in a High Press Combustor (HPC) equipped with a double cone burner, which was designed by Pusan Clean Coal Center (PC3). The exhaust-gas temperature and NOx emissions were measured at the end of the combustion chamber. The NOx emissions generally decreased as a function of increasing ${\lambda}$. On the other hand, NOx emissions were influenced by ${\lambda}$, inlet air temperature and pressure of the combustion chamber. In particular, when the inlet air temperature increased, the flammability limit was extended to leaner conditions. As a result, a higher adiabatic temperature and lower NOx emissions could be achieved under these operation conditions. The NOx emissions that were governed by thermal NOx were greatly increased under elevated pressures, and slightly increased at sufficiently low fuel concentrations (${\lambda}$ >1.8).

A Study on the Measurement of Explosion Range by CO2 Addition for the Process Safety Operation of Propylene (프로필렌의 공정안전 운전을 위한 CO2 첨가량에 따른 폭발범위 측정에 관한 연구)

  • Choi, Yu-Jung;Heo, Jong-Man;Kim, Jung-Hun;Choi, Jae-Wook
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.20 no.7
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    • pp.599-606
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    • 2019
  • Most facilities that manufacture products made from the hazardous materials operate at high temperatures and pressures. Therefore, there is a risk of fire explosion. In particular, an explosion accident is a major risk factor for facilities with hazardous materials, such as oil, chemical, and gas. Propylene is often used in sites producing basic raw materials and synthetic materials by addition polymerization at petrochemical plants. To prevent an explosion in the business using propylene, the explosion range with the oxygen concentration was calculated according to the changes in temperature and pressure using an inert gas, carbon dioxide. In these measurements, the temperature was $25^{\circ}C$, $100^{\circ}C$, and $200^{\circ}C$ and the amount of carbon dioxide in the container was $1.0kgf/cm^2.G$, $1.5kgf/cm^2.G$, $2.0kgf/cm^2.G$, and $2.5kgf/cm^2.G$. The explosion limit was related to temperature, pressure, and oxygen concentration. The minimum oxygen concentration for an explosion decreased with increasing temperature and pressure. The range of explosion narrowed with decreasing oxygen concentration. In addition, no explosion occurred at concentrations below the minimum oxygen concentration, even with steam and an ignition source of propylene.

Heat transfer analysis in sub-channels of rod bundle geometry with supercritical water

  • Shitsi, Edward;Debrah, Seth Kofi;Chabi, Silas;Arthur, Emmanuel Maurice;Baidoo, Isaac Kwasi
    • Nuclear Engineering and Technology
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    • v.54 no.3
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    • pp.842-848
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    • 2022
  • Parametric studies of heat transfer and fluid flow are very important research of interest because the design and operation of fluid flow and heat transfer systems are guided by these parametric studies. The safety of the system operation and system optimization can be determined by decreasing or increasing particular fluid flow and heat transfer parameter while keeping other parameters constant. The parameters that can be varied in order to determine safe and optimized system include system pressure, mass flow rate, heat flux and coolant inlet temperature among other parameters. The fluid flow and heat transfer systems can also be enhanced by the presence of or without the presence of particular effects including gravity effect among others. The advanced Generation IV reactors to be deployed for large electricity production, have proven to be more thermally efficient (approximately 45% thermal efficiency) than the current light water reactors with a thermal efficiency of approximately 33 ℃. SCWR is one of the Generation IV reactors intended for electricity generation. High Performance Light Water Reactor (HPLWR) is a SCWR type which is under consideration in this study. One-eighth of a proposed fuel assembly design for HPLWR consisting of 7 fuel/rod bundles with 9 coolant sub-channels was the geometry considered in this study to examine the effects of system pressure and mass flow rate on wall and fluid temperatures. Gravity effect on wall and fluid temperatures were also examined on this one-eighth fuel assembly geometry. Computational Fluid Dynamics (CFD) code, STAR-CCM+, was used to obtain the results of the numerical simulations. Based on the parametric analysis carried out, sub-channel 4 performed better in terms of heat transfer because temperatures predicted in sub-channel 9 (corner subchannel) were higher than the ones obtained in sub-channel 4 (central sub-channel). The influence of system mass flow rate, pressure and gravity seem similar in both sub-channels 4 and 9 with temperature distributions higher in sub-channel 9 than in sub-channel 4. In most of the cases considered, temperature distributions (for both fluid and wall) obtained at 25 MPa are higher than those obtained at 23 MPa, temperature distributions obtained at 601.2 kg/h are higher than those obtained at 561.2 kg/h, and temperature distributions obtained without gravity effect are higher than those obtained with gravity effect. The results show that effects of system pressure, mass flowrate and gravity on fluid flow and heat transfer are significant and therefore parametric studies need to be performed to determine safe and optimum operating conditions of fluid flow and heat transfer systems.