• Clean Technology
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• v.29 no.2
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• pp.126-134
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• 2023

Direct catalytic decomposition is a promising method for controlling the emission of nitrous oxide (N₂O) from the semiconductor and display industries. In this study, a γ-Al₂O₃ catalyst was developed to reduce N₂O emissions by a catalytic decomposition reaction. The γ-Al₂O₃ catalyst was prepared by an extrusion method using boehmite powder, and a N₂O decomposition test was performed using a catalyst reactor that was approximately 25.4 mm (1 in) in diameter packed with approximately 5 mm of catalysts. The N₂O decomposition tests were carried out with approximately 1% N₂O at 550 to 750 ℃, an ambient pressure, and a GHSV=1800-2000 h^-1. To confirm the N₂O decomposition properties and the effect of O₂ and steam on the N₂O decomposition, nitrogen, air, and air and steam were used as atmospheric gases. The catalytic decomposition tests showed that the 1% N₂O had almost completely disappeared at 700 ℃ in an N₂ atmosphere. However, air and steam decreased the conversion rate drastically. The long term stability test carried out under an N₂ atmosphere at 700 ℃ for 350 h showed that the N₂O conversion rate remained very stable, confirming no catalytic activity changes. From the results of the N₂O decomposition tests and long-term stability test, it is expected that the prepared γ-Al₂O₃ catalyst can be used to reduce N₂O emissions from several industries including the semiconductor, display, and nitric acid manufacturing industry.

• KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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• v.18 no.1_2
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• pp.1-8
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• 2012

Kimchi, a Korean fermented vegetable is packaged without pasteurization and distributed with live bacteria actively working to produce lactic acid and carbon dioxide gas in the product. The $CO_2$ production consisting of two distinct phases of initial fast and later slow rates depends on kimchi type, salt content and storage temperature. The $CO_2$ produced from kimchi is accumulated in the product package causing volume expansion and pressure buildup. The dependence of $CO_2$ production rate on salt content and storage temperature has been published formerly and can be used for estimating the package volume and pressure under a variety of storage conditions. As methods to alleviate the problems from the produced $CO_2$, package designs with controlled diffusion pinhole, high $CO_2$ permeable film or $CO_2$ absorber have been tried by several researchers. Properly designed packages adopting the device or tool were shown to have high dissolved $CO_2$ in kimchi without volume expansion and pressure buildup, giving good sensory quality with carbonic taste. Advantages and limitations of each method have been discussed.

• Analytical Science and Technology
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• v.27 no.2
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• pp.79-91
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• 2014

Solubility data of carbon dioxide ($CO_2$) in 1-butyl-3-methylpiperidinium bis(trifluoromethylsulfonyl)imide ($[bmpip][Tf_2N]$) ionic liquid are presented at pressures up to about 30 MPa and at temperatures between 303 K and 343 K. As far as we know, the data on the $CO_2$ solubility in the $[bmpip][Tf_2N]$ ionic liquid have never been reported in the literature by other investigators. The solubilities of $CO_2$ were determined by measuring the bubble point or cloud point pressures of the $CO_2+[bmpip][Tf_2N]$ mixtures with various compositions using a high-pressure equilibrium apparatus equipped with a variable-volume view cell. To observe the effect of the cation composing the ionic liquid on the $CO_2$ solubility, the $CO_2$ solubilities in $[bmpip][Tf_2N]$ used in this study were compared with those in 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)-imide ($[bmim]Tf_2N]$). As the equilibrium pressure increased, the $CO_2$ solubility in $[bmpip][Tf_2N]$ increased sharply. On the other hand, the $CO_2$ solubility decreased with increasing temperature. The mole fraction-based $CO_2$ solubilities were almost the same for both $[bmpip][Tf_2N]$ and $[bmim][Tf_2N]$, regardless of temperature and pressure. The phase equilibrium data for the $CO_2+[bmpip][Tf_2N]$ systems have been correlated using the Peng-Robinson equation of state.

• Korean Journal of Materials Research
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• v.9 no.8
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• pp.817-824
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• 1999

The $Al_2$$O_3$-SiC composite powder was prepared by Self-propagating High-Temperature Synthesis(SHS) process using $SiO_2$Al and C powders as raw material. The effects of the molar ratio in raw material, compaction pressure, initial temperature of reactants on the products and combustion process were studied. Self-propagating high temperature synthesis of $SiO_2$/Al/C system should be preheated above $400^{\circ}C$ owing to the low combustion temperature. As the result of the combustion reaction, the purity of final product became better than that of reactants. In this system, the optimum molar ratio of $SiO_2$:Al:C was 3.0:4.0:6.0. The free carbon was removed by roasting at $650^{\circ}C$ for 30min. In this study, pressureless sintering was very dffective both for controlling the disintegration of specimen with powder bed and for obtaining dense sintered-body at $1700^{\circ}C$. The sintered-body produced with hot-pressing was about 98% of the theoretical relative density.

• Korean Chemical Engineering Research
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• v.58 no.4
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• pp.581-587
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• 2020

In this study, a new reaction system is proposed to solve the problems of the existing 2,3-Butanediol (2,3-BDO) dehydration reaction system. It was confirmed that the reaction system did not wok as it should operate properly when using a furnace, which is commonly used in commercial processes, to raise the reactant, 2,3-BDO, to the reaction temperature, 360 ℃, at near atmoshperic pressure. It is because of the substance considered to be oligomers of 2,3-BDO. It can lead to safety problems, such as blockages inside the furnace's tube and explosions, as well as tricky maintenance issues in the reaction system. To solve it, the temperature of reactant can be brought down by using a heat exchanger with High Pressure (HP) steam instead of the furnace, which has a hot spot problem through the vacuum operation and reduce the reaction temperature. It can be seen that the reactor performance is almost similar under the vacuum operation and the lower reaction temperature, 330 ℃, by using a reaction kinetics. This result explains why the new reaction system is proposed.

• Fire Science and Engineering
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• v.13 no.2
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• pp.26-32
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• 1999

We had investigated combustion pro야$\pi$ies of rice bran dusts. Decomposition of rice bran d dusts with temperature were investigated using DSC and the weight loss according to t temperature using TGA in order to find the thermal hazard of rice bran dusts, and the p properties of dust explosion in variation of their dust with the same particle size. Using H Hartman's dust explosion apparatus which estimate dust explosion by electric ignition after m making dust disperse by compressed air, dust explosion experiments have been conducted by v varying concen$\sigma$ation and size of rice br뻐 dust. According to the results for thermodynamic stability of rice bran dust, there are little change of initiation temperature of heat generation 때d heating value for used particle size. But i initiation temperature of heat generation decreased with high heating rate whereas d decomposition heat increased with particle size. Also, the explosion pressure was increased as t the ignition energy increased and average maximum explosion pressure was 13.5 kgv'cnt for 5 BJ/60 mesh and 1.5 뼈Ie미 dust concentration.

• Economic and Environmental Geology
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• v.25 no.3
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• pp.283-296
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• 1992

The Keumryeong deposits is a low grade copper deposits in which copper minerals form disseminated grains and thin veinlets in felsic volcanics seem to be dacite. Alteration of the volcanics consists mainly pervasive propylitization and silicification. Potassic alteration characterized by biotite developed locally adjacent to southwestern contact of granodiorite body. Principal sulfide minerals in altered zone are mainly pyrite and lesser chalcopyrite. Chalcopyrite content in potassic zone is relatively higher than that of surrounding propylitized zone. Pyrite and chalcopyrite accompanies magnetite, molybdenite, sphalerite, pyrrhotite, arsenopyrite, pentlandite, marcasite, hematite, ilmenite, rutile, bismuthinite and native Bi as disseminations, veinlets and knots. Granodiorite body is propylitized and contains veinlets of pyrite, chalcopyrite and molybdenite. Fluid inclusions in sulfide-bearing quartz veinlets and quartz grains of felsic volcanics and granodiorite in altered zone consist of liquid-rich, vapor-rich, $CO_2-bearing$ and halite-bearing inclusions. These four types of inclusion intimately associated on a microscopic scale and indicate condensing or boiling of ore fluid during mineralization. Homogenization temperature of coexisting fluid inclusions are mostly in the range of 350 to $450^{\circ}C$. High salinity fluid contains 28.6 to 48.4 weight percent NaCI equivalent and moderate salinity fluid cotains 0.5 to 12.5 weight percent NaCl equivalent. Pressure estimated from $CO_2$ mole fraction of $CO_2-bearing$ inclusion range 160 to 375 bars. The Kigu copper deposits is a fissure filling copper vein developed 500 m south from the Keumryong deposits. Mineralogy and fluid inclusion data of the Kigu deposits are similar to that of the Keumryeong deposits. Homogenization temperature of fluid inclusions from the Kigu deposits are reasonable agreement with temperature estimated from sulfidation curve of cubanite-chalcopyrite-pyrite-pyrrhotite and pyrite-pyrrhotite mineral assemblages. Not only mineral occurrence and wall rock alteration in the Keumryeong deposits but also fluid inclusion data such as temperature, salinity, pressure and boiling evidences are similar to those of porphyry copper deposits.

• Progress in Superconductivity and Cryogenics
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• v.16 no.4
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• pp.66-70
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• 2014

The superconducting fault current limiter (SFCL) is an electrical power system device that detects the fault current automatically and limits the magnitude of the current below a certain safety level. The SFCL module does not have any electrical resistance below the critical temperature, which facilitates lossless power transmission in the electric power system. Once given the fault current, however, the superconducting conductor exhibits extremely high electrical resistance, and the magnitude of the current is accordingly limited to a low value. Therefore, SFCL should be maintained at a temperature below the critical temperature, which justifies the cryogenic cooling system as a mandatory component. This report is a study which reported on the cooling system for the 154 kV-class hybrid SFCL owned by Korea Electric Power Corporation (KEPCO). Using the cryocooler, the temperature of liquid nitrogen (LN2) was lowered to 71 K. The cryostat was pressurized to 5 bars to improve the dielectric strength of nitrogen and suppress nitrogen bubble foaming during operation of SFCL. The SFCL module was immersed in the liquid nitrogen of the cryostat to maintain the superconducting state. The performance test results of the key components such as cryocooler, LN2 circulation pump, cold box, and pressure builder are shown in this paper.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2004.03a
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• pp.713-721
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• 2004

Variable air intake and variable exhaust nozzle of hypersonic engines are designed and tested in this study. Dimensions for variable geometry air intake, ram combustor and variable geometry exhaust nozzle are defined based on the requirements of a pre-cooled turbojet engine. Hypersonic Ramjet Engine is designed as a scaled test bed for each component. Actuation forces of moving parts for variable intake and variable nozzle are reduced by balancing the other force in the opposite direction. A demonstrator engine which includes variable intake and variable nozzle is designed and the components are fabricated. Composite material with silicone carbide is applied for high temperature parts under oxidation environment such as leading edge of the variable intake and combustor liner. Internal cooling structure is adopted for both moving and static parts of the variable nozzle. Pressure recovery and mass capture ratio of the variable intake at Mach 5 is obtained by a hypersonic wind tunnel test. Flow characteristics of the variable nozzle are obtained by a low temperature flow test. Wall temperature and heat flux of the nozzle at Mach 3 is obtained by a firing test. As results, the intake and the nozzle are proved to be used at designed pressure and temperature environment.

• Journal of Sensor Science and Technology
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• v.6 no.5
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• pp.414-422
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• 1997

CdS thin films with low resistivity and adequate transmittance in the visible region for the window of CdS/CdTe hetero junction solar cel1 were prepared by close spaced vapor transport(CSVT) method. The electrical and optical properties of the CdS thin films were investigated in terms of the deposition conditions, such as the substrate temperature, the working pressure, and the source temperature. The substrate temperature, the working pressure, and the source temperature for the optimum deposition of the CdS thin films were $300^{\circ}C$, 100mTorr, and $730^{\circ}C$, respectively. The resistivity and the transmittance of the CdS thin films deposited under this condition were about $7.21{\times}10^{3}{\Omega}cm$ and over 65%, respectively. The crystallinity, the resistivity, and optical band gap were improved greatly compared to the CdS thin films deposited by general high vacuum evaporation.