• Title/Summary/Keyword: high temperature high pressure

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Deposition of Yttria Stabilized Zirconia by the Thermal CVD Process

  • In Deok Jeon;Latifa Gueroudji;Nong M. Hwang
    • The Korean Journal of Ceramics
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    • v.5 no.2
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    • pp.131-136
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    • 1999
  • Yttria stabilized zirconia(YSZ) films were deposited on porous NiO substrates and quartz plates by the thermal CVD using $ZrCl_4, YCl_3$ as precursors, and $O_2$ as a reactive gas at atmospheric pressure. The evaporation temperature of $ZrCl_4$ was varied from $250^{\circ}C$ to $550^{\circ}C$ while the temperatures of $YCl_3$ and the substrate were varied from $1000^{\circ}C$ to $1030^{\circ}C$. As the evaporation temperature of $ZrCl_4$ increased, the deposition rate of $ZrO_2$ decreased, contrary to our expectation. As a result of the decreased deposition rate of $ZrO_2$, the yttria content increase. The high evaporation temperature of $ZrCl_4$ makes the well-faceted crystal while the low evaporation temperature leads to the cauliflower-shaped structure. The dependence of the evaporation temperature on the growth rate and the morphological evolution was interpreted by the charged cluster model.

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Dynamic Characteristics of Thermal Stratification Build-up by Unsteady Natural Convection (비정상 자연대류에 의한 온도성층화의 동특성에 관한 연구)

  • Kang, B.S.;Lee, J.S.;Lee, T.S.;Ro, S.T.
    • The Magazine of the Society of Air-Conditioning and Refrigerating Engineers of Korea
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    • v.17 no.4
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    • pp.382-394
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    • 1988
  • Dynamic characteristics of thermally-forced stratification process in a square enclosure with a linear temperature profile at the side walls have been investigated through flow visualization experiment and numerical analysis. The experiment was performed on air with the Rayleigh numbers of order $10^5$. A particle tracer method is used for the flow visualization and to obtain a sudden linear temperature profile at the side walls copper blocks which already have a linear temperature profile are come into contact with the thin copper plates of the test section. Immediately a meridional circulation is developed and heat transfer takes place from the wall to the interior region by circulation of fluid and finally a thermal stratification is achieved. In the numerical study, QUICK scheme for convective terms, SIMPLE algorithm for pressure correction, and the implicit method for the time marching are adopted for the integration of conservation equations. Comparison of flow visualization and numerical results shows that the developing flow patterns are very similar in dynamic nature even though there is a time lag due to the inevitable time delay in setting up a linear temperature profile. For high Rayleigh numbers, the oscillatory motion is likely to take place and stratified region is extended. However, initial temperature adjustment process is much slower than that for low Rayleigh numbers.

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Effect of PT/CT contact on the circumferential temperature distribution over a fully voided nuclear channel of IPHWR

  • Sharma, Mukesh;Kumar, Ravi;Majumdar, Prasanna;Mukhopadhyay, Deb
    • Nuclear Engineering and Technology
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    • v.51 no.5
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    • pp.1314-1321
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    • 2019
  • In case of multiple failure scenario, such as LOCA with ECCS failure, the decay heat continues to raise the reactor core temperature, eventually leading to the core voiding. In such scenario the convective heat transfer becomes poor and the majority of the heat transfer from fuel bundle takes place by radiation mode. During this abnormal working condition, if the channel pressure is less than 1 MPa, the PT sags and come in contact with the CT. This results in high rate of heat transfer from contact location to moderator. The present paper aims to capture the temperature profile over a simulated nuclear channel during such scenario at a steady state temperature of $600^{\circ}C$ (Centre pin) at two different configurations of PT i.e. PT concentric with CT and PT contact with CT. The results showed that the bottom nodes of all the components (Fuel bundle, PT and CT) of the simulated channel was greatly influenced by the PT/CT contact. Moreover, higher temperature were observed at top nodes of the PT and outer pins of the fuel bundle. However, no significant variation in temperatures were obtained in fuel bundle and CT in concentric condition.

A Theoretical Study on the Hydrogen Temperature Evolution Inside the Tank under Fast Filling Process (급속 충전에서 탱크 내부의 수소 온도 변화에 관한 이론 연구)

  • JI-CHAO LI;JI-QIANG LI;HENG XU;BYUNG CHUL CHOI;JEONG-TAE KWON
    • Journal of Hydrogen and New Energy
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    • v.34 no.6
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    • pp.608-614
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    • 2023
  • The fast filling process of high-pressure hydrogen has an important impact on the filling efficiency and safety. In this paper, a specific study is carried out on the thermophysical phenomena during the fast filling process. Starting from the gas state equation of hydrogen, the change law of the hydrogen storage temperature is obtained, and then the temperature rise prediction is constructed. The model can clarify the relationship between the filling parameters and the temperature rise during the fast filling process, thereby revealing the flow and heat transfer laws of the fast charging process. To improve the theoretical research basis for the evaluation of vehicle-mounted hydrogen fast charging capacity, temperature prediction and optimization of hydrogenation methods.

Effect of Tempering Temperature on Hydrogen Embrittlement of Cr-Mo Low Alloy Steels for High-pressure Gaseous Hydrogen Storage (고압수소 저장용 Cr-Mo계 저합금강의 수소취성에 미치는 템퍼링 온도의 영향)

  • M. S. Jeong;H. C. Shin;S. G. Kim;B. Hwang
    • Transactions of Materials Processing
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    • v.33 no.3
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    • pp.185-192
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    • 2024
  • This study examined how varying tempering temperatures affect the susceptibility of Cr-Mo low alloy steels to hydrogen embrittlement. A slow strain-rate test (SSRT) was carried out on the steels electrochemically pre-charged with hydrogen in order to examine the hydrogen embrittlement behavior. The results showed that the hydrogen embrittlement resistance of the Cr-Mo low alloy steels improved with increasing tempering temperature. Thermal desorption analysis (TDA) revealed that diffusible hydrogen content decreased with increasing tempering temperature, accompanied by a slight increase in the peak temperature. This decrease in hydrogen content was likely due to a reduction in dislocation density which served as reversible hydrogen trap sites. These findings underline the significant role of tempering temperature in enhancing the hydrogen embrittlement resistance of Cr-Mo low alloy steels.

Thermal Behavior and Leaf Temperature in a High Pressure Sodium Lamp Supplemented Greenhouse (고압나트륨등 보광 온실의 열적 거동 및 엽온 분석)

  • Seungri Yoon;Jin Hyun Kim;Minju Shin;Dongpil Kim;Ji Wong Bang;Ho Jeong Jeong;Tae In Ahn
    • Journal of Bio-Environment Control
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    • v.32 no.1
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    • pp.48-56
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    • 2023
  • High-pressure sodium (HPS) lamps have been widely used as a useful supplemental light source to emit sufficient photosynthetically active radiation and provide a radiant heat, which contribute the heat requirement in greenhouses. The objective of this study to analyze the thermal characteristics of HPS lamp and thermal behavior in supplemented greenhouse, and evaluate the performance of a horizontal leaf temperature of sweet pepper plants using computational fluid dynamics (CFD) simulation. We simulated horizontal leaf temperature on upper canopy according to three growth stage scenarios, which represented 1.0, 1.6, and 2.2 plant height, respectively. We also measured vertical leaf and air temperature accompanied by heat generation of HPS lamps. There was large leaf to air temperature differential due to non-uniformity in temperature. In our numerical calculation, thermal energy of HPS lamps contributed of 50.1% the total heat requirement on Dec. 2022. The CFD model was validated by comparing measured and simulated data at the same operating condition. Mean absolute error and root mean square error were below 0.5, which means the CFD simulation values were highly accurate. Our result about vertical leaf and air temperature can be used in decision making for efficient thermal energy management and crop growth.

Extremophiles as a Source of Unique Enzymes for Biotechnological Applications

  • Antranikian G.
    • Proceedings of the Microbiological Society of Korea Conference
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    • 2001.11a
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    • pp.39-45
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    • 2001
  • Extremophiles are unique microorganisms that are adapted to survive in ecological niches such as high or low temperatures, extremes of pH, high salt concentrations and high pressure. These unusual microorganisms have unique biochemical features which can be exploited for use in the biotechnological industries. Due to the high biodiversity of extremophilic archaea and bacteria and their existence in various biotopes a variety of biocatalysts with different physicochemical properties have been discovered. The extreme molecular stability of their enzymes, membranes and the synthesis of unique organic compounds and polymers make extremophiles interesting candidates for basic and applied research. Some of the enzymes from extremophiles, especially hyperthermophilic marine microorganisms (growth above $85^{\circ}C$), have already been purified in our laboratory. These include the enzyme systems from Pyrococcus, Pyrodictium, Thermococcus and Thermotoga sp. that are involved in polysacharide modification and protein bioconversion. Only recently, the genome of the thermoalkaliphilic strain. Anaerobranca gottschalkii has been completely sequenced providing a unique resource of novel biocatalysts that are active at high temperature and pH. The gene encoding the branching enzyme from this organism was cloned and expressed in a mesophilic host and finally characterized. A novel glucoamylase was purified from an aerobic archaeon which shows optimal activity at $90^{\circ}C$ and pH 2.0. This thermoacidophilic archaeon Picrophilus oshimae grows optimally at pH 0.7 and $60^{\circ}C$. Furthermore, we were able to detect thermoactive proteases from two anaerobic isolates which are able to hydrolyze feather keratin completely at $80^{\circ}C$ forming amino acids and peptides. In addition, new marine psychrophilic isolates will be presented that are able to secrete enzymes such as lipases, proteases and amylases possessing high activity below the freezing point of water.

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The Influence of Compressive Strength and Moisture Contents on Explosive Spalling of Concrete (압축강도 및 함수율이 콘크리트의 폭렬에 미치는 영향)

  • Kim, Dong-Joon;Han, Byung-Chan;Lee, Jae-Young;Harada, Kazunori;Kwon, Young-Jin
    • Fire Science and Engineering
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    • v.25 no.1
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    • pp.42-49
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    • 2011
  • In the high temperature situation like in a fire, the high strength of concrete (HSC) has extreme danger named explosive spalling. It is assumed that the major cause of explosive spalling is water vapour pressure inside concrete. This paper examines the effect of the compressive strength and the moisture content on the initial occurrence of explosive spalling. For the effective experiment of the initial explosive spalling, the curve of ISO834 temperature profile is applied on the basis of 15 minute and 30 minute. As a result, the more increase the compressive strength and the moisture content, the more increase the occurrence and phenomenon of explosive spalling. This paper analyzes the territory of explosive spalling depending the compressive strength and the moisture content. The explosive spalling is not examined in the case of the compressive strength 50~100 MPa and the moisture content below 3% and the compressive strength over 100 MPa and the moisture content below 1%. Also, due to the HSC, which makes it more difficult to transport vapour and moisture, very high vapour-pressure may occur close to the surface, there is a greater risk that HSC spalls compared with normal strength concrete (NSC).

Study on the Pretreatment of Rice Hull to Enhance Enzymatic Saccharification Efficiency (효소 당화효율 증진을 위한 왕겨의 전처리 방법 연구)

  • Bark, Surn-Teh;Koo, Bon-Cheol;Moon, Youn-Ho;Cha, Young-Lok;Yoon, Young-Mi;Kim, Jung Kon;An, Gi Hong;Park, Kwang-Geun;Park, Don-Hee
    • Applied Chemistry for Engineering
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    • v.23 no.4
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    • pp.399-404
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    • 2012
  • The objective of this study was to investigate the efficient pretreatment method for bioethanol production from rice hull. Ammonia and sodium hydroxide as an alkaline solution and dilute sulfuric acid as an acidic solution were used in a batch reactor under high-temperature and high-pressure conditions. The highest enzymatic saccharification efficiency of 82.8% and ash removal rate of 94.7% were obtained in the dilute sulfuric acid treated sample after the sodium hydroxide solution treatment. The enzymatic saccharification efficiencies and ash removals of pretreated rice hull samples have very similar variation tendency. This means that the maximum obstructive factor for the enzymatic saccharification of rice hull is the ash (silicate) content in biomass. The findings suggest that the combined sodium hydroxide-dilute sulfuric acid treatment system under high-temperature and high-pressure conditions is a promising pretreatment method to enhance the enzymatic saccharification of the silica-rich biomass.

The Effects of High Temperature High Pressure Steam Sterilization on Woohwangchungsimwon (고온고압증기멸균이 우황청심원에 미치는 영향)

  • Cho, Chang-Young;Lee, In-Hee;Lee, Jae-Woong;Kim, Eun-Jee;Lee, Jin-Ho;Kim, Min-Jeong
    • Journal of Korean Medicine Rehabilitation
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    • v.25 no.1
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    • pp.45-52
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    • 2015
  • Objectives To check marker content for appropriate quality control of Woohwangchungsimwon sterilized to ensure microbiological safety and to observe antioxidant activity for any changes in efficacy. Methods To measure any effects of sterilization on the effective compounds, 8 ingredients of Woohwangchungsimwon were screened for any changes in marker content using HPLC-DAD. Using the colorimetric method on the microplate reader any changes in total phenolic compound and flavonoid levels were observed. Antioxidant activity was measured using the DPPH, ABTS, and FRAP. Results Of the ingredients of Woohwangchungsimwon, 8 were subject to quantitative analysis before and after sterilization. 21.6 mg and 1.93 mg of Glycyrrhizin was found in Glycyrrhiza uralensis Fischer pre and post sterilization, respectively. Decursin found in Angelica gigas Nakai increased from 0.16 mg to 0.29 mg after sterilization. Bilirubin found in Gallstone of Bostaurusvar. domesticus increased from 0.24 mg to 0.33 mg. Cinnamic acid found in Cinnamomum cassia Blume increased from 0.02 mg to 0.05 mg. Ginsenoside Rb1 found in Panax ginseng C. A. Meyer decreased from 0.02 mg to 0.14 mg. Paeoniflorin found in Paeonia lactiflora Pallas increased from 1.05 mg to 1.13 mg. Amygdalin found in Armeniacae Amarum Semen increased from 2.68 mg to 2.83 mg. L-muscone found in Musk increased from 0.63 mg to 0.76 mg. As for total phenolic compound and total flavonoid content, there was a 1.22 and 4.15-fold increase. DPPH and ABTS increased by 20.45% and 20.69%, respectively. FRAP activity was 2.78 times more active post stabilization. Conclusions This study confirmed that high temperature high pressure steam sterilization, a method used to ensure microbiological safety of Woohwangchungsimwon, does not affect marker content; in other words, does not affect quality of the Woohwangchungsimwon. It could also be seen that total phenolic compound and flavonoid content increased after sterilization. An antioxidant activity test showed that there was significantly increased activity of antioxidants.