• International journal of advanced smart convergence
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• v.4 no.1
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• pp.154-161
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• 2015

A novel process has successfully been developed by overcoming major difficulties through the elimination of number of process steps involved in the Classical Transesterification reaction during the preparation of Fatty Acid Methyl/Ethyl Ester (FAME.FAEE) called biodiesel. The Classical process with cost intensive process steps such as the utilization of excess alcohol, needing downstream distillation for the recovery and reutilization of excess alcohol/cosolvent, unrecoverable homogenous catalyst which consumes vast quantity of fresh distilled water during the purification of the product and downstream waste water treatment before its safe disposal to the surface water body. The Novel Process FAME/FAEE is produced from any vegetable oil irrespective of edible or inedible variety using sonication energy. The novelty of the finding is the use of only theoretical quantity of alcohol along with a co-solvent and reduced quantity of homogeneous catalyst. Under this condition neither the homogeneous catalyst goes to the FAME layer nor is the distillation needed. The same ester also has been prepared in high pressure high temperature reactor without using catalyst at sub critical temperature. The quality of prepared biodiesel without involving any purification step meets the ASTM standards. Blended Biodiesel with Common Diesel Fuel (CDF) and FAME is prepared, characterized and used as fuel in the Kirloskar make CI Engines. The evaluation of the engine performance result of pure CDF, B05 biodiesel, B10 biodiesel of all types of biodiesel prepared by using the feedstock of Soybean (Glycine max) and Karanja (Pongamia pinnate) oil along with their mixed oil provides useful information such as brake power, brake thermal efficiency, brake specific fuel consumption, etc, and established it as ideal fuel for unmodified CI engine.

• Korean Journal of Materials Research
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• v.20 no.4
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• pp.217-222
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• 2010

Zirconium diboride (ZrB2) and mixed diboride of (Zr0.7Ta0.3)B2 containing 30 vol.% silicon carbide (SiC) composites were prepared by hot-pressing at $1800^{\circ}C$. XRD analysis identified the high crystalline metal diboride-SiC composites at $1800^{\circ}C$. The TaB2 addition to ZrB2-SiC showed a slight peak shift to a higher angle of 2-theta of ZrB2, which confirmed the presence of a homogeneous solid solution. Elastic modulus, hardness and fracture toughness were slightly increased by addition of TaB2. A volatility diagram was calculated to understand the oxidation behavior. Oxidation behavior was investigated at $1500^{\circ}C$ under ambient and low oxygen partial pressure (pO2~10-8 Pa). In an ambient environment, the TaB2 addition to the ZrB2-SiC improved the oxidation resistance over entire range of evaluated temperatures by formation of a less porous oxide layer beneath the surface SiO2. Exposure of metal boride-SiC at low pO2 resulted in active oxidation of SiC due to the high vapor pressure of SiO (g), and, as a result, it produced a porous surface layer. The depth variations of the oxidized layer were measured by SEM. In the ZrB2-SiC composite, the thickness of the reaction layer linearly increased as a function of time and showed active oxidation kinetics. The TaB2 addition to the ZrB2-SiC composite showed improved oxidation resistance with slight deviation from the linearity in depth variation.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.22 no.7
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• pp.595-601
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• 2009

For the silicon oxide $(SiO_x)$ films prepared by using the facing target sputtering (FTS) apparatus that was manufactured to enhance the preciseness of the fabricated thin-film and sputtering yield rate by forming a higher-density plasma in the electrical discharge space for using it as a thin-film passivation system for flexible organic light emitting devices (FOLEDs). The deposition characteristics were investigated under various process conditions, such as array of the cathode magnets, oxygen concentration$(O_2/Ar+O_2)$ introduced during deposition, and variations of distance between two targets and working pressure. We report that the optimum conditions for our FTS apparatus for the deposition of the $SiO_x$ films are as follows: $d_{TS}\;and\;d_{TT}$ are 90mm and 120mm, respectively and the maximum deposition rate is obtained under a gas pressure of 2 mTorr with an oxygen concentration of 3.3%. Under this optimum conditions, it was found that the $SiO_x$ film was grown with a very high deposition rate of $250{\AA}$/min by rf-power of $4.4W/cm^2$, which was significantly enhanced as compared with a deposition rate (${\sim}55{\AA})$/min) of the conventional sputtering system. We also reported that the FTS system is a suitable method for the high speed and the low temperature deposition, the plasma free deposition, and the mass-production.

• Korean Journal of Health Education and Promotion
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• v.11 no.2
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• pp.125-145
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• 1994

The objectives of this study were to characterize the health status, the requirement of home nursing care, and dependency of daily life of the elderly so that the result could be used to provide basic data necessary for establishing home nursing care practices. The study subjects were 249 elders over 65 years old who resided at home in low income areas of three districts in Pusan. The field survey was conducted from December 27, 1993 through January 27, 1994, with a structured questionnaire. Statistical analysis was done by X²-test and Student's T-test using SPSS/PC/sup +/ program. The result were as follows; 1. Alcohol drinking rate was 50.0% for men and 27.7% for women, and cigarette smoking rate was 77.8% for men and 27.1% for women. 92.9% of elders aged 65-75 exercised regularly as compared to 81.9% of elders aged 75 and over(p<0.05). 2. 63.9% of male and 85.9% of female elders had chronic diseases showing singnificant differences(p<0.01), and both sexes had 1.7 kinds of chronic diseases in average; musculoskeletal diseases were the most common in 25.7%, while 6.8% of the elderly had cardiovascular diseases. 3. Partially movable elderly was 6.9% for men and 6.8% for woman, showing 47.1% of causes being cerebrovascular accidents. 4. The home nursing requirement was the highest for medication(66.3%), intramuscular injection(53.8%), and measurement of blood pressure·body·temperature·pulse rate(47.0%). 5. Among Physical Activities of Daily Life, bathing(10.4%) and movement(4.0%) showed high dependency rates, and among Instrumental Activities of Daily Life, phone calling(25.3%), shopping(24.5%), going out by bus(22.5%) showed high dependency rates. 6. For five categories of home nursing showing high requirements such as physical health examination, blood pressure·temperature·pulas rate measurements, medication, and intravascular injection, the requirements were different by age groups, education, and marital status(p<0.05).

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.48 no.3
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• pp.187-194
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• 2020

In this study, computational analyses are carried out to investigate the interference flows and the aerodynamic characteristics of a hit-to-kill intercepter due to lateral jets at medium altitude. In addition, the analyses are performed for air and multi-species gas used in the side jet. The results indicate that the position of the barrel shock are shifted upstream and the structure of the shock wave are changed for the multi-species jet when compared to the air jet. As a result, the high pressure region with multi-species jet moves forward and the pitching moment is higher under the same flow condition. Moreover, the inclusion of high temperature effects makes drastic changes in pressure distribution. The jet width is much bigger, and the jet diffuses over wider range in medium altitude than in low altitude, because of the low density of the freestream.

• Journal of the Korean Institute of Gas
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• v.13 no.3
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• pp.15-21
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• 2009

Gas hydrate is an ice-like crystalline compound that forms at low temperature and high pressure conditions. It consists of gas molecules surrounded by cages of water molecules. Although hydrate formation was initially found to pose serious flow-assurance problems in the gas pipelines or facilities, gas hydrates have much potential for application in a wide variety of areas, such as natural gas storage and transportation. Its very high gas-to-solid ratio and remarkably stable characteristics makes it an attractive candidate for such use. However, it needs to be researched further since it has a slow and complex formation process and a high production cost. In this study, formation experiments have been carried out to investigate the effects of pressure, temperature, water-to-storage volume ratio, SDS concentration, heat transfer and stirring. The results are presented to clarify the relationship between the formation process and each factor, which consequently will help find the most efficient production method.

• Journal of the Korean Society of Combustion
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• v.22 no.4
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• pp.19-26
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• 2017

This study investigates the gasification of coal char by $CO_2$ under high pressures in a drop tube furnace(DTF). The rate constants are derived for the shrinking core model using the conventional method based on the set reactor conditions. The computational fluid dynamic(CFD) simulations adopting the rate constants revealed that the carbon conversion was much slower than the experimental results, especially under high temperature and high partial pressure of reactants. Three reasons were identified for the discrepancy: i) shorter reaction time because of the entry region for heating, ii) lower particle temperature by the endothermic reaction, and iii) lower partial pressure of $CO_2$ by its consumption. Therefore, the rate constants were corrected based on the actual reaction conditions of the char. The CFD results updated using the corrected rate constants well matched with the measured values. Such correction of reaction conditions in a DTF is essential in deriving rate constants for any char conversion models by $H_2O$ and $O_2$ as well as $CO_2$.

• Proceedings of the Korean Vacuum Society Conference
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• 2011.02a
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• pp.106-106
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• 2011

Recently, zinc oxide (ZnO) thin films have attracted great attention as a promising candidate for various electronic applications such as transparent electrodes, thin film transistors, and optoelectronic devices. ZnO thin films have a wide band gap energy of 3.37 eV and transparency in visible region. Moreover, ZnO thin films can be deposited in a poly-crystalline form even at room temperature, extending the choice of substrates including even plastics. Therefore, it is possible to realize thin film transistors by using ZnO thin films as the active channel layer. In this work, we investigated influence of oxygen partial pressure on ZnO thin films and fabricated ZnO-based thin film transistors. ZnO thin films were deposited on glass substrates by using a pulsed laser deposition technique in various oxygen partial pressures from 20 to 100 mTorr at room temperature. X-ray diffraction (XRD), transmission line method (TLM), and UV-Vis spectroscopy were employed to study the structural, electrical, and optical properties of the ZnO thin films. As a result, 80 mTorr was optimal condition for active layer of thin film transistors, since the active layer of thin film transistors needs high resistivity to achieve low off-current and high on-off ratio. The fabricated ZnO-based thin film transistors operated in the enhancement mode with high field effect mobility and low threshold voltage.

• Plant Journal
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• v.4 no.2
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• pp.60-65
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• 2008

As the operating conditions in a supercritical oxidation reactor are set in high temperature with high pressure causing a reactor suffering from the harsh circumstances. It means the reactor adopts itself with Fe-Cr alloy in acidic atmosphere with low pH value and Ni alloy in basic atmosphere with high pH value due to its superior corrosion resistance. The study, whose target waster water is pertinent to the latter part, has selected Ni alloy such as ostenite type stainless steel 304 and 316, superstainless steel AL6XN, Inconel 625, MAT 21, and titanium Gr. 5 in order to measure corrosion resistance against those samples under the same conditions of temperature and pressure applied for a supercritical oxidation reactor. The result shows the identifiable difference in corrosion resistance by observing the surface states through a scanning probe microscope as well as measuring the weight loss through making the samples above deposited in wastewater for two-week and four-week stay. The purpose of this corrosion experiment is to identify the most corrosion-resistant material among sample species pre-selected according to pH concentration of wastewater in pursue of applying for a reactor exposed to the extreme corrosion environment. It is because such a reactor made of a verified material enables to safeguard a stable operation under the supercritical wastewater processing facility.

• Journal of the Korean Applied Science and Technology
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• v.25 no.1
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• pp.58-64
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• 2008

Pretreatment of eliminating FFA is needed to make biodiesel from animal fat recovered from leather wastes because its acid value is high. This study was carried out to investigate the influence of 4 different pretreatment methods, which are heterogeneous catalyst method, ion exchange resin method, low pressure.high temperature method, and alkali method on the eliminating FFA and fatty acid composition. The results showed that the rate of eliminating FFA increased in the order of alkali method > catalyst method > low pressure high temperature method > ion exchange method. In the case of pretreatment of alkali method using NaOH, the rate of eliminating FFA appeared more than 86% regardless of acid value. Therefore, it was considered that alkali method using NaOH was the most effective in the view of economical and productive aspects, taking it into account that the acid value of animal fat recovered from fleshing scrap generated during leather making processes was 7 to 8.