• Title/Summary/Keyword: high temperature high pressure

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Numerical Model Simulation of DF-CO$_2$ Transfer Chemical Laser

  • Kim, Sung-Ho;Cho, Ung-In
    • Bulletin of the Korean Chemical Society
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    • v.10 no.3
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    • pp.282-288
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    • 1989
  • Theoretical analysis of DF-$CO_2$ transfer chemical laser is performed through simple kinetic model consisting of 30 chemical reactions. In this model, we calculate the power theoretically by solving the rate equations, which are related to the $D_2\;+\;F_2$ chain reaction and the DF-$CO_2$ resonance energy transfer, combined with both the gain processes and the stimulated emission processes. The calculated powers are verified with previously reported results in good agreements. The output energy rises linearly with the increase in pressure, and the duration time of output pulse show the inverse dependence on pressure. Through the detailed calculation of temperature and concentrations of reactants as a function of time, it is found that the deactivation processes of DF(v) can be neglected in low pressure, but they have to be considered in high pressure. From the parametric study for the variation on [$D_2]/[F_2$] and [$CO_2]/[D_2\;+\;F_2$] at several constant total pressure, the optimum lasing conditions are found to be in a range of 1/3 to 1 and 2 to 4, respectively.

The Pressure Effect on the Activity Coefficient of Sodium Chloride and Bromide Ions

  • Jee, Jong-Gi;Lee, Sun-Haing;Cha, Seong-Keuck
    • Bulletin of the Korean Chemical Society
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    • v.7 no.3
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    • pp.163-166
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    • 1986
  • A new paraffin salt bridge was developed for the concentration cell in high pressure system. The emf values of the concentration cells were measured to calculate the activity coefficients of the electrolytic ions depending upon the pressure of the system. The activity coefficients of sodium, chloride and bromide ions increase with the temperature of the cell and decreased, nearly half at 2500 bars, $20^{\circ}C$, with the pressure. These results can be explained to be attributed to the volume change of the hydrated ion due to the electrostriction. The volume change decreased with pressure due to an increase in the degree of the hydration.

Interpretation and Comparison of High PM2.5 Characteristics in Seoul and Busan based on the PCA/MLR Statistics from Two Level Meteorological Observations (두 층 관측 기상인자의 주성분-다중회귀분석으로 도출되는 고농도 미세먼지의 부산-서울 지역차이 해석)

  • Choi, Daniel;Chang, Lim-Seok;Kim, Cheol-Hee
    • Atmosphere
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    • v.31 no.1
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    • pp.29-43
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    • 2021
  • In this study, two-step statistical approach including Principal Component Analysis (PCA) and Multiple Linear Regression (MLR) was employed, and main meteorological factors explaining the high-PM2.5 episodes were identified in two regions: Seoul and Busan. We first performed PCA to isolate the Principal Component (PC) that is linear combination of the meteorological variables observed at two levels: surface and 850 hPa level. The employed variables at surface are: temperature (T2m), wind speed, sea level pressure, south-north and west-east wind component and those at 850 hPa upper level variables are: south-north (v850) and west-east (u850) wind component and vertical stability. Secondly we carried out MLR analysis and verified the relationships between PM2.5 daily mean concentration and meteorological PCs. Our two-step statistical approach revealed that in Seoul, dominant factors for influencing the high PM2.5 days are mainly composed of upper wind characteristics in winter including positive u850 and negative v850, indicating that continental (or Siberian) anticyclone had a strong influence. In Busan, however, the dominant factors in explanaining in high PM2.5 concentrations were associated with high T2m and negative u850 in summer. This is suggesting that marine anticyclone had a considerable effect on Busan's high PM2.5 with high temperature which is relevant to the vigorous photochemical secondary generation. Our results of both differences and similarities between two regions derived from only statistical approaches imply the high-PM2.5 episodes in Korea show their own unique characteristics and seasonality which are mostly explainable by two layer (surface and upper) mesoscale meteorological variables.

Design and Performance Evaluation of Solar Air Receivers (공기식 태양열 흡수기의 설계 및 성능평가)

  • Cho, Hyun-Seok;Lee, Hyun-Jin;Kim, Jong-Kyu;Lee, Sang-Nam;Kang, Yong-Heack
    • Journal of the Korean Solar Energy Society
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    • v.32 no.spc3
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    • pp.207-212
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    • 2012
  • It is important to produce the high-temperature and high-pressure air for the concentrated solar power system using the combined cycle. In this paper, we designed two types of tubular receivers to heat up the compressed air and provided their preliminary experimental results for performance evaluation and further improvements. The developed receivers are in a square cavity shape surrounded by flow conduits for easy scale-up and radiation loss reduction. The two receivers were tested with 5 bar air in the KIER solar furnace and evaluated in terms of the outlet temperature and the efficiency.

A Review of Ag Paste Bonding for Automotive Power Device Packaging (자동차용 파워 모듈 패키징의 은 소재를 이용한 접합 기술)

  • Roh, Myong-Hoon;Nishikawa, Hiroshi;Jung, Jae-Pil
    • Journal of the Microelectronics and Packaging Society
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    • v.22 no.4
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    • pp.15-23
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    • 2015
  • Lead-free bonding has attracted significant attention for automotive power device packaging due to the upcoming environmental regulations. Silver (Ag) is one of the prime candidates for alternative of high Pb soldering owing to its superior electrical and thermal conductivity, low temperature sinterability, and high melting temperature after bonding. In this paper, the bonding technology by Ag paste was introduced. We classified into two Ag paste bonding according to applied pressure, and each bonding described in detail including recent studies.

A study on the Physiological Character of living Space in Traditional Koaean House - Focsed on the rural house in Chonbuk province - (전통주거(傳統住居) 공간의 생리적(生理的) 특성(特性)에 관한 연구 - 전북지방 농촌주택(農村住宅)을 중심으로 -)

  • Kim, Yong-Jip
    • Journal of architectural history
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    • v.8 no.2 s.19
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    • pp.59-72
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    • 1999
  • The purpose of this study is to find the spatial factors, strucure of living and activity in traditional Korean house through the Phiysiological view, Spatial factors of the house are concerned to the interior environment and sanitary condition, The elements of respiratory, nerve, temperature sence. vision, hearing, smelling have good condition and touch, pressure sence, pain, metabolism are poor in the house, Ventilation, Lighting, pleasant condition of interior environment are concerned to the elements that mentioned above and have most important meaning in the relation rate of space as 1st factor. And 2nd factor is for metabolism, housework and rest, 3rd factor ie for temperature sence, privacy and reproduction. The relation rate of factors concering interior environment are high in the upper class house. Anbang has important meaning in the relation of living structure and relation sequence of space is anbang, Konnonbang, kitchen, toilet, water place, auxiliary buildings. The relation rate of activity is high in interior space in winter and exterior space in summer.

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Preparation and Characterization of Epitaxial $YBa_2Cu_3O_{7-\delta}$ Thin Films for Fabrication of High-$T_{c}$ Superconducting Microwave Devices (마이크로파 소자 응용을 위한 고온초전도 $YBa_2Cu_3O_{7-\delta}$ 에피택셜 박막의 제조 및 특성분석)

  • 강광용;한석길;김제하;이상렬
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1995.05a
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    • pp.26-30
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    • 1995
  • We describe the preparation and characterization of epitaxial thin films made with high temperature superconductor, $YBa_2Cu_3O_{7-\delta}$. The influence of processing parameters for YBCO thin films on MgO substrates in-situ grown by the pulsed laser deposition, including parameters of a laser beam energy, oxygen pressure, substrate temperature, target-substrate dis-tance is discussed. The characteristics of YBCO thin films were analyzed by using XRD, R-T measurement, AFM, crosssectional TEM, and RBS. For examples of microwave device applications, The fabrication and characterization of the microstrip lowpass filter and bandpass filter are also presented.

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Growth and Characterization of Superconducting Thin Films of BiSrCaCuO / Bi ( Pb ) SrcaCuO Multilayers (BiSrCaCuO / Bi ( Pb ) SrCaCuO의 다층구조를 갖는 초전도 박막의 성장 및 특성)

  • Mun, Gwang-Seok;Gwon, Tae-Ha
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.30 no.4
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    • pp.350-356
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    • 1994
  • We have prepared superconducting Bi-Pb-Sr-Ca.Cu-O thin films by RF magnetron sputtering technique, on heated MgO(100) substrates. Sputtering was carried out in a mixture of argon and oxygen(10%) and the pressure was maintained at 5 mTorr during deposition. The substrate temperature was maintained $400^{\circ}C$ during deposition. The films sputtered were amorphous and insulating. All the films became superconducting by annealing, The films annealed at $880^{\circ}C$ for 30 minutes in air showed high-Tc phase with zero resistivity of 93K. These results indicate that the growth of the high-Tc phase is promoted by the presence of Pb at annealing temperature.

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Characteristics of Sub-cooled Nitrogen Cryogenic System for Applied High-Tc Superconducting Devices (고온초전도 응용기기용 과냉질소 냉각시스템의 냉각특성)

  • 강형구;김형진;배덕권;안민철;윤용수;장호명;고태국
    • Progress in Superconductivity and Cryogenics
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    • v.6 no.1
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    • pp.38-42
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    • 2004
  • The cryogenic system for 6.6 kV/200 A inductive superconducting fault current limiter (SFCL) was developed at Yonsei university in 2003. The sub-cooled nitrogen cryogenic system could be applied to not only SFCL but also many other applied high-Tc superconducting (HTS) devices like superconducting motor, superconducting generator and superconducting magnetic energy storage (SMES). Generally, the cooling capacity of GM-cryocooler depends on the load temperature. Therefore it is necessary to perform the cooling capacity test at no load condition to calculate the exact cooling power and heat load of cryogenic system. In this research, the cooling capacity test of GM-cryocooler was executed and the heat load of developed cryogenic system was calculated. The long run operation test results of sub-cooled nitrogen cryogenic system were successful in pressure and temperature condition. Moreover, the design and fabrication method of cryogenic system were introduced and the test results were described.

Modeling of Electrical Conductivity from $\sigma$tot vs. Po21/4 Plot in Wet Atmosphere for High-Temperature Proton-Conducting Oxides

  • Baek, Hyun-Deok
    • The Korean Journal of Ceramics
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    • v.4 no.2
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    • pp.136-140
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    • 1998
  • This work demonstrates a method for modeling of electrical conductivity in high-temperature proton-conducting oxides. Total conductivity was calculated assuming that it comprises partial conductivities contributed by protons, oxygen ions and electron holes. From the polt $\sigma_{tot}$ vs. $po_2\;{1/4}$ in wet atmosphere, thermodynamic and kinetic parameters were obtained representing transport properties such as concentration and mobility of the charge-carrying defects. The formulas for the calculation of partial conduction were derived based on the defect structure of HTPCs. Illustrative calculation were made for $SrCe_{0.95}Yb_{0.05}O_{2.975}$ system.

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