• Title/Summary/Keyword: high temperature high pressure

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Shock Tube and Modeling Study of the Monomethylamine Oxidation at High Temperature

  • Shin, Kuan-Soo;Yoo, Sang-Jo
    • Bulletin of the Korean Chemical Society
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    • v.25 no.2
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    • pp.293-297
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    • 2004
  • The ignition of monomethylamine was studied in reflected shock waves over the temperature range of 1255- 1579 K and the pressure range of 1.04-1.51 bar. The ignition delay time was measured by the sudden increase of pressure profile and the radiation emitted by OH radicals. The relationship between the ignition delay time and the concentrations of monomethylamine and oxygen was determined in the form of mass-action expressions with an Arrhenius temperature dependence. In contrast to the behavior observed in hydrocarbons, monomethylamine acts to accelerate rather than inhibit its own ignition. And numerical modeling of the ignition of $CH_3NH_2$ has also been carried out to test the several kinetic mechanisms.

Thermal Analysis of a Combined Absorption Cycle of Cogeneration of Power and Cooling for Use of Low Temperature Source (저온 열원의 활용을 위한 흡수 발전/냉각 복합 사이클의 열적 해석)

  • Kim, Kyoung-Hoon
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.23 no.6
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    • pp.413-420
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    • 2011
  • Thermodynamic cycles using binary mixtures as working fluids offer a high potential for utilization of low-temperature heat sources. This paper presents a thermodynamic performance analysis of Goswami cycle which was recently suggested to produce power and cooling simultaneously and combines the Rankine cycle and absorption refrigeration cycle by using ammoniawater mixture as working fluid. Effects of the system parameters such as concentration of ammonia and turbine inlet pressure on the system are parametrically investigated. Results show that refrigeration capacity or thermal efficiency has an optimum value with respect to ammonia concentration as well as to turbine inlet pressure.

The effect of melt flow index on polymer deformation in hot embossing process (고분자 분자량 변화에 따른 핫 엠보싱 공정 연구)

  • Yoon, Keun-Byoung;Jeong, Myung-Young
    • Proceedings of the KSME Conference
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    • 2003.04a
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    • pp.1025-1029
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    • 2003
  • We studied the cross-sectional profiles of deformed thermoplastics in hot embossing process and compared with melt flow index for various embossing conditions such as embossing temperature, embossing pressure and initial thickness of the thermoplastics. The fastest embossing times for complete penetration of the cavities were obtained at temperature greater than $60^{\circ}C$ above glass transition temperature (Tg). When the melt flow index of polymer is low, the penetration ratio does not become large even if the embossing pressure increases. The complete occupation of the cavities was easier obtained with high melt flow index polymer than low melt flow index polymer at the same process condition. We believe these results can be very useful for optimizing nanostructured hot embossing also known nanoimprinting process conditions.

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Electrical and Optical Properties of $SnO_2$ Thin Films by Chemical Vapor Deposition (화학증착법에 의한 $SnO_2$ Film의 전기적 및 광학적 성질)

  • 김광호;김태옥;천성순
    • Journal of the Korean Ceramic Society
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    • v.23 no.5
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    • pp.81-85
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    • 1986
  • $SnO_2$ thin films have been prepared by chemical vapor deposition technique. Electrical and optical properties of the films have been investigated. It is found that the electrical condictivity and optical transparency of the films are most affected by deposition temperature and more affected by $SnCl_4$ partial pressure than by $O_2$ partial pressure. Experimental results show that the conductivity increases with high optical transparency as deposition temperature increases up to 50$0^{\circ}C$ but the conductivity decreases with the loss of transparency as deposition temperature increases above $600^{\circ}C$.

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Changes of Electrical Conductivity and Temperature Caused by Cathode Erosion in a Free-Burning Argon Arc

  • Jeon, Hong-Pil;Lee, Jong-Cheol
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.255.2-255.2
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    • 2014
  • Electrode erosion is indispensable for atmospheric plasma systems, as well as for switching devices, due to the high heat flux transferred from arc plasmas to contacts, but experimental and theoretical works have not identified the characteristic phenomena because of the complex physical processes. Our investigation is concerned with argon free-burning arcs with anode erosion at atmospheric pressure by computational fluid dynamics (CFD) analysis. We are also interested in the energy flux and temperature transferring to the anode with a simplified unified model of arcs and their electrodes. In order to determine two thermodynamic quantities such as temperature and pressure and flow characteristics we have modified Navier-Stokes equations to take into account radiation transport, electrical power input and the electromagnetic driving forces with the relevant Maxwell equations. From the simplified self-consistent solution the energy flux to the anode can be derived.

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An Experimental Study on the Small Power Generation of Temperature difference using the Freon-22 as Working Fluid (프레온-22를 작동유체로 사용한 소용량 온도차 발전에 관한 실험적 연구)

  • Jhoun, C.S.;Shin, I.H.;Huh, C.S.
    • Solar Energy
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    • v.8 no.2
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    • pp.26-38
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    • 1988
  • If proper design and selection of the working fluid are made the power generation system of temperature difference could achieve more efficient results than others. This paper is to analysis the production of its power generation due to several parameters. Making the power generation system, the characteristics of power output are investigated to obtain its basic data for design. This results of this experiment are as follows. 1. The most proper working fluid in the system is Freon-22 having high stability and difference between the outlet pressure, $P_E$ of evaporator and outlet pressure, $P_c$ of Condenser. 2. With the increase of temperature difference between evaporator and condenser, the output in the system increases linearly. 3. The generation efficiency is largely dependent on the type or form of propeller, nozzle and optimum design of heat exchanger.

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Hydrogen Absorption Characteristics of Al/Pd Film (Al/Pd 박막의 수소 흡수 특성)

  • Cho, Young-Sin
    • Journal of Hydrogen and New Energy
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    • v.17 no.2
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    • pp.234-240
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    • 2006
  • Al film(135.5 nm thick) with Pd film(39.6 nm thick) on the top of it was made by thermal evaporation method. Hydrogen absorption of Al/Pd film was measured by quartz crystal microbalance(QCM) method at room temperature. The sample was activated by hydrogen absorption and desorption cycling at room temperature. Hydrogen was introduced into the film by increasing hydrogen gas pressure step by step up to 640 torr at room temperature. Hydrogen concentration reached up to 25% at $5{\sim}10$ torr. But at high pressure the concentration decreased. This strange tendency was not understood yet. Further study is needed to find out the mechanism of hydrogen absorption in Al in Al/Pd film.

Experimental Study on Evaporation and Combustion Characteristics of Fuel Droplet with Carbon Nano-particle in RCM (급속압축장치에서 탄소 나노입자가 첨가된 연료 액적의 증발 및 연소 특성에 관한 실험적 연구)

  • Ahn, Hyeongjin;Won, Jonghan;Beak, Seungwook;Kim, Hyemin
    • 한국연소학회:학술대회논문집
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    • 2015.12a
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    • pp.209-211
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    • 2015
  • Evaporation characteristics of a single droplet of carbon nanofluids were investigated in a rapid compression machine(RCM). n-Heptane and carbon black N990 were used to synthesize the carbon nanofluids. RCM is an experimental set-up to simulate a single compression stroke of reciprocating engine. Temperature and pressure in a reaction chamber were measured during the compression stroke. After the piston reaches top dead center(TDC), temperature and pressure decreased due to the heat loss at wall. In that process, a single droplet of carbon nanofluids underwent unsteady condition. A single droplet was put at the center of reaction chamber. Thermocouple whose tip is $50{\mu}m$ was used not only to measure transient bulk temperature, but also to suspend the droplet. The picture of single droplet was taken using high speed camera with a frame rate of 500 fps. From those pictures, the droplet diameter was measured by visual basic program.

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The Characteristics of Combustion and Exhaust Emission according to Operating Condition and Fuel Composition in a Direct Injection Type HCCI Diesel Engine (직분식 예혼합 압축착화 디젤엔진의 운전조건과 연료조성에 따른 연소 및 배기 특성)

  • 이기형;류재덕;이창식
    • Transactions of the Korean Society of Automotive Engineers
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    • v.12 no.1
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    • pp.10-16
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    • 2004
  • The Homogeneous Charge Compression Ignition (HCCI) engine has advantage for reducing the NOx and P.M. simultaneously. Therefore, HCCI engine is receiving attention as a low emission diesel engine concept. This study was carried out to investigate the characteristics of combustion and exhaust emission for operating conditions in a direct injection type of HCCI engines such as supercharged and naturally aspirated using diesel fuel and additive. From the experimental result, we found that cool flame was always appeared and also it was difficult to control combustion characteristics by changing the injection timing in HCCI. In addition, at the lean air-fuel ratio and high speed range, it was observed that charging air pressure, additive or increasing intake air temperature is effective to increase combustion performance and reduce exhaust emission. We concluded that chemical reaction by the increasing intake air temperature or additive without physical improvement has limitation for reduction of exhaust emission.

An Experimental Study on the Warpage of a Film Insert Molded Plate (필름 인서트 사출성형 평판의 휨 변형에 관한 실험적 연구)

  • Yoo, Y.G.;Lee, H.S.
    • Transactions of Materials Processing
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    • v.21 no.1
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    • pp.30-35
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    • 2012
  • FIM(Film Insert Molding) is an innovative method of producing decorated parts for a wide range of products. Because it requires fewer steps when compared to conventional production methods, the time and cost of manufacturing high quality components can be reduced considerably. In this paper, the effects of processing conditions on the warpage of film-insert molded plate were investigated by using a design of experiments. The dominant factors affecting warpage were mold temperature and holding pressure. Warpage increased with the temperature difference between stationary mold and fixed one. Even when the mold temperature difference was zero, the plate with a film was bent after ejection such that the film side protruded. As holding pressure increased, warpage decreased significantly. In addition warpage increased with time increment for the film-insert molded plates.