• Title/Summary/Keyword: high temperature high pressure

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Preparation of High $J_c$ YBCO Films on LAO by Spray Pyrolysis Process Using Nitrate Precursors (질산염 무기금속 화합물의 분무열분해법에 의한 High-$J_c$ YBCO 박막 제조)

  • Hong, Suk-Kwan;Kim, Jae-Gun;Kim, Ho-Jin;Cho, Han-Woo;Yu, Seok-Koo;Ahn, Jin-Hyun;Joo, Jin-Hoo;Lee, Hee-Gyoun;Hong, Gye-Won
    • Progress in Superconductivity
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    • v.8 no.1
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    • pp.71-74
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    • 2006
  • High $J_c$ over 1 $MA/cm^2$ YBCO film has been successfully prepared using nitrate precursors by spray pyrolysis method. Aerosol drolpets generated using a concentric spray nozzle were directly sprayed on a $LaAlO_3$(100) single crystal substrate. The cation ratio of precursor solution was Y:Ba:Cu=1:2.65:1.35. The distance between nozzle and substrate was 15 cm. Deposition temperature was ranging from $750^{\circ}C\;to\;800^{\circ}C$. Deposition pressure was 100 Torr, and oxygen partial pressure was varied from 10 Torr to 50 Torr. The microstructure, phase formation, texture development and superconducting properties of deposited films were largely changed with oxygen partial pressure. Deposited films showed a texture with(001) planes parallel to substrate plane. High quality film was obtained when film was deposited at $760^{\circ}C$ with an oxygen partial pressure of 30 Torr. The critical current density($J_c$) of the YBCO film was 1.75 $MA/cm^2$ at 77 K and self-field.

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Formation of the Fullerene-type Graphite Spherulites in the Ni-C Liquid under High Pressure (고압하(高壓下) Ni-C 액상(液相) 속에서의 fullerene형(型) 구상흑연입자(球狀黑鉛粒子)의 형성(形成))

  • Park, Jong-Ku
    • Analytical Science and Technology
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    • v.6 no.2
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    • pp.149-156
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    • 1993
  • The formation of the graphite spherulites has been studied experimentally in the Ni-C liquid under high pressure and temperature. In the diamond-stable region the graphite spherulites were formed and grew stably. They were not the polycrystalline particles but the single crystals of the fullerene-type, respectively, grown spirally with much imperfection. And they were proved to be in a mixture state of carbon atoms with $sp^2$- and $sp^3$-bonding by an Auger electron spectroscope and a high resolution transmission electron microscope. As the pressure decreased from the diamond-stable region to the graphite-stable region, the shape of the graphite particles changed gradually from the sphere to the flaky shape. The formation of the graphite spherulites was attributed to the stable existence of the carbon atoms with $sp^3$ bonding in the diamond-stable region. The formation of the large fullerene-type graphite spherulites with much imperfection is well agreed with Kroto's prediction for growth of the giant fullerene.

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Physicochemical Characteristics of Acid Thinned and High Pressure Treated Waxy Rice Starch for Yugwa (Korean Rice Snack) Production

  • Cha, Jae-Yoon;Choi, Ae-Jin;Chun, Bo-Youn;Kim, Min-Ji;Chun, Hyang-Sook;Kim, Chul-Jin;Cho, Yong-Jin;Kim, Chong-Tai
    • Food Science and Biotechnology
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    • v.16 no.6
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    • pp.943-947
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    • 2007
  • The acid modification of waxy rice starch was conducted to improve the yugwa production process. The intrinsic viscosity, paste viscosity, and differential scanning calorimetry characteristics of acid modified starch were measured, and bandaegi and yugwa prepared from acid modified starch were evaluated. The intrinsic viscosities of acid thinned starches were 1.48, 1.27, 1.15, and 0.91 mL/g after reaction times of 1, 2, 3, and 4 hr, respectively. The gelatinization enthalpy was reduced from 16.3 J/g in native starch to 15.8, 15.3, 14.7, and 14.5 J/g in acid thinned starches as the time of acid thinning increased. The peak viscosity and final viscosity decreased with increasing the time of acid thinning, but the pasting temperature was slightly increased in acid thinned starches. The hardness of bandaegi from acid thinned starches under high pressure greatly decreased relative to the control, typical yugwa. Yugwa from acid thinned starch under high pressure maintained a homogeneous structure containing tiny and uniform cells similar to that of native waxy rice starch used for typical yugwa. Acid thinning under high pressure appears to be a good alternative to the existing steeping process for better yugwa quality.

Fabrication and Evaluation of Hydorgenation Propeties on Mg8Ti2-(10, 20 wt.%)Ni Composites (Mg8Ti2-(10, 20 wt.%)Ni 수소저장합금의 제조 및 수소화 특성 평가)

  • Kim, Kyeong-Il;Hong, Tae-Whan
    • Korean Journal of Materials Research
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    • v.20 no.10
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    • pp.543-549
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    • 2010
  • The hydrogen energy had recognized clean and high efficiency energy source. The research field of hydrogen energy was production, storage, application and transport. The commercial storage method was using high pressure tanks but it was not safety. However metal hydride was very safety due to high chemical stability. Mg and Mg alloys are attractive as hydrogen storage materials because of their lightweight and high absorption capacity (about 7.6 wt%). Their range of applications could be further extended if their hydrogenation properties and degradation behavior could be improved. The main emphasis of this study was to find an economical manufacturing method for Mg-Ti-Ni-H systems, and to investigate their hydrogenation properties. In order to examine their hydrogenation behavior, a Sievert's type automatic pressure-compositionisotherm (PCI) apparatus was used and experiments were performed at 423, 473, 523, 573, 623 and 673 K. The results of the thermogravimetric analysis (TGA) revealed that the absorbed hydrogen contents were around 2.5wt.% for (Mg8Ti2)-10 wt.%Ni. With an increasing Ni content, the absorbed hydrogen content decreased to 1.7 wt%, whereas the dehydriding starting temperatures were lowered by some 70-100 K. The results of PCI on (Mg8Ti2)-20 wt.%Ni showed that its hydrogen capacity was around 5.5 wt% and its reversible capacity and plateau pressure were also excellent at 623 K and 673 K.

Corrosion Behavior of Dental Alloys Cast by Various Casting Methods (치과용 주조합금의 주조방법에 따른 부식거동)

  • Choe Han-Cheol;Ko Yeong-Mu
    • Journal of Surface Science and Engineering
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    • v.37 no.5
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    • pp.296-300
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    • 2004
  • The defects of partial denture frameworks are mainly shrinkage porosity, inclusions, micro-crack, particles from investment, and dendritic structure. In order to investigate a good casting condition of partial denture frameworks, the three casting alloys and casting methods were used and detected casting defects were analyzed by using electrochemical methods. Three casting alloys (63Co-27Cr-5.5Mo, 63Ni-16Cr, 63Co-30Cr-5Mo) were prepared for fabricating partial denture frameworks with various casting methods; centrifugal casting (Kerr, USA), high frequency induction casting (Jelenko Eagle, USA), vacuum pressure casting (Bego, Germany). The casting temperature was $1,380^{\circ}C$ (63Co-27Cr-5.5Mo and 63Ni-16Cr) and $1,420^{\circ}C$ (63Co-30Cr-5Mo). The casting morphologies were analyzed using FE-SEM and EDX. The corrosion test of the dendritic structure was performed through potentiodynamic method in 0.9% NaCl solutions at $36.5^{\circ}C$ and corrosion surface was observed using SEM. The defects of partial denture frameworks improved in the order of centrifugal casting, high frequency induction casting, and vacuum pressure casting method, especially, pore defects were found at part of clasp in the case of centrifugal casting method. The structure of casting showed dendritic structure for three casting alloys. In the 63Co-27Cr-5.5Mo and 63Co-30Cr-5Mo, $\alpha$-Co and $\varepsilon$-Co phases were identified at matrix and $${\gamma}$-Ni_2$Cr second phase were shown in 63Ni-16Cr. Also, the corrosion resistance of cast structure increased in the order of vacuum pressure casting, high frequency induction casting, and centrifugal casting method.

A Study on the Measurement of Temperature and Soot in a Visualized D.I Diesel Engine Using the Laser Diagnostics (광계측 기법을 이용한 직분식 디젤 가시화 엔진내의 온도 및 매연 측정에 관한 연구)

  • Han, Yong-Taek;Lee, Ki-Hyung
    • Transactions of the Korean Society of Automotive Engineers
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    • v.15 no.5
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    • pp.38-47
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    • 2007
  • Based upon temperature calibration using the diffusion flame, the temperature and soot concentration of the turbulent flame in a visualized Diesel engine's turbulent flow of flame was qualitatively measured. Two different heads were used to judge the effect of swirl ratio within the combustion chamber. It was possible to measure the highest temperature of the non-swirl head visualized engine which is approximately 2400K, and that the swirl head engine managed up to 2100K. Also, the more the pressure of the spray increases the more the temperature increases due to the improved combustion situation with respect to the visualized diesel engine soot. This experiment also revealed that the KL factor was high where the fuel collided with the walls of the combustion chamber. Moreover the KL factor was high on parts of the chamber where the temperature dropped rapidly.

Evaluation of Temperature and Salinity Fields of HYCOM Reanalysis Data in the East Sea (HYCOM 재분석 자료가 재현한 동해 수온 및 염분 평가)

  • Hong, JinSil;Seo, Seongbong;Jeon, Chanhyung;Park, Jae-Hun;Park, Young-Gyu;Min, Hong Sik
    • Ocean and Polar Research
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    • v.38 no.4
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    • pp.271-286
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    • 2016
  • We evaluate the temperature and salinity fields in the East Sea reproduced by the global ocean reanalysis data using HYbrid Coordinate Ocean Model (HYCOM for short). Temporal correlation of Sea Surface Temperature (SST) change between HYCOM and the Group for High Resolution Sea Surface Temperature (GHRSST) are higher in summer than winter. Though distributions of temperature and salinity in the HYCOM are similar to those from historical data (World Ocean Atlas 2013 V2), salinity in the HYCOM is lower (highter) in the region where the salinity is high (low). Temperature fields in the Ulleung basin of HYCOM are quite similar to those derived from Pressure-recording Inverted Echo Sounder (PIES), such as the correlation coefficient is higher than 0.7. This indicates that the HYCOM represents well the circulation and meso-scale phenomena in the Ulleung basin.

Structural and temperature coefficient of resistance characteristics of colossal magnetoresistance Mn oxides prepared by RF sputtering

  • Choi, Sun-Gyu;Ha, Tae-Jung;Reddy, A.Sivasankar;Yu, Byoung-Gon;Park, Hyung-Ho
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.11a
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    • pp.361-361
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    • 2007
  • A lot of efforts have been paid to develop infrared imaging systems in last decades. Bolometer has a wide range of applications from military to commercial, such as military night vision, medical imaging system and so on. Bolometer is a resistive sensor that detects temperature changes through resistance change. To improve detecting ability, bolometer should have a good resistive film which has high temperature coefficient of resistance (TCR) value. Colossal magnetoresistance (CMR) $L_{1-x}A_xMnO_3$ (where L and A are trivalent rare-earth ions and divalent alkaline earth ions, respectively.) are received attention to apply bolometer resistive film because it has a high TCR property which was discovered in the metal to semiconductor phase transition temperature region. In this work, CMR films were deposited on various substrates in relative low substrate temperature by RF magnetron sputtering. The influence of deposition parameters such as substrate temperature, gas partial pressure, and so on have been studied. The structural and TCR properties of the films were also investigated for applying to microbolometer.

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Physicochemical Characteristics of Garlic (Allium sativum L.) on the High Temperature and Pressure Treatment (고온고압처리에 따른 마늘(Allium sativum L.)의 이화학적 특성)

  • Kwon, Oh-Chan;Woo, Koan-Sik;Kim, Tae-Myoung;Kim, Dae-Joong;Hong, Jin-Tae;Jeong, Heon-Sang
    • Korean Journal of Food Science and Technology
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    • v.38 no.3
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    • pp.331-336
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    • 2006
  • Effects of high temperature and pressure treatment on garlic (Allium sativum L.) treated at 110, 120, 130, 140, and $150^{\circ}C$ for 1, 2, 3, 4, and 5 hr were evaluated by investigating changes in antioxidant activities, and total polyphenol, total flavonoid, and 5-hydroxymethyl-2-furaldehyde (5-HMF) contents of garlic juice. Antioxidant activities, and total polyphenol, total flavonoid, and 5-HMF contents increased with increasing treated temperature and time. $IC_{50}$ (1.952 mg/g) was achieved at $150^{\circ}C$ for 4 hr, 50 times higher than untreated garlics. Highest total polyphenol content was 18.155 mg/g at $140^{\circ}C$ and 2 hr, seven times higher than untreated garlics. Highest total flavonoid content was $532.73\;{\mu}g/g$ at $150^{\circ}C$ and 1 hr, sixteen times higher than untreated garlics. 5-HMF content was highest (7,765.9 ppm) at $150^{\circ}C$ and 2 hr. Correlation coefficients among antioxidant activities, and total polyphenol, total flavonoid, and 5-HMF contents were very high (p<0.01).

Review on the Fire Resistance and Pumpability Performance of Fiber Reinforced High Strength Concrete

  • Kwon, Hae-Won;Kim, Young-Su
    • Journal of the Korea Institute of Building Construction
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    • v.13 no.1
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    • pp.58-65
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    • 2013
  • Currently, many high-rise buildings are built in Korea for land-efficient utilization and vista. In high-rise buildings this tall, the use of high-strength concrete is essential to reduce the cross-section of structure members and secure axial load. However, this high strength concrete is vulnerable to spalling by fire, due to the water vapor pressure caused by the very high temperature in fire. To prevent this, the main method used is to reinforce the concrete with fiber. However, there has been little research on the pumpability of fiber reinforced high strength concrete. For this reason, this study features a performance review based on the properties and pumpability of fiber reinforced high strength concrete. In addition, the parameter of rheology was measured by extracting mortar from the concrete, and friction factor was measured through a 400 m horizontal pipe pumping test using the fiber reinforced high strength concrete. The basic information on fiber reinforced high strength concrete that we obtain through the experiments and review will contribute to the field.