• 제목/요약/키워드: high pressure $CO_2$

검색결과 986건 처리시간 0.03초

CO2-Hydrate와 CO2 가스 혼합물의 전달물성과 관내측 열전달계수 및 압력강하 예측 (Thermophysical Properties of CO2 and CO2-Hydrate Mixture and In-Tube Heat Transfer Characteristics)

  • 윤린
    • 설비공학논문집
    • /
    • 제25권5호
    • /
    • pp.233-239
    • /
    • 2013
  • The Thermophysical properties of thermal conductivity, viscosity, and heat capacity for $CO_2$ slurry ($CO_2$ gas and $CO_2$-hydrate mixture) having a high gas phase volume fraction were predicted using the conventional mixture models and the TRAPP model under hydrate formation conditions. Based on the calculated thermophysical properties, the heat transfer coefficient and pressure drop of the $CO_2$ slurry in the tube were predicted. The thermal conductivity of $CO_2$ slurry ranged from 0.02 to 0.2 W/m-K, and the mixture viscosity was larger than that of pure $CO_2$ by 1.9~2.7 times. The heat capacity of $CO_2$ slurry ranged from 63 to 68% of that for pure $CO_2$. The predicted heat transfer coefficient of $CO_2$ slurry was 6 times higher than that of pure $CO_2$. In the separate model, the estimated pressure drop increased with an increase of $CO_2$-hydrate mole fraction, and was 60% of that of pure $CO_2$.

High density plasma etching of CoFeB and IrMn magnetic films with Ti hard mask

  • Xiao, Y.B.;Kim, E.H.;Kong, S.M.;Chung, C.W.
    • 한국진공학회:학술대회논문집
    • /
    • 한국진공학회 2009년도 제38회 동계학술대회 초록집
    • /
    • pp.233-233
    • /
    • 2010
  • Magnetic random access memory (MRAM), based on magnetic tunnel junction (MTJ) and CMOS, is a prominent candidate among prospective semiconductor memories because it can provide nonvolatility, fast access time, unlimited read/write endurance, low operating voltage and high storage density. The etching of MTJ stack with good properties is one of a key process for the realization of high density MRAM. In order to achieve high quality MTJ stack, the use of CoFeB and IrMn magnetic films as free layers was proposed. In this study, inductively coupled plasma reactive ion etching of CoFeB and IrMn thin films masked with Ti hard mask was investigated in a $Cl_2$/Ar gas mix. The etch rate of CoFeB and IrMn films were examined on varying $Cl_2$ gas concentration. As the $Cl_2$ gas increased, the etch rate monotonously decreased. The effective of etch parameters including coil rf power, dc-bais voltage, and gas pressure on the etch profile of CoFeB and IrMn thin film was explored, At high coil rf power, high dc-bais voltage, low gas pressure, the etching of CoFeB and IrMn displayed better etch profiles. Finally, the clean and vertical etch sidewall of CoFeB and IrMn free layers can be achieved by means of thin Ti hard mask in a $Cl_2$/Ar plasma at the optimized condition.

  • PDF

국내 주요 콩과식물인 돌콩(Glycine soja)과 백태(Glycine max) 간의 생리적 차이에 관한 연구 (The Study on the Physiological Differences for Major Fabaceae, Glycine soja and Glycine max in Korea)

  • 박재훈;김의주;유영한
    • 생태와환경
    • /
    • 제54권2호
    • /
    • pp.120-124
    • /
    • 2021
  • In order to understand the vegetative role of Glycine soja, we studied the basic physiological characteristics between Glycine soja and Glycine max. For this study, the light intensity (μmol m-2 s-1) on leaf surface, leaf temperature (℃), transpiration rate (mmol m-2 s-1), photosynthetic rate (μmol m-2 s-1), substomatal CO2 partial pressure (vpm) of Glycine soja and Glycine max were measured, and the quantum yield, photosynthesis rate per substomatal CO2 partial pressure were calculated. In the results of simple regression analysis, the increasing quantum yield decreases leaf temperature both of Glycine soja and Glycine max and the increasing leaf temperature decreases transpiration rate in case of Glycine soja. However, in case of Glycine max, the increasing leaf temperature decreases substomatal CO2 partial pressure, photosynthetic rate, and photosynthetic rate per substomatal CO2 partial pressure as well as transpiration rate. Also, increasing transpiration rate increases substomatal CO2 partial pressure while decreases photosynthetic rate per substomatal CO2 partial pressure. Thus, Glycine soja is relatively more easily adaptable to severe environments with low soil nutrients and high light levels. Compared to Glycine max susceptible to water loss due to a water-poor terrestrial habitat, the physiological traits of Glycine soja has a high average transpiration rate and are less susceptible to water loss will act as a factor that limits the habitat according to soil moisture.

고온 고압 환경에서 레이저를 이용한 알루미늄 입자 생성과 점화 (Aluminum ignition in laser-generated aluminum particles in high temperature and high pressure environment)

  • 이경철;타이라 쯔바사;구군모;이재영;박정수;여재익
    • 한국연소학회:학술대회논문집
    • /
    • 한국연소학회 2012년도 제45회 KOSCO SYMPOSIUM 초록집
    • /
    • pp.101-103
    • /
    • 2012
  • Characteristic of aluminum ignition under high temperature and high pressure is studied using lasers. The laser ablation method is used to generate aluminum particles exposed to a high pressure by using a nanosecond pulsed laser where the range of ablation pressure varies between 0.35 and 2.2 GPa. A $CO_2$ laser is used to supply radiative heat to the aluminum target surface for providing high temperature ranging between 5000~9300 Kelvin. The ignition is confirmed using spectroscopy analysis of AlO vibronic band 484 nm wavelength. Also the radiative temperature is measured in various high pressure range for tracing the ignition temperature in high pressure conditions.

  • PDF

Numerical study of CO2 hydrate dissolution rates in the ocean: Effect of pressure, temperature, and salinity

  • Kyung, Daeseung;Ji, Sukwon;Lee, Woojin
    • Advances in environmental research
    • /
    • 제4권1호
    • /
    • pp.17-24
    • /
    • 2015
  • In this study, we numerically investigated the effect of pressure (100-250 bar), temperature (274-288 K), and salinity (3.5% w/w electrolytes) on $CO_2$ hydrate dissolution rates in the ocean. Mass transfer equations and $CO_2$ solubility data were used to estimate the $CO_2$ hydrate dissolution rates. The higher pressure and lower temperature significantly reduced the $CO_2$ hydrate dissolution rates due to the increase of $CO_2$ particle density. In the high salinity condition, the rates of $CO_2$ hydrate dissolution were decreased compared to pure water control. This is due to decrease of $CO_2$ solubility in surrounding water, thus reducing the mass transfer of $CO_2$ from the hydrate particle to $CO_2$ under-saturated water. The results obtained from this study could provide fundamental knowledge to slow down or prevent the $CO_2$ hydrate dissolution for long-term stable $CO_2$ storage in the ocean as a form of $CO_2$ hydrate.

가압 유동층 반응기에서 산소공여입자의 메탄 연소 특성에 미치는 온도, 압력 및 기체체류시간의 영향 (Effects of Temperature, Pressure, and Gas Residence Time on Methane Combustion Characteristics of Oxygen Carrier Particle in a Pressurized Fluidized Bed Reactor)

  • 류호정;박상수;문종호;최원길;이영우
    • 한국수소및신에너지학회논문집
    • /
    • 제23권2호
    • /
    • pp.173-182
    • /
    • 2012
  • Effects of temperature, pressure, and gas residence time on methane combustion characteristics of mass produced oxygen carrier particle (OCN706-1100) were investigated in a pressurized fluidized bed reactor using methane and air as reactants for reduction and oxidation, respectively. The oxygen carrier showed high fuel conversion, high $CO_2$ selectivity, and low CO concentration at reduction condition and very low NO emission at oxidation condition. Moreover OCN706-1100 particle showed good regeneration ability during successive reduction-oxidation cyclic tests up to the 10th cycle. Fuel conversion and $CO_2$ selectivity decreased and CO emission increased as temperature increased. These results can be explained by trend of calculated equilibrium CO concentration. However, $CO_2$ selectivity increased as pressure increased and fuel conversion increased as gas residence time increased.

대구지역 CO농도에 미치는 기상효과에 관한 연구 (On the Meteorological Influence on the Automobile Air Pollution in Daegu)

  • 김해동;박명희;이정영
    • 한국환경과학회지
    • /
    • 제12권9호
    • /
    • pp.987-996
    • /
    • 2003
  • In this study, we analyzed the relationship between the time-variation trend of air pollution concentration index and the meteorological conditions with CO(carbon monoxide) concentration and meteorological observation data in high-CO episode days. CO is a representative automobile air pollutant. The results are as follows; 1. Most of the high-CO episode days within 30 classes appeared in winter season. 2. Most of them appeared under the surface weather conditions with east-west high-pressure system. The surface winds in this high-pressure area were very light. 3. The high-CO episode days were due to unusual accumulation within urban atmosphere in the morning. 4. The Atmospheric stabilities were more stable, and then the wind-ventilation conditions were worse than yearly mean atmospheric condition in Daegu.

수확 후 고농도 CO2 단기처리가 '매향' 딸기의 저장에 미치는 영향 (Effects of short-term treatment of high pressure CO2 on the changes in fruit quality during the storage of 'Maehyang' strawberries)

  • 안선은;왕무화;이아연;황용수
    • 농업과학연구
    • /
    • 제41권1호
    • /
    • pp.9-16
    • /
    • 2014
  • This experiment was conducted to examine the effects of a short-term treatment of high pressure $CO_2$ on shelf-life of strawberry fruit. A short-term treatment (12 hr) of 100% $CO_2$ resulted in the increase of fruit firmness up to 71.9% compared to that at harvest. The firmness of $CO_2$ treated fruit remained a significantly higher than that of control (air) up to 15 days. The alteration of pectic polymers was observed by $CO_2$ treatment such as an increase of EDTA soluble pectins and decrease of water soluble ones. The $CO_2$ treatment resulted in the increase of total amount of wall bound calcium. Pectate lyase activity, an important agent of strawberry fruit softening, was also significantly reduced by $CO_2$ treatment. Contents of soluble solids and acids of $CO_2$ treated fruit were higher than those of control fruit. Short-term treatment of high pressure $CO_2$ affected shelf-life through firmness increase whereas the visual quality and decay incidence of strawberry fruit were not affected.

이산화탄소(CO2) 가스에 의한 케이크 여과속도의 향상 (The Improvement of Cake Filtration Rate using CO2 Gas Saturation)

  • 임성삼;송연민
    • Korean Chemical Engineering Research
    • /
    • 제44권5호
    • /
    • pp.468-475
    • /
    • 2006
  • 압축성이 큰 케이크에 의한 여과에서는 압력의 증가가 여과속도를 거의 향상시키지 못한다. 이 경우 높은 압력은 여과매체 옆의 케이크 공간률을 급격히 감소시켜 dense skin(치밀층, 緻密層)을 형성하여 이 층이 물의 통과속도를 매우 느리게 하기 때문이다. 실제로 압축성이 큰 케이크의 여과에서 여과속도를 향상시키기 위한 특별한 방법이 없었다. 본 연구에서는 여과 대상액을 여과조작 전에 $CO_2$ 가스로 포화시켜 용액에 녹아 있던 $CO_2$ 가스가 압력이 급격히 변하는 치밀층에서 기체 상태로 변화하여 치밀층 내에 작은 공간을 확보하고, 그 공간이 물길을 형성하여 여과속도를 향상시 킬 수 있는 가능성에 대해 연구하였다.

0.5 MWth 케미컬루핑 연소 시스템 적용을 위한 신규 산소전달입자의 고온·고압 반응 특성 (Reaction Characteristics of New Oxygen Carrier for 0.5 MWth Chemical Looping Combustion System at High Temperature and High Pressure Conditions)

  • 김정환;이도연;남형석;조성호;황병욱;백점인;류호정
    • 한국수소및신에너지학회논문집
    • /
    • 제29권5호
    • /
    • pp.473-482
    • /
    • 2018
  • To check applicability of recently developed new oxygen carrier for 0.5 MWth chemical looping combustion system, reactivity tests were carried out at high temperature and high pressure conditions. Pressure, temperature, gas velocity, $CH_4$ flow rate, and solid height were considered as operating variables. The new oxygen carrier (N016-R4) showed not only high fuel conversion but also high $CO_2$ selectivity within all the operating conditions in this study. The reactivity of N016-R4 particle was compared with previous oxygen carriers. The N016-R4 particle represented outstanding reactivity among 10 oxygen carriers in terms of fuel conversion and $CO_2$ selectivity.