• Title/Summary/Keyword: high porosity

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Comparative Study on a Special Low-Porosity Portland Cement (저 기공성 특수 포틀랜드 시멘트에 대한 비교연구)

  • 장복기
    • Journal of the Korean Ceramic Society
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    • v.25 no.5
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    • pp.532-540
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    • 1988
  • Even the finest cement as having a specific surface area of 6.000~8.500$\textrm{cm}^2$/g (Blaine) is to convert into low-porosity hardened cement paste by the use of appropriate plasticizer. In this study, tests were carried out on such a special cement mix(fineness of 6.000$\textrm{cm}^2$/g, Ca-lignosulfonate plus k2CO3 as plasticizer and W/C=0.25) in comparison with ordinary Portland cement. Owing mainly to the high fineness of the cement powder and the low water-to-cement ratio, the hardened low-porosity cement paste showed a very tight microstructure, the pore texture of which consisted of micropores and wide pores only of small radii. The consequence of such mix was hence that the low-porosity special cement had excellent properties of early-high and very high strengths as compared to ordinary Portland cement. Its volume change when dried in the air or re-wetted, exhibited superor behaviour as well.

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Morphological and Physicochemical Changes of NBKP by Alkali Pretreatment (알카리 전처리에 의한 NBKP의 형태학적 및 이화학적 변화)

  • Mun, Sung-Phil;Jang, Min-Hwan
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.41 no.4
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    • pp.58-64
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    • 2009
  • This study was carried out to prepare high porosity pulp for oil and air filter media from commercial grade NBKP with 6 - 20% NaOH treatment. The fiber width of NBKP remarkably decreased by NaOH pretreatment. The air permeability of the test sheet prepared from alkali-pretreated NBKP increased with increasing NaOH concentration up to 15%. The burst factor was greatly decreased by alkali pretreatment. By 15 - 20% NaOH pretreatment of NBKP, it could be possible to prepare a high porosity pulp. It seems that the high porosity of the pulp was due to a strong swelling and a great change of the cellulose crystalline lattice from cellulose I to cellulose II with NaOH treatment of NBKP. The study suggested that alkali- pretreated NBKP could be used for manufacturing oil and air filter media.

Relationship between Mechanical Properties and Porosity of Porous Polymer Sheet Fabricated using Water-soluble Particles (수용성 입자를 이용한 다공성 폴리머 구조체의 공극률 향상과 기계적 물성과의 관계)

  • So, Sae-Rom;Park, Suk-Hee;Park, Sang-Hu
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.17 no.6
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    • pp.16-23
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    • 2018
  • A polymer porous sheet, which can be applied to diverse wearable devices, has some advantages such as light-weight, high flexibility, high elongation, and so many others. In order to fabricate a porous sheet, water-soluble particles like sugar were utilized frequently, and there has been great advances. However, with our best knowledge, there are not enough reports on the mechanical behavior of porous sheets having different porosity. So, in this work, we tried to find out the relationship between porosity and mechanical deformation of a porous sheet. The process parameters such as a particle size, sheet thickness and PDMS mixing ratio with curing agent were analyzed on the effect of increasing the porosity of a sheet. Also, mechanical deformation of a sheet was tested using a tensile experiment. Through the experimental results, we make a conclusion that a highly porous sheet with thin thickness has high flexibility, and it deformed nearly double elongation comparing to worst one among nine cases.

Effects of Physicochemical/Mineralogical Characteristics of Limestones and Porosity after Calcination on Desulfurization Reactivities

  • Baek, Chul-Seoung;Seo, Jun-Hyung;Cho, Jin-Sang;Cho, Kye-Hong;Han, Choon
    • Journal of the Korean Ceramic Society
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    • v.53 no.1
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    • pp.34-42
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    • 2016
  • Characteristics of wet flue gas desulfurization and in-furnace desulfurization of domestic and overseas limestone with different crystallinity and crystalline size are studied in this article. Properties of desulfurization were evaluated in relation to physicochemical/ mineralogical characteristics, degree of pore formation for different calcination temperatures and TNC(total neutralizing capability). TNC of domestic high crystalline limestone was lower than that of overseas one. On the other hand, the porosity after calcination was shown to be relatively high for domestic limestone, which had high initial rates of desulfurization reactions in-furnace. Based on low pore formation and porosity with high TNC of crystalline high-Ca limestones compared to macrocrystalline ones, the former are preferred for wet desulfurization processes.

Model Prediction and Experiments for the Electrode Design Optimization of LiFePO4/Graphite Electrodes in High Capacity Lithium-ion Batteries

  • Yu, Seungho;Kim, Soo;Kim, Tae Young;Nam, Jin Hyun;Cho, Won Il
    • Bulletin of the Korean Chemical Society
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    • v.34 no.1
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    • pp.79-88
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    • 2013
  • $LiFePO_4$ is a promising active material (AM) suitable for use in high performance lithium-ion batteries used in automotive applications that require high current capabilities and a high degree of safety and reliability. In this study, an optimization of the electrode design parameters was performed to produce high capacity lithium-ion batteries based on $LiFePO_4$/graphite electrodes. The electrode thickness and porosity (AM density) are the two most important design parameters influencing the cell capacity. We quantified the effects of cathode thickness and porosity ($LiFePO_4$ electrode) on cell performance using a detailed one-dimensional electrochemical model. In addition, the effects of those parameters were experimentally studied through various coin cell tests. Based on the numerical and experimental results, the optimal ranges for the electrode thickness and porosity were determined to maximize the cell capacity of the $LiFePO_4$/graphite lithium-ion batteries.

Properties of Pohang Mudstone with High Porosity According to Water Immersion (수침에 따른 공극률이 큰 포항 이암의 특성)

  • Kim, Byung-Soo;Lee, Yun-Jae;Kim, Tae-Hyung;Kim, Byeong-Jun
    • Journal of the Korean Geotechnical Society
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    • v.37 no.11
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    • pp.83-92
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    • 2021
  • In this study, effective porosity measurement, electron microscope (SEM) observation, X-ray diffraction analysis (XRD), slaking, swelling, and unconfined compression strength according to water immersion were analyzed to evaluate the properties of mudstone with high porosity in Pohang. As a result of the test for 16 square samples (5 cm), the effective porosity was 14.67% on average, higher than porosity of general mudstone, and electron microscope observation confirmed that the porosity was actually high. As a result of X-ray diffraction analysis, the swelling clay mineral content was 2.3~4.1%, which was lower than the results of previous studies in Pohang. The slake durability index was 37.73~87.73%, showing low to medium durability, which was lower than the results of previous studies. It was confirmed that the swelling property rapidly expanded to 1.79~1.82% of maximum swelling strain in the major axis direction for 30 minutes. As the properties of decreasing the unconfined compression strength according to water immersion, the samples rapidly weathered after 10 minutes of water immersion, and the strength decreased. It was confirmed that the results of previous studies related to mudstone in Pohang were different. This is judged to be due to the high porosity of mudstone in study.

A Study to Effect on the Porosity when Model Making for Control of Vibrator (진동기의 단계별 조절이 모형 제작시 기포발생에 미치는 영향에 관한 연구)

  • Lee, Do-Kyeng
    • Journal of Technologic Dentistry
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    • v.13 no.1
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    • pp.15-19
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    • 1991
  • This study was made to effect on the porosity when model making for control of vibrator. Samples of total 600 were made by plaster and stone divided low, medium and high which is 100 each. The following results were obtained to observation porosity of surface by eyes. 1. Second stage was fewer than third stage, first stage was fewer than third stage in porosity number of plaster model. 2. Second stage was fewer than first stage in porosity number of stone model. 3. Stone model was fewer than plaster model in porosity number of third stage.

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Gate Design to Reduce Porosity in High Pressure Die Cast Impeller Blade (임펠러 블레이드용 다이캐스팅 금형의 게이트 방안 설계)

  • Jung, S.K.;Cho, I.H.;Lee, J.H.;Kim, D.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2009.05a
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    • pp.435-436
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    • 2009
  • In the effort on cost reduction in marine equipment company, the medium sized impeller blade ($500mm{\times}200mm{\times}20mm$) of an axial flow pan was manufactured by the high pressure die casting, with which was replaced the gravity die casting. High pressure die casting is a practical alternative because of some advantages such as excellent accuracy and smooth cast surface as well as cost reduction if a certain amount of porosity in the parts can be minimized. In order to reduce the porosity in the center of the neck which is thickest region of the impeller blade, the several gate designs were proposed in this work. The flow simulations for each gate design were performed and then the optimal design was determined by considering the air pressure distribution in neck section. Finally, the size of porosity in the neck of the die cast impeller blade for optimal design was less than 1mm, which satisfied the requirement.

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Analysis of a functionally graded nanocomposite sandwich beam considering porosity distribution on variable elastic foundation using DQM: Buckling and vibration behaviors

  • Nejadi, Mohammad Mehdi;Mohammadimehr, Mehdi
    • Computers and Concrete
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    • v.25 no.3
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    • pp.215-224
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    • 2020
  • In the present study, according to the important of porosity in low specific weight in comparison of high stiffness of carbon nanotubes reinforced composite, buckling and free vibration analysis of sandwich composite beam in two configurations, of laminates using differential quadrature method (DQM) is studied. Also, the effects of porosity coefficient and three types of porosity distribution on critical buckling load and natural frequency are discussed. It is shown the buckling loads and natural frequencies of laminate 1 are significantly larger than the results of laminate 2. When configuration 2 (the core is made of FRC) and laminate 1 ([0/90/0/45/90]s) are used, the first natural frequency rises noticeably. It is also demonstrated that the influence of the core height in the case of lower carbon volume fractions is negligible. Even though, when volume fraction of fiber increases, the critical buckling load enhances smoothly. It should be noticed the amount of decline has inverse relationship with the beam aspect ratio. Investigating three porosity patterns, beam with the distribution of porosity Type 2 has the maximum critical buckling load and first natural frequency. Among three elastic foundations (constant, linear and parabolic), buckling load and natural frequency in linear variation has the least amount. For all kind of elastic foundations, when the porosity coefficient increases, critical buckling load and natural frequency decline significantly.

Veriation of Pore Structure of High Strength Concrete Including Silica Fume Exposed to High Temperature (고온에 노출된 실리카퓸 혼입 고강도 콘크리트의 공극구조 변화)

  • Song Hun;Soh Yang-Seob
    • Journal of the Korea Concrete Institute
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    • v.16 no.5 s.83
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    • pp.597-604
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    • 2004
  • This work involves quantitatively investigating the correlation between reductions in strength and variations in pore structure under high temperature that can be utilized as estimation for predicting the inner temperature of member damaged by fire. The experimental results were remarkedly affected by micro-filling effect of silica fume and the different water-binder ratios. The increase of the exposure temperature caused the increase of porosity, which resulted from the reason that evaporable water in gel pore or capillary pores as well as chemically bound water was eliminated from hardened cement paste due to the dehydration of C-S-H and $Ca(OH)_2$. Thermal shrinkage of hardened cement paste gives rise to micro-crack, which cause the increase of porosity. Based on the experimental result that the increase of porosity is in charge of exposure temperature, how porosity is distributed can predict temperature-time history and assess the performance of concrete damaged by fire.