• Title/Summary/Keyword: high porosity

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Characteristics and Microstructure of Matrix Retaining Electrolyte in Phosphoric Acid Fuel Cell Prepared by Tape Casting (Tape Casting법으로 제조한 인산형 연료전지 전해질 매트릭스의 미세구조 및 특성)

  • 윤기현;허재호;장재혁;김창수
    • Journal of the Korean Ceramic Society
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    • v.31 no.4
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    • pp.375-380
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    • 1994
  • Matrices retaining electrolyte in phosphoric acid fuel cell were prepared with SiC to SiC whisker mixing ratios of 1:0.5, 1:1, 1:1.5, 1:2, 1:3 by tape casting method. When viscosity of the slurry was 5.9 poise and the SiC to SiC whisker mixing ratios were 1:1, 1:1.5, 1:2, the ranges of porosity, acid absorbency and bubble pressure were 80~90%, 2.5~6 and 700~2200 mmH2O, respectively. Those ranges are acceptable for a practical electrolyte-retaining matrix. With increasing the mixing ratio of SiC whisker to SiC, the porosity and the vol.% of large pores in the main pore size distribution which is between 1 and 10 ${\mu}{\textrm}{m}$, increased rapidly. Impedance spectroscopy was measured to know characteristics of matrix inside and contact region of matrix to catalyst layer. When the SiC to SiC whisker mixing ratio was 1:2, hydrogen ions were transported in the matrix most effectively because of high ionic conductivity and low activation energy due to high acid absorbency in spite of high interfacial resistance. The cell current density of the cell made using the matrix was 220 mA/$\textrm{cm}^2$ at 0.7 V.

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An Experimental Study on the Propagation Characteristics and Reduction of Impulse Noises from a High Voltage COS Fuse (고전압 COS 퓨즈로부터 방사된 충격성 소음의 전파특성과 저감에 관한 실험적 연구)

  • Song, Hwa-Young;Ju, Kyung-Min;Lee, Dong-Hoon;Kang, Rae-Goog;Jung, Nak-Hun
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2005.11a
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    • pp.71-74
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    • 2005
  • This experimental study describes the propagation characteristics and reduction of impulse noises emitted from a high voltage COS(Cut Out Switch) fuse of a transformer. When a high voltage COS fuse becomes a short circuit by the over current. The peak sound Pressure above 150dB(A) is generated. In this study, an impulse noise generator is designed for generating the impulse noises similar to the noise level of COS fuse, which is utilized to test the noise reduction of a reactive silencer. The reactive silencers have been tested for 10 different types with each different porosity, hole diameter and length. From the experimental results, it is found that the reactive silencer has an excellent performance to greatly suppress the impulse noise and that its performance is closely connected with the porosity and hole diameter.

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The Effect of Fe and Fe2O3 Powder Mixing Ratios on the Pore Properties of Fe Foam Fabricated by a Slurry Coating Process (슬러리 코팅 공정으로 제조된 Fe 폼의 기공 특성에 미치는 Fe 및 Fe2O3 분말의 혼합 비율의 영향)

  • Choi, Jin Ho;Jeong, Eun-Mi;Park, Dahee;Yang, Sangsun;Hahn, Yoo-Dong;Yun, Jung-Yeul
    • Journal of Powder Materials
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    • v.21 no.4
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    • pp.266-270
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    • 2014
  • Metal foams have a cellular structure consisting of a solid metal containing a large volume fraction of pores. In particular, open, penetrating pores are necessary for industrial applications such as in high temperature filters and as a support for catalysts. In this study, Fe foam with above 90% porosity and 2 millimeter pore size was successfully fabricated by a slurry coating process and the pore properties were characterized. The Fe and $Fe_2O_3$ powder mixing ratios were controlled to produce Fe foams with different pore size and porosity. First, the slurry was prepared by uniform mixing with powders, distilled water and polyvinyl alcohol(PVA). After slurry coating on the polyurethane(PU) foam, the sample was dried at $80^{\circ}C$. The PVA and PU foams were then removed by heating at $700^{\circ}C$ for 3 hours. The debinded samples were subsequently sintered at $1250^{\circ}C$ with a holding time of 3 hours under hydrogen atmosphere. The three dimensional geometries of the obtained Fe foams with an open cell structure were investigated using X-ray micro CT(computed tomography) as well as the pore morphology, size and phase. The coated amount of slurry on the PU foam were increased with $Fe_2O_3$ mixing powder ratio but the shrinkage and porosity of Fe foams were decreased with $Fe_2O_3$ mixing powder ratio.

Changes in Cement Hydrate Characteristics and Chloride Diffusivity in High Performance Concrete with Ages (재령에 따른 고성능 콘크리트의 수화 특성치와 염화물 확산성 변화)

  • Koh, Tae-Ho;Kwon, Seung-Jun
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.23 no.6
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    • pp.9-17
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    • 2019
  • Cement hydrates and the related characteristics change with ages, and the behaviors are much related with chloride diffusion. In this work, 30% replacement ratio with FA(Fly Ash) and GGBFS(Ground Granulated Blast Furnace Slag) are considered for concrete with three levels of W/B (Water to Binder ratio) and 2 years of curing period. Chloride diffusion coefficients from accelerated condition are obtained at 5 measurement period (28days, 56days, 180days, 365days, and 730days), and the results are compared with porosity, binding capacity, and permeability from program-DUCOM. The similar changing pattern between chloride diffusion and permeability is observed since permeability is proportional to the square of porosity. Curing period is grouped into 4 periods and the changing ratios are investigated. Cement hydrate characteristics such as porosity, permeability, and diffusion coefficient are dominantly changed at the early ages (28~56 days), and diffusion coefficient in OPC concrete with low W/B continuously changes to 180days.

A Passive Control of Interaction of Condensation Shock Wave anc Boundary Layer(I) (응축충격파와 경계층 간섭의 피동제어(I))

  • Choe, Yeong-Sang;Jeong, Yeong-Jun;Gwon, Sun-Beom
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.21 no.2
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    • pp.316-328
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    • 1997
  • There were appreciable progresses on the study of shock wave / boundary layer interaction control in the transonic flow without nonequilibrium condensation. But in general, the actual flows associated with those of the airfoil of high speed flight body, the cascade of steam turbine and so on accompany the nonequilibrium condensation, and under a certain circumstance condensation shock wave occurs. Condensation shock wave / boundary layer interaction control is quite different from that of case without condensation, because the droplets generated by the result of nonequilibrium condensation may clog the holes of the porous wall for passive control and the flow interaction mechanism between the droplets and the porous system is concerned in the flow with nonequilibrium condensation. In these connections, it is necessary to study the condensation shock wave / boundary layer interaction control by passive cavity in the flow accompanying nonequilibrium condensation with condensation shock wave. In the present study, experiments were made on a roof mounted half circular arc in an indraft type supersonic wind tunnel to evaluate the effects of the porosity, the porous wall area and the depth of cavity on the pressure distribution around condensation shock wave. It was found that the porosity of 12% which was larger than the case of without nonequilibrium condensation produced the largest reduction of pressure fluctuations in the vicinity of condensation shock wave. The results also showed that wider porous area, deeper cavity for the same porosity of 12% are more favourable "passive" effect than the cases of its opposite. opposite.

Response of anisotropic porous layered media with uncertain soil parameters to shear body-and Love-waves

  • Sadouki, Amina;Harichane, Zamila;Elachachi, Sidi Mohammed;Erken, Ayfer
    • Earthquakes and Structures
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    • v.14 no.4
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    • pp.313-322
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    • 2018
  • The present study is dedicated to investigate the SH body-as well as Love-waves propagation effects in porous media with uncertain porosity and permeability. A unified formulation of the governing equations for one-dimensional (1-D) wave propagation in anisotropic porous layered media is presented deterministically. The uncertainties around the above two cited parameters are taken into account by random fields with the help of Monte Carlo Simulations (MCS). Random samples of the porosity and the permeability are generated according to the normal and lognormal distribution functions, respectively, with a mean value and a coefficient of variation for each one of the two parameters. After performing several thousands of samples, the mathematical expectation (mean) of the solution of the wave propagation equations in terms of amplification functions for SH waves and in terms of dispersion equation for Love-waves are obtained. The limits of the Love wave velocity in a porous soil layer overlaying a homogeneous half-space are obtained where it is found that random variations of porosity change the zeros of the wave equation. Also, the increase of uncertainties in the porosity (high coefficient of variation) decreases the mean amplification function amplitudes and shifts the fundamental frequencies. However, no effects are observed on both Love wave dispersion and amplification function for random variations of permeability. Lastly, the present approach is applied to a case study in the Adapazari town basin so that to estimate ground motion accelerations lacked in the fast-growing during the main shock of the damaging 1999 Kocaeli earthquake.

The Effect of Free Silica on the Strength of Chamotte Refractory (Chamotte질 내화물의 강도에 미치는 유이 Silica의 영향)

  • 박금철;최영섭
    • Journal of the Korean Ceramic Society
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    • v.13 no.1
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    • pp.35-44
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    • 1976
  • The effect of quartz which exists in clays, especially in kaolin used for the production of chamotte sagger, on the strength of refractory was examined. In this study, a mixture of chamotte 50%, kaolin 25%, plastic clay 25% in ternary component system was selected as a batch composition. To this mixture 1%, 3% and 5% of feldspar and sericite were added respectively. The plastic clay used here was separated under 170 mesh by dry process. Feldspar and sericite were separated under 325 mesh by dry process. Feldspar and sericite were separated under 325 mesh by dry process. In order to change the particle size and the content of quartz, the kaolin was separated under 60, 115, 170 and 325 mesh by wet process, substituted quartz for coarse parts of it. Chamotte was classified into three grades, coarse (5-10mesh): medium (10-20mesh): fine(20-115mesh) and the ratio was 1:1:1. Samples were formed in 0.8xIx10cm size with 12.5% water at 160kg/$\textrm{cm}^2$ pressure, and fired at 130$0^{\circ}C$ for 1 hr. The fired samples were ivnestigated by means of x-ray diffraction analysis and microscopic observation, and the physical properties of them were also examined, such as firing shrinkage, apparent specific gravity and bulk specific gravity, apparent porosity, water absorption and modulus of rupture. The obtained results are as follows: 1. When screened kaolin with low content of quartz was added to fixed chamotte-plastic clay system, the sample lowered modulus of rupture and increased apparent porosity as the size of kaolin became finer. 2. When kaolin under 325 mesh with 7.2-15.81% quartz between 60-325 mesh was added to fixed chamotte-plastic clay system, the sample had higher apparent porosity and lower modulus of ruputure as the size and the amount of quartz became larger. 3. The addition of feldspar and sericite to chamotte-plastic clay system improved apparent porosity and modulus of rupture. The effect of feldspar was better when quartz content was low, although that of sericite was better than quartz content was high.

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Analysis of wave propagation and free vibration of functionally graded porous material beam with a novel four variable refined theory

  • Ayache, Belqassim;Bennai, Riadh;Fahsi, Bouazza;Fourn, Hocine;Atmane, Hassen Ait;Tounsi, Abdelouahed
    • Earthquakes and Structures
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    • v.15 no.4
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    • pp.369-382
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    • 2018
  • A free vibration analysis and wave propagation of functionally graded porous beams has been presented in this work using a high order hyperbolic shear deformation theory. Unlike other conventional shear deformation theories, a new displacement field that introduces indeterminate integral variables has been used to minimize the number of unknowns. The constituent materials of the beam are assumed gradually variable along the direction of height according to a simple power law distribution in terms of the volume fractions of the constituents. The variation of the pores in the direction of the thickness influences the mechanical properties. It is therefore necessary to predict the effect of porosity on vibratory behavior and wave velocity of FG beams in this study. A new function of the porosity factor has been developed. Hamilton's principle is used for the development of wave propagation equations in the functionally graded beam. The analytical dispersion relationship of the FG beam is obtained by solving an eigenvalue problem. Illustrative numerical examples are given to show the effects of volume fraction distributions, beam height, wave number, and porosity on free vibration and wave propagation in a functionally graded beam.

Simplified Carbonation Model Considering Ca(OH)2 Solubility and Porosity Reduction (수산화칼슘 용해도와 공극률 감소를 고려한 간략화 된 탄산화 모델)

  • Lee, Yun;Kwon, Seung-Jun;Park, Ki-Tae
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.19 no.1
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    • pp.128-138
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    • 2015
  • Carbonation is one of the most critical deterioration phenomena to concrete structures exposed to high $CO_2$ concentration, sheltered from rain. Lots of researches have been performed on evaluation of carbonation depth and changes in hydrate compositions, however carbonation modeling is limitedly carried out due to complicated carbonic reaction and diffusion coefficient. This study presents a simplified carbonation model considering diffusion coefficient, solubility of $Ca(OH)_2$, porosity reduction, and carbonic reaction rate for low concentration. For verification, accelerated carbonation test with varying temperature and MIP (Mercury Intrusion Porosimetry) test are carried out, and carbonation depths are compared with those from the previous and the proposed model. Field data with low $CO_2$ concentration is compared with those from the proposed model. The proposed model shows very reasonable results like carbonation depth and consuming $Ca(OH)_2$ through reduced diffusion coefficient and porosity compared with the previous model.

Ultrasonic Nondestructive Evaluation of Creep-Induced Cavities (크리프 기공의 초음파 비파괴평가에 관한 연구)

  • Jang, Young-Su;Jeong, Hyun-Jo
    • Journal of the Korean Society for Nondestructive Testing
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    • v.19 no.2
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    • pp.110-117
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    • 1999
  • In order to ultrasonically evaluate creep cavities pure copper samples were subjected to creep test and their microstructures were examined. Ultrasonic velocities. frequency-dependent magnitude spectra and attenuations were measured on a series of copper samples obtained from the different stages of creep test. Velocities measured in three directions with respect to the loading axis decreased and their anisotropy increased as a function of the creep-induced porosity. The anisotropic behavior could be attributed to the progressive change of pore shape and preferred orientation as the creep advanced. The 2% porosity by volume decreased the longitudinal and shear wave velocities by 11% and 4%, respectively. Furthermore, both velocities decreased nonlinearly with the porosity. As the creep damage developed, the magnitude spectra lost high frequency components and their central frequencies shifted to lower values. The attenuation showed almost linear behavior in the frequency range used. Normalized velocity, central frequency shift and attenuation slope were selected as nondestructive evaluation parameters. These results were presented and showed good relations with the porosity content.

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