• 제목/요약/키워드: high corrosion resistance

검색결과 1,075건 처리시간 0.028초

2방향 슬래브의 펀칭전단성능 향상을 위한 고성능 철근의 적용 (Application of High-Performance Steels to Enhance the Punching Shear Capacity of Two-Way Slabs)

  • 양준모;신현오;이주하;윤영수
    • 한국구조물진단유지관리공학회 논문집
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    • 제15권2호
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    • pp.161-169
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    • 2011
  • 본 연구에서는, 철근 밀집 감소, 노무비 및 보수 보강비 절약, 향상된 부식 저항성, 공기 단축 등의 장점을 가지고 있는 고성능 철근으로 휨 보강된 이방향 슬래브를 제작하고 구조실험을 실시하였다. 상부 휨철근비, 기둥 인접부 휨철근의 집중배근, 강섬유 보강 콘크리트의 타설을 변수로 하여 실험하였고, 펀칭 전단강도 및 균열후 강성을 일반 철근 및 GFRP bar로 휨 보강된 슬래브의 펀칭 전단실험 결과와 비교하였다. 또한, 휨철근의 변형률 분포 및 균열제어 효과 등을 비교, 분석하였고, 휨철근비 계산을 위한 유효폭 산정 방법을 검토하였다. 고성능 철근의 사용으로 펀칭 전단강도가 향상되었고, 휨 철근량을 감소시킬 수 있었다. 기둥 인접부 휨철근의 집중배근을 통해 철근비의 감소 때문에 작아진 강성을 회복시킬 수 있었고, 훌륭한 변형률 분포 및 균열제어 효과를 나타내었다. 또한, 기둥 인접부에 대한 강섬유 보강 콘크리트의 타설은 펀칭 전단강도의 증가와 균열 제어에 탁월한 효과를 보였다. 휨철근비 산정을 위한 유효폭은 기둥면으로부터 슬래브 두께의 2배 이상으로 확대하는 것이 합리적이라 판단된다.

SiCf/SiC 복합체 보호막 금속피복관의 열충격 거동 분석 (Analysis of Thermal Shock Behavior of Cladding with SiCf/SiC Composite Protective Films)

  • 이동희;김원주;박지연;김대종;이현근;박광헌
    • Composites Research
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    • 제29권1호
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    • pp.40-44
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    • 2016
  • 원자력발전소에서 사용되고 있는 핵연료 피복관은 핵분열 생성물들의 외부 유출을 방지하기 위해 고온 고압의 냉각수 분위기에서 우수한 산화저항성을 가져야 한다. 그러나 후쿠시마 원전사고의 LOCA(Loss-Of-Coolant-Accident)와 같은 중대사고에서 핵연료의 피복관과 수증기 사이의 격렬한 반응으로 인해 급격한 고온산화를 동반한 다량의 수소발생으로 수소폭발을 방지하기 위한 핵연료의 개발이 요구되고 있다. 이에 따라 핵연료 피복관의 안전성 향상을 위해 내방사선성이 우수하며 높은 강도와 산화, 부식에 대한 내화학적 안정성 및 우수한 열전도도 의 특성을 갖는 SiC와 같은 구조용 세라믹스가 활발히 연구되고 있다. $SiC_f/SiC$ 복합체 보호막 금속 피복관은 지르코늄 피복관 튜브에 SiC 섬유를 필라멘트 와인딩 한 후 Polycarbosilane을 polymer로 함침하여 기지상을 형성하는 공정을 이용하였다. 따라서 이렇게 제조한 $SiC_f/SiC$ 복합체 금속 피복관을 Drop Tube Furnace를 이용한 열충격에 따른 시편의 산화 및 미세조직을 분석하였다.

물질전과정평가(MLCA)를 통한 TiN-Zr 수소분리막의 환경성 평가 (Evaluation of TiN-Zr Hydrogen Permeation Membrane by MLCA (Material Life Cycle Assessment))

  • 김민겸;손종태;홍태환
    • 청정기술
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    • 제24권1호
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    • pp.9-14
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    • 2018
  • 본 연구에서는 TiN-Zr 수소분리막의 제조 공정에 대한 환경 영향 특성을 분석하기 위해 물질전과정평가를 수행하였다. Material Life Cycle Assessment (MLCA)의 소프트웨어로는 Gabi를 사용하였다. 이를 통하여 각 공정에서 미치는 영향과 특성화 별 환경영향평가를 수행하였다. 졸겔법에 의해 전구체 TiN을 합성하고 볼밀법을 이용하여 지르코늄을 코팅하였다. 이를 CIP, HPS에 의해 디스크 형으로 제작하였고 주사전자현미경(scanning electron microscopy, SEM), 에너지분산형 분광분석법(energy dispersive X-ray spectroscopy, EDS), X-선 회절분석기(X-ray diffraction, XRD), 열중량분석(thermo gravimetry/differential thermal analysis, TG/DTA), 비표면적분석(Brunauer, Emmett, Teller, BET) 및 가스 크로마토그래프 시스템(gas chromatograph system, GP)을 이용하여 분리막의 야금학적, 물리학적, 열역학적 특성을 분석하였다. 또한, 물질전과정평가를 위해 수행한 특성화와 정규화 결과, 영향범주 별 환경영향은 해양 생태 독성이 94%, 수계 생태 독성 2%, 인간독성 2%의 기여도를 보였다. 아울러, 제조공정 중 전기 사용이 생태계 영향에 큰 영향을 미친다는 것을 알 수 있었다. 물질 전 과정 평가는 Eco-Indicator '99 (EI99)와 CML 2001 방법론을 기반으로 분석하였다.

증해추출 왕겨분말을 혼입한 지오폴리머의 황산마그네슘 저항성에 관한 연구 (Magnesium Sulfate Resistance of Geopolymer Incorporating Evaporated Rice Husk Powder)

  • 조승비;김영수
    • 한국건축시공학회지
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    • 제22권6호
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    • pp.663-672
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    • 2022
  • 왕겨분말 혼입 지오폴리머의 황산마그네슘 저항성을 평가하기 위해, 비교대상으로 보통 콘크리트, 실리카 흄 혼입 콘크리트, 플라이애시와 고로슬래그를 혼입한 2성분계 지오폴리머를 비교대상으로 선정하여 황산마그네슘 용액침지시험을 실시하였다. 재령별 압축강도를 이용하여 산출한 황산염 열화지수는 황산마그네슘 용액 침지재령 56일에서 보통 콘크리트의 경우 6.75%이었으나, 왕겨분말 혼입 지오폴리머의 경우 모든 시편에서 1.28~1.87%의 낮은 수준을 보였다. 이는 실리카 흄 혼입 콘크리트의 2.48%보다 낮게 나타나 왕겨분말이 황산마그네슘 침식 저항성에 큰 도움이 되는 것으로 판단된다. 또한, 콘크리트 내부 미세균열과 외부열화에 대한 평가를 위해 시험체의 중량변화율의 경우 황산마그네슘 용액 침지재령28일 이후부터 모든 시험체에서 중량이 크게 변화하였으며, 침지재령 56일에서 보통 콘크리트는 3.78%로써 황산마그네슘에 의한 열화가 가장 심각한 수준임을 알 수 있었다. 그러나, 왕겨분말 혼입 지오폴리머의 경우 0.9~1.45%의 작은 중량변화율을 보였다. 지오폴리머 내의 에트린자이트 생성 정도를 X선 회절 분석법을 통하여 확인하였으며, 왕겨분말 혼입 지오폴리머에서는 소량으로 생성되어 있는 것을 확인할 수 있어, 황산마그네슘 침식 저항성에 높은 상관성이 있음을 알 수 있었다.

하이브리드 Ti2AlC 세라믹 소결체의 재료특성 및 Micro-EDM 유용성 연구 (Micro-EDM Feasibility and Material Properties of Hybrid Ti2AlC Ceramic Bulk Materials)

  • 정국현;김광호;강명창
    • 한국분말재료학회지
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    • 제21권4호
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    • pp.301-306
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    • 2014
  • Titanium alloys are extensively used in high-temperature applications due to their excellent high strength and corrosion resistance properties. However, titanium alloys are problematic because they tend to be extremely difficult-to-cut material. In this paper, the powder synthesis, spark plasma sintering (SPS), bulk material characteristics and machinability test of hybrid $Ti_2AlC$ ceramic bulk materials were systematically examined. The bulk samples mainly consisted of $Ti_2AlC$ materials with density close to theoretical value were synthesized by a SPS method. Random orientation and good crystallization of the $Ti_2AlC$ was observed at $1100^{\circ}C$ for 10 min under SPS sintering conditions. Scanning electron microscopy results indicated a homogeneous distribution and nano-laminated structure of $Ti_2AlC$ MAX phase. The hardness and electrical conductivity of $Ti_2AlC$ were higher than that of Ti 6242 alloy at sintering temperature of $1000^{\circ}C{\sim}1100^{\circ}C$. Consequently, the machinability of the hybrid $Ti_2AlC$ bulk materials is better than that of the Ti 6242 alloy for micro-EDM process of micro-hole shape workpiece.

주조 형상기억 니켈-티타늄 합금의 초탄성 (SUPERELASTICITY OF CAST SHAPE MEMORY Ni-Ti ALLOY)

  • 최동익;최목균
    • 대한심미치과학회지
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    • 제3권1호
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    • pp.32-43
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    • 1995
  • Ni-Ti alloy has excellent corrosion resistance, biocompatibility, shape memory effect and superelasticity, so it has been used widely in biomedical fields. But it has difficulty in casting due to its high melting temperature and oxygen affinity at high temperature. Recently it has been attempted to cast Ni-Ti alloy using new casting machine and investment. The purpose of this study was to examine the superelastic behavior of cast shape memory Ni-Ti alloy and to compare the mechanical properties of the cast shape memory alloy with those of commercial alloys for removable partial denture framework. Ni-Ti alloy(Ni 50.25%, Ti 49.75% : atomic ratio) was cast with dental argon-arc pressure casting machine and Type IV gold alloy, Co-Cr alloy, Ni-Cr alloy, pure titanium were cast as reference. Experimental cast Ni-Ti alloy was treated with heat($500{\pm}2^{\circ}C$) in muffle furnace for 1 hour. Transformation temperature range of cast Ni-Ti alloy was measured with differential scanning calorimetry. The superelastic behavior and mechanical properties of cat Ni-Ti alloy were observed and evaluated by three point bending test, ultimate tensile test, Vickers microhardness test and scanning electron microscope. The results were as follows : 1. Cast Ni-Ti alloy(Ni 50.25%, Ti 49.75% : atomic ratio) was found to have superelastic behavior. 2. Stiffness of cast Ni-Ti alloy was considerably lesser than that of commercial alloys for removable partial denture. 3. Permanent deformation was observed in commercial alloys for removable partial denture framework at three point bending test over proportional limit(1.5mm deflection), but was not nearly observed in cast Ni-Ti alloy. 4. On the mechanical properties of ultimate tensile strength, elongation and Vickers microhardness number, cast Ni-Ti alloy was similiar to Type IV gold alloy, Co-Cr alloy, Ni-Cr alloy and pure titanium. With these results, cast Ni-Ti alloy had superelastic behavior and low stiffness. Therefore, it is suggested that cast Ni-Ti alloy may be applicated to base metal alloy for removable partial denture framework.

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Nd:YAG 레이저빔을 이용한 SCP 강판과 STS304강판 용접시 오프셋(off-set) 위치 결정에 관한 연구 (A study of the determination of off-set position for Nd:YAC laser welding between SCP steel sheet and STS304 sheet)

  • 윤부선;김도훈;박기영;이경돈
    • 한국레이저가공학회지
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    • 제7권2호
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    • pp.1-10
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    • 2004
  • This work was attempted to join SCP sheet and STS304 sheet by using Nd:YAC laser beam. SCP sheet has good formability and low cost, while STS304 has excellent corrosion resistance and mechanical properties in high temp. In this experiment, butt joint type was used to develop the tailored blank welding for dissimilar steel. Sheets which have different thermal properties. Computer simulation was conducted to obtain the off-set position for efficient welding by considering laser power, scanning speed, focal length and basic properties. The result showed that the optimum thermal distribution was obtained when the laser beam was irradiated at $0.05{\sim}0.1$ mm off-set toward the SCP sheet side. The experiment was conducted based on the result of computer simulation to show the same optimum conditions. Optimum conditions were 3KW in laser beam power, 6m/min in scanning speed, -0.5mm in focal position, 0.1mm off-set toward SCP. Microhardness test, tensile test, bulge test, optical microscopy, EDS, and XRD were performed to observe the microstructure around fusion zone and to evaluate the mechanical properties of optimum conditions, The weld zone had high microhardness values by the formation of the martensitic structure. Tensile test measured the strength of welded region by vertical to strain direction and the elongation of welded region by parallel to strain direction. Bulge test showed $52\%$ formability of the original materials. Bead shape, grain size, and martensitic structure were observed by the optical microscopy in the weld zone. Detailed results of EDS, XRD confirmed that the welded region was connected of martensitic structure.

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주철 - 알루미늄 합금의 Hot Dip Aluminizing시 흑연 및 금속간화합물 층의 형성 거동 (Behavior of Graphite and Formation of Intermetallic Compound Layer in Hot Dip Aluminizing of Cast Iron)

  • 한광식;강용주;강문석;강성민;김진수;손광석;김동규
    • 한국주조공학회지
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    • 제31권2호
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    • pp.66-70
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    • 2011
  • Hot dip aluminizing (HDA) is widely used in industry for improving corrosion resistance of material. The formation of intermetallic compound layers during the contact between dissimilar materials at high temperature is common phenomenon. Generally, intermetallic compound layers of $Fe_2Al_5$ and $FeAl_3$ are formed at the Al alloy and Fe substrate interface. In case of cast iron, high contact angle of graphite existed in the matrix inhibits the formation of intermetallic compound layer, which carry with it the disadvantage of a reduced reaction area and mechanical properties. In present work, the process for the removal of graphite existed on the surface of specimen has been investigated. And also HDA was proceeded at $800^{\circ}C$ for 3 minutes in aluminum alloy melt. The efficiency of graphite removal was increased with the reduction of particle size in sanding process. Graphite appears to be present both in the region of melting followed by re-solidification and in the intermetallic compound layer, which could be attributed to the fact that the surface of cast iron is melted down by the formation of low melting point phase with the diffusion of Al and Si to the cast iron. Intermetallic compound layer consisted of $Fe(Al,Si)_3$ and $Fe_2Al_5Si$, the layer formed at cast iron side contained lower amount of Si.

하중저항계수설계법 및 정밀해법에 의한 PFRP I형 단면 압축재의 국부좌굴강도 (Local Buckling Strength of PFRP I-Shape Compression Members Obtained by LRFD Design Method and Closed-Form Solution)

  • 최진우;서수홍;주형중;윤순종
    • 복합신소재구조학회 논문집
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    • 제5권2호
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    • pp.1-8
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    • 2014
  • Fiber reinforced polymeric plastic (FRP) materials have many advantages over conventional structural materials, i.e., high specific strength and stiffness, high corrosion resistance, right weight, etc. Among the various manufacturing methods, pultrusion process is one of the best choices for the mass production of structural plastic members. Since the major reinforcing fibers are placed along the axial direction of the member, this material is usually considered as an orthotropic material. However, pultruded FRP (PFRP) structural members have low modulus of elasticity and are composed of orthotropic thin plate components the members are prone to buckle. Therefore, stability is an important issue in the design of the pultruded FRP structural members. Many researchers have conducted related studies to publish the design method of FRP structures and recently, referred to the previous researches, pre-standard for LRFD of pultruded FRP structures is presented. In this paper, the accuracy and suitability of design equation for the local buckling strength of pultruded FRP I-shape compression members presented by ASCE are estimated. In the estimation, we compared the results obtained by design equation, closed-form solution, and experiments conducted by previous researches.

Compressive behavior of galvanized steel wire mesh (GSWM) strengthened RC short column of varying shapes

  • Marthong, Comingstarful
    • Structural Monitoring and Maintenance
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    • 제7권3호
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    • pp.215-231
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    • 2020
  • In a reinforced concrete building different shapes of column are adopted depending on the structural orientation and the architectural aspect. When there is an increase in loading due to changes in usage or revision in the design codes these columns need to be strengthened for enhanced performance during their service life. Strengthening materials such as carbon fiber and glass fiber polymer has been successfully used however, due to high cost application other alternative materials need to be explore. Galvanized steel wire mesh (GSWM) is one of the suitable materials locally available. High tensile strength, low weight, corrosion resistance, easy installation, minimum change in dimensions of the sections and cost effectives are the advantages of GSWM. Therefore, in this paper, four different shapes of column such as circular, square, rectangular and L were wrapped with different layers GSWM and jacketed with mortar. All the specimens were tested under axial compression. The objective of the study is to investigate the effectiveness of GSWM as a confining material for strengthening of column having varying shape. Test results shows that the axial strength enhanced with wrapping of GSWM jacket and a circular column presented the highest load carrying capacity and ductility as compared to the others. From the study of 22 column specimens, it is found that axial load is increased upto 20% and 19% when circular and square column are strengthened with one wrap of GSWM respectively, while a rectangular and L column required a wraps of two and three layers respectively in order to achieved the same load capacity as that of a circular column. Based on the present study, it is concluded that GSWM can be effectively used for strengthening of different shapes of concrete columns economically.