• Title/Summary/Keyword: high conductivity

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Development of Multiple Layers Insulation for SOFC (SOFC를 위한 고온용 적층단열재 개발)

  • CHOI, CHONGGUN;HWANG, SEUNG-SIK;CHOI, GYU-HONG
    • Transactions of the Korean hydrogen and new energy society
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    • v.29 no.4
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    • pp.386-392
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    • 2018
  • Fuel cells are known as eco - friendly energy facilities that can use heat energy and electric energy at the same time. Fuel cells are classified according to the temperature and material used, and solid oxide fuel cell (SOFC) is relatively high temperature ($700-800^{\circ}C$). SOFC requires a hot box consisting of a high temperature stack, a reformer, a burner, and the heat exchangers in order to use energy efficiently. The hot box needs to maintain heat insulation performance at high temperature to reduce heat loss. However, Fibrous insulation, which is widely used, needs to be improved because it has a disadvantage that the thermal conductivity is rapidly increased due to the increase of temperature. Therefore, this study was carried out to develop a thermal insulation, which is applied to multiple layers insulation (MLI) technic, that can be used under SOFC operating conditions and prevent a drastic drop in thermal conductivity at high temperature. The developed insulation is consist of a thermally conductive material, a spacer, and a reflective plate. The thermal conductivity of the insulation was measured by in the thermal conductivity measuring device at high temperature range. As a result, it was confirmed that the developed layers insulation have an good thermal conductivity (0.116 W/mK) than fibrous insulation (0.24 W/mK) as a radiation shielding effect at a high temperature of 1,173 K.

A Study on Transparent Polymer Composite Films with High Emissivity (고 열방사 투명 고분자 합성막 연구)

  • Kim, Jeong-Hwan;Shin, Dong-Kyun;Seo, Hwa-Il;Park, Jong-Woon
    • Journal of the Semiconductor & Display Technology
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    • v.12 no.1
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    • pp.29-33
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    • 2013
  • We have fabricated transparent polymer composite films with high thermal emissivity, which can be used for heat dissipation of transparent electronics. PMMA (poly(methyl methacrylate)) solution with high transparency and thermal emissivity is mixed with various fillers (carbon nanotubes (CNTs), aluminum nitride (AlN), or silicon carbide (SiC)) with high thermal conductivity. We have achieved the thermal emissivity as high as 0.94 by the addition of CNTs. Compared with the PMMA film on glass, however, the addition of AlN or SiC is shown to rather decrease the thermal emissivity. It is also observed that the thickness of the PMMA film does not affect its thermal emissivity. To avoid any degradation of the thermal conductivity, therefore, the PMMA film thickness is desirable to be $1{\mu}m$. There also exists a tradeoff between the optical transmittance and thermal conductivity on the selection of the amount of fillers.

Properties and Casting Capabilities of Al-Fe-Zn-Cu Alloys for High Conductivity Parts (고전도성 부품용 Al-Fe-Zn-Cu합금의 물성 및 주조성)

  • Yun, Ho-Seob;Kim, Jeong-Min;Park, Joon-Sik;Kim, Ki-Tae;Ko, Se-Hyun
    • Journal of Korea Foundry Society
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    • v.33 no.6
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    • pp.242-247
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    • 2013
  • The most widely utilized commercial, aluminum-casting alloys are based on an aluminum-silicon system due to its excellent casting, and good mechanical, properties. Unfortunately, these Al-Si based alloys are inherently poor energy conductors; compared to pure aluminum, because of their high silicon content. This means that they are not suitable for applications demanding high eletrical or thermal conductivity. Therefore, efforts are currently being made to develop new, highly-conductive aluminum-casting alloys containing no silicon. In this research, a number of properties; including potential for castability, were investigated for a number of Al-Fe-Zn-Cu alloys with varying Cu content. As the copper content was increased, the tensile strength of Al-Fe-Zn-Cu alloy tended to increase gradually, while the electrical conductivity was slightly reduced. Fluidity was found to be lower in high-Cu alloys, and susceptibility to hot-cracking was generally high in all the alloys investigated.

Development of PolymerElectrolytes Based on Ionic Liquids forHigh Temperature/Low Humidity PEFC Applications (고온/저가습 고분자전해질 연료전지를 위한 이온성 액체 기반 고분자 전해질막 개발)

  • Sekhon, Satpal Singh;Park, Jin-Soo;Cho, Eun-Kyung;Park, Gu-Gon;Kim, Chang-Soo;Lee, Won-Yong
    • 한국신재생에너지학회:학술대회논문집
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    • 2008.10a
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    • pp.40-43
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    • 2008
  • High temperature polymer electrolyte membranes incorporating ionic liquids (ILs) in different polymers such as commercial fluorinated polymers, sulfonated polymers and recasted nafion have been developed. ILs based on imidazolium cation and different anions possess high ionic conductivity and good thermal stability and have been used in the present study. The membranes containing IL show conductivity ${\sim}10^{-2}S\;cm^{-1}$ above $100^{\circ}C$ under anhydrous conditions and are thermally stable up to $250-300^{\circ}C$. IL acts as a conducting medium in these electrolytes and plays the same role as played by water in fully hydrated nafion membranes. Due to high conductivity and good thermal stability, these membranes are promising materials for PEFCs at higher temperatures under anhydrous conditions.

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Evaluation of Thermal Diffusivity and Electrochemical Properties of LiAlH4-PVDF Electrolyte Composites (LiAlH4-PVDF 전해질 복합체의 열확산 및 전기화학적 특성평가)

  • HWANG, JUNE-HYEON;HONG, TAE-WHAN
    • Transactions of the Korean hydrogen and new energy society
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    • v.33 no.5
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    • pp.574-582
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    • 2022
  • A lithium-ion battery exhibits high energy density but has many limitations due to safety issues. Currently, as a solution for this, research on solid state batteries is attracting attention and is actively being conducted. Among the solid electrolytes, sulfide-based solid electrolytes are receiving much attention with high ion conductivity, but there is a limit to commercialization due to the relatively high price of lithium sulfide, which is a precursor material. This study focused on the possibility of relatively inexpensive and light lithium hydride and conducted an experiment on it. In order to analyze the characteristics of LiAlH4, ion conductivity and thermal stability were measured, and a composites mixed with PVDF, a representative polymer electrolyte, was synthesized to confirm a change in characteristics. And metallurgical changes in the material were performed through XRD, SEM, and BET analysis, and ion conductivity and thermal stability were measured by EIS and LFA methods. As a result, Li3AlH6 having ion conductivity higher than LiAlH4 is formed by the synthesis of composite materials, and thus ion conductivity is slightly improved, but thermal stability is rapidly degraded due to structural irregularity.

Thermal conductivity and viscosity of graphite-added bentonite grout for backfilling ground heat exchanger (지중 열교환기용 뒤채움재로서 흑연을 첨가한 벤토나이트 그라우트재의 열전도도 및 점도 특성)

  • Lee, Chul-Ho;Lee, Kang-Ja;Choi, Hang-Seok;Choi, Hyo-Pum
    • Journal of the Korean Society for Geothermal and Hydrothermal Energy
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    • v.5 no.1
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    • pp.19-24
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    • 2009
  • Bentonite-based grouting has been usually used for sealing a borehole installed for a closed-loop vertical ground heat exchanger in a geothermal heat pump system (GHP) because of its high swelling potential and low hydraulic conductivity. The bentonite-based grout, however, has relatively lower thermal conductivity than that of ground formation. Accordingly, it is common to add some additives such as silica sand into the bentonite-based grout for enhancing heat transfer. In this study, graphite is adapted to substitute silica sand as an addictive because graphite has very high thermal conductivity. The effect of graphite on the thermal conductivity of bentonite-based grouts has been quantitatively evaluated for seven bentonite grouts from different product sources. In addition, the viscosity of graphite-added bentonite grout was measured to evaluate the field pumpability of the grout.

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Study on physical characteristics of Graphite-added bentonite grout for backfilling closed-loop groud heat exchanger (수직 밀폐형 지중 열교환기용 뒤채움재로서 흑연(Graphite)을 첨가한 벤토나이트 그라우트재의 물리적 특성연구)

  • Lee, Kang-Ja;Gil, Hu-Jeong;Lee, Chul-Ho;Choi, Hang-Seok;Choi, Hyo-Pum
    • Proceedings of the Korean Geotechical Society Conference
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    • 2009.03a
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    • pp.179-187
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    • 2009
  • Bentonite-based grouting has been popularly used to seal a borehole installed for a closed-loop vertical ground heat exchanger in a geothermal heat pump system (GHP) because of its high swelling potential and low hydraulic conductivity. The bentonite-based grout, however, has relatively lower thermal conductivity than that of ground formation. Accordingly, it is common to add some additives such as silica sand to the bentonite-based grout for enhancing thermal performance. In this study, graphite is adapted to substitute silica sand as an addictive because graphite has very high thermal conductivity. The effect of graphite on the thermal conductivity of bentonite-based grouts has been quantitatively evaluated for seven bentonite grouts from different product sources. In addition, comparisons of viscosity between applications of graphite and silica sand as additives has been carried out. In conclusion, using graphite has thermal conductivity about three times higher than that of silica sand.

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Effects of Added Cr Element on the Tensile Strength and Electrical Conductivity of Cu-Fe Based Alloys (Cu-Fe계 합금의 강도 및 전기전도도에 미치는 Cr 원소첨가의 영향)

  • Kim, Dae-Hyun;Lee, Kwang-Hak
    • Korean Journal of Materials Research
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    • v.20 no.2
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    • pp.60-64
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    • 2010
  • This study looked at high performance copper-based alloys as LED lead frame materials with higher electrical-conductivity and the maintenance of superior tensile strength. This study investigated the effects on the tensile strength, electrical conductivity, thermal softening, size and distribution of the precipitation phases when Cr was added in Cu-Fe alloy in order to satisfy characteristics for LED Lead Frame material. Strips of the alloys were produced by casting and then properly treated to achieve a thickness of 0.25 mm by hot-rolling, scalping, and cold-rolling; mechanical properties such as tensile strength, hardness and electrical-conductivity were determined and compared. To determine precipitates in alloy that affect hardness and electrical-conductivity, electron microscope testing was also performed. Cr showed the effect of precipitation hardened with a $Cr_3Si$ precipitation phase. As a result of this experiment, appropriate aging temperature and time have been determined and we have developed a copper-based alloy with high tensile strength and electrical-conductivity. This alloy has the possibility for use as a substitution material for the LED Lead Frame of Cu alloy.

Study of Thermal Conductivity and Mechanical Property of Elastic Epoxy (탄성형 에폭시의 열전도율 및 기계적 특성에 대한 연구)

  • Lee, Kwan-Woo;Lee, Kyoung-Yong;Choi, Yong-Sung;Park, Bok-Ki;Park, Dae-Hee
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.11a
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    • pp.319-322
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    • 2004
  • In this paper, we studied on the thermal conductivity and a mechanical property of the elastic epoxy. According to industrial development, insulation materials have various properties. They are solid, liquid, gas state, there are various type. Epoxy, a kind of insulation material, demand of not only high hardness but also elastic property. When the electric current flows into the conductor and the place where the heat occurs, this heat becomes the cause which shortens the life of the electrical appliance. Therefore, for the heat occurred transmit quickly, thermal conductivity of the insulation material is highly demanded. We studied on the thermal conductivity of elastic epoxy on the high voltage. In this result, thermal conductivity confirmed that it followed thermal property of mixed epoxy and addictives. Hardness is decreased when addictives increased.

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Thick Graphene Embedded Metal Heat Spreader with Enhanced Thermal Conductivity

  • Park, Minsoo;Chun, Kukjin
    • Journal of Sensor Science and Technology
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    • v.23 no.4
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    • pp.234-237
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    • 2014
  • In this paper, a copper foil-thick grapheme (thin graphite sheet)-copper foil structure is reported to achieve mechanically strong and high thermal conductive layer suitable for heat spreading components. Since graphene provides much higher thermal conductivity than copper, thick graphene embedded copper layer can achieve higher effective thermal conductivity which is proportional to graphene/copper thickness ratio. Since copper is nonreactive with carbon material which is graphene, chromium is used as adhesion layer to achieve copper-thick graphene-copper bonding for graphene embedded copper layer. Both sides of thick graphene were coated with chromium as an adhesion layer followed by copper by sputtering. The copper foil was bonded to sputtered copper layer on thick graphene. Angstrom's method was used to measure the thermal conductivity of fabricated copper-thick graphene-copper structure. The thermal conductivity of the copper-thick graphene-copper structures is measured as $686W/m{\cdot}K$ which is 1.6 times higher than thermal conductivity of pure copper.