• Title/Summary/Keyword: hexagonal oxygen electrode

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Simultaneous measurement of oxygen permeability by using of multi-functional oxygen electrode (다기능 산소전극에 의한 산소투과특성 동시측정)

  • 이동희;정진휘;유형풍;김태진
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.07a
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    • pp.532-535
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    • 2000
  • We have fabricated a sensor system for on-line monitoring the oxygen permeability and diffusivity of six different polymer films using the miniaturized 6 cathode(Ag)-single anode(Ag/AgCl) type hexagonal oxygen electrode. This system consists of multiple input front-end electronics, signal conditioning circuit using the embedded microcontroller 80C196KC, PC interface circuit and PC with the OS for microcontroller and the operating program for this system. The digital low-[ass filter was programmed and the simulated filter characteristics were enough to eliminate the noise from sensor signal. According to the experimental results, the linearity coefficients of the output voltage to oxygen partial pressure for each sensor electrode of six cathode type oxygen sensor are 0.998, 0.997, 0.998, 0.997, 0.997, 0.997 respectively, and the response times are all within 4 minutes.

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A Study on the Apparatus for Measuring Oxygen-Permeability of Membranes with a Multi-Electrode Oxygen Sensor (다전극 산소 센서를 이용한 고분자 막의 산소 투과도 측정 장치 연구)

  • Jeong, Il-Son;Jung, Jae-Chil;Kim, Tai-Jin
    • Journal of Sensor Science and Technology
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    • v.21 no.3
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    • pp.229-234
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    • 2012
  • The existing permeability measurements based on pressure differential between the polymer membrane that is permeable to measure the amount of oxygen used, but these methods must be kept in a vacuum, and the measurement of the membrane with low permeability in the membrane is too time consuming. In recent years by using electrochemical method polymer membrane currents caused by the amount of oxygen is a measure of how much is used. In this study, apparatus consisting of one anode and six cathodes for multi-oxygen permeability tester used the same number of membranes produced by electrochemical oxygen permeation characteristics. In this study, one silver/silver chloride anode electrochemical method with a hexagonal sensor to put various kinds of polymer membranes with the six oxygen permeability for simultaneous measurement in real-time systems. Six cathodes (Pt), and one of the coil-shaped anode (Ag/AgCl) to form a hexagonal one of the polarographic oxygen sensor in a single measurement system by six sensors. Each sensor for making hexagonal specificity of the sensor to compensate for the conditions obtained in a pure nitrogen gas and pure oxygen gas conditions. With this study, self-developed hexagonal sensor capable of measuring sensors and oxygen permeability tester, for a multi-six different oxygen permeability characteristics of the membrane measured at the same time.

Synthesis and Electrochemical Properties of Li[Ni1/3Co1/3Mn1/3]O2 Nanowire by the Electrospinning Method (전기방사법을 이용한 Li[Ni1/3Co1/3Mn1/3]O2 나노 섬유의 합성 및 전기화학적 특성)

  • Kang, Chung-Soo;Son, Jong-Tae
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.24 no.10
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    • pp.850-854
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    • 2011
  • Nano-fibers of the $Li[Ni_{1/3}Co_{1/3}Mn_{1/3}]O_2$ electrode were synthesized from a metal oxide precursor using the electrospun method. The XRD patterns of all prepared powders showed a hexagonal ${\alpha}$ - $NaFeO_2$ structure (space group: R-3 m, 166). Scanning electron microscopy showed that all the synthesized samples were comprised of nanofibers with a size of 100~800 nm. Among the samples tested, the calcined $Li[Ni_{1/3}Co_{1/3}Mn_{1/3}]O_2$ nanowires in oxygen heating atmosphere showed a high charge and discharge capacity of 239.22 and 172.81 $mAhg^{-1}$ at the $1^{st}$ cycle, respectively. In addition, the charge transfer resistance was also improved significantly compared to the other samples.

Development of Biosensor for Simultaneous Determination of Glucose, Lactic Acid and Ethanol (포도당, 젖산 및 에탄올의 동시 측정용 바이오센서의 개발)

  • Kim, Jung-Ho;Rhie, Dong-Hee;Kim, Tae-Jin;Noh, Bong-Soo
    • Korean Journal of Food Science and Technology
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    • v.30 no.1
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    • pp.22-34
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    • 1998
  • The purpose of this study is to develop biosensor for determination of glucose, lactate, and ethanol in foods and food-stuffs simultaneously. The multiple cathode system was prepared with an oxygen electrode having one anode and hexagonal cathode. Glucose oxidase, mutarotase, lactate oxidase, alcohol oxidase and catalase were used for immobilization to determine glucose, lactate, and ethanol. These components including ethanol were simultaneously determined by the immobilized enzymes in the multiple cathode system. The determination of the components by enzyme sensor was based on the maximum slope of oxygen consumption from enzyme reaction of each sensor part. The response time for analysis was 1 min. The optimum condition for glucose, lactate and ethanol sensor was found to be 0.1 M potassium phosphate buffer, pH 7.0 at $40^{\circ}C$. Interferences of various sugars and organic acids were investigated. Less than 10% of error was found in determination of the components except organic acids. This difference was compensated by the modified equation. This system was confirmed by conventional methods. It was concluded that the multiple cathode system of this study is for an effective method to determine sugar, organic acid, ethanol simultaneously in foods.

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