• 한국신재생에너지학회:학술대회논문집
• /
• 한국신재생에너지학회 2009년도 추계학술대회 논문집
• /
• pp.231-231
• /
• 2009

In this work, we prepared the Ni-loaded porous SBA-15 (SBA-15) by a depositionprecipitation (D-P) method, in order to enhance the hydrogen storage capacity. The structure and morphology of the Ni/SBA-15 were characterized by X-ray diffraction (XRD) and field emission transmission electron microscopy (FE-TEM). The results showed that, at the Ni loading used at the DP times in the range of 0-120 min, SBA-15 preserved the well-ordered hexagonal porous arrangement. The textural properties of the Ni/SBA-15 were analyzed using N2 adsorption isotherms at 77 K. Specific surface area and mesopore volume of the samples were determined from the Brunauer-Emmett-Teller (BET) equation and Barrett-Joiner-Halenda (BJH) method, respectively. The hydrogen storage capacity of the Ni/SBA-15 was evaluated at 298 K/10 MPa. The hydrogen storage capacity of the Ni/SBA-15 was increased in accordance with Ni content. Consequently, it was found that the presence of Ni on mesoporous SBA-15 created hydrogen-favorable sites which enhanced the hydrogen storage capacity by spillover effect.

• Steel and Composite Structures
• /
• 제23권6호
• /
• pp.633-646
• /
• 2017

The compressive behavior of special-shaped concrete filled tube (CFT) mega column coupled with multiple cavities is studied by testing six columns subjected to cyclically uniaxial compressive load. The six columns include three pentagonal specimens and three hexagonal specimens. The influence of cavity construction, arrangement of reinforcement, concrete strength on failure feature, bearing capacity, stiffness, and residual deformation is examined. Experimental results show that cavity construction and reinforcements make it possible to form a combined confinement effect to in-filled concrete, and the two groups of special-shaped CFT columns show good elastic-plastic compressive behavior. As there is no axial bearing capacity calculation method currently available in any Code of practice for special-shaped CFT columns, values predicted by normal CFT column formulas in GB50936, CECS254, ACI-318, EC4, AISCI-LRFD, CECS159, and AIJ are compared with tested values. The calculated values are lower than the tested values for most columns, thus the predicted bearing capacity is safe. A reasonable calculation method by dividing concrete into active and inactive confined regions is proposed. And high accuracy shows in estimating special-shaped CFT columns either coupled with multiple cavities or not. In addition, a finite element method (FEM) analysis is conducted and the simulated results match the test well.

• 공업화학
• /
• 제16권6호
• /
• pp.737-741
• /
• 2005

본 연구에서는 제조한 MCM-41에 Cu의 함량에 따른 NO의 전환율을 고찰하였다. MCM-41은 실리카 원으로 colloid silica를 사용하였고, template로 cetyltrimethylammonium chloride (CTMACl)를 사용하여 수열 합성하였으며, Cu/MCM-41은 Cu(II) acetylacetonate를 사용해서 Cu의 농도를 5, 10, 20 그리고 40%로 변화시켜 제조하였다. 표면 특성은 pH, FT-IR로 분석하였고, 육방배열의 1차원 기공 구조는 XRD로 고찰하였다. $N_2/77K$ 등온흡착 특성은 BET식과 t-plot을 이용하여 확인하였으며, NO 제거 효율은 가스크로마토그래프를 이용하여 측정하였다. 실험 결과, Si-OH와 Si-O-Si의 stretching vibration peak가 관찰되었으며, (100), (110), (200) 그리고 (210)의 육방배열의 1차원 구조를 확인하였다. Cu 금속이 도입된 MCM-41은 Cu 도입량이 증가할수록 비표면적과 미세기공부피는 감소한 반면에 NO 제거 효율은 증가하였다. 결과적으로 Cu/MCM-41의 Cu의 함량이 증가함에 따라 전체 촉매작용 반응과 NO 제거율이 증가하였다.

• 한국진공학회:학술대회논문집
• /
• 한국진공학회 2015년도 제49회 하계 정기학술대회 초록집
• /
• pp.222.2-222.2
• /
• 2015

A $Ge_2Sb_2Te_5$ nanowire (GST NW) phase change memory device is investigated with Joule heating electrodes. GST is the most promising phase change materials, thus has been studied for decades but atomic structure transition in the phase-change area of single crystalline phase-change material has not been clearly investigated. We fabricated a phase change memory (PCM) device consisting of GST NWs connected with WN electrodes. The GST NW has switching performance with the reset/set resistance ratio above $10^3$. We directly observed the changes in atomic structure between the ordered hexagonal close packed (HCP) structure and disordered amorphous phase of a reset-stop GST NW with cross-sectional STEM analysis. Amorphous areas are detected at the center of NW and side areas adjacent to heating electrodes. Direct imaging of phase change area verified the atomic structure transition from the migration and disordering of Ge and Sb atoms. Even with the repeated phase transitions, periodic arrangement of Te atoms is not significantly changed, thus acting as a template for recrystallization. This result provides a novel understanding on the phase-change mechanism in single crystalline phase-change materials.

• 대한기계학회논문집A
• /
• 제30권3호
• /
• pp.260-268
• /
• 2006

The micromechanical approach was used to investigate the interfacial strain distributions of a unidirectional composite under transverse loading in which fibers were usually found to be randomly packed. Representative volume elements (RVE) for the analysis were composed of both regular fiber arrays such as a square array and a hexagonal array, and a random fiber array. The finite element analysis was performed to analyze the normal, tangential and shear strains at the interface. Due to the periodic characteristics of the strain distributions at the interface, the Fourier series approximation with proper coefficients was utilized to evaluate the strain distributions at the interface for the regular and random fiber arrays with respect to fiber volume fractions. From the analysis, it was found that the random arrangement of fibers had a significant influence on the strain distribution at the interface, and the strain distribution in the regular fiber arrays was one of special cases of that in the random fiber array.

• 한국재료학회지
• /
• 제13권9호
• /
• pp.593-597
• /
• 2003

Anodic aluminum oxide (AAO) membrane was made of aluminum sheet (99.6%, 0.2 mm thickness). The regular array of hexagonal nano pores or channels were prepared by two step anodization process. A detail description of the AAO fabrication is presented. After the 1st anodization in oxalic acid (0.3 M) at 45 V, The formed AAO was removed by etching in a solution of 6 wt% $H_3$$PO_4$＋1.8 wt% $H_2$$CrO_4$. The regular arrangement of the pores was obtained by the 2nd anodization, which was carried out in the same condition as the 1st anodization. Subsequently, the alumina barrier layer at the bottom of the channel layer was removed in phosphoric acid (1M) after removing of aluminum. Pore diameter, density, and thickness could be controlled by the anodization process parameters such as applied voltage, anodizing time, pore widening time, etc. The pore diameter is proportional to the applied voltage and pore widening time. The pore density and thickness can be controlled by anodization temperature and voltage.

• Transactions on Electrical and Electronic Materials
• /
• 제13권1호
• /
• pp.16-18
• /
• 2012

LED lighting systems that combine lighting capability, emotional and physiological characteristics are required for lighting source and multifunctional applications. In this work, Simulation studies using optical analysis software packages, Light Tools, are presented. This is done to estimate the uniformity ratio of illuminance and photosynthetic photon flux density (PPFD) of the periodic 2D lattice arrangements, such as square, diamond, two-way bias quadrangular, hexagonal, and Kagome lattices, under the same transmissivity, absorptance and reflectivity. It has been found out that the two-dimensional Kagome lattice arrangement exhibited high uniformity ratio of illuminance and PPFD compared to other lattices. Accordingly, these results can be used to guide a design and improve the lighting environment which in turn would maximize the uniform distributions of illuminance.

• Wind and Structures
• /
• 제38권3호
• /
• pp.203-214
• /
• 2024

Large-span cantilevered roof represents a unique type of structure that is vulnerable to wind loads. Inspired by the need to maximumly reducing the rooftop wind loads, this study examined the feasibility of positioning vented slots on the leading edge, and the effectiveness of such aerodynamic mitigation measures are assessed via both physical and numerical simulations. The reliability of numerical simulation was evaluated via comparisons with the wind tunnel tests. The results indicated that, the variation of venting hole arrangement can cause significant change in the rooftop wind load characteristics. For the cases involved in this study, the maximum reduction of mean and peak wind suction coefficients are found to be 9% and 8% as compared to the original circular slot without venting holes. In addition, the effect of slot shape is also evident. It was shown that the triangular shaped slot tends to increase the wind suction near the leading edge, whereas the hexagonal and octagonal shaped slots are found to decrease the wind suction. In particular, with the installation of octagonal shaped slot, the maximum reduction of wind suction coefficients near the leading edge reaches up to 31% as compared to the circular shaped slot, while the maximum reduction of mean wind suction coefficients is about 30%.

• 한국자기학회지
• /
• 제13권2호
• /
• pp.64-69
• /
• 2003

Si 기판 위에 $\alpha$-Fe$_2$O$_3$을 하지층으로 하는 Ba-ferrite 박막을 pulsed laser deposition system으로 제조하여 결정학적 및 자기적 성질을 X선 회절, SEM, Mossbauer 분광법 및 VSM을 사용하여 연구하였다. $\alpha$-Fe$_2$O$_3$박막은 Si 기판위에 PLD를 이용하여 기판온도 400 $^{\circ}C$, 산소압력 0.1 Torr로 5분간 증착 하였고 그 위에 두께를 달리하여 Ba-ferrite 박막을 제조하였다. Ba-ferrite 결정은 가늘고 긴 모양의 결정립들로 형성되었으며 두께에 따라 그 모양과 상태가 변화하였다. Mossbauer 분광법으로부터 Ba-ferrite 결정내의 Fe 원자의 스핀 방향은 두께가 얇을수록 하지층의 영향으로 기판에 수직으로 정렬하려는 경향을 보이고 있음을 확인하였다. 자기이력곡선의 각형비 역시 두께가 얇을수록 더 크며 이러한 특성은 수평에 비하여 수직의 경우가 더 강하게 나타났다. 보자력 역시 같은 경향을 보이나 포화자화의 값은 수평의 경우에 더 큰 값을 나타내었다. 결정구조는 Magnetoplumbite로서 두께가 작아질수록 결정상수 $\alpha$는 감소하고 c는 증가하는 경향을 보였다.

• Current Optics and Photonics
• /
• 제3권6호
• /
• pp.541-547
• /
• 2019

A novel photonic crystal fiber (PCF) sensor with three D-shaped holes based on surface plasmon resonance (SPR) is analyzed in this paper. Three D-shaped holes are filled with the analyte, and the gold film is deposited on the side of three planes. The design of D-shaped holes with outward expansion can effectively solve the uniformity problem of metallized nano-coating, it is beneficial to the filling of the analyte and is convenient for real-time measurement of the analyte. Compared with the hexagonal lattice structure, the triangular arrangement of the clad air holes can significantly reduce the transmission loss of light and improve the sensitivity of the sensor. The influences of the air hole diameter, the distance between D-shaped holes and core, and the counterclockwise rotation angle of D-shaped holes on sensing performance are studied. The simulation results show that the wavelength sensitivity of the designed sensor can be as high as 10100 nm/RIU and the resolution can reach 9.9 × 10^-6 RIU.